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EP0888902A1 - An ink jet recording medium - Google Patents

An ink jet recording medium Download PDF

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Publication number
EP0888902A1
EP0888902A1 EP97202022A EP97202022A EP0888902A1 EP 0888902 A1 EP0888902 A1 EP 0888902A1 EP 97202022 A EP97202022 A EP 97202022A EP 97202022 A EP97202022 A EP 97202022A EP 0888902 A1 EP0888902 A1 EP 0888902A1
Authority
EP
European Patent Office
Prior art keywords
ink jet
jet recording
monomer unit
recording medium
ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP97202022A
Other languages
German (de)
French (fr)
Inventor
Steven J. Sargeant
Joshua D. Rundus
Jonathan Mccarney
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkwright Inc
Original Assignee
Arkwright Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkwright Inc filed Critical Arkwright Inc
Priority to EP97202022A priority Critical patent/EP0888902A1/en
Priority to JP9178349A priority patent/JPH1128417A/en
Priority to CA002213637A priority patent/CA2213637A1/en
Publication of EP0888902A1 publication Critical patent/EP0888902A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/506—Intermediate layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • B41M5/5281—Polyurethanes or polyureas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/529—Macromolecular coatings characterised by the use of fluorine- or silicon-containing organic compounds

Definitions

  • This invention relates to ink jet recording media, and more particularly to ink sorptive coatings that can be used in combination with a suitable substrate to provide an ink jet recording media.
  • Patent 4,889,765 discloses an ink-receptive coating composition comprising a polymer of 2-oxazoline, preferably polyethyl oxazoline, and an olefin copolymer containing pendant acid groups which are substantially neutralized by a base.
  • U.S. Patent 5,389,723 discloses coatings formed from semi-interpenetrating polymeric networks comprising a blend of a polymeric matrix component, a liquid absorbent component, and a polyfunctional aziridine crosslinking agent for forming water durable networks.
  • a polyethyl oxazoline is mentioned as a possible liquid absorbent material.
  • ink sorptive coating that can be used for ink jet recording media (e.g., ink jet recording paper, ink jet recording film and other substrate based ink jet recording products).
  • the ink sorptive coating can be used to provide ink jet recording media having improved performance for ink jet recording applications.
  • an object of the present invention is to provide an ink sorptive coating that can be used for ink jet recording media.
  • Another object of the present invention is to provide an ink jet recording media, wherein an ink sorptive coating is applied to the surface of a suitable substrate, and wherein the coating provides improved image quality, curl performance and dry time to the prepared media.
  • the ink sorptive coatings and recording media of the present invention comprise:
  • a surface coating layer containing a cellulose ether may be employed over the ink sorptive coatings of the inventive media in order to achieve desired performance properties.
  • the ink jet recording medium of the present invention contains a substrate having on a surface thereof at least one ink sorptive coating layer that comprises:
  • Typical examples of polyalkyl oxazoline and polyphenyl oxazoline monomer units that are useful in preparing the ink sorptive coatings and ink jet recording media of the present invention are polymethyl oxazoline, polyethyl oxazoline, polypropyl oxazoline, polyphenyl oxazoline, and the like. Both, polymers and copolymers containing such monomer units are useful in preparing the ink sorptive coatings and ink jet recording media of the present invention.
  • the weight average molecular weight of such polymers and copolymers should be greater than about 40,000 and more preferably greater than about 200,000.
  • hydroxyl group (-OH) containing polymers and copolymers that are useful in preparing the ink sorptive coatings and ink jet recording media of the present invention are those that contain a cellulose acetate butyrate monomer unit, a cellulose acetate propionate monomer unit, a poly(vinyl butyral) monomer unit, a ethylcellulose monomer unit, a partially hydrolyzed poly(vinyl acetate) monomer unit, a nitrocellulose monomer unit, a hydroxyethyl methacrylate monomer unit, and the like.
  • the weight average molecular weight of such polymers and copolymers should be greater than about 25,000 and more preferably greater than about 100,000.
  • the ink sorptive coating(s) of the present invention preferably contain about 50% to about 98% of the polyalkyl oxazoline and/or polyphenyl oxazoline containing polymer(s) or copolymer(s) therein, on a weight/weight basis; more preferably about 80% to about 95%, on a weight/weight basis.
  • a surface coating over said ink sorptive coating layer(s) is required.
  • the ink sorptive coating(s) are coated directly on the base substrate and then dried.
