EP0807310B1 - Insulator with cemented joint and process for producing it - Google Patents
Insulator with cemented joint and process for producing it Download PDFInfo
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- EP0807310B1 EP0807310B1 EP96901742A EP96901742A EP0807310B1 EP 0807310 B1 EP0807310 B1 EP 0807310B1 EP 96901742 A EP96901742 A EP 96901742A EP 96901742 A EP96901742 A EP 96901742A EP 0807310 B1 EP0807310 B1 EP 0807310B1
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- layer
- metal part
- electrical insulator
- shell
- filler
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B17/00—Insulators or insulating bodies characterised by their form
- H01B17/38—Fittings, e.g. caps; Fastenings therefor
Definitions
- the invention relates to an electrical insulator with at least one on one Insulated body cemented armature.
- Isolators and in particular High voltage insulators are used in large numbers in overhead lines and Outdoor switchgear used.
- Most isolators consist of one Insulating body with a non-positive and / or positive fit at the ends of the insulating body attached fittings in the form of metal caps. These serve primarily the Power transmission.
- the outer diameter of the insulated trunk and at Hollow insulators in addition to the wall thickness of the insulator body trunk are all designed according to the mechanical load on the insulator. Each according to the size and type of mechanical stress, the trunk ends and Faucets designed differently.
- the insulating body and the associated Fittings are usually essentially rotationally symmetrical educated.
- Support or / and hollow insulators have predominantly cylindrical trunk ends. Such trunk ends are often round or at the socket crushed crushed stone, which is sintered in a glaze layer; this improves as well as corrugations, corrugations or rough areas in the area the socket the positive and / or positive connection.
- the gap between the valve and shank end is usually with setting or hardening Putty materials such as Cement mortar filled out.
- support or / and hollow insulators become the cylindrical, split trunk ends often with a lean Portland cement with a non-positive and / or positive fit connected to a fitting, usually made of galvanized cast iron or one Aluminum alloy is made.
- EP-A-0 615 259 teaches a method of making a putty joint between an insulating body and a fitting, in which the cement gap only with partially filled with a quick-curing first putty and then with a slowly setting second putty is filled.
- the permanent valve displacement is the one day after routine tests still existing displacement between the underside of the valve and the end face of the insulation trunk as a result of the previously applied routine test load according to EN 50062, DIN VDE 0674, Part 3, November 1992, in relation to the position before the routine test load.
- the valve is mainly moved in the longitudinal direction of the isolator and also tilts when the forces are applied laterally. It can be connected to an expansion of the valve circumference.
- the position of the fitting is measured by means of a dial gauge as the distance between the ground insulating body face and a flat, position-marked bar placed on the fitting face every 90 ° in the direction of the longitudinal axis of the insulator;
- the largest difference value determined on a valve between assigned measured values before and after routine tests is used as the value for the permanent valve displacement.
- the break attempt is one of the more frequently performed mechanical tests, where a hollow insulator is subjected to a bending test in accordance with EN 50062, DIN VDE 0674, Part 3, November 1992, in a multi-stage trial maximum resilience and is therefore tested until it breaks.
- Isolators that are not hollow insulators can in a similar way according to IEC 168, 1988, being checked.
- the insulator is firmly clamped at the foot end and on opposite end drawn perpendicular to its longitudinal axis. Under the The bending stress becomes the maximum load that can be tolerated Understood.
- the invention has for its object an insulator with a putty connection propose both a high bending moment and a low one permanent valve movement guaranteed.
- kits bowl and the fitting different layers There are preferably two, three or four between the kit bowl and the fitting different layers applied.
- Each of these layers can be made several layers of the same material.
- One of those layers can be an adhesive layer applied directly to the valve, which the Adhesion between the fitting and the second one applied to the fitting Layer should improve.
- the insulator can u. a. made of ceramic or glass according to IEC 672, 1980, exist.
- the fittings usually consist of galvanized Cast iron or an aluminum alloy. The shapes of the fittings are specifically designed. You can have a sawtooth profile on the Have side facing the socket.
- the kit bowl is there usually from a set or hardened putty material.
- the layer of the laminate facing the valve which the valve of Protects corrosion, has a layer thickness of 5 to 1000 microns, preferably from 20 to 500, in particular from 80 to 200 microns.
- This layer consists of Use of mortars or cements from an alkali-resistant layer, preferably from alkali resistant corrosion protection materials such as. B. cast resin, reaction or synthetic resin paint, particularly preferably made of two-component epoxy resin.
- the anti-corrosion material is preferred sprayed or spread.
- the slippery layer of the laminate which is a movement between Kit tray and fitting enables and catches, can rather a subordinate Have anti-corrosion function. You can directly on the Corrosion protection layer must be applied.
- This layer can consist of one Bitumen-containing paint, from another lubricious Paint or a lubricant such as Lubricants based Molybdenum disulfide or graphite, metal lubricants, lubricating varnishes, greases and / or Oils exist.
- the material of this layer must be against the putty material Kit bowl made of hardened or water-set putty material and also be largely resistant to the water it may contain. It can be spread or sprayed onto the coated fitting.
- the layer thickness of this layer can be 2 to 1000 ⁇ m, preferably 5 to 200 ⁇ m, in particular 10 to 80 microns.
- the object is achieved by a method for producing a electrical insulator with at least one cemented onto an insulating body Fitting released, in which the insulating body is connected to the fitting via a kit bowl is connected and that is characterized in that the kit bowl facing inside of the valve with at least one Corrosion protection layer and the movement between the kit shell and Armature-enabling layer is coated.
- Mainly mortar and cement can be used as cement material.
- a grouting mortar that is easy to install in the Gap cast between the trunk end of the insulating body and the fitting is particularly easy to process and because of the quick setting Cheap.
- a grout does not need like other mortars and Cements to be shaken.
- valve and insulating body materials are used, using cement, mortar or similar putty materials and, if necessary be cemented with the addition of other substances.
- the isolators according to the invention, especially high-voltage insulators, are particularly suitable as support or / and hollow insulators.
- the individual layers can usually be Sawing the fitting and scratching the layered composite visually well perceive.
- the task could only be accomplished by using at least two layers with different composition of matter and with different properties of the layer materials, wherein the layer facing the kit shell is necessary in order to to enable controlled relative movement between the kit bowl and the fitting, to absorb the forces that occur and the kit bowl in the Tension the fitting so that both high bending moments and also small permanent valve movements due to a controlled Sliding movement can be achieved.
