EP0931609A1 - Fluid cooled mould - Google Patents
Fluid cooled mould Download PDFInfo
- Publication number
- EP0931609A1 EP0931609A1 EP99100854A EP99100854A EP0931609A1 EP 0931609 A1 EP0931609 A1 EP 0931609A1 EP 99100854 A EP99100854 A EP 99100854A EP 99100854 A EP99100854 A EP 99100854A EP 0931609 A1 EP0931609 A1 EP 0931609A1
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- EP
- European Patent Office
- Prior art keywords
- mold according
- cooling
- area
- chill mold
- mold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/0408—Moulds for casting thin slabs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/001—Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
- B22D11/004—Copper alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/055—Cooling the moulds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/12—Accessories for subsequent treating or working cast stock in situ
- B22D11/124—Accessories for subsequent treating or working cast stock in situ for cooling
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
Definitions
- the invention relates to a liquid-cooled mold for a continuous caster a mold body made of a material with high thermal conductivity, like copper or a copper alloy.
- Chill molds are designed to extract heat from the molten metal and, initially, through the the formation of a strand shell enables the strand to solidify.
- mold geometries are in use, like mold tubes in round, rectangular or complex form. Mold plates are used for square / rectangular blooms or for slabs with larger Aspect ratio used. There are also special geometries, such as pre-profiles for double-T beams and thin slab molds with funnel extension in the upper one Plate area for receiving the pouring nozzle. It is characteristic of all these molds that homogeneous cooling of the surfaces is sought. Make the corner areas Special cases, since z. B. due to the design of plate molds with butt edges disturbed cooling are present. There are also areas with larger areas Given volumes of material for the rear fasteners that with Specially designed groove-like coolant channels with respect to the same Cooling can be adjusted again.
- the local stress conditions when using funnel mold plates are on the one hand operational. They are essentially determined by on the casting side the type of steel / casting temperature, the speed, the lubrication / cooling conditions of the mold powder, the geometry of the pouring nozzle and the associated flow of the Melt. On the other hand, cooling water quality and cooling water quantity determine on the water side and water speed the mold temperatures. These sizes are partly due to the mold construction - as with the geometry of the Coolant channels - determined.
- the invention is based on the object To create mold body, in which the heat flow in the bathroom mirror area increases is and the risk of cracking in the thermally and mechanically stressed Areas can be avoided.
- the core point of the invention thus forms the measure in the supercritically claimed Areas on both sides of the funnel a significantly stronger cooling of the Adjust mold body.
- the cooling capacity is proposed in these critical areas preferably by 10 to 20% over the increase horizontal neighboring areas.
- Coolant channels can e.g. B. advantageous here be set closer so that the cooled area increases.
- the coolant channels can also be brought closer to the surface locally; in this Case, one works unusually with different - effectively effective - cooling wall thicknesses above the cooling water.
- wide side plates can be formed with groove-like coolant channels in the critical areas of the funnel transition with additional cooling holes Mistake; here too surprisingly increases despite less Wall thickness the crack resistance of the mold material and thus the total service life the mold plate.
- the funnel mold plate 1 shown in FIG. 1 has the highest thermal stress at the horizontal outlet (vertical line C) of the funnel 2 on the casting side. As a direct result, there is a maximum area-related heat flow of 4.7 to 5.2 MW / m 2 at C in the casting direction GR directly below the bath level 3. There are arithmetically determined maximum temperatures of approximately 400 ° C. on the casting side 4 of the mold plate 1.
- the cooling grooves 6 which are introduced more deeply (wall thickness between casting and cooling surface 18 mm instead of 20 mm) Intensively cooled area 5 extends in the present case over the following areas (see FIG. 1): Length horizontally from the turning point B of the funnel 2 over 370 mm to the end point D. The more intensive cooling area extends from the top edge of the plate 7 to 200 mm in the casting direction GR; this is followed by a transition zone 8 of 50 mm, in which the depth d of the cooling grooves 6 is adjusted.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Continuous Casting (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Abstract
Description
Die Erfindung betrifft eine flüssigkeitsgekühlte Kokille für eine Stranggießanlage mit einem formgebenden Kokillenkörper aus einem Material hoher Wärmeleitfähigkeit, wie Kupfer oder einer Kupferlegierung.The invention relates to a liquid-cooled mold for a continuous caster a mold body made of a material with high thermal conductivity, like copper or a copper alloy.
