EP0905099A2 - Form und Formungsverfahren - Google Patents
Form und Formungsverfahren Download PDFInfo
- Publication number
- EP0905099A2 EP0905099A2 EP98307892A EP98307892A EP0905099A2 EP 0905099 A2 EP0905099 A2 EP 0905099A2 EP 98307892 A EP98307892 A EP 98307892A EP 98307892 A EP98307892 A EP 98307892A EP 0905099 A2 EP0905099 A2 EP 0905099A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- shaping
- mold
- mold member
- sleeve member
- fixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 238000007493 shaping process Methods 0.000 title claims abstract description 325
- 239000013307 optical fiber Substances 0.000 claims abstract description 122
- 239000000463 material Substances 0.000 claims description 57
- 239000011521 glass Substances 0.000 claims description 39
- 230000003287 optical effect Effects 0.000 claims description 22
- 239000000758 substrate Substances 0.000 claims description 9
- 238000004806 packaging method and process Methods 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 4
- 239000002241 glass-ceramic Substances 0.000 claims description 4
- 239000011256 inorganic filler Substances 0.000 claims description 4
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 238000000465 moulding Methods 0.000 description 29
- 238000000034 method Methods 0.000 description 23
- 230000008961 swelling Effects 0.000 description 19
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000003247 decreasing effect Effects 0.000 description 7
- 238000003491 array Methods 0.000 description 6
- 239000011261 inert gas Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000007733 ion plating Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
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- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
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- 238000004544 sputter deposition Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
- C03B11/06—Construction of plunger or mould
- C03B11/08—Construction of plunger or mould for making solid articles, e.g. lenses
- C03B11/082—Construction of plunger or mould for making solid articles, e.g. lenses having profiled, patterned or microstructured surfaces
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
- C03B11/06—Construction of plunger or mould
- C03B11/08—Construction of plunger or mould for making solid articles, e.g. lenses
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2215/00—Press-moulding glass
- C03B2215/40—Product characteristics
- C03B2215/41—Profiled surfaces
- C03B2215/412—Profiled surfaces fine structured, e.g. fresnel lenses, prismatic reflectors, other sharp-edged surface profiles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2215/00—Press-moulding glass
- C03B2215/40—Product characteristics
- C03B2215/41—Profiled surfaces
- C03B2215/413—Profiled surfaces optical fibre alignment, fixing or connecting members having V-grooves
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2215/00—Press-moulding glass
- C03B2215/50—Structural details of the press-mould assembly
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2215/00—Press-moulding glass
- C03B2215/78—Pressing together along two or more perpendicular axes
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/36—Mechanical coupling means
- G02B6/38—Mechanical coupling means having fibre to fibre mating means
- G02B6/3807—Dismountable connectors, i.e. comprising plugs
- G02B6/3833—Details of mounting fibres in ferrules; Assembly methods; Manufacture
- G02B6/3865—Details of mounting fibres in ferrules; Assembly methods; Manufacture fabricated by using moulding techniques
Definitions
- the present invention relates to a shaping mold and a shaping process, particularly to a shaping mold comprising an upper mold member, a lower mold member and a sleeve member and a shaping process using said shaping mold.
- a mold shaping of hot-molding a shapeable material by means of a shaping mold (also called “hot press molding") having a cavity having a predetermined form permits the production of shaped articles having a predetermined form with a high productivity after the shaping mold for the above mold shaping is once prepared, and shaped articles having a variety of forms are therefore produced by mold shaping. Further, since the mold shaping can be used for mass-producing shaped articles having high accuracy, attempts are being made to produce articles required to have high accuracy such as optical fiber fixing members including an optical fiber guide block.
- the above optical fiber guide block is a thin-sheet-like member having fixing groove or grooves (e.g., V groove(s)) for fixing 1 to several optical fibers in predetermined position(s), for example, like a V-groove substrate shown in Fig. 2 of JP-A-7-5341.
- the work accuracy which the above fixing groove or grooves is or are required to satisfy differs depending upon kinds of optical fiber(s), while the fixing groove or grooves is or are made so as to have a positional accuracy of ⁇ 0.5 to ⁇ 1.0 ⁇ m with regard to the center of each optical fiber (center in diameter direction) when the optical fiber or fibers to be fixed is or are single-mode optical fiber(s).
- optical fiber guide blocks have a lower-level part having its upper surface formed lower than the level of the surface where the above fixing groove(s) is/are formed.
- the above lower-level part is suitable for fixing the whole of optical fiber(s) and coating(s) thereof when the optical fiber or fibers is or are protected with coating(s) like an optical fiber tape.
- Optical fibers have low strength and are difficult to handle.
- it is arranged to fix an optical fiber end portion exposed, for example, from an optical fiber tape to the above fixing groove in a state where the whole of an optical fiber tape with a coating is fixed to, or placed on, the above lower-level part, it is easier to handle the optical fiber.
- the material for the above optical fiber guide block is selected from glass, glass-ceramic, ceramic, silicon, a resin or a composite material formed from a resin and an inorganic filler.
- glass glass-ceramic, ceramic, silicon, a resin or a composite material formed from a resin and an inorganic filler.
- it is general practice to fix optical fibers to an optical fiber fixing member with a ultraviolet-curable adhesive, so that glass having good transmittance to ultraviolet light is used in many cases.
- An optical fiber guide block formed of glass is conventionally produced by making fixing grooves in a glass plate with a diamond grinder and cutting the glass plate in a predetermined form. Since, however, it is required to work the glass to form the fixing grooves having high accuracy, its production cost increases. Further, when the above lower-level part is formed, the amount of work increases, which results in a further increase in the production cost.
- an optical fiber guide block is a thin-sheet-like block as described above and is small in size
- a shaping mold comprising three mold members such as an upper mold member, a lower mold member and a sleeve member is generally used for the following reason when mold shaping is employed for producing the optical fiber guide block.