- One applied between the sintered split layer and the kit bowl Layer of bituminous paint has on the permanent Fitting movement has little or no impact.
- This layer preferably has an adhesive effect and with regard to the different Thermal expansion has a dampening effect, especially between the insulating body and Kit bowl.
- Figure 1 shows a longitudinal section through a hollow insulator in the area around the Socket.
- the insulating body 1 has one in its center In the longitudinal direction extending, cylindrical cavity 2.
- grit 4 In the field of Socket 3 is applied to the surface of the insulating body 1 grit 4, which can be sintered with a glaze and possibly also an additional layer 5 can have bituminous paint material.
- the armature 6 shows a sawtooth-like profile on the side facing socket 3 and is covered with a layer composite 7 from two layers 8 and 9.
- the Corrosion protection layer 8 is one of the movement between armature 6 and kit shell 10 enabling and catching lubricious layer 9 overlaid.
- the gap between the insulating body 1 and armature 6 is mainly with set or hardened putty material that forms the kit shell 10, filled out.
- the slippery layer 9 occurs after and for a limited time a load a relative movement between the valve and the kit bowl takes place: When loaded, approximately in the direction of the arrow, then in approximately opposite direction.
- the insulating body end face 11 is approximately parallel to the valve face 12.
- Figure 2 shows the detail II of Figure 1 enlarged.
- a so-called medium-sized earth insulator was used for the tests selected, which is common and for operation as a hollow insulator at 145 kV is provided.
- the insulating bodies of the test specimens were made of alumina porcelain.
- the cylindrical trunk ends had one in the area of the socket Outside diameter of approximately 200 mm.
- the fittings consisted of the aluminum alloy G-AlSi10Mg wa and had an internal sawtooth profile.
- the Fittings were covered over the entire inside with the in Table 1 specified materials coated. The coatings were applied by spraying. Other parameters influencing the cementation were kept constant.
- the structure of the layers and the results of the tests are listed in Tables 1 and 2.
- the layer thicknesses were measured eight times over the valve circumference and are approximate values for the slightly fluctuating layer thickness. Structure of the layers. The layer thicknesses are averages over several tests. The layer thickness of the assembly spray was not determined.
- the break test was carried out in the same orientation of the insulator to the test apparatus as in the fourth loading of the bending test. The load was applied until the hollow insulators broke by bending. In each experiment, the three insulators were broken at the top and bottom. Here, 8 strain gauges were attached perpendicular to the longitudinal direction of the insulator on the outwardly projecting edge of the fitting of each fitting in order to determine the fitting expansions. The values of the bending moments were averaged from 6 measured values in each case. Results of the experiments.
- the measured values for the valve expansion which are used in the wrapping tests according to EN 50062 measured at a nominal bending moment of 20 kNm, confirm as it is known analogously from shrink connections that high Radial stresses allow high bending moments.
- the measured high Strain values are based on a relative movement between the kit shell and Fitting, in which the fitting essentially in the longitudinal direction of the isolator Kit case is pulled away from the insulating body; here the fitting is sawtooth-like profile of the fitting and the kit bowl expanded in diameter.
- the moveable layer is crucial for the high valve expansion Load on the putty. This results in a high on the kit bowl effective radial stress with the consequence of high break values. Farther is released when the kit tray is relieved at the end of each mechanical test controlled slide back of the valve and thus a low permanent Valve shift reached.
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Abstract
Description
Die Erfindung betrifft einen elektrischen Isolator mit mindestens einer auf einen Isolierkörper aufgekitteten Armatur. Isolatoren und insbesondere Hochspannungsisolatoren werden in großer Zahl in Freileitungen und Freiluftschaltanlagen eingesetzt. Die meisten Isolatoren bestehen aus einem Isolierkörper mit kraft- oder/und formschlüssig an den Enden des Isolierkörpers aufgesetzten Armaturen in Form von Metallkappen. Diese dienen vor allem der Kraftübertragung. Der Außendurchmesser des Isolierkörperstrunkes und bei Hohlisolatoren zusätzlich die Wandstärke des Isolierkörperstrunkes werden vor allem entsprechend der mechanischen Belastung des Isolators ausgelegt. Je nach Größe und Art der mechanischen Belastung sind die Strunkenden und Armaturen unterschiedlich gestaltet. Die Isolierkörper und die zugehörigen Armaturen sind üblicherweise im wesentlichen rotationssymmetrisch ausgebildet.The invention relates to an electrical insulator with at least one on one Insulated body cemented armature. Isolators and in particular High voltage insulators are used in large numbers in overhead lines and Outdoor switchgear used. Most isolators consist of one Insulating body with a non-positive and / or positive fit at the ends of the insulating body attached fittings in the form of metal caps. These serve primarily the Power transmission. The outer diameter of the insulated trunk and at Hollow insulators in addition to the wall thickness of the insulator body trunk are all designed according to the mechanical load on the insulator. Each according to the size and type of mechanical stress, the trunk ends and Faucets designed differently. The insulating body and the associated Fittings are usually essentially rotationally symmetrical educated.
Die Strunkenden der hauptsächlich auf Zugkräfte beanspruchten Langstabisolatoren sind meistens konisch ausgebildet; um die erforderliche kraft- oder/und formschlüssige Verbindung zwischen Isolierkörper und Armatur herzustellen, wird der Spalt zwischen Isolierkörperstrunk und Armatur üblicherweise mit einer Bleilegierung ausgegossen.The drunkards of the mainly stressed tensile forces Long rod insulators are mostly conical; to the required force or / and positive connection between the insulating body and the fitting the gap between the insulated trunk and the valve usually cast with a lead alloy.