Kokillen sollen dem schmelzflüssigen Metall Wärme entziehen und über die anfangs erfolgende Strangschalenbildung eine Durcherstarrung des Strangs ermöglichen.Chill molds are designed to extract heat from the molten metal and, initially, through the the formation of a strand shell enables the strand to solidify.
Es sind abhängig vom Anwendungszweck verschiedene Kokillengeometrien in Gebrauch, wie Kokillenrohre in runder, rechteckiger oder komplexer Form. Kokillenplatten werden für quadratische/rechteckige Vorblöcke oder für Brammen mit größerem Seitenverhältnis verwendet. Daneben gibt es spezielle Geometrien, wie Vorprofile für Doppel-T-Träger und Dünnbrammenkokillen mit Trichtererweiterung im oberen Plattenbereich zur Aufnahme der Gießdüse. Allen diesen Kokillen ist zu eigen, daß eine homogene Kühlung der Flächen angestrebt wird. Die Eckenbereiche stellen Sonderfälle dar, da z. B. konstruktionsbedingt bei Plattenkokillen Stoßkanten mit gestörter Kühlung vorhanden sind. Darüber hinaus sind zum Teil Bereiche mit größeren Materialvolumina für die rückseitigen Befestigungselemente gegeben, die mit speziell gestalteten nutenartigen Kühlmittelkanälen ansatzweise in Bezug auf gleiche Kühlung wieder angeglichen werden. Depending on the application, different mold geometries are in use, like mold tubes in round, rectangular or complex form. Mold plates are used for square / rectangular blooms or for slabs with larger Aspect ratio used. There are also special geometries, such as pre-profiles for double-T beams and thin slab molds with funnel extension in the upper one Plate area for receiving the pouring nozzle. It is characteristic of all these molds that homogeneous cooling of the surfaces is sought. Make the corner areas Special cases, since z. B. due to the design of plate molds with butt edges disturbed cooling are present. There are also areas with larger areas Given volumes of material for the rear fasteners that with Specially designed groove-like coolant channels with respect to the same Cooling can be adjusted again.
Ferner ist bekannt, thermisch besonders hoch beanspruchte Kokillen besser zu kühlen, um eine frühzeitige Schädigung der Kokille zu vermeiden. Das heißt für Dünnbrammenkokillen zum einen, daß der Wärmewiderstand der Kokillenwand nicht zu groß sein darf, weshalb dann geringere Wanddicken gewählt werden. Zum anderen werden bei den angestrebten höheren Gießgeschwindigkeiten besondere Ansprüche an die Kühlwasserqualität und die Kühlwassergeschwindigkeit gestellt.It is also known that molds that are particularly highly thermally stressed are better cool to avoid premature damage to the mold. That means for Thin slab molds on the one hand, that the thermal resistance of the mold wall is not may be too large, which is why smaller wall thicknesses are selected. On the other hand become special demands at the desired higher casting speeds the cooling water quality and the cooling water speed.
Mit allen genannten Maßnahmen verfolgt man dasselbe Ziel, eine möglichst gute, homogene Kühlung der Gießseite des Kokillenkörpers einzustellen. Mögliche bauartbedingte Störbereiche - wie an rückseitigen Kühlflächen - werden gegebenenfalls beseitigt, um wieder eine gleichmäßige Kühlung zu erhalten.With all of the measures mentioned, the same goal is pursued, the best possible, Set homogeneous cooling of the casting side of the mold body. Possible design-related Interference areas - such as on cooling surfaces on the back - may be eliminated to get an even cooling again.
Die lokalen Beanspruchungsbedingungen beim Einsatz von Trichterkokillenplatten sind zum einen betriebsbedingt. Sie werden gießseitig wesentlich bestimmt durch die Stahlsorte/Gießtemperatur, die Geschwindigkeit, die Schmier-/Kühlbedingungen des Gießpulvers, die Geometrie der Gießdüse und die zugehörige Strömung der Schmelze. Auf der anderen Seite bestimmen wasserseitig Kühlwasserqualität, Kühlwassermenge und Wassergeschwindigkeit die Kokillentemperaturen. Diese Größen sind teilweise bereits durch die Kokillenkonstruktion - wie mit der Geometrie der Kühlmittelkanäle - bestimmt.The local stress conditions when using funnel mold plates are on the one hand operational. They are essentially determined by on the casting side the type of steel / casting temperature, the speed, the lubrication / cooling conditions of the mold powder, the geometry of the pouring nozzle and the associated flow of the Melt. On the other hand, cooling water quality and cooling water quantity determine on the water side and water speed the mold temperatures. These sizes are partly due to the mold construction - as with the geometry of the Coolant channels - determined.