- one of two shaping surfaces such as a transfer shaping surface for shaping the upper surface (surface on a side where fixing groove(s) is/are formed) of an optical fiber guide block and a transfer shaping surface for shaping the bottom surface thereof and transfer shaping surfaces for shaping side surfaces of the optical fiber guide block are required to be formed in the female mold member. Since, however, an optical fiber guide block is a small and high-precision member formed of a thin-sheet-like block, it is difficult to produce the above female mold member.
- a shaping mold constituted of three members of an upper mold member, a lower mold member and a sleeve member is generally used for producing an optical fiber guide block by mold shaping, and a cylindrical part formed of one member is used as the above sleeve member.
- a mold shaping method is suitable for mass-producing shaped articles having high accuracy.
- a fixing groove which is an essential part of an optical fiber guide block and its vicinities
- defects e.g., an undulation, projection, swelling (bump) and molding burr
- a shapeable material does not uniformly deform when mold-shaped.
- a plate-like glass shapeable preform when mold shaped, central portions of its sides are outwardly deformed to a greater degree, and corner portions are deformed to a smaller degree.
- mold members upper mold member, lower mold member and sleeve member constituting a conventional shaping mold have some clearances between them for a structural reason.
- shapeable material is liable to enter the above clearances to form molding burrs.
- the occurrence of a swelling (bump) which is only about 1 ⁇ m high causes a problem, to say nothing of a molding burr, as far as the above optical interconnection end face vicinity of an optical fiber guide block is concerned.
- an optical fiber guide block is a small and high-precision member formed of a thin-sheet-like block as described above.
- a single cylindrical member is employed as a sleeve member of a shaping mold used for mold shaping the above optical fiber guide block, therefore, working on a cylindrical material to produce a hollow portion of the cylindrical member is greatly limited.
- edge portions formed by the inner surfaces of the sleeve member (cylindrical member) are inevitably formed as curved surfaces.
- edge portions formed by side surfaces of an upper mold member and edge portions formed by side surfaces of a lower mold member are also required to be formed as curved surfaces.
- the above curvature in the sleeve member is greater than the curvature in the upper or lower mold member, the upper or lower mold member cannot be inserted into the sleeve member.
- the above curvature in the sleeve member is too small as compared with the curvature in the upper or lower mold member, an extreme clearance is formed.
- the above object of the present invention is achieved by a shaping mold having an upper mold member, a lower mold member and a sleeve member, the upper or lower mold member being used as a movable mold member which is movable relative to the sleeve member when mold shaping is carried out, the sleeve member being for shaping side surfaces of a shaped article with transfer shaping surfaces of the sleeve member, the sleeve member being constituted of a plurality of sleeve member parts having transfer shaping surfaces, a plurality of the sleeve member parts being forcibly fixed to side surfaces of the upper mold member or side surfaces of the lower mold member in a state where the sleeve member parts are tightly attached to the side surfaces of the upper mold member or the side surfaces of the lower mold member (the above shaping mold will be referred to as "shaping mold I" hereinafter).
- the above object of the present invention is also achieved by a shaping mold having an upper mold member, a lower mold member and a sleeve member, one of the upper mold member and the lower mold member having a transfer shaping surface in which a fine transfer pattern is formed and being a fixed mold member tightly fixed to the sleeve member so as not to have a clearance with the sleeve member to prevent shapeable material from entering the clearance, the other of the upper mold member and the lower mold member being a movable mold member which is movable relative to the sleeve member, a positional accuracy of the fine transfer pattern which positional accuracy is defined on the basis of one side surface of the fixed mold member and a positional accuracy of the fine transfer pattern which positional accuracy is defined on the basis of an inner side surface of the sleeve member tightly attached to the above one side surface of the fixed mold member when the fixed mold member is tightly attached and fixed to the sleeve member, being substantially the same (the above shaping mold will be referred to
- the above object of the present invention is achieved by a shaping process of shaping a preform into a shaped article having a predetermined form with the above shaping mold I (the above method will be referred to as “method I" hereinafter).
- the above object is also achieved by a shaping process of producing a shaped article, which comprises placing a preform in a cavity of the above shaping mold II of the present invention, mold shaping the preform with the shaping mold II, and thereby obtaining a shaped article to which (i) a fine transfer pattern formed in a transfer shaping surface of the fixed mold member and (ii) at least part of a transfer pattern formed in that inner side surface of the sleeve member of which a positional accuracy of the fine transfer pattern which positional accuracy is defined on the basis is substantially the same as a positional accuracy of the fine transfer pattern which positional accuracy is defined on the basis of that side surface of the fixed mold member which is tightly attached and fixed to the above inner side surface of the sleeve member were transferred (the above method will be referred to as "method II" hereinafter).
- the shaping mold of the present invention When the shaping mold of the present invention is used, there can be easily obtained, by mold shaping, a shaped article which is required to have high accuracy which does not allow any fine swelling (bump), to say nothing of a molding burr.
- the present invention therefore, enables the mass-production of shaped articles required to have high accuracy.
- the shaping mold I of the present invention has an upper mold member, a lower mold member and a sleeve member as described above, and when it is used, the above upper or lower mold member is used as a movable mold member relative to the sleeve member and the sleeve member is for shaping side surfaces of a shaped article with the transfer shaping surfaces of the sleeve member.
- the above movable mold member may be a member which moves itself or which does not move itself but is seen moved relative to the sleeve member since the sleeve member moves.
- One of the upper and lower mold members is used as a member which does not move relative to the sleeve member (this mold member will be referred to as "fixed mold member” hereinafter).
- this mold member will be referred to as "fixed mold member” hereinafter.
- a shaping mold constituted of three mold members of an upper mold member, a lower mold member and a sleeve member
- one of the upper and lower mold members as a movable mold member movable relative to the sleeve member and the other as a fixed mold member not movable relative to the sleeve member
- the above sleeve member is constituted of a plurality of sleeve member parts each of which has transfer shaping surface(s) and that a plurality of the sleeve member parts are fixed to side surfaces of the above upper or lower mold member under force in a state where they are tightly attached thereto when they are used, that is, the sleeve member parts are fixed to side surfaces of the fixed mold member in a state where they are tightly attached thereto.