Stütz- oder/und Hohlisolatoren weisen vorwiegend zylindrische Strunkenden auf. Häufig werden derartige Strunkenden an der Fassungsstelle mit rundem oder gebrochenem Splitt umhüllt, der in einer Glasurschicht versintert wird; dies verbessert ebenso wie Riffelungen, Wellungen oder rauhe Flächen im Bereich der Fassungsstelle den Kraft- oder/und Formschluß. Der Spalt zwischen Armatur und Strunkende wird üblicherweise mit abbindenden oder aushärtenden Kittmaterialien wie z.B. Zementmörtel ausgefüllt. Insbesondere bei Stütz- oder/und Hohlisolatoren werden die zylindrischen, gesplitteten Strunkenden häufig mit einem gemagerten Portlandzement kraft- oder/und formschlüssig mit einer Armatur verbunden, die meistens aus verzinktem Gußeisen oder aus einer Aluminiumlegierung besteht.Support or / and hollow insulators have predominantly cylindrical trunk ends. Such trunk ends are often round or at the socket crushed crushed stone, which is sintered in a glaze layer; this improves as well as corrugations, corrugations or rough areas in the area the socket the positive and / or positive connection. The gap between the valve and shank end is usually with setting or hardening Putty materials such as Cement mortar filled out. Especially with support or / and hollow insulators become the cylindrical, split trunk ends often with a lean Portland cement with a non-positive and / or positive fit connected to a fitting, usually made of galvanized cast iron or one Aluminum alloy is made.
EP-A-0 615 259 lehrt ein Verfahren zum Herstellen einer Kittverbindung zwischen einem Isolierkörper und einer Armatur, bei dem der Kittspalt erst mit einer schnellhärtenden ersten Kittmasse teilweise gefüllt und danach mit einer langsam abbindenden zweiten Kittmasse aufgefüllt wird.EP-A-0 615 259 teaches a method of making a putty joint between an insulating body and a fitting, in which the cement gap only with partially filled with a quick-curing first putty and then with a slowly setting second putty is filled.
Aus der EP 0 613 156 A1 ist ein Isolator bekannt, dessen Armatur zur Befestigung zum Schutz vor Korrosion durch eine Bitumenschicht gegen die Kittverbindung, einem Zement, isoliert ist. Diese Ausführung ist als Stand der Technik in der Figur 1 dargestellt. In Figur 2 ist die Erfindung dargestellt. Dort ist die Armatur ohne Isolationsschicht mittels einer Polyurethanschicht direkt am Isolator befestigt. Die Polyurethanschicht soll bei Vibrationen eine Bewegung zwischen Isolator und Armatur ermöglichen.From EP 0 613 156 A1 an isolator is known, the armature for Fastening for protection against corrosion by a bitumen layer against the Putty, a cement, is insulated. This version is as of Technique shown in Figure 1. The invention is shown in FIG. There is the valve without insulation layer by means of a polyurethane layer directly on Insulator attached. The polyurethane layer is said to move when vibrated allow between isolator and valve.
In der US-PS 4,316,054 ist eine Verbindung zwischen einer Armatur und einem Isolator dargestellt, auf dem zunächst eine Harzmasse aufgetragen ist. Diese Harzmasse trägt eine sogenannte federnde Kappe, eine elastische Schicht, über die eine Metallhülle geschrumpft ist. Diese Metallhülle trennt den Zement von der die Bewegung ermöglichenden elastischen Schicht. Die Armatur grenzt direkt an den Zement, ohne daß eine die Armatur vor Korrosion schützende Schicht vorgesehen ist. In US-PS 4,316,054 there is a connection between a fitting and a Insulator shown, on which a resin mass is first applied. This Resin compound carries a so-called resilient cap, an elastic layer which has shrunk a metal shell. This metal shell separates the cement from the the elastic layer allows movement. The fitting is directly adjacent the cement without a layer protecting the valve from corrosion is provided.
Es ist bekannt, die Innenseiten der Armaturen mit einem bituminösen Anstrich vor dem chemischen Angriff des Portlandzementes/Mörtels zu schützen. Wasser, das sich im Spalt zwischen Armatur und Strunkende befindet, kann sowohl während des Abbindens des Portlandzementes/Mörtels, als auch beim Einsatz der Hochspannungsisolatoren in feuchtem Klima durch Reaktion mit dem Zement/Mörtel einen pH-Wert von etwa 12 bis 13 entwickeln. Darüber hinaus sind auch Ausführungsformen bekannt, bei denen anstelle des bituminösen Anstriches ein aushärtender Epoxidharzanstrich oder eine Kunstharzbeschichtung mit eingebetteten Quarzsandkörnern gewählt wird.It is known to paint the inside of the fittings with a bituminous paint to protect against the chemical attack of Portland cement / mortar. Water that is in the gap between the tap and the end of the trunk can both during setting of the Portland cement / mortar, as well as during Use of the high voltage insulators in a humid climate by reaction with the Cement / mortar develop a pH of around 12 to 13. Furthermore Embodiments are also known in which instead of the bituminous Painting a curing epoxy resin paint or Resin coating with embedded quartz sand grains is selected.
Die Ausführungsformen nach dem Stand der Technik weisen - wenn von einer gelegentlich auf die Armatur aufgetragenen Haftvermittlerschicht abgesehen wird, die die Haftung der nachfolgenden Beschichtung verbessern soll - nur eine einzige Schicht zwischen der Armatur und der abgebundenes Kittmaterial enthaltenden Kittschale auf. Diese einzige Schicht kann aus mehreren Lagen des gleichen Materials bestehen. Es wurde in Versuchen ermittelt, daß es mit dieser einen Schicht zwischen Armatur und Kittschale nach dem Stand der Technik nicht möglich ist, sowohl hohe Biegebruchmomente bei Umbruchversuchen, als auch eine niedrige bleibende Armaturenverschiebung nach Stückprüfungen mit Biege- oder/und Innendruckbelastung zu realisieren. Entweder wurden - wie bei den bituminösen Anstrichen - nach Stückprüfungen gemäß EN 50062 hohe bleibende Armaturenverschiebungen und in Umbruchversuchen hohe Biegebruchmomente erzielt oder die bleibenden Armaturenverschiebungen waren - wie bei Epoxidharz- bzw. besandetem Kunstharzanstrich - gering, wobei sich gleichzeitig eine erhöhte Anfälligkeit für Scheibenbrüche und niedrige Biegebruchmomente ergab. Als Scheibenbruch wird das Abschiefern des Isolierkörpers an seinen Enden im wesentlichen senkrecht zur Längsachse bezeichnet.The embodiments according to the prior art - if by one occasionally applied adhesive layer applied to the valve that should improve the adhesion of the subsequent coating - only one only layer between the fitting and the set putty containing kit bowl. This single layer can consist of several layers of the same material. It has been determined in experiments that it works with this one layer between armature and kit bowl according to the state of the Technology is not possible with both high bending moments Attempting to wrap, as well as a low permanent valve movement to be implemented after routine tests with bending or / and internal pressure loading. Either - as with bituminous paints - after routine tests according to EN 50062 high permanent valve displacements and in Trying to achieve high bending moments or the permanent ones Faucet shifts were - as with epoxy or sanded Synthetic resin painting - low, whereby at the same time there is an increased susceptibility to Disc breaks and low bending moments resulted. As a broken window is the peeling of the insulating body at its ends essentially perpendicular to the longitudinal axis designated.