  • the surface coating layer is then applied on top of the ink sorptive coating layer(s), with the surface coating layer containing at least one cellulose ether.
  • Typical examples of cellulose ethers that may be used in the surface coatings of the present invention are methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl ethyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose and carboxymethyl cellulose.
  • the ink sorptive coatings of the present invention should have a glass transition temperature, Tg, that is greater than about 40°C, and preferably that is greater than about 60°C. (When the Tg is not attainable, the softening temperature is used.) When the Tg is below about 40°C, the coatings are too tacky for commercial applications.
  • Glass transition temperature is measured on a Differential Scanning Calorimeter (TA Instruments, Model DC 2910), calibrated with appropriate standards. The reading and baseline errors from running replicate DSC experiments leads to a typical accuracy in measuring the Tg of about 3°C. Measurements of heat flow versus temperature are made upon heating in the range of about 5° to 200°C at a heating rate of 20°C/minute. The sample chamber is purged with nitrogen. Film-like samples are encapsulated in an aluminum pan. The midpoint method is used to obtain the glass transition temperature of the polymer blend from the measured DSC curve of heat flow versus temperature.
  • the thickness of the inventive ink sorptive coatings of the present invention is not particularly restricted, but is generally governed by application of each ink sorptive coating layer to the substrate in an amount of from about 2 grams per square meter to about 30 grams per square meter.
  • suitable substrates for such purposes include transparent plastics, translucent plastics, matte plastics, opaque plastics, papers and the like.
  • suitable polymeric materials for use as the base substrate include polyester, cellulose esters, polystyrene, polypropylene, poly(vinyl acetate), polycarbonate, and the like.
  • Poly(ethylene terephthalate) film is a particularly preferred base substrate.
  • clay coated papers and polyolefin coated papers are particularly preferred as base substrate papers.
  • the thickness of the base substrate is not particularly restricted but should generally be in the range of from about 1 to about 10 mils, preferably from about 3.0 to about 5.0 mils.
  • the base substrate may be pretreated to enhance adhesion of the ink sorptive coating thereto, if so desired.
  • the ink sorptive coatings of the present invention may further comprise about 0.1 to about 15% by weight of a particulate(s) based on the weight of the dry coating.
  • Suitable particulates that can be used in the ink sorptive coating(s) to modify their surface properties include inorganic particulates such as silica, alumina, kaolin, glass beads, calcium carbonate and titanium oxide, and organic particulate such as polyolefins, polystyrene, polyurethane, starch, poly(methyl methacrylate) and polytetrafluoroethylene.
  • Such particulates may also be used in the optional surface coating layers that may be used in the inventive media, if so desired. In such an instance, the particulate(s) may be present in the optional surface coating layers in an amount of about 0.1 to about 15% by weight, based on the weight of the dry coatings.
  • additives may also be employed in the ink sorptive coatings of the present invention, as well as in the optional surface coatings of the present invention.
  • These additives can include surface active agents which control the wetting or spreading action of coating solutions, antistatic agents, suspending agents, and acidic compounds to control pH of the coatings.
  • Other additives may also be used, if so desired.
  • the surface of the base substrate which does not bear the ink sorptive coating may have a backing material placed thereon in order to reduce electrostatic charge and to reduce sheet-to-sheet friction and sticking, if so desired.
  • the backing material may either be a polymeric coating, a polymer film or a paper backing material.
  • any of a number of coating methods may be employed to coat the ink sorptive coating(s) onto a suitable substrate.
  • roller coating, blade coating, wire-bar coating, dip coating, extrusion coating, air knife coating, curtain coating, slide coating, doctor coating or gravure coating may be used and are well known in the art.
  • Such coating methods may also be used to coat the optional surface coating layers on the inventive ink jet recording media, if so desired.
  • a coating composition is prepared according to the following formulation: Ink Sorptive Coating: Poly (2-ethyl-2-oxazoline) 85 parts Poly vinylbutyral 15 parts Methyl Ethyl Ketone 280 parts Propylene Glycol Monomethyl Ether 120 parts Poly(methyl methacrylate) beads 1 part
  • the coating is applied to a polyester film (ICI Films) using a No. 42 Meyer rod.
  • the ink sorptive coating is dried at about 130°C for about 4 minutes.
  • a coating composition is prepared according to the following formulation: Ink Sorptive Coating: Poly (2-ethyl-2-oxazoline) 85 parts Copolymer A 15 parts Methyl Ethyl Ketone 280 parts Propylene Glycol Monomethyl Ether 120 parts Poly(methyl methacrylate) beads 1 part