- the reason for constituting the sleeve member with a plurality of the above sleeve member parts for the shaping mold I is as follows.
- a plurality of the sleeve member parts can be fixed to side surfaces of the fixed mold member under force in a state where they are tightly attached to the side surfaces when they are used, whereby a clearance between each side surface of the fixed mold member and each side surface of the sleeve member can be nearly removed.
- the above clearance is nearly removed, there can be prevented a phenomenon that a shapeable material enters the clearance to form a molding burr and a fine swelling (bump).
- the means of fixing the sleeve member parts to the side surfaces of the fixed mold member under force in a tightly attached state may be basically any means so long as the above clearance can be nearly removed.
- means which utilize a thermal expansion coefficient difference between the sleeve member and the fixed mold member for fixing under force involve some risks of the mold chipping or the accuracy of the transfer shaping surfaces decreasing since an excess pressure is liable to be exerted on the fixed mold member.
- screws are used to fixe the sleeve member parts to side surfaces of the fixed mold member under force in a tightly attached state.
- screws it is preferred to employ a constitution in which an outer frame specialized for fixing the sleeve member parts to side surfaces of the fixed mold member is prepared and the sleeve member parts are fixed to the above side surfaces in a tightly attached state with a force exerted by the screws threaded through the outer frame on the sleeve member parts rather than directly fixing the sleeve member parts to the above side surfaces with the screws.
- the sleeve member parts are fixed to the side surfaces of the fixed mold member under force in a tightly attached state by threading the screws such that the screws reach the sleeve member parts through the outer frame.
- the above method of using the specialized outer frame substantially removes some risks of the strength of the fixed mold member decreasing and a decrease in the accuracy of the transfer shaping surface being caused.
- a molding burr and a fine swelling (bump) caused by the entering of a shapeable material into a clearance between each side surface of the fixed mold member and the sleeve member can be prevented by keeping the sleeve member parts fixed to the side surfaces of the fixed mold member under force in a tightly attached state as described above when the sleeve member parts are used.
- a clearance between the sleeve member parts may cause a molding burr or a fine swelling (bump) on a shaped article since a shapeable material may enter the clearance.
- corner portions of a shapeable material are not much deformed when the shapeable material is shaped in the shaping mold as described above, the risk of a molding burr and a fine swelling (bump) being formed by the entering of shapeable material into the above clearance can be decreased by arranging the sleeve member parts so as to have the clearance between the sleeve member parts in corner portions when the cavity is viewed as a plan view.
- the form of the transfer shaping surface of a movable mold member and the form of the transfer shaping surface of a fixed mold member constituting a shaping mold when the transfer shaping surfaces are viewed as plan views are properly selected depending upon the form of a shaped article to be obtained.
- the form of the transfer shaping surface of the movable mold member and the form of the transfer shaping surface of the fixed mold member of the shaping mold I of the present invention when these shaping surfaces are viewed as plan views can be also selected depending upon a shaped article to be obtained by means of the shaping mold I.
- the side surfaces of the fixed mold member are formed as flat surfaces
- the inner side surfaces of the sleeve member parts at a time of use are also formed as flat surfaces
- the sleeve member parts to be placed side by side at a time of use are brought into surface-surface contact.
- side surfaces of the movable mold member are formed as flat surfaces.
- the movable mold member (upper or lower mold member) and the fixed mold member (lower or upper mold member) are preferably produced so as to have polygonal forms when viewed as plan views.
- the shaping mold I of the present invention is preferably a shaping mold for producing, by mold shaping, a shaped article having a solid shape which shows a polygonal form when viewed as a plan view and having flat side surfaces.
- the forms of the sleeve member parts are selected so as not to form one side surface of a shaped article with two or more transfer shaping surfaces, in other words, so as to form one side surface of a shaped article with a single transfer shaping surface.
- the forms of the sleeve member parts may be selected so as to shape a plurality of side surfaces of a shaped article with a single sleeve member part 20a or 20b as shown in Fig. 4(a).
- the forms of the sleeve member parts may be selected so as to shape one side surface of a shaped article with a single sleeve member part, any one of 21a to 21d, 22a to 22d and 23a to 23d, as shown in Figs. 4(b) to 4(d).
- the arrangement of the sleeve member parts shown in Fig. 4(a) to 4(d the arrangement of the sleeve member parts shown in Fig.
- 4(c) is the most preferred from the viewpoint of removing a clearance between sleeve member parts positioned side by side. From the viewpoint of the cost of production of the sleeve member parts, the fewer the sleeve member parts in number, the more preferred.
- reference numeral 24 indicates a fixed mold member (lower or upper mold member), and reference numeral 25 indicates the above outer frame.
- reference numeral 25a indicates a threaded runner (internal threads) made in the outer frame 25 from its circumference toward a center, and a screw (not shown) is tightened into the threaded runner 25a so as to reach a sleeve member part through the outer frame 25, and in this manner, the sleeve member parts can be fixed to side surfaces of the fixed mold member under force in a tightly attached state.
- the transfer shaping surfaces can be easily improved in surface accuracy. Further, even when the forms of the sleeve member parts are selected so as to shape a plurality of side surfaces of a shaped article with a single sleeve member part, each edge portion(s) formed by the transfer shaping surfaces of one sleeve member part can be easily formed as one line.
- each edge portions in inner side surfaces of the sleeve member constituted of predetermined number of the sleeve member parts can be easily formed as one line.
- each of edge portions of side surfaces of the upper mold member and edge portions of side surfaces of the lower mold member can be also formed as one line, so that there can be easily advantageously prevented a phenomenon that the upper or lower mold member cannot be inserted into the sleeve member or that an extreme clearance is formed between a corner portion of the sleeve member and a corner portion of the upper or lower mold member.