Die bleibende Armaturenverschiebung ist die einen Tag nach Stückprüfungen noch vorhandene Verschiebung zwischen Armaturenunterseite und der Stirnfläche des Isolierkörperstrunkes als Folge der zuvor aufgebrachten Stückprüfbelastung nach EN 50062, DIN VDE 0674, Teil 3, November 1992, in Bezug auf die Lage vor der Stückprüfbelastung. Die Armaturenverschiebung erfolgt vorwiegend in Längsrichtung des Isolators und führt bei seitlich angreifenden Kräften auch zu einer Verkippung. Sie kann mit einer Dehnung des Armaturenumfangs verbunden sein. Die Lage der Armatur wird mittels einer Meßuhr als Abstand zwischen der geschliffenen Isolierkörperstirnfläche und einem ebenen, lagemarkierten, auf die Armaturstirnfläche aufgelegten Balken alle 90° in Richtung der Isolatorlängsachse gemessen; der größte an einer Armatur ermittelte Differenzwert zwischen zugeordneten Meßwerten vor und nach Stückprüfungen wird als Wert für die bleibende Armaturenverschiebung verwendet. Je größer die bleibende Armaturenverschiebung ist und je stärker Zerrüttungen der Kittschale aufgrund von Bewegungen zwischen Splitt und Kittschale sind, desto größer ist das Risiko, daß ein auf die Isolierkörperstirnfläche aufgelegtes Dichtungssystem nicht auf Dauer gasdicht ist. Undichtigkeiten sind bei den mit SF6-Gas gefüllten Apparateisolatoren unbedingt zu vermeiden.The permanent valve displacement is the one day after routine tests still existing displacement between the underside of the valve and the end face of the insulation trunk as a result of the previously applied routine test load according to EN 50062, DIN VDE 0674, Part 3, November 1992, in relation to the position before the routine test load. The valve is mainly moved in the longitudinal direction of the isolator and also tilts when the forces are applied laterally. It can be connected to an expansion of the valve circumference. The position of the fitting is measured by means of a dial gauge as the distance between the ground insulating body face and a flat, position-marked bar placed on the fitting face every 90 ° in the direction of the longitudinal axis of the insulator; The largest difference value determined on a valve between assigned measured values before and after routine tests is used as the value for the permanent valve displacement. The greater the permanent movement of the fittings and the greater the disruption of the kit shell due to movements between grit and kit shell, the greater the risk that a sealing system placed on the face of the insulating body is not permanently gas-tight. Leaks in the device insulators filled with SF 6 gas must be avoided.
Der Umbruchversuch ist eine der öfter ausgeführten mechanischen Prüfungen, bei denen ein Hohlisolator bei einer Biegeprüfung entsprechend EN 50062, DIN VDE 0674, Teil 3, November 1992, in einem mehrstufigen Versuch auf maximale Belastbarkeit und damit bis zum Bruch getestet wird. Isolatoren, die keine Hohlisolatoren sind, können in ähnlicher Weise gemäß IEC 168, 1988, geprüft werden. Hierbei wird der Isolator am Fußende fest eingespannt und am entgegengesetzten Ende senkrecht zu seiner Längsachse gezogen. Unter dem Biegebruchmoment wird die hierbei maximal ertragene Beanspruchung verstanden. The break attempt is one of the more frequently performed mechanical tests, where a hollow insulator is subjected to a bending test in accordance with EN 50062, DIN VDE 0674, Part 3, November 1992, in a multi-stage trial maximum resilience and is therefore tested until it breaks. Isolators that are not hollow insulators, can in a similar way according to IEC 168, 1988, being checked. Here, the insulator is firmly clamped at the foot end and on opposite end drawn perpendicular to its longitudinal axis. Under the The bending stress becomes the maximum load that can be tolerated Understood.
Der Erfindung liegt die Aufgabe zugrunde, einen Isolator mit einer Kittverbindung vorzuschlagen, die sowohl ein hohes Biegebruchmoment, als auch eine geringe bleibende Armaturenverschiebung gewährleistet. Darüber hinaus bestand die Aufgabe, die Fertigung derartiger Isolatoren möglichst einfach zu gestalten.The invention has for its object an insulator with a putty connection propose both a high bending moment and a low one permanent valve movement guaranteed. In addition, the Task to make the manufacture of such isolators as simple as possible.
Diese Aufgabe wird erfindungsgemäß mit einem elektrischen Isolator mit mindestens einer auf einen Isolierkörper aufgekitteten Armatur gelöst, bei dem der Isolierkörper über eine Kittschale mit der Armatur verbunden ist, der dadurch gekennzeichnet ist, daß auf der Armatur zwischen der Kittschale und der Armatur ein Schichtverbund aufgetragen ist, der mindestens zwei Schichten aus unterschiedlichen Materialien enthält, daß mindestens eine der Schichten die Armatur vor Korrosion schützt und daß mindestens eine andere Schicht eine Bewegung zwischen Kittschale und Armatur ermöglicht.This object is achieved with an electrical insulator solved at least one fitting cemented onto an insulating body, in which the insulating body is connected to the fitting via a kit shell, which thereby is characterized in that on the fitting between the kit bowl and the Armature a layer composite is applied, which consists of at least two layers contains different materials that at least one of the layers Fitting protects against corrosion and that at least one other layer is a Allows movement between kit bowl and fitting.