  • the coating is applied to a polyester film (ICI Films) using a No. 42 Meyer rod.
  • the ink sorptive coating is dried at about 130°C for about 4 minutes.
  • a coating composition is prepared according to the following formulation: Ink Sorptive Coating: Poly (2-ethyl-2-oxazoline)-co-(2-phenyl-2-oxazoline) 85 parts Copolymer A 15 parts Methyl Ethyl Ketone 280 parts Propylene Glycol Monomethyl Ether 120 parts Poly(methyl methacrylate) beads 1 part
  • the coating is applied to a polyester film (ICI Films) using a No. 42 Meyer rod.
  • the ink sorptive coating is dried at about 130°C for about 4 minutes.
  • a surface coating layer is then coated over the ink sorptive coating according to the following formulation: Surface Coating Layer Hydroxypropyl Methyl Cellulose 1 part Water 99 parts
  • the surface coating layer is applied with a No. 8 Meyer rod and is dried at about 130°C for about 2 minutes.
  • Example I The ink sorptive coating of Example I is applied to polyester film (ICI Films) using a No. 42 rod and dried for about 4 minutes at about 130°C.
  • the surface coating layer of Example III is then coated over the ink sorptive coating.
  • the surface coating layer is applied with a No. 8 Meyer rod and is dried at about 130°C for about 2 minutes.
  • a coating composition is prepared according to the following formulation: Ink Sorptive Coating: Poly (2-ethyl-2-oxazoline) 85 parts Polyurethane 15 parts Methyl Ethyl Ketone 280 parts Propylene Glycol Monomethyl Ether 120 parts Poly(methyl methacrylate) beads 1 part
  • the coating is applied to a polyester film (ICI Films) using a No. 42 Meyer rod.
  • the ink sorptive coating is dried at 130°C for about 4 minutes.
  • a coating composition is prepared according to the following formulation: Ink Sorptive Coating: PVP K-90 85 parts Copolymer A 15 parts Methyl Ethyl Ketone 280 parts Propylene Monomethyl Ether 120 parts Poly(methyl methacrylate) beads 1 part
  • the coating is applied to a polyester film (ICI Films) using a No. 42 Meyer rod.
  • the ink sorptive coating is dried at 130°C for about 4 minutes.
  • the prepared ink jet recording media are evaluated for performance on a HEWLETT PACKARD DESKJET 850C printer with the ink jet pens supplied by HEWLETT PACKARD for the DESKJET 850C printer.
  • the dry time of each example is measured by initially printing a test plot onto each ink jet recording medium example.
  • the printed sheet is then placed on top of a 20 lb. ream of XEROX 4200 paper. This is taken as time zero (t 0 ).
  • a sheet of white bond paper is placed onto the surface of the print.
  • Another 20 lb. ream of XEROX 4200 paper is placed on top of the white bond paper.
  • the top ream of paper and white bond paper is removed from on top of the print.
  • the print is dry when no transfer of ink between the example and the white bond paper has occurred, which is termed the dry time (t dry ).
  • the projector curl performance is conducted on a POLAROID overhead projector.
  • the projector platen surface is allowed to warm up to 40°C.
  • the ink jet recording medium is placed onto the platen surface for one minute. After one minute the distance that each of the corners of the ink jet recording medium has raised from the platen surface is measured. The highest measured distance is the projector curl of the ink jet recording medium. It is the inventors' experience that the ink jet recording media will give defocused images or low image resolution when their projector curl is greater than about 10 mm.
  • the black image optical density or KOD is measured on a MACBETH TD904 (Macbeth Process Measurements). A reading is taken at four different locations along a solid black image strip. The average of the four readings is the black image optical density.
  • the glass transition temperature, dry time, projector curl and black image optical density of each example and comparative example are provided in Table I, below.
  • each of the inventive Examples I-IV exhibited an improved combination of properties when compared with the Comparative Examples C-I and C-II. This is evident from their performances in curl, dry time and optical density.
  • the inventive media of Examples I-IV possess good black image optical densities. This is important, since good performance in this test is an indicator of a low amount of pigment ink cracking. Specifically, the lower the optical density, the higher the degree of cracking.
  • the ink jet recording media of the present invention possess an improved optical density without experiencing a deterioration in other properties such as curl.
  • Table I clearly shows that the ink jet recording media of the present invention possesses good projector curl performance properties (i.e, much less than 10 mm of curl).
  • the ink jet recording media of the present invention possesses the advantage of an improved dry time, which can allow for a higher throughput in ink jet printing devices.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Ink Jet (AREA)