Durch zerstörende Prüfung zahlreicher Kokillenplatten aus dem Einsatz in verschiedenen Stahlwerken ist jedoch die tatsächliche Beanspruchung und auch die daraus resultierende Schädigung des Kokillenwerkstoffs eindeutig festzustellen. Auf Basis dieser Untersuchungen ist eine über der Breite des Meniskus' unterschiedliche Erweichung der Oberfläche bzw. des oberflächennahen Bereichs festzustellen.Through destructive testing of numerous mold plates from use in different Steelworks, however, is the actual stress and also the result the resulting damage to the mold material can be clearly determined. Based of these examinations is a different softening across the width of the meniscus the surface or the area near the surface.
So fällt die Härte von 100 % des Ausgangswerts im kritischen Bereich auf etwa 60 % ab, während auf derselben Höhe neben dem kritischen Bereich nur ein Abfall auf etwa 70 % der Ausgangshärte gemessen wird; der Randbereich der Kokillenplatte ist hierbei nicht betrachtet. Eine ähnliche Aussage zeigen Messungen in der Wanddicke nach Einsatz der Kokillenplatten; gleiche Materialerweichungen erstrecken sich im kritischen Bereich des Badspiegels auf etwa ein Drittel größere Tiefen im Vergleich zu unkritischen Bereichen.So the hardness drops from 100% of the initial value in the critical range to about 60% down, while at the same height next to the critical area only a drop on about 70% of the initial hardness is measured; the edge area of the mold plate is not considered here. A similar statement is shown by measurements in the wall thickness after using the mold plates; extend the same material softening in the critical area of the bath level to about a third greater depths in the Comparison to non-critical areas.
Dünnbrammen-Kokillen werden infolge verschiedener Einflüsse auf den Breitseitenwänden unterschiedlich stark beansprucht. Zu diesen Einflüssen zählen im wesentlichen:
- eine hohe Strömungsgeschwindigkeit der Stahlschmelze; Turbulenzen der Schmelze beanspruchen insbesondere die Übergangsbereiche des Trichters in die planparallelen Seiten des Gießquerschnittes.
- eine höhere mechanische Beanspruchung der im Trichterauslauf gebogenen Wand der Kupferplatte infolge thermischer Ausdehnung. Die resultierenden Spannungen sind hier an der Gießseite besonders hoch.
- a high flow rate of the molten steel; Turbulence of the melt particularly stresses the transition areas of the funnel into the plane-parallel sides of the casting cross-section.
- a higher mechanical stress on the wall of the copper plate bent in the funnel outlet due to thermal expansion. The resulting stresses are particularly high here on the casting side.
Das führt zu besonders ausgeprägter Erweichung des Kokillenwerkstoffes in diesem Übergangsbereich des Trichters. Aufgrund der lokal relativ höheren Temperaturen und der auf die jeweilige Warmfestigkeit eines Werkstoff-Volumenelements bezogenen höheren Werkstoffbelastung erfolgt in diesem Oberflächenbereich frühzeitig Rißbildung. Diese Rißbildung kann dann aufgrund eines hier temperaturbedingt ausgeprägter ablaufenden Diffusionsvorgangs von Zn-Atomen aus dem Stahl in die Cu-Matrix eher stattfinden, weil die sich bildenden CuZn-Phasen eine harte und spröde Oberflächenschicht bilden, die eine höhere Rißfortschrittsgeschwindigkeit ermöglicht. This leads to a particularly pronounced softening of the mold material in it Transition area of the funnel. Because of the locally relatively higher temperatures and related to the respective heat resistance of a solid material element higher material load occurs early in this surface area Cracking. This crack formation can then be caused by temperature here pronounced diffusion process of Zn atoms from the steel into the Cu matrix tend to take place because the CuZn phases that form are hard and form brittle surface layer, which has a higher crack propagation speed enables.