- the shaping mold is a type which requires the sliding or movement of the movable mold member within the sleeve member, it is required to provide a clearance, which is at least necessary for the sliding or movement of the movable mold member, between the movable mold member and the sleeve member.
- the shaping mold conditions are determined as described later, there can be prevented a phenomenon that shapeable material enters a clearance between the movable mold member and the sleeve member to cause the formation of a molding burr and a fine swelling (bump).
- the shaping mold I of the present invention has the following advantages.
- the sleeve member parts are fixed to the side surfaces of the fixed mold member under force in a state where the sleeve member parts are tightly attached to the fixed mold member. Therefore, almost no eccentricity takes place at least between the fixed mold member and the sleeve member. There can be therefore easily obtained a shaped article in which a specific surface relative to the surface shaped with the transfer shaping surface of the sleeve member (side surface of the shaped article), i.e., the surface shaped with the transfer shaping surface of the fixed mold member (upper or lower surface of the shaped article) has high positional accuracy.
- the shaping mold I having various advantages as explained above, provided by the present invention, can be used as a shaping mold for obtaining shaped articles having various forms, while it is particularly suitable as a shaping mold for obtaining, by mold shaping, articles required to have high accuracy such as a precision-positioning member including an optical fiber fixing member (e.g. an optical fiber guide block) and an optical parts packaging substrate, a prism, a polygon mirror, or the like.
- a precision-positioning member including an optical fiber fixing member (e.g. an optical fiber guide block) and an optical parts packaging substrate, a prism, a polygon mirror, or the like.
- the shaping mold I can be used for obtaining mold shaped articles having various forms as described above, and the forms of the transfer shaping surface of the movable mold member (upper or lower mold member) and the transfer shaping surface of the fixed mold member (lower or upper mold member) of the above shaping mold I are properly determined as required depending upon a shaped article to be obtained as an end product.
- the shaping mold I when the shaping mold I is for use as a shaping mold for obtaining an optical fiber guide block, convex portions in a desired number for forming fixing grooves for fixing end portions of optical fibers in the optical fiber guide block are formed in the transfer shaping surface of one of the movable mold member and the fixed mold member.
- optical fiber guide block(s) A optical fiber guide block(s) A
- optical fiber guide block A When the above optical fiber guide block A is used for producing an optical fiber array in which optical fibers in a predetermined number are fixed, the following advantages can be obtained.
- the advantage is that when a plurality of the above optical fiber arrays are produced and used for optically interconnecting optical fibers of the optical fiber arrays, e.g., to incidence ports of optical waveguides by an active alignment method, the optical fibers of the optical fiber array and the incidence ports of optical waveguides can be optically connected by only scanning in a perpendicular direction in operations of optical interconnection after the first operation, since the positions of the optical fibers relative to the incidence ports of the optical waveguides in a horizontal direction in operations after the first are substantially the same as the position of the optical fibers relative to the incidence ports of the optical waveguide in a horizontal direction at the first operation when the optical fiber guide blocks of the optical fiber arrays are produced by means of the same shaping mold I.
- the shaping mold I when the shaping mold I is worked on highly accurately, i.e., processed highly accurately so as to obtain optical fiber guide blocks in which the variability of positions of fixing grooves from a side surface is the smallest possible, the above effect can be achieved regardless of which shaping mold I is used for producing the optical fiber guide blocks constituting optical fiber arrays.
- the eccentricity of the fixed mold member relative to the sleeve member can be decreased to approximately ⁇ 1 ⁇ m or smaller.
- optical fiber guide blocks is an optical fiber guide block of a type having an optical fiber fixing part having an upper surface on which the above fixing grooves are formed in a desired number and a lower-level part having an upper surface formed lower than the upper surface level of the optical fiber fixing part (the optical fiber guide block of the above type will be referred to as "optical fiber guide block B" hereinafter).
- optical fiber guide block B the optical fiber guide block of the above type will be referred to as "optical fiber guide block B" hereinafter.
- the optical fiber guide block B when the optical fiber guide block B is produced, for improving the accuracy of the fixing grooves to be formed, it is preferred to fabricate a shaping part having a transfer shaping surface for shaping the upper surface of the optical fiber fixing part (the above transfer shaping surface has convex portions in a predetermined number for forming the fixing grooves) and a shaping part having a transfer shaping surface for shaping the upper surface of the lower-level portion from separate materials and mechanically integrate these shaping parts with a fixing frame, etc., to produce one mold (movable mold member or fixed mold member).
- the two shaping parts are merely integrated with a fixing frame, a clearance is liable to be formed between these shaping parts, and shapeable material is liable to enter the clearance to cause a molding burr.
- the sleeve member is fixed to the fixed mold member under force in a tightly attached state. If the fixed mold member is formed of the above two shaping parts, therefore, the above two shaping parts can be fixed to each other under force when the sleeve member is fixed to the fixed mold member under force in a tightly attached state. As a result, there can be obtained an advantage that the formation of a clearance between the above two shaping parts is prevented so that the formation of a molding burr is also prevented.
- the releasability of the shaped article differs depending upon a shapeable material and a material of the shaping mold, and a release film is provided on a predetermined surface of the shaping mold as required.
- the shaping mold I and the shaping mold II to be explained below, provided by the present invention, include embodiments provided with the above release film.
- the shaping mold II of the present invention will be explained hereinafter.
- the shaping mold II of the present invention has an upper mold member, a lower mold member and a sleeve member as described above.
- One of the upper and lower mold members is a fixed mold member having a transfer shaping surface in which a fine transfer pattern is formed, and it is tightly attached and fixed to the sleeve member so as not to form any clearance with the sleeve member which clearance shapeable material may enter.
- the other of the upper and lower mold members is a movable mold member movable relative to the sleeve member.
- One specific example of the shaping mold having the above structure is one embodiment of the shaping mold I of the present invention, i.e., a shaping mold which is included in the shaping mold I for producing an optical fiber guide block and in which convex portions in a desired number for forming fixing grooves for fixing end portions of optical fibers in an optical fiber guide block are formed in the transfer shaping surface of the fixed mold member.