Abstract

An ink sorptive coating for ink jet recording media, and ink jet recording media that contain the same, wherein the ink jet recording medium contains a substrate having coated on a surface of the substrate the ink sorptive coating layer. The ink sorptive coating layer contains (1) a polymer or copolymer that comprises a polyalkyl oxazoline monomer unit or a polyphenyl oxazoline monomer unit, or a copolymer that comprises a polyalkyl oxazoline monomer unit and a polyphenyl oxazoline monomer unit, and (2) a hydroxyl group (-OH) containing polymer or coplymer. The ink sorptive coating provides the ink jet media with improved image quality, dry time and a low degree of curl.
The ink jet recording medium may further comprise a surface coating layer that is overcoated on said ink sorptive coating layer.

Description

Field of The Invention
This invention relates to ink jet recording media, and more particularly to ink sorptive coatings that can be used in combination with a suitable substrate to provide an ink jet recording media.
Background of The Invention
Recently, ink jet printing technology has been used for presentation, graphic arts, engineering drawing and home office applications. The performance requirements for ink jet recording media used for these applications are quite stringent. The media should provide fast drying, good color fidelity, high image resolution, and archivability. For transparency applications, curl performance on various commercial projectors is also important. There are many commercial products and proposed designs available in the field. Among them, oxazoline based polymeric ink sorptive coatings have shown promising performance, even though only a limited amount of effort was previously expended by those skilled in the art exploring this type of chemistry for ink jet applications. As a result, only a limited amount of information on this subject is available in the prior art, or was otherwise available to the present inventors prior to their present inventive discovery. U.S. Patent 4,889,765 discloses an ink-receptive coating composition comprising a polymer of 2-oxazoline, preferably polyethyl oxazoline, and an olefin copolymer containing pendant acid groups which are substantially neutralized by a base. U.S. Patent 5,389,723 discloses coatings formed from semi-interpenetrating polymeric networks comprising a blend of a polymeric matrix component, a liquid absorbent component, and a polyfunctional aziridine crosslinking agent for forming water durable networks. A polyethyl oxazoline is mentioned as a possible liquid absorbent material. U.S. Patent 4,956,230 discloses coatings containing (1) a hydrophilic polymer containing a carbonylamido group and (2) a hydrophobic polymer without acidic, hydroxyl, =NH and -NH2 functional groups.
The above designs differ from the design of the recording media of the present invention, and the ink sorptive coatings used therein, in both concept and compositions. For example, the present inventive design does not require acidic functional groups containing polyolefin copolymers and aziridine crosslinking agents. Instead, in the present invention, hydrogels are formed through inherent physical and chemical interactions. Furthermore, we have found that the present inventive design provides optimal performance by using acidic, hydroxyl, =NH and -NH2 functional groups, especially hydroxyl groups, in the inventive polyalkyl- or polyphenyl- oxazoline based ink sorptive coatings of the present invention. That is, we have discovered that such functional groups can be helpful in designing ink jet media containing alkyl and phenyl oxazoline based polymeric ink sorptive coatings.
Summary of The Invention
We have designed an ink sorptive coating that can be used for ink jet recording media (e.g., ink jet recording paper, ink jet recording film and other substrate based ink jet recording products). The ink sorptive coating can be used to provide ink jet recording media having improved performance for ink jet recording applications.
Accordingly, an object of the present invention is to provide an ink sorptive coating that can be used for ink jet recording media. Another object of the present invention is to provide an ink jet recording media, wherein an ink sorptive coating is applied to the surface of a suitable substrate, and wherein the coating provides improved image quality, curl performance and dry time to the prepared media.
The good performance properties of the ink sorptive coatings and recording media of the present invention are believed to result from the fact that the ink sorptive coatings of the present invention, comprise:
  • (1) a polyalkyl oxazoline polymer, a polyphenyl oxazoline polymer, a copolymer containing a polyalkyl oxazoline monomer unit, a copolymer containing a polyphenyl oxazoline monomer unit, or a copolymer containing a polyalkyl oxazoline monomer unit and a polyphenyl oxazoline monomer unit; and
  • (2) a hydroxyl (-OH) group containing polymer or copolymer.
    • Optionally, a surface coating layer containing a cellulose ether may be employed over the ink sorptive coatings of the inventive media in order to achieve desired performance properties.
    Detailed Description of The Invention
    The following detailed description is provided as an aid to those desiring to practice the present invention. However, it is not to be construed as being unduly limiting to the present inventive discovery, since those of ordinary skill in the art will readily recognize that the various inventive embodiments disclosed herein may be modified using standard techniques and materials known in the art, without departing from the spirit or scope of the present inventive discovery.
    The ink jet recording medium of the present invention contains a substrate having on a surface thereof at least one ink sorptive coating layer that comprises:
  • (1) a polyalkyl oxazoline polymer, a polyphenyl oxazoline polymer, a copolymer containing a polyalkyl oxazoline monomer unit, a copolymer containing a polyphenyl oxazoline monomer unit, or a copolymer containing a polyalkyl oxazoline monomer unit and a polyphenyl oxazoline monomer unit; and (2) a hydroxyl group (-OH) containing polymer or copolymer.