Ausgehend vom Stand der Technik liegt der Erfindung die Aufgabe zugrunde, einen Kokillenkörper zu schaffen, bei dem der Wärmestrom im Badspiegelbereich erhöht ist und die Gefahr von Rißbildungen in den thermisch und mechanisch höher beanspruchten Bereichen vermieden werden kann.Starting from the prior art, the invention is based on the object To create mold body, in which the heat flow in the bathroom mirror area increases is and the risk of cracking in the thermally and mechanically stressed Areas can be avoided.
Die Lösung dieser Aufgabe besteht nach der Erfindung in den im kennzeichnenden
Teil des Anspruchs 1 aufgeführten Merkmalen. Vorteilhafte Weiterbildungen der
Erfindung sind in den Unteransprüchen angegeben.This object is achieved according to the invention in the characterizing
Features listed in
Kernpunkt der Erfindung bildet somit die Maßnahme, in den überkritisch beanspruchten Bereichen beidseitig des Trichters eine deutlich stärkere Kühlung des Kokillenkörpers einzustellen. Erfindungsgemäß wird vorgeschlagen, die Kühlleistung in diesen kritischen Bereichen vorzugsweise um 10 bis 20 % gegenüber den horizontalen Nachbarbereichen zu erhöhen. Kühlmittelkanäle können z. B. hier vorteilhaft enger gesetzt werden, so daß sich die gekühlte Fläche vergrößert. Alternativ lassen sich die Kühlmittelkanäle lokal auch näher an die Oberfläche bringen; in diesem Fall arbeitet man ungewöhnlicherweise mit unterschiedlichen - effektiv wirksamen - Kühlwanddicken über dem Kühlwasser. Ähnliches gilt für Kühlbohrungen. Außerdem lassen sich mit nutenartigen Kühlmittelkanälen ausgebildete Breitseitenplatten in den kritischen Bereichen des Trichterübergangs zusätzlich mit Kühlbohrungen versehen; auch hier erhöht sich überraschenderweise trotz geringer Wanddicke der Rißwiderstand des Kokillenwerkstoffs und damit die Gesamtlebensdauer der Kokillenplatte.The core point of the invention thus forms the measure in the supercritically claimed Areas on both sides of the funnel a significantly stronger cooling of the Adjust mold body. According to the invention, the cooling capacity is proposed in these critical areas preferably by 10 to 20% over the increase horizontal neighboring areas. Coolant channels can e.g. B. advantageous here be set closer so that the cooled area increases. Alternatively the coolant channels can also be brought closer to the surface locally; in this Case, one works unusually with different - effectively effective - cooling wall thicknesses above the cooling water. The same applies to cooling holes. In addition, wide side plates can be formed with groove-like coolant channels in the critical areas of the funnel transition with additional cooling holes Mistake; here too surprisingly increases despite less Wall thickness the crack resistance of the mold material and thus the total service life the mold plate.
Darüber hinaus erreicht man mit rückseitig verschiedenen Kühlintensitäten einen deutlich besser ausgeglichenen Temperaturverlauf an der Gießseite der Plattenoberfläche. Dieser Effekt ermöglicht ein kleineres Temperaturintervall für einen sinnvollen, engeren Arbeitstemperaturbereich des Gießpulvers. Damit kann die Abstimmung des Gießpulvers auf einen kälteren oder heißeren Temperaturbereich vermieden werden. In addition, one achieves one with different cooling intensities on the back significantly better balanced temperature curve on the casting side of the plate surface. This effect allows a smaller temperature interval for one reasonable, narrower working temperature range of the mold powder. So that the vote the mold powder to a colder or hotter temperature range be avoided.
Die Erfindung ist nachfolgend anhand von in den Zeichnungen dargestellten Ausführungsbeispielen noch näher erläutert.The invention is based on the embodiments shown in the drawings explained in more detail.