- the most distinguishing feature of the shaping mold II is that the positional accuracy of the fine transfer pattern which positional accuracy is defined on the basis of one side surface of the fixed mold member and the positional accuracy of the fine transfer pattern which positional accuracy is defined on the basis of an inner side surface of the sleeve member tightly attached to the above one side surface of the fixed mold member when the fixed mold member is tightly attached and fixed to the sleeve member, are substantially the same.
- the shaping mold II having the above feature has advantages similar to those of the shaping mold I, and in addition to those advantages, it particularly has an advantage that there can be easily obtained a shaped article having the above fine pattern formed under a predetermined positional accuracy relative to a specific side surface.
- the shaping mold II when used for producing an optical fiber guide block, there can be easily obtained an optical fiber guide block in which fixing grooves are formed under a predetermined positional accuracy relative to a specific side surface.
- optical fiber guide block When the above optical fiber guide block is used for fabricating an optical fiber array, the optical interconnection of optical fibers constituting the optical fiber array to other optical fibers or optical parts by an active alignment method is eased for reasons in "optical fiber guide block A" described in the explanation of the shaping mold I. Further, there can be easily obtained an optical fiber guide block suitable for the production of an optical fiber array which permits the optical interconnection of optical fibers to other optical fibers or optical parts by a passive alignment method.
- the shaping mold II having the above advantages, provided by the present invention, can be used as a shaping mold for producing shaped article having various forms, like the above shaping mold I of the present invention.
- the shaping mold II is particularly suitable as a shaping mold for producing, by mold shaping, a precision positioning member such as an optical fiber fixing member including an optical fiber guide block or an optical parts packaging substrate.
- the shaping mold II can be obtained by forming a fine transfer pattern under a predetermined positional accuracy with one side surface (preferably a flat surface) of a fixed mold member being as a reference surface when the fixed mold member is fabricated, and forming the whole of one inner side surface of a sleeve member part to be fixed to the above reference surface under force at a mold shaping time, as a surface having a flatness which permits a surface-surface contact to the above reference surface when the sleeve member is fabricated.
- the fixed mold member is formed of a plurality of parts (shaping parts), preferably, one side surface of the part (shaping part) in which a fine transfer pattern is formed is used as the above reference surface.
- the fine pattern has a plurality of grooves or lines-forming convex portions (e.g., convex portions for forming fixing grooves of an optical fiber guide block) which are in parallel with one another, preferably, the right-hand or left-hand side surface of the fixed mold member viewed in the longitudinal direction of the grooves or convex portions is used as the above reference surface.
- the distance between each inner side surface of the sleeve member and each predetermined side surface of the fixed mold member is substantially zero. Therefore, the positional accuracy of the fine transfer pattern relative to the predetermined one inner side surface of the sleeve member (one inner side surface fixed to the one predetermined side surface of the fixed mold member when mold shaping is carried out) can be indirectly determined by measuring the fine transfer pattern for a positional accuracy relative to the specific one side surface of the fixed mold member.
- the method I of the present invention comprises mold shaping a preform with the shaping mold I of the present invention to obtain a shaped article.
- the method II of the present invention comprises placing a preform in a cavity of the above shaping mold II of the present invention, mold shaping the preform with the shaping mold II, and thereby obtaining a shaped article to which a fine transfer pattern formed in a transfer shaping surface of the fixed mold member and at least part of a transfer pattern formed in that inner side surface of the sleeve member of which a positional accuracy of the fine transfer pattern which positional accuracy is defined on the basis is substantially the same as a positional accuracy of the fine transfer pattern which positional accuracy is defined on the basis of that side surface of the fixed mold member which is tightly attached and fixed to the above inner side surface of the sleeve member were transferred.
- the preform used in the method I or II can be selected from conventional preforms formed of glass, glass-ceramic, a resin and a composite material of a resin and an inorganic filler.
- the method I and the method II are the same as a known mold shaping process except that the mold to be used is the above shaping mold I or II.
- the temperature for mold shaping (shaping temperature) differs depending upon shapeable materials as is well known, and the material for the shaping mold (the shaping mold I or II of the present invention) for use in the method I or II is properly determined depending upon the material of a shaped article to be obtained.
- the shaping mold I of the present invention is particularly suitable as a shaping mold for obtaining, by mold shaping, articles required to have high accuracy such as a precision-positioning member including an optical fiber fixing member (e.g. an optical fiber guide block) and an optical parts packaging substrate, a prism, a polygon mirror, or the like. Therefore, the method I is as well particularly suitable as a method for obtaining, by mold shaping, articles required to have high accuracy such as a precision-positioning member including an optical fiber fixing member and an optical parts packaging substrate, a prism, a polygon mirror, or the like.
- a precision-positioning member including an optical fiber fixing member and an optical parts packaging substrate, a prism, a polygon mirror, or the like.
- the shaping mold II of the present invention is particularly suitable as a shaping mold for obtaining, by mold shaping, articles required to have high accuracy such as a precision-positioning member including an optical fiber fixing member (e.g. an optical fiber guide block) and an optical parts packaging substrate. Therefore, the method II is as well particularly suitable as a method for obtaining, by mold shaping, articles required to have high accuracy such as a precision-positioning member including an optical fiber fixing member (e.g. an optical fiber guide block) and an optical parts packaging substrate.
- a molding burr or a fine swelling (bump) on a shaped article caused by the entering of shapeable material into a clearance between the movable mold member and the sleeve member of a shaped article when the method I or II is used for obtaining the shaped article
- the transfer shaping surface of the movable mold member or the fixed mold member has a concave-convex surface concerning the above condition (a)
- the form and size of the transfer shaping surface of the movable mold member or the fixed mold member viewed as a plan view is assumed to be a form and size of the above transfer shaping surface, and it is to be assumed that the so-assumed transfer shaping surface as a whole is brought into contact with the preform, for determining the above contact area.