    • Typical examples of polyalkyl oxazoline and polyphenyl oxazoline monomer units that are useful in preparing the ink sorptive coatings and ink jet recording media of the present invention are polymethyl oxazoline, polyethyl oxazoline, polypropyl oxazoline, polyphenyl oxazoline, and the like. Both, polymers and copolymers containing such monomer units are useful in preparing the ink sorptive coatings and ink jet recording media of the present invention. Preferably, the weight average molecular weight of such polymers and copolymers should be greater than about 40,000 and more preferably greater than about 200,000.
    Typical examples of the hydroxyl group (-OH) containing polymers and copolymers that are useful in preparing the ink sorptive coatings and ink jet recording media of the present invention are those that contain a cellulose acetate butyrate monomer unit, a cellulose acetate propionate monomer unit, a poly(vinyl butyral) monomer unit, a ethylcellulose monomer unit, a partially hydrolyzed poly(vinyl acetate) monomer unit, a nitrocellulose monomer unit, a hydroxyethyl methacrylate monomer unit, and the like. Preferably, the weight average molecular weight of such polymers and copolymers should be greater than about 25,000 and more preferably greater than about 100,000.
    The ink sorptive coating(s) of the present invention preferably contain about 50% to about 98% of the polyalkyl oxazoline and/or polyphenyl oxazoline containing polymer(s) or copolymer(s) therein, on a weight/weight basis; more preferably about 80% to about 95%, on a weight/weight basis.
    For some applications, a surface coating over said ink sorptive coating layer(s) is required. In such an instance, the ink sorptive coating(s) are coated directly on the base substrate and then dried. The surface coating layer is then applied on top of the ink sorptive coating layer(s), with the surface coating layer containing at least one cellulose ether.
    Typical examples of cellulose ethers that may be used in the surface coatings of the present invention are methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl ethyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose and carboxymethyl cellulose.
    The ink sorptive coatings of the present invention should have a glass transition temperature, Tg, that is greater than about 40°C, and preferably that is greater than about 60°C. (When the Tg is not attainable, the softening temperature is used.) When the Tg is below about 40°C, the coatings are too tacky for commercial applications.
    Glass transition temperature is measured on a Differential Scanning Calorimeter (TA Instruments, Model DC 2910), calibrated with appropriate standards. The reading and baseline errors from running replicate DSC experiments leads to a typical accuracy in measuring the Tg of about 3°C. Measurements of heat flow versus temperature are made upon heating in the range of about 5° to 200°C at a heating rate of 20°C/minute. The sample chamber is purged with nitrogen. Film-like samples are encapsulated in an aluminum pan. The midpoint method is used to obtain the glass transition temperature of the polymer blend from the measured DSC curve of heat flow versus temperature.
    The thickness of the inventive ink sorptive coatings of the present invention is not particularly restricted, but is generally governed by application of each ink sorptive coating layer to the substrate in an amount of from about 2 grams per square meter to about 30 grams per square meter.
    The ink sorptive coatings disclosed in this invention can be applied to various base substrates in order to provide one of the present inventive ink jet recording media. For example, suitable substrates for such purposes include transparent plastics, translucent plastics, matte plastics, opaque plastics, papers and the like. Suitable polymeric materials for use as the base substrate include polyester, cellulose esters, polystyrene, polypropylene, poly(vinyl acetate), polycarbonate, and the like. Poly(ethylene terephthalate) film is a particularly preferred base substrate. Further, while almost any paper can be used as the base substrate, clay coated papers and polyolefin coated papers are particularly preferred as base substrate papers. The thickness of the base substrate is not particularly restricted but should generally be in the range of from about 1 to about 10 mils, preferably from about 3.0 to about 5.0 mils. The base substrate may be pretreated to enhance adhesion of the ink sorptive coating thereto, if so desired.
    According to a preferred embodiment of the invention, the ink sorptive coatings of the present invention may further comprise about 0.1 to about 15% by weight of a particulate(s) based on the weight of the dry coating. Suitable particulates that can be used in the ink sorptive coating(s) to modify their surface properties include inorganic particulates such as silica, alumina, kaolin, glass beads, calcium carbonate and titanium oxide, and organic particulate such as polyolefins, polystyrene, polyurethane, starch, poly(methyl methacrylate) and polytetrafluoroethylene. Such particulates may also be used in the optional surface coating layers that may be used in the inventive media, if so desired. In such an instance, the particulate(s) may be present in the optional surface coating layers in an amount of about 0.1 to about 15% by weight, based on the weight of the dry coatings.
    In practice, various additives may also be employed in the ink sorptive coatings of the present invention, as well as in the optional surface coatings of the present invention. These additives can include surface active agents which control the wetting or spreading action of coating solutions, antistatic agents, suspending agents, and acidic compounds to control pH of the coatings. Other additives may also be used, if so desired.
    The surface of the base substrate which does not bear the ink sorptive coating may have a backing material placed thereon in order to reduce electrostatic charge and to reduce sheet-to-sheet friction and sticking, if so desired. The backing material may either be a polymeric coating, a polymer film or a paper backing material.
    Any of a number of coating methods may be employed to coat the ink sorptive coating(s) onto a suitable substrate. For example, roller coating, blade coating, wire-bar coating, dip coating, extrusion coating, air knife coating, curtain coating, slide coating, doctor coating or gravure coating, may be used and are well known in the art. Such coating methods may also be used to coat the optional surface coating layers on the inventive ink jet recording media, if so desired.