Die in Figur 1 dargestellte Trichterkokillenplatte 1 weist am horizontalen Auslauf
(vertikale Linie C) des Trichters 2 gießseitig die höchste thermische Beanspruchung
auf. Als direkte Folge ergibt sich ein bei C in Gießrichtung GR direkt unterhalb des
Badspiegels 3 liegender maximaler flächenbezogener Wärmestrom von 4,7 bis 5,2
MW/m2. Es liegen rechnerisch ermittelte maximale Temperaturen von etwa 400 ° C
an der Gießseite 4 der Kokillenplatte 1 vor. Die effektiv wirksame Wanddicke d der
Kokillenplatte 1 aus Kupfer wird nun im kritischen Bereich 5 zwischen den Linien B,
C, D auf den oberen 200 mm der Kokillenplatte von d1 = 20 mm auf d2 = 18 mm verringert
(Fig. 2).The
Damit wird eine um 28 ° C verringerte maximale Oberflächentemperatur eingestellt;
diese bevorzugte Kühlung bleibt bei entsprechender Nacharbeit der Kokillenplatte 1
erhalten. Obwohl die Wanddicke d2 im kritisch beanspruchten Bereich 5 um 2 mm
geringer ist, kommt es einschließlich Nacharbeiten überraschenderweise dennoch
zu einer insgesamt höheren Lebensdauer der Kokillenplatten 1. Der mit tiefer eingebrachten
Kühlnuten 6 (Wanddicke zwischen Gieß- und Kühlfläche 18 mm statt 20
mm) intensiver gekühlte Bereich 5 erstreckt sich im vorliegenden Fall über folgende
Flächen (siehe Fig. 1): Länge horizontal ab dem Wendepunkt B des Trichters 2 über
370 mm bis zum Endpunkt D. Die intensivere Kühlfläche erstreckt sich von der
Plattenoberkante 7 bis 200 mm in Gießrichtung GR; es schließt sich eine Übergangszone
8 von 50 mm an, in der die Tiefe d der Kühlnuten 6 angeglichen wird.This sets a maximum surface temperature reduced by 28 ° C; this preferred cooling is retained when the
Claims (12)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK99100854T DK0931609T3 (en) | 1998-01-27 | 1999-01-19 | The liquid-cooled coconut |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19802809A DE19802809A1 (en) | 1998-01-27 | 1998-01-27 | Liquid-cooled mold |
DE19802809 | 1998-01-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0931609A1 true EP0931609A1 (en) | 1999-07-28 |
EP0931609B1 EP0931609B1 (en) | 2004-11-24 |
Family
ID=7855667
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99100854A Expired - Lifetime EP0931609B1 (en) | 1998-01-27 | 1999-01-19 | Fluid cooled mould |
Country Status (19)
Country | Link |
---|---|
US (1) | US6926067B1 (en) |
EP (1) | EP0931609B1 (en) |
JP (1) | JPH11267794A (en) |
KR (1) | KR100566741B1 (en) |
CN (1) | CN1227778A (en) |
AR (1) | AR014307A1 (en) |
AT (1) | ATE283132T1 (en) |
AU (1) | AU756323B2 (en) |
BR (1) | BR9900188A (en) |
CA (1) | CA2258451C (en) |
CZ (1) | CZ300075B6 (en) |
DE (2) | DE19802809A1 (en) |
DK (1) | DK0931609T3 (en) |
ES (1) | ES2230749T3 (en) |
PL (1) | PL194641B1 (en) |
PT (1) | PT931609E (en) |
RU (1) | RU2240892C2 (en) |
TW (1) | TW448081B (en) |
ZA (1) | ZA99141B (en) |
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EP1445045A1 (en) * | 2003-02-04 | 2004-08-11 | SMS Demag Aktiengesellschaft | Process and apparatus for continuous casting of liquid metals in particular steels |
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KR100490985B1 (en) * | 2000-11-25 | 2005-05-24 | 주식회사 포스코 | Funnel Type Copper Plate For Continuous Casting Mold |
DE10226214A1 (en) * | 2002-06-13 | 2003-12-24 | Sms Demag Ag | Continuous casting mold for liquid metals, especially for liquid steel |
DE10337205A1 (en) * | 2003-08-13 | 2005-03-10 | Km Europa Metal Ag | Liquid-cooled mold |
DE102004021899A1 (en) * | 2004-05-04 | 2005-12-01 | Sms Demag Ag | Chilled continuous casting mold |