Vorzugsweise sind zwischen der Kittschale und der Armatur zwei, drei oder vier verschiedenartige Schichten aufgetragen. Jede dieser Schichten kann aus mehreren Lagen des gleichen Materials aufgebaut sein. Eine dieser Schichten kann eine direkt auf der Armatur aufgetragene Haftvermittlerschicht sein, die die Haftung zwischen der Armatur und der zweiten auf der Armatur aufgetragenen Schicht verbessern soll.There are preferably two, three or four between the kit bowl and the fitting different layers applied. Each of these layers can be made several layers of the same material. One of those layers can be an adhesive layer applied directly to the valve, which the Adhesion between the fitting and the second one applied to the fitting Layer should improve.
Die Isolierkörper können u. a. aus Keramik oder Glas entsprechend IEC 672, 1980, bestehen. Die Armaturen bestehen üblicherweise aus verzinktem Gußeisen oder einer Aluminiumlegierung. Die Formen der Armaturen sind spezifisch ausgelegt. Sie können ein sägezahnartiges Profil auf der der Fassungsstelle zugewandten Seite aufweisen. Die Kittschale besteht üblicherweise aus einem abgebundenen oder ausgehärteten Kittmaterial.The insulator can u. a. made of ceramic or glass according to IEC 672, 1980, exist. The fittings usually consist of galvanized Cast iron or an aluminum alloy. The shapes of the fittings are specifically designed. You can have a sawtooth profile on the Have side facing the socket. The kit bowl is there usually from a set or hardened putty material.
Die der Armatur zugewandte Schicht des Schichtverbundes, die die Armatur von Korrosion schützt, weist eine Schichtdicke von 5 bis 1000 µm, bevorzugt von 20 bis 500, insbesondere von 80 bis 200 µm auf. Diese Schicht besteht bei Verwendung von Mörteln oder Zementen aus einer laugenbeständigen Schicht, vorzugsweise aus gegen Laugen beständige Korrosionsschutzmaterialien wie z. B. Gießharz, Reaktions- oder Kunstharzlack, besonders bevorzugt aus Zweikomponenten-Epoxidharz. Das Korrosionsschutzmaterial wird vorzugsweise aufgespritzt oder aufgestrichen.The layer of the laminate facing the valve, which the valve of Protects corrosion, has a layer thickness of 5 to 1000 microns, preferably from 20 to 500, in particular from 80 to 200 microns. This layer consists of Use of mortars or cements from an alkali-resistant layer, preferably from alkali resistant corrosion protection materials such as. B. cast resin, reaction or synthetic resin paint, particularly preferably made of two-component epoxy resin. The anti-corrosion material is preferred sprayed or spread.
Die gleitfähige Schicht des Schichtverbundes, die eine Bewegung zwischen Kittschale und Armatur ermöglicht und auffängt, kann eher eine untergeordnete Korrosionsschutzfunktion besitzen. Sie kann direkt auf der Korrosionsschutzschicht aufgetragen sein. Diese Schicht kann aus einem Bitumen-haltigen Anstrichmaterial, aus einem anderen gleitfähigen Anstrichmaterial oder einem Schmierstoff wie z.B. Schmiermitteln auf Basis Molybdändisulfid oder Grafit, Metallschmiermitteln, Gleitlacken, Fetten oder/und Ölen bestehen. Das Material dieser Schicht muß gegen das Kittmaterial, die Kittschale aus ausgehärtetem oder mit Wasser abgebundenem Kittmaterial und auch weitestgehend gegen das gegebenenfalls enthaltene Wasser resistent sein. Es kann auf die beschichtete Armatur aufgestrichen oder aufgespritzt werden. Die Schichtdicke dieser Schicht kann 2 bis 1000 µm, bevorzugt 5 bis 200 µm, insbesondere 10 bis 80 µm betragen.The slippery layer of the laminate, which is a movement between Kit tray and fitting enables and catches, can rather a subordinate Have anti-corrosion function. You can directly on the Corrosion protection layer must be applied. This layer can consist of one Bitumen-containing paint, from another lubricious Paint or a lubricant such as Lubricants based Molybdenum disulfide or graphite, metal lubricants, lubricating varnishes, greases and / or Oils exist. The material of this layer must be against the putty material Kit bowl made of hardened or water-set putty material and also be largely resistant to the water it may contain. It can be spread or sprayed onto the coated fitting. The layer thickness of this layer can be 2 to 1000 μm, preferably 5 to 200 μm, in particular 10 to 80 microns.
Desweiteren wird die Aufgabe durch ein Verfahren zur Herstellung eines elektrischen Isolators mit mindestens einer auf einen Isolierkörper aufgekitteten Armatur gelöst, bei dem der Isolierkörper über eine Kittschale mit der Armatur verbunden wird und das dadurch gekennzeichnet ist, daß die der Kittschale zugewandte Innenseite der Armatur mindestens mit einer Korrosionsschutzschicht und einer die Bewegung zwischen Kittschale und Armatur ermöglichenden Schicht beschichtet wird.Furthermore, the object is achieved by a method for producing a electrical insulator with at least one cemented onto an insulating body Fitting released, in which the insulating body is connected to the fitting via a kit bowl is connected and that is characterized in that the kit bowl facing inside of the valve with at least one Corrosion protection layer and the movement between the kit shell and Armature-enabling layer is coated.
Als Kittmaterial können vor allem Mörtel und Zemente verwendet werden. Unter den Mörteln und Zementen ist ein Vergußmörtel, der in einfacher Weise in den Spalt zwischen dem Strunkende des Isolierkörpers und der Armatur gegossen wird, besonders leicht zu verarbeiten und wegen des schnellen Abbindens günstig. Außerdem braucht ein Vergußmörtel nicht wie andere Mörtel und Zemente eingerüttelt zu werden.Mainly mortar and cement can be used as cement material. Under The mortars and cements is a grouting mortar that is easy to install in the Gap cast between the trunk end of the insulating body and the fitting is particularly easy to process and because of the quick setting Cheap. In addition, a grout does not need like other mortars and Cements to be shaken.
Der Verbund mit mehreren Schichten zwischen Armatur und Kittschale kann bei allen bekannten Armaturen- und Isolierkörperwerkstoffen angewandt werden, die mittels Zement, Mörtel oder ähnlichen Kittmaterialien und gegebenenfalls unter Zusatz weiterer Stoffe gekittet werden. Die erfindungsgemäßen Isolatoren, vor allem Hochspannungsisolatoren, eignen sich insbesondere als Stütz- oder/und Hohlisolatoren. Üblicherweise lassen sich die einzelnen Schichten beim Aufsägen der Armatur und Anritzen des Schichtenverbundes visuell gut wahrnehmen.The combination with several layers between the fitting and kit bowl can be used all known valve and insulating body materials are used, using cement, mortar or similar putty materials and, if necessary be cemented with the addition of other substances. The isolators according to the invention, especially high-voltage insulators, are particularly suitable as support or / and hollow insulators. The individual layers can usually be Sawing the fitting and scratching the layered composite visually well perceive.