    The following Examples are given merely as illustrative of the invention and are not to be considered as limiting. In the following examples, parts are given as parts by weight, based on solid content.
    Example I
    A coating composition is prepared according to the following formulation:
    Ink Sorptive Coating:
    Poly (2-ethyl-2-oxazoline) 85 parts
    Poly vinylbutyral 15 parts
    Methyl Ethyl Ketone 280 parts
    Propylene Glycol Monomethyl Ether 120 parts
    Poly(methyl methacrylate) beads 1 part
    The coating is applied to a polyester film (ICI Films) using a No. 42 Meyer rod. The ink sorptive coating is dried at about 130°C for about 4 minutes.
    Example II
    A coating composition is prepared according to the following formulation:
    Ink Sorptive Coating:
    Poly (2-ethyl-2-oxazoline) 85 parts
    Copolymer A 15 parts
    Methyl Ethyl Ketone 280 parts
    Propylene Glycol Monomethyl Ether 120 parts
    Poly(methyl methacrylate) beads 1 part
    The coating is applied to a polyester film (ICI Films) using a No. 42 Meyer rod. The ink sorptive coating is dried at about 130°C for about 4 minutes.
    Example III
    A coating composition is prepared according to the following formulation:
    Ink Sorptive Coating:
    Poly (2-ethyl-2-oxazoline)-co-(2-phenyl-2-oxazoline) 85 parts
    Copolymer A 15 parts
    Methyl Ethyl Ketone 280 parts
    Propylene Glycol Monomethyl Ether 120 parts
    Poly(methyl methacrylate) beads 1 part
    The coating is applied to a polyester film (ICI Films) using a No. 42 Meyer rod. The ink sorptive coating is dried at about 130°C for about 4 minutes. A surface coating layer is then coated over the ink sorptive coating according to the following formulation:
    Surface Coating Layer
    Hydroxypropyl Methyl Cellulose 1 part
    Water 99 parts
    The surface coating layer is applied with a No. 8 Meyer rod and is dried at about 130°C for about 2 minutes.
    Example IV
    The ink sorptive coating of Example I is applied to polyester film (ICI Films) using a No. 42 rod and dried for about 4 minutes at about 130°C. The surface coating layer of Example III is then coated over the ink sorptive coating. The surface coating layer is applied with a No. 8 Meyer rod and is dried at about 130°C for about 2 minutes.
    Comparative Example I
    A coating composition is prepared according to the following formulation:
    Ink Sorptive Coating:
    Poly (2-ethyl-2-oxazoline) 85 parts
    Polyurethane 15 parts
    Methyl Ethyl Ketone 280 parts
    Propylene Glycol Monomethyl Ether 120 parts
    Poly(methyl methacrylate) beads 1 part
    The coating is applied to a polyester film (ICI Films) using a No. 42 Meyer rod. The ink sorptive coating is dried at 130°C for about 4 minutes.
    Comparative Example II
    A coating composition is prepared according to the following formulation:
    Ink Sorptive Coating:
    PVP K-90 85 parts
    Copolymer A 15 parts
    Methyl Ethyl Ketone 280 parts
    Propylene Monomethyl Ether 120 parts
    Poly(methyl methacrylate) beads 1 part
    The coating is applied to a polyester film (ICI Films) using a No. 42 Meyer rod. The ink sorptive coating is dried at 130°C for about 4 minutes.
    The prepared ink jet recording media are evaluated for performance on a HEWLETT PACKARD DESKJET 850C printer with the ink jet pens supplied by HEWLETT PACKARD for the DESKJET 850C printer.
    The dry time of each example is measured by initially printing a test plot onto each ink jet recording medium example. The printed sheet is then placed on top of a 20 lb. ream of XEROX 4200 paper. This is taken as time zero (t0). At one minute intervals a sheet of white bond paper is placed onto the surface of the print. Another 20 lb. ream of XEROX 4200 paper is placed on top of the white bond paper. After five seconds the top ream of paper and white bond paper is removed from on top of the print. The print is dry when no transfer of ink between the example and the white bond paper has occurred, which is termed the dry time (tdry).
    The projector curl performance is conducted on a POLAROID overhead projector. The projector platen surface is allowed to warm up to 40°C. The ink jet recording medium is placed onto the platen surface for one minute. After one minute the distance that each of the corners of the ink jet recording medium has raised from the platen surface is measured. The highest measured distance is the projector curl of the ink jet recording medium. It is the inventors' experience that the ink jet recording media will give defocused images or low image resolution when their projector curl is greater than about 10 mm.
    The black image optical density or KOD is measured on a MACBETH TD904 (Macbeth Process Measurements). A reading is taken at four different locations along a solid black image strip. The average of the four readings is the black image optical density.
    The glass transition temperature, dry time, projector curl and black image optical density of each example and comparative example are provided in Table I, below.
    The Performance Comparison of Ink Jet Recording Media
    Example Glass Transition Temperature (Tg, °C) Dry Time (minutes) Projector Curl (mm) Black Image Optical Density (KOD)
    I 56 2.5 3 .80
    II 57 2.5 2 .88
    III 57 3 4 1.39
    IV 60 >4 5 1.03
    CI 50 >4 0 .42
    CII 156 >4 54 1.43
    As shown in Table I, each of the inventive Examples I-IV exhibited an improved combination of properties when compared with the Comparative Examples C-I and C-II. This is evident from their performances in curl, dry time and optical density.
    For example, the inventive media of Examples I-IV possess good black image optical densities. This is important, since good performance in this test is an indicator of a low amount of pigment ink cracking. Specifically, the lower the optical density, the higher the degree of cracking.
    Notably, the ink jet recording media of the present invention possess an improved optical density without experiencing a deterioration in other properties such as curl. In this regard, Table I clearly shows that the ink jet recording media of the present invention possesses good projector curl performance properties (i.e, much less than 10 mm of curl).
    Additionally, the ink jet recording media of the present invention possesses the advantage of an improved dry time, which can allow for a higher throughput in ink jet printing devices.
    Each of the patents referred to herein is incorporated by reference herein in its entirety.