- the shapeable material is glass
- the shaping viscosity of the shapeable material on the movable mold member side is less than five times the shaping viscosity of the shapeable material on the fixed mold member side
- the following difficulties are caused. That is, (i) even when the above condition (a) is satisfied for carrying out mold shaping, it is difficult to prevent shapeable material from entering a clearance between the movable mold member and the sleeve member to form a molding burr.
- a fine transfer pattern is formed on the fixed mold member, shapeable material is liable to spread into a large space rather than into the above fine transfer pattern, and the filling of shapeable material into the above fine transfer pattern is liable to be deficient.
- the shapeable material is glass and if the shaping viscosity of the shapeable material on the movable mold member side is more than 100 times the shaping viscosity of the shapeable material on the fixed mold member side, the elongation of the glass on the transfer shaping surface of the movable mold member and the elongation of the glass on the transfer shaping surface of the fixed mold member are poorly balanced, and it is therefore difficult to obtain an excellent shaped article.
- the shaping viscosity of the shapeable material on the movable mold member side is preferably approximately 10 to 50 times the shaping viscosity of the shapeable material on the fixed mold member side.
- a cemented carbide containing tungsten carbide as a main component was processed precisely to obtain the following blocks (i) to (v).
- the blocks (i), (ii) and (v) were obtained in an quantity of 1 each, and the blocks (iii) and (iv) were obtained in a quantity of 2 each.
- a carbon-containing release film having a thickness of 500 angstroms was formed, by an ion plating method, on each of predetermined surfaces of the above blocks (i) to (v), i.e., the upper surfaces of the blocks (i), (ii) and (v), one of two surfaces having the form of a 12 x 10 mm rectangle in the block (iii) when the block (iii) was viewed as a plan view, and one of two surfaces having the form of a 13 x 10 mm rectangle in the block (iv) when the block (iv) was viewed as a plan view.
- a first shaping part for a lower mold member was obtained from the above block (i)
- a second shaping part for a lower mold member was obtained from the above block (ii)
- first sleeve member parts were obtained from the above blocks (iii)
- second sleeve member parts were obtained from the above blocks (iv)
- an upper mold member was obtained from the above block (v).
- the first shaping part for a lower mold member and the second shaping part for a lower mold member are arranged in a predetermined direction to form a lower mold member having the form of a 5 x 12 mm rectangle when viewed as a plan view.
- the first sleeve member parts and the second sleeve member parts are combined in a predetermined form, to form a sleeve member having a hollow portion having the cross-sectional form of a 5 x 12 mm rectangle in the diameter direction of the hollow portion.
- the above lower mold member, the above sleeve member and the above upper mold member constitute a shaping mold together with an outer frame to be described in detail below.
- the outer frame is used for fixing the first sleeve member parts and the second sleeve member parts to side surfaces of the lower mold member under force in a tightly attached state.
- the outer frame was prepared by making a 13.1 x 20.1 x 10 mm (depth 10 mm) hole in the center of a disc which was formed of the same material as the above cemented carbide and had a diameter of 40 mm and a thickness of 15 mm and further making 4 screw runners (internal threads) in the disc from its circumference to its center.
- Each of the above screw runners is formed so as to open in the central portion of each of four side walls of the above hole.
- the above first shaping part for the lower mold member, the above second shaping part for the lower mold member, the first sleeve member parts and the second sleeve member parts are arranged as follows by utilizing the above frame.
- the first shaping part 2a for the lower mold member and the second shaping part 2b for the lower mold member are arranged in the central portion of the above hole made in the outer frame 1, so as to have the form of a 5 x 12 mm rectangle when viewed as a plan view, and they are used as a lower mold member 2.
- the first sleeve member parts 3a are arranged so as to be fixed to longer side surfaces of the lower mold member 2 under force in a tightly attached state
- the second sleeve member parts 3b are arranged so as to be fixed to shorter side surfaces of the lower mold member 2 under force in a tightly attached state.
- first shaping part 2a for the lower mold member the second shaping parts 2b for the lower mold member, the first sleeve member parts 3a and the second sleeve member parts 3b are arranged such that their release film surfaces form transfer shaping surfaces.
- screws are threaded into the screw runners la made in the outer frame 1 so as to reach the first sleeve member parts 3a or the second sleeve member parts 3b through the outer frame la, whereby the first sleeve member parts 3a are fixed to the longer side surfaces of the lower mold member 2 under force in a tightly attached state and the second sleeve member parts 3b are fixed to the shorter side surfaces of the lower mold member 2 under force in a tightly attached state.
- first shaping part 2a for the lower mold member, which constitutes the lower mold member 2 and the second shaping part 2b for the lower mold member, which constitutes the lower mold member 2 are tightly attached to each other, and adjacent pairs of the first sleeve member parts 3a and the second sleeve member parts 3b are brought into surface-surface contact in a tightly attached state to form a sleeve member 3.
- reference numeral 2c indicates convex portions (having the release film formed on the surface) which are formed on the first shaping part 2a for the lower mold member and used for shaping V grooves.
- the first shaping part 2a for the lower mold member, the second shaping part 2b for the lower mold member, the first sleeve member parts 3a and the second sleeve member parts 3b were arranged as shown in Fig. 1 by utilizing the outer frame 1, and then, as shown in Fig. 2, a glass preform 5 was placed in the central portion of the upper surface of the lower mold member 2.
- the glass preform 5 had the form of a 4.5 x 11.5 x 1.8 mm rectangular parallelepiped (thickness 1.8 mm) whose corners were rounded, and it was formed of a glass having a sag temperature of 510°C.
- the outer frame 1, the lower mold member 2, the sleeve member 3 and the glass preform 5 were heated in an inert gas atmosphere such that the lower mold member 2 had a temperature of 565°C (corresponding to a temperature at which the glass as a shapeable material had a viscosity of 10 8 poise), and on the other hand, the upper mold member 6 (prepared in the above (1), see Fig. 2) was heated to 535°C (corresponding to a temperature at which the glass as a shapeable material had a viscosity of 10 9.4 poise) in the same inert gas atmosphere as the above. And, the upper mold member 6 was lowered toward the lower mold member 2 as shown by an arrow C in Fig.