Es war überraschend, daß die Aufgabe nur durch die Anwendung von mindestens zwei Schichten mit unterschiedlicher Stoffzusammensetzung und mit unterschiedlichen Eigenschaften der Schichtmaterialien ermöglicht wurde, wobei die der Kittschale zugewandte Schicht notwendig ist, um eine kontrollierte Relativbewegung zwischen Kittschale und Armatur zu ermöglichen, um die hierbei auftretenden Kräfte aufzufangen und die Kittschale in der Armatur zu verspannen, damit sowohl gleichzeitig hohe Biegebruchmomente, als auch geringe bleibende Armaturenverschiebungen infolge einer kontrollierten Gleitbewegung erzielt werden.It was surprising that the task could only be accomplished by using at least two layers with different composition of matter and with different properties of the layer materials, wherein the layer facing the kit shell is necessary in order to to enable controlled relative movement between the kit bowl and the fitting, to absorb the forces that occur and the kit bowl in the Tension the fitting so that both high bending moments and also small permanent valve movements due to a controlled Sliding movement can be achieved.
Eine zwischen der versinterten Splittschicht und der Kittschale aufgebrachte Schicht aus bituminösem Anstrichmaterial hat auf die bleibende Armaturenverschiebung nur einen geringen oder keinen Einfluß. Diese Schicht hat vorzugsweise eine klebende Wirkung und bezüglich der unterschiedlichen Wärmedehnung eine dämpfende Wirkung, besonders zwischen Isolierkörper und Kittschale.One applied between the sintered split layer and the kit bowl Layer of bituminous paint has on the permanent Fitting movement has little or no impact. This layer preferably has an adhesive effect and with regard to the different Thermal expansion has a dampening effect, especially between the insulating body and Kit bowl.
Im folgenden wird die Erfindung anhand einer Ausführungsform beispielhaft erläutert:In the following, the invention is exemplified using an embodiment explains:
Figur 1 stellt einen Längsschnitt durch einen Hohlisolator im Bereich um die
Fassungsstelle dar. Der Isolierkörper 1 weist in seiner Mitte einen sich in
Längsrichtung erstreckenden, zylindrischen Hohlraum 2 auf. Im Bereich der
Fassungsstelle 3 ist auf die Oberfläche des Isolierkörpers 1 Splitt 4 aufgebracht,
der mit einer Glasur versintert sein kann und ggbfs. auch zusätzlich eine Schicht
5 aus bituminösem Anstrichmaterial aufweisen kann. Die Armatur 6 zeigt ein
sägezahnartiges Profil auf der zur Fassungsstelle 3 zugewandten Seite und ist
mit einem Schichtverbund 7 aus zwei Schichten 8 und 9 bedeckt. Die
Korrosionsschutzschicht 8 wird von einer die Bewegung zwischen Armatur 6
und Kittschale 10 ermöglichenden und auffangenden, gleitfähigen Schicht 9
überlagert. Der Spalt zwischen Isolierkörper 1 und Armatur 6 ist vor allem mit
abgebundenem oder ausgehärtetem Kittmaterial, das die Kittschale 10 bildet,
ausgefüllt. In der gleitfähigen Schicht 9 findet bei und über begrenzte Zeit nach
einer Belastung eine Relativbewegung zwischen Armatur und Kittschale statt:
Bei Belastung annähernd in Pfeilrichtung, danach in annähernd
entgegengesetzter Richtung. Die Isolierkörperstirnfläche 11 liegt in etwa parallel
zur Armaturstirnfläche 12.Figure 1 shows a longitudinal section through a hollow insulator in the area around the
Socket. The insulating body 1 has one in its center
In the longitudinal direction extending,
Figur 2 gibt den Ausschnitt II der Figur 1 vergrößert wieder.Figure 2 shows the detail II of Figure 1 enlarged.
Im folgenden werden die Beispiele 1 und 2 als Vergleichsbeispiele und die erfindungsgemäßen Beispiele 3 bis 6 näher erläutert:In the following, Examples 1 and 2 are used as comparative examples and Examples 3 to 6 according to the invention are explained in more detail:
Für die Prüfungen wurde ein sogenannter Erdisolator mittlerer Größe ausgewählt, der gängig ist und für einen Betrieb als Hohlisolator bei 145 kV vorgesehen ist. Die Isolierkörper der Prüflinge bestanden aus Tonerdeporzellan. Die zylindrischen Strunkenden hatten im Bereich der Fassungsstelle einen Außendurchmesser von etwa 200 mm. Hierauf wurde ein runder Splitt aufgetragen, der mit einer Glasur versintert wurde; darauf wurde ein bituminöser Anstrich aufgebracht. Die Armaturen bestanden aus der Aluminiumlegierung G-AlSi10Mg wa und wiesen eine innenliegende Sägezahnprofilierung auf. Die Armaturen wurden über die ganze Innenseite mit den in der Tabelle 1 angegebenen Materialien beschichtet. Der Auftrag der Beschichtungen erfolgte durch Aufspritzen. Andere, die Kittung beeinflussende Parameter wurden konstant gehalten.A so-called medium-sized earth insulator was used for the tests selected, which is common and for operation as a hollow insulator at 145 kV is provided. The insulating bodies of the test specimens were made of alumina porcelain. The cylindrical trunk ends had one in the area of the socket Outside diameter of approximately 200 mm. Then there was a round grit applied, which was sintered with a glaze; on it became a bituminous Paint applied. The fittings consisted of the aluminum alloy G-AlSi10Mg wa and had an internal sawtooth profile. The Fittings were covered over the entire inside with the in Table 1 specified materials coated. The coatings were applied by spraying. Other parameters influencing the cementation were kept constant.
Der Aufbau der Schichten und die Ergebnisse der Versuche werden in den
Tabellen 1 und 2 aufgeführt. Die Schichtdicken wurden jeweils achtmal über
den Armaturenumfang gemessen und gelten als Näherungswerte für die leicht
schwankende Schichtdicke.