    Claims (19)

    1. An ink jet recording medium, comprising a substrate having coated on a surface of said substrate an ink sorptive coating layer that contains:
      a polymer or copolymer that comprises a polyalkyl oxazoline monomer unit or a polyphenyl oxazoline monomer unit, or a copolymer that comprises a polyalkyl oxazoline monomer unit and a polyphenyl oxazoline monomer unit; and
      a hydroxyl group (-OH) containing polymer or copolymer.
    2. The ink jet recording medium according to claim 1, wherein said polyalkyl oxazoline monomer unit is selected from the group consisting of a polymethyl oxazoline monomer unit, a polyethyl oxazoline monomer unit, and a polypropyl oxazoline monomer unit.
    3. The ink jet recording medium according to claim 1, wherein said polymer or copolymer that comprises said polyalkyl oxazoline monomer unit or said polyphenyl oxazoline monomer unit, possesses a weight average molecular weight that is greater than about 40,000.
    4. The ink jet recording medium according to claim 1, wherein copolymer that comprises said polyalkyl oxazoline monomer unit and said polyphenyl oxazoline monomer unit, possesses a weight average molecular weight that is greater than about 40,000.
    5. The ink jet recording medium according to claim 1, wherein said hydroxyl group containing polymer or copolymer, comprises:
      a cellulose acetate butyrate monomer unit,
      a cellulose acetate propionate monomer unit,
      a poly(vinyl butyral) monomer unit,
      a ethylcellulose monomer unit,
      a partially hydrolyzed poly(vinyl acetate) monomer unit,
      a nitrocellulose monomer unit, or
      a hydroxyethyl methacrylate monomer unit.
    6. The ink jet recording medium according to claim 1, wherein said hydroxyl group containing polymer or copolymer possesses a weight average molecular weight that is greater than about 25,000.
    7. The ink jet recording medium according to claim 1, wherein said ink sorptive coating has a glass transition temperature or softening temperature of at least about 40°C.
    8. The ink jet recording medium according to claim 1, wherein said medium further comprises a surface coating layer that is overcoated on said ink sorptive coating layer.
    9. The ink jet recording medium according to claim 8, wherein said surface coating layer contains a cellulose ether.
    10. The ink jet recording medium according to claim 9, wherein said cellulose ether is selected from the group consisting of:
      methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl ethyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose and carboxymethyl cellulose.
    11. The ink jet recording medium according to claim 1, wherein said ink sorptive coating contains a particulate that is selected from the group consisting of:
      silica, alumina, kaolin, glass beads, calcium carbonate, titanium oxide, polyolefins, polystyrene, polyurethane, starch, poly(methyl methacrylate) and polytetrafluoroethylene.
    12. The ink jet recording medium according to claim 9, wherein said surface layer contains a particulate that is selected from the group consisting of:
      silica, alumina, kaolin, glass beads, calcium carbonate, titanium oxide, polyolefins, polystyrene, polyurethane, starch, poly(methyl methacrylate) and polytetrafluoroethylene.
    13. The ink jet recording medium according to claim 1, wherein said substrate is a transparent plastic substrate.
    14. The ink jet recording medium according to claim 1, wherein said substrate is an opaque plastic substrate.
    15. The ink jet recording medium according to claim l, wherein said substrate is a paper.
    16. The ink jet recording medium according to claim 1, wherein said substrate is a matte plastic substrate.
    17. The ink jet recording medium according to claim 1, wherein said substrate is a translucent substrate.
    18. The ink jet recording medium according to claim 1, wherein said substrate is a textile material.
    19. A process of ink jet printing, that comprises: applying a liquid ink to the ink sorptive coating layer of the ink jet recording medium of claim 1.
    EP97202022A 1997-07-02 1997-07-02 An ink jet recording medium Withdrawn EP0888902A1 (en)