- the glass preform 5 was mold shaped with the upper mold 6 at a load of 100 kg (about 200 kg/cm 2 as a pressure) for 30 seconds.
- the upper mold member 6 was used such that its surface on the side where a convex portion (having the release film formed on the surface) 6a was formed faced the lower mold member 2 side, and the convex portion 6a was allowed to slide within the sleeve member 3 with keeping a clearance of 10 ⁇ m from the transfer shaping surfaces of the sleeve member 3.
- the shaping mold was cooled to room temperature, and then a shaped article was taken out.
- the above-obtained shaped article is an optical fiber guide block having an optical fiber fixing part having an upper surface on which eight fixing grooves (V grooves) for fixing end portions of optical fibers are formed and a lower-level part having an upper surface (flat surface) formed lower than the upper surface level of the optical fiber fixing part.
- the above optical fiber guide block has the form of a 5 x 12 mm rectangle when viewed as a plan view, the optical fiber fixing part has the cross-sectional form of a 5 x 5 mm rectangle in the horizontal direction (disregarding a portion where the above fixing grooves are formed), and the lower-level part has the cross-sectional form of a 5 x 7 mm rectangle in the horizontal direction.
- the optical fiber fixing part has a maximum thickness of 1.5 mm, and the lower-level part has a thickness of 1.25 mm.
- a lower mold member having the form of a regular hexagonal prism having a predetermined size and being formed of one member, an upper mold member having a convex portion having the form of a regular hexagonal prism having a predetermined size and an outer frame having a hole having the horizontal cross-sectional from of a regular hexagon formed in its center were fabricated in the same manner as in Example 1.
- the above convex portion of the upper mold member was formed such that it was allowed to slide within a sleeve member to be described later with keeping a clearance of 10 ⁇ m from the transfer shaping surfaces of the sleeve member.
- 6 screw runners internal threads
- sleeve member parts having various forms which were to form a sleeve member having a hollow portion having the cross-sectional form of a regular hexagon having a predetermined size in a diameter direction when fixed to side surfaces of the lower mold member in a tightly attached state, were fabricated in the same manner as in Example 1.
- Figs. 3(a) to 3(d) are schematic plan views showing arrangements of the above lower mold member, outer frame and sleeve member parts when they are used.
- the lower mold member 11 In a state shown in Fig. 3(a), the lower mold member 11 is placed in the central portion of the above hole made in the outer frame 10, and six sleeve member parts of three kinds, 12a, 12b and 12c, are fixed to side surfaces of the lower mold member 11, respectively, under force in a tightly attached state, to form the sleeve member 12.
- the lower mold member 11 In a state shown in Fig. 3(b), the lower mold member 11 is placed in the central portion of the above hole made in the outer frame 10, and six sleeve member parts of one kind 13a are fixed to side surfaces of the lower mold member 11, respectively, under force in a tightly attached state, to form the sleeve member 13.
- a state shown in Fig. 3(a) the lower mold member 11 is placed in the central portion of the above hole made in the outer frame 10, and six sleeve member parts of one kind 13a are fixed to side surfaces of the lower mold member 11, respectively, under force in a tightly attached state, to form the
- the lower mold member 11 is placed in the central portion of the above hole made in the outer frame 10, and six sleeve member parts of three kinds, 14a, 14b and 14c, are fixed to side surfaces of the lower mold member 11, respectively, under force in a tightly attached state, to form the sleeve member 14.
- the lower mold member 11 is placed in the central portion of the above hole made in the outer frame 10, and four sleeve member parts of two kinds, 15a and 15b, are fixed to side surfaces of the lower mold member 11, respectively, under force in a tightly attached state, to form the sleeve member 15.
- the sleeve member parts are fixed to the lower mold member 11 under force by threading screws (not shown) through screw runners 10a made in the outer frame 10 so as to reach the sleeve member parts through the outer frame 10 in the same manner as in Example 1. In this case, adjacent pairs of the sleeve member parts are brought into surface-surface contact in a tightly attached state, to form the sleeve member.
- the above lower mold member, sleeve member and outer frame constitute a shaping mold together with the above upper mold member.
- Polygon mirrors having the form of a regular hexagonal prism were obtained by carrying out mold shaping under the same conditions as those in Example 1 except that the shaping mold was replaced with the shaping molds prepared in the above (1) and the glass preform was replaced with glass preforms having the form of a disc having a size inscribed in each inner side surface of the sleeve member (regular hexagon when its whole shape was viewed as a plan view).
- a 4.5 x 11.5 x 1.75 rectangular parallelepiped (thickness 1.75 mm) formed of a glass having the same composition as that of the glass preform used in Example 1 was prepared, and four edges of one main surface present in the thickness direction were chamfered to obtain a glass preform.
- the above chamfering was carried out such that each surface formed by the chamfering had a width (when the glass preform was viewed in the thickness direction as a plan view) of 0.8 mm.
- the glass preform was placed in the central portion of the upper surface of the lower mold member (fixed mold member) of the same shaping mold as that used in Example 1 with the chamfered main surface facing upwardly, and the outer frame, the lower mold member, the sleeve member and the glass preform were heated in an inert gas atmosphere such that the lower mold member had a temperature of 560°C.
- the upper mold member movable mold member
- the glass preform was mold shaped at a load of 80 kg (about 160 kg/cm 2 as a pressure) with the above upper mold member for 60 seconds.
- the shaping mold was cooled to room temperature, and then a shaped article was taken out.
- the contact area of the lower mold member and the glass preform at an initial stage of the mold shaping equals the area of that main surface of the glass preform which is not chamfered in edges. Meanwhile, the contact area of the upper mold member and the glass preform at an initial stage of the mold shaping is smaller than the contact area of the lower mold member and the glass preform by a portion decreased by the chamfering of edges of the main surface which is in contact with the upper mold member.