Einen Tag vor dem Umbruchversuch wurden folgende Stückprüfungen durchgeführt: Zuerst ein Biegeversuch auf 70 % des Nennbiegemomentes an jeweils 3 gleichartig hergestellten Prüflingen und anschließend ein Innendruckversuch mit einer Minute Haltezeit nach EN 50062 auf bis zu annähernd 70 % des Mindestberstdruckes. Bei den Biegeversuchen wurden die oberen und unteren Enden getrennt geprüft; die Krafteinleitung erfolgte am zylindrischen Porzellankörper außerhalb der Armatur. Die Prüflinge wurden beim Biegeversuch jeweils um 90° versetzt über 10 s belastet. Bei der anschließenden visuellen Prüfung wurden an keinem der Prüflinge Beschädigungen als Folge der Stückprüfungen festgestellt. Am Tag des Umbruchversuches wurde die bleibende Armaturenverschiebung, die aus dem Biegeversuch und dem Innendruckversuch herrühren, bestimmt.The following routine tests were carried out one day before the break attempt carried out: First a bending test to 70% of the nominal bending moment 3 test specimens produced in the same way and then one Internal pressure test with a one minute hold time according to EN 50062 up to approximately 70% of the minimum burst pressure. In the bending tests, the upper and lower ends tested separately; the force was introduced on cylindrical porcelain body outside the fitting. The test subjects were at Bending test, each offset by 90 °, loaded for 10 s. In the Subsequent visual inspections were performed on none of the examinees Damage found as a result of routine tests. On the day of The permanent valve movement resulting from the Bending test and the internal pressure test, determined.
Der Umbruchversuch erfolgte in der gleichen Ausrichtung des Isolators zur
Prüfapparatur wie bei der vierten Belastung des Biegeversuches. Die Belastung
erfolgte bis zum Bruch der Hohlisolatoren durch Biegung. Bei jedem Versuch
wurden die drei Isolatoren jeweils oben und unten gebrochen. Hierbei wurden
am nach außen ragenden Armaturenrand jeder Armatur 8 Dehnungsmeßstreifen
senkrecht zur Isolatorlängsrichtung angebracht, um die Armaturendehnungen zu
ermitteln. Die Werte der Biegebruchmomente wurden aus jeweils 6 Meßwerten
gemittelt.
Wie die in Tabelle 2 wiedergegebenen Versuchsergebnisse zeigen, wurden bei den erfindungsgemäßen Beispielen gegenüber den Vergleichsbeispielen ausreichend hohe Biegebruchmomente und geringe bleibende Armaturenverschiebungen erzielt. Gegenüber der Variante mit Epoxidharzanstrich (VB 2) konnte der Meßwert des jeweils kleinsten Biegebruchmomentes um etwa 50 % gesteigert werden. Die bleibende Armaturenverschiebung liegt im Bereich der als sehr niedrig einzustufenden Armaturenverschiebung der Variante mit Epoxidharzanstrich (VB 2).As the test results shown in Table 2 show, at the examples according to the invention compared to the comparative examples sufficiently high bending moments and low permanent ones Valve shifts achieved. Compared to the variant with Epoxy resin paint (VB 2) could measure the smallest Bending moment can be increased by about 50%. The permanent one Valve displacement is in the range of very low Fitting the variant with epoxy resin paint (VB 2).
Die Meßwerte zur Armaturendehnung, die bei den Umbruchversuchen gemäß EN 50062 bei einem Nennbiegemoment von 20 kNm gemessen wurden, bestätigen, wie es analog von Schrumpfverbindungen bekannt ist, daß hohe Radialspannungen hohe Biegebruchmomente gewähren. Die gemessenen hohen Dehnungswerte beruhen auf einer Relativbewegung zwischen Kittschale und Armatur, bei der die Armatur im wesentlichen in Isolatorlängsrichtung aus der Kittschale weg vom Isolierkörper gezogen wird; hierbei wird die Armatur bei sägezahnartigem Profil der Armatur und der Kittschale im Durchmesser gedehnt. Die bewegliche Schicht ist ausschlaggebend für die hohe Armaturendehnung bei Belastung des Kittverbundes. Daraus resultiert eine hohe, auf die Kittschale wirkende Radialspannung mit der Folge von hohen Umbruchwerten. Weiterhin wird bei Entlastung der Kittschale am Ende jeder mechanischen Prüfung ein kontrolliertes Zurückgleiten der Armatur und somit eine niedrige bleibende Armaturenverschiebung erreicht.The measured values for the valve expansion, which are used in the wrapping tests according to EN 50062 measured at a nominal bending moment of 20 kNm, confirm as it is known analogously from shrink connections that high Radial stresses allow high bending moments. The measured high Strain values are based on a relative movement between the kit shell and Fitting, in which the fitting essentially in the longitudinal direction of the isolator Kit case is pulled away from the insulating body; here the fitting is sawtooth-like profile of the fitting and the kit bowl expanded in diameter. The moveable layer is crucial for the high valve expansion Load on the putty. This results in a high on the kit bowl effective radial stress with the consequence of high break values. Farther is released when the kit tray is relieved at the end of each mechanical test controlled slide back of the valve and thus a low permanent Valve shift reached.
Claims (13)
- Electrical insulator having at least one metal part (6) cemented to an insulating body (1), the insulating body (1) being connected by means of a shell of filler (10) to the metal part (6), characterised in that between the shell of filler (10) and the metal part (6) there is applied to the metal part (6) a laminate composite (7), which contains at least two layers (8, 9) of different materials, at least one of the layers protects the metal part against corrosion and at least one other layer allows movement between the shell of filler (1) and the metal part (6).
- Electrical insulator according to claim 1, characterised in that the layer (8) having the anti-corrosive function has a layer thickness of from 5 to 1000 µm, preferably from 20 to 500 µm, especially from 80 to 200 µm.
- Electrical insulator according to claim 1 or 2, characterised in that the layer (9) allowing movement between shell of filler and metal part has a layer thickness of from 2 to 1000 µm, preferably from 5 to 200 µm, especially from 10 to 80 µm.
- Electrical insulator according to any one of claims 1 to 3, characterised in that two, three or four layers of different materials are applied to the metal part (6).