EP1785206A1 (en) * | 2005-11-10 | 2007-05-16 | Siemens Aktiengesellschaft | Method and apparatus for cooling a continuous casting mould by steam |
DE102006036708A1 (en) | 2006-08-05 | 2008-02-07 | Sms Demag Ag | Continuous casting mold for liquid metals, in particular for liquid steel materials |
DE102007002806A1 (en) * | 2007-01-18 | 2008-07-24 | Sms Demag Ag | Mold with coating |
CZ2016267A3 (en) * | 2016-05-10 | 2017-06-28 | MATERIÁLOVÝ A METALURGICKÝ VÝZKUM s.r.o. | An ingot mould assembly with water cooling |
US10350674B2 (en) | 2017-06-12 | 2019-07-16 | Wagstaff, Inc. | Dynamic mold shape control for direct chill casting |
US11883876B2 (en) | 2017-06-12 | 2024-01-30 | Wagstaff, Inc. | Dynamic mold shape control for direct chill casting |
DE102018123948B3 (en) * | 2018-09-27 | 2019-09-12 | Kme Germany Gmbh & Co. Kg | mold plate |
CN109822065B (en) * | 2019-04-11 | 2024-03-22 | 安徽工业大学 | Wide-surface copper plate of continuous casting crystallizer and continuous casting crystallizer with same |
DE102021215030A1 (en) * | 2021-12-23 | 2023-06-29 | Sms Group Gmbh | Wide side mold plate, continuous casting mold and method for producing a wide side mold plate |
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-
1999
- 1999-01-08 ZA ZA9900141A patent/ZA99141B/en unknown
- 1999-01-13 CA CA002258451A patent/CA2258451C/en not_active Expired - Fee Related
- 1999-01-13 AR ARP990100118A patent/AR014307A1/en active IP Right Grant
- 1999-01-19 ES ES99100854T patent/ES2230749T3/en not_active Expired - Lifetime
- 1999-01-19 EP EP99100854A patent/EP0931609B1/en not_active Expired - Lifetime
- 1999-01-19 DK DK99100854T patent/DK0931609T3/en active
- 1999-01-19 DE DE59911117T patent/DE59911117D1/en not_active Expired - Lifetime
- 1999-01-19 AT AT99100854T patent/ATE283132T1/en active
- 1999-01-19 PT PT99100854T patent/PT931609E/en unknown
- 1999-01-20 KR KR1019990001570A patent/KR100566741B1/en not_active IP Right Cessation
- 1999-01-25 AU AU13220/99A patent/AU756323B2/en not_active Ceased
- 1999-01-25 PL PL331035A patent/PL194641B1/en unknown
- 1999-01-26 RU RU99102238/02A patent/RU2240892C2/en not_active IP Right Cessation
- 1999-01-26 CN CN99101377A patent/CN1227778A/en active Pending
- 1999-01-26 CZ CZ0026399A patent/CZ300075B6/en not_active IP Right Cessation
- 1999-01-26 JP JP11017442A patent/JPH11267794A/en active Pending
- 1999-01-27 BR BR9900188-8A patent/BR9900188A/en not_active Application Discontinuation
- 1999-01-27 TW TW088101120A patent/TW448081B/en not_active IP Right Cessation
- 1999-08-11 US US09/372,636 patent/US6926067B1/en not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
PL194641B1 (en) | 2007-06-29 |
US6926067B1 (en) | 2005-08-09 |
DE59911117D1 (en) | 2004-12-30 |
CZ26399A3 (en) | 2000-05-17 |
KR19990068007A (en) | 1999-08-25 |
ES2230749T3 (en) | 2005-05-01 |
RU2240892C2 (en) | 2004-11-27 |
DE19802809A1 (en) | 1999-07-29 |
CZ300075B6 (en) | 2009-01-21 |
CA2258451C (en) | 2005-03-29 |
PL331035A1 (en) | 1999-08-02 |
JPH11267794A (en) | 1999-10-05 |
KR100566741B1 (en) | 2006-04-03 |
CN1227778A (en) | 1999-09-08 |
AU756323B2 (en) | 2003-01-09 |
CA2258451A1 (en) | 1999-07-27 |
TW448081B (en) | 2001-08-01 |
EP0931609B1 (en) | 2004-11-24 |
AU1322099A (en) | 1999-08-19 |
DK0931609T3 (en) | 2005-03-29 |
AR014307A1 (en) | 2001-02-07 |
PT931609E (en) | 2005-01-31 |
ATE283132T1 (en) | 2004-12-15 |
ZA99141B (en) | 1999-07-09 |
BR9900188A (en) | 2000-01-04 |
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