    Priority Applications (3)

    Application Number Priority Date Filing Date Title
    EP97202022A EP0888902A1 (en) 1997-07-02 1997-07-02 An ink jet recording medium
    JP9178349A JPH1128417A (en) 1997-07-02 1997-07-03 Ink jet recording medium
    CA002213637A CA2213637A1 (en) 1997-07-02 1997-08-22 An ink jet recording medium

    Applications Claiming Priority (3)

    Application Number Priority Date Filing Date Title
    EP97202022A EP0888902A1 (en) 1997-07-02 1997-07-02 An ink jet recording medium
    JP9178349A JPH1128417A (en) 1997-07-02 1997-07-03 Ink jet recording medium
    CA002213637A CA2213637A1 (en) 1997-07-02 1997-08-22 An ink jet recording medium

    Publications (1)

    Publication Number Publication Date
    EP0888902A1 true EP0888902A1 (en) 1999-01-07

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    EP (1) EP0888902A1 (en)
    JP (1) JPH1128417A (en)
    CA (1) CA2213637A1 (en)

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    EP1072428A1 (en) * 1999-07-22 2001-01-31 Mitsubishi Polyester Film Corporation Ink-jet recording sheet having an intermediate layer containing oxazoline-copolymer
    US6403224B1 (en) 1999-06-15 2002-06-11 Mitsubishi Polyester Film Corporation Coated film
    US6455136B1 (en) 1999-06-15 2002-09-24 Mitsubishi Polyester Film Corporation Film for ink jet recording sheet
    US9889695B2 (en) 2014-09-30 2018-02-13 Fujifilm Corporation Image recording method

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    GB0600576D0 (en) * 2006-01-12 2006-02-22 Ici Plc Thermal transfer printing
    JP6116045B2 (en) * 2013-03-01 2017-04-19 ケイミュー株式会社 Painted building materials

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    JPS6357276A (en) * 1986-08-29 1988-03-11 Tomoegawa Paper Co Ltd Recording sheet
    US4889765A (en) * 1987-12-22 1989-12-26 W. R. Grace & Co. Ink-receptive, water-based, coatings
    US4956230A (en) * 1987-04-13 1990-09-11 Minnesota Mining And Manufacturing Company Ink receptive transparency sheet
    EP0484016A1 (en) * 1990-10-24 1992-05-06 Minnesota Mining And Manufacturing Company Transparent liquid absorbent materials for use as ink-receptive layers
    EP0696516A1 (en) * 1994-08-08 1996-02-14 Arkwright Inc. A full range ink jet recording medium
    EP0716929A1 (en) * 1994-12-12 1996-06-19 Arkwright Inc. Ink-jet recording material having a polymer matrix coating

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    JPS6357276A (en) * 1986-08-29 1988-03-11 Tomoegawa Paper Co Ltd Recording sheet
    US4956230A (en) * 1987-04-13 1990-09-11 Minnesota Mining And Manufacturing Company Ink receptive transparency sheet
    US4889765A (en) * 1987-12-22 1989-12-26 W. R. Grace & Co. Ink-receptive, water-based, coatings
    EP0484016A1 (en) * 1990-10-24 1992-05-06 Minnesota Mining And Manufacturing Company Transparent liquid absorbent materials for use as ink-receptive layers
    EP0696516A1 (en) * 1994-08-08 1996-02-14 Arkwright Inc. A full range ink jet recording medium
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    US6403224B1 (en) 1999-06-15 2002-06-11 Mitsubishi Polyester Film Corporation Coated film
    US6455136B1 (en) 1999-06-15 2002-09-24 Mitsubishi Polyester Film Corporation Film for ink jet recording sheet
    EP1072428A1 (en) * 1999-07-22 2001-01-31 Mitsubishi Polyester Film Corporation Ink-jet recording sheet having an intermediate layer containing oxazoline-copolymer
    US9889695B2 (en) 2014-09-30 2018-02-13 Fujifilm Corporation Image recording method

    Also Published As

    Publication number Publication date
    CA2213637A1 (en) 1999-02-22
    JPH1128417A (en) 1999-02-02

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