- the molding burr was found in no place. Further, the optical interconnection end face vicinity was searched for a fine swelling (bump), it was not at all found.
- the filling of glass in V grooves formed in the optical fiber fixing part seemed to be deficient to slight extent as compared with the optical fiber guide block obtained in Example 1.
- the obtained optical fiber guide block had no problem on the positional accuracy of optical fibers, and it was a practical shaped article.
- Edge portions of the bottom surface of the above optical fiber guide block were formed of free surfaces having a small curvature since the glass preform had been chamfered and consequently caused a delay in the filling of glass.
- the surface of the block which surface is to be formed as the right or left side surface of the block when the block is viewed in the length direction of convex portions for forming V grooves, is processed to form a flat surface, and the above convex portions for forming V grooves are formed under predetermined positional accuracy with using the above flat surface as a reference surface.
- inner side surface A of sleeve member part (on which a release film is to be formed, and the inner side surface coated with a release film will be referred to as "inner side surface A of sleeve member part" hereinafter) of a block for a sleeve member part which is to be fixed to the above flat surface used as a reference surface (right or left side surface of the block for the first shaping part) is processed to form a flat surface.
- a shaping mold is produced in the same manner as in Example 1 except for the above.
- an optical fiber guide block in which the positional accuracy of the fixing grooves (V grooves) relative to the side surface formed of the inner side surface A of the above sleeve member part is substantially the same as the positional accuracy of the convex portions for forming the V grooves relative to the flat surface used as the above reference surface in the production of the first shaping part of the lower mold member.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26571997 | 1997-09-30 | ||
JP265719/97 | 1997-09-30 | ||
JP26571997 | 1997-09-30 | ||
JP24688298A JPH11165323A (ja) | 1997-09-30 | 1998-09-01 | モールド成形型および成形方法 |
JP24688298 | 1998-09-01 | ||
JP246882/98 | 1998-09-01 |
Publications (2)
Publication Number | Publication Date |
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EP0905099A2 true EP0905099A2 (de) | 1999-03-31 |
EP0905099A3 EP0905099A3 (de) | 1999-08-18 |
Family
ID=26537956
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP98307892A Withdrawn EP0905099A3 (de) | 1997-09-30 | 1998-09-29 | Form und Formungsverfahren |
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EP (1) | EP0905099A3 (de) |
JP (1) | JPH11165323A (de) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7423297B2 (en) | 2006-05-03 | 2008-09-09 | 3M Innovative Properties Company | LED extractor composed of high index glass |
WO2009022099A1 (en) * | 2007-08-10 | 2009-02-19 | Qinetiq Limited | Mould comprising two internal corner-cubes and component comprising cuboid elements forming two internal corner-cubes |
US8141384B2 (en) | 2006-05-03 | 2012-03-27 | 3M Innovative Properties Company | Methods of making LED extractor arrays |
CN117382063A (zh) * | 2023-11-29 | 2024-01-12 | 广东扬格新材料科技有限公司 | 一种密胺餐具节能型生产用热压成型设备及其使用方法 |
US20240059599A1 (en) * | 2022-08-22 | 2024-02-22 | AAC Optics (Chongqing) Co., Ltd. | Mold for molding glass product |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4907316B2 (ja) * | 2006-11-29 | 2012-03-28 | 株式会社型システム | 成形装置および成形方法 |
JP5128309B2 (ja) * | 2008-02-20 | 2013-01-23 | Towa株式会社 | 電子部品の圧縮成形方法及び金型 |
JP5059540B2 (ja) * | 2007-10-17 | 2012-10-24 | オリンパス株式会社 | 光学素子の成形装置 |
JP5220491B2 (ja) * | 2008-06-24 | 2013-06-26 | オリンパス株式会社 | 光学素子の製造方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1549502A (de) * | 1967-10-31 | 1968-12-13 | ||
JPH08211244A (ja) * | 1995-02-07 | 1996-08-20 | Copal Co Ltd | 光ファイバ固定用基板及びその製造方法 |
-
1998
- 1998-09-01 JP JP24688298A patent/JPH11165323A/ja not_active Withdrawn
- 1998-09-29 EP EP98307892A patent/EP0905099A3/de not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1549502A (de) * | 1967-10-31 | 1968-12-13 | ||
JPH08211244A (ja) * | 1995-02-07 | 1996-08-20 | Copal Co Ltd | 光ファイバ固定用基板及びその製造方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7423297B2 (en) | 2006-05-03 | 2008-09-09 | 3M Innovative Properties Company | LED extractor composed of high index glass |
US8141384B2 (en) | 2006-05-03 | 2012-03-27 | 3M Innovative Properties Company | Methods of making LED extractor arrays |
WO2009022099A1 (en) * | 2007-08-10 | 2009-02-19 | Qinetiq Limited | Mould comprising two internal corner-cubes and component comprising cuboid elements forming two internal corner-cubes |
GB2464242A (en) * | 2007-08-10 | 2010-04-14 | Qinetiq Ltd | Mould comprising two internal corner-cubes and component comprising cuboid elements forming two internal corner-cubes |
GB2464242B (en) * | 2007-08-10 | 2012-07-25 | Qinetiq Ltd | Mould comprising two internal corner-cubes and component comprising cuboid elements forming two internal corner-cubes |
US20240059599A1 (en) * | 2022-08-22 | 2024-02-22 | AAC Optics (Chongqing) Co., Ltd. | Mold for molding glass product |
CN117382063A (zh) * | 2023-11-29 | 2024-01-12 | 广东扬格新材料科技有限公司 | 一种密胺餐具节能型生产用热压成型设备及其使用方法 |
CN117382063B (zh) * | 2023-11-29 | 2024-03-19 | 广东扬格新材料科技有限公司 | 一种密胺餐具节能型生产用热压成型设备及其使用方法 |
Also Published As
Publication number | Publication date |
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EP0905099A3 (de) | 1999-08-18 |
JPH11165323A (ja) | 1999-06-22 |
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