- Electrical insulator according to any one of claims 1 to 4, characterised in that one of at least three layers is an adhesion-promoting layer applied to the metal part (6).
- Electrical insulator according to any one of claims 1 to 5, characterised in that in the region of a base part (3) a grit layer (4) is applied to the insulating body (1), to which grit layer a layer (5) of a bituminous coating material is preferably applied.
- Electrical insulator according to any one of claims 1 to 6, characterised in that the layer (8) having the anti-corrosive function contains a casting resin or a reaction resin or synthetic resin lacquer, especially an epoxy resin.
- Electrical insulator according to any one of claims 1 to 7, characterised in that the layer (9) allowing movement between shell of filler (10) and metal part (6) contains an anti-friction coating material or lubricant.
- Electrical insulator according to claim 8, characterised in that the anti-friction coating material or lubricant is a bitumen-containing coating material, lubricant based on molybdenum disulphide or graphite, anti-seize lacquer, metal lubricant, grease or oil.
- Method for the manufacture of an electrical insulator having at least one metal part (6) cemented to an insulating body (1), the insulating body (1) being connected by means of a shell of filler (10) to the metal part (6), characterised in that the inside of the metal part (6) facing the shell of filler (10) is coated with at least one layer (8) having an anti-corrosive function and a layer (9) allowing movement between the shell of filler and metal part.
- Method for the manufacture of an electrical insulator according to claim 10, characterised in that the material for the layer (8) having the anti-corrosive function is spread onto or sprayed onto the metal part (6) or onto an adhesion-promoting layer applied to the metal part (6).
- Method for the manufacture of an electrical insulator according to claim 10, characterised in that the layer (9) allowing movement between the shell of filler (10) and the metal part (6) is spread onto or sprayed onto the coated metal part (6).
- Method for the manufacture of an electrical insulator according to any one of claims 10 to 12, characterised in that a casting compound is poured as filler material into the gap between insulating body (1) and coated metal part (6) and sets there.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19503324 | 1995-02-02 | ||
DE19503324A DE19503324A1 (en) | 1995-02-02 | 1995-02-02 | Insulator with putty joint and process for its manufacture |
PCT/EP1996/000226 WO1996024144A1 (en) | 1995-02-02 | 1996-01-19 | Insulator with cemented joint and process for producing it |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0807310A1 EP0807310A1 (en) | 1997-11-19 |
EP0807310B1 true EP0807310B1 (en) | 1998-10-14 |
Family
ID=7752969
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96901742A Revoked EP0807310B1 (en) | 1995-02-02 | 1996-01-19 | Insulator with cemented joint and process for producing it |
Country Status (15)
Country | Link |
---|---|
US (1) | US5985087A (en) |
EP (1) | EP0807310B1 (en) |
JP (1) | JPH10513004A (en) |
CN (1) | CN1089936C (en) |
AT (1) | ATE172321T1 (en) |
BR (1) | BR9607580A (en) |
CA (1) | CA2212255C (en) |
CZ (1) | CZ289279B6 (en) |
DE (2) | DE19503324A1 (en) |
ES (1) | ES2122783T3 (en) |
FI (1) | FI960446L (en) |
IL (1) | IL116979A (en) |
PL (1) | PL178732B1 (en) |
WO (1) | WO1996024144A1 (en) |
ZA (1) | ZA96775B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2765385B1 (en) * | 1997-06-26 | 2003-12-05 | Gec Alsthom T & D Sa | COMPOSITE INSULATOR HANGER |
IT1299049B1 (en) * | 1998-04-08 | 2000-02-07 | Abb Research Ltd | ISOLATOR ESPECIALLY FOR ELECTRICAL TRANSMISSION AND DISTRIBUTION LINES, HAVING IMPROVED RESISTANCE TO THE |
DE10213111A1 (en) * | 2002-03-23 | 2003-10-02 | Tesa Ag | Multi-layer laser transfer film for permanent marking of components |
ATE521070T1 (en) * | 2007-05-23 | 2011-09-15 | Abb Technology Ag | HIGH VOLTAGE INSULATOR AND COOLING ELEMENT WITH THIS HIGH VOLTAGE INSULATOR |
US10584475B1 (en) * | 2019-06-19 | 2020-03-10 | Soleman Abdi Idd | Method and system for construction and building |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3576938A (en) * | 1969-11-07 | 1971-05-04 | Gen Electric | Electrical insulator with polymer-containing joint between the porcelain and the hardware |
FR2292318A1 (en) * | 1974-11-25 | 1976-06-18 | Ceraver | IMPROVEMENT IN THE BOND BETWEEN CORE AND REINFORCEMENTS OF STRUCTURES CONTAINING A CORE OF AGGLOMERATED FIBERS |
US4267402A (en) * | 1978-08-07 | 1981-05-12 | Gould Inc. | Polymer concrete body with vibration molded threads, method of making same, and electrical insulator provided with the same |
FR2445596A2 (en) * | 1978-12-27 | 1980-07-25 | Ceraver | IMPROVEMENT IN THE LINK BETWEEN CORE AND STRUCTURES OF STRUCTURES COMPRISING A CORE OF AGGLOMERATED FIBERS |
FR2499301A1 (en) * | 1981-02-05 | 1982-08-06 | Ceraver | ORGANIC INSULATOR COMPRISING A LAMINATE SOUL |
DE4212146C1 (en) * | 1992-04-10 | 1993-08-19 | Siemens Ag, 8000 Muenchen, De | Light conductor with optical fibres inside three consecutive layers - has its fibres loosely embedded in filling paste, then inside second polymer with higher thermal stability and outermost extruded sleeve |
FR2702081B1 (en) * | 1993-02-26 | 1995-05-12 | Gec Alsthom T & D Sa | Insulator. |
DE59302607D1 (en) * | 1993-03-12 | 1996-06-20 | Gec Alsthom T & D Ag | Method for making a cement connection between an isolator and a fitting and isolator arrangement |
WO1995026560A1 (en) * | 1994-03-28 | 1995-10-05 | Ngk Insulators, Ltd. | Conductive insulator |
-
1995
- 1995-02-02 DE DE19503324A patent/DE19503324A1/en not_active Ceased
-
1996
- 1996-01-19 ES ES96901742T patent/ES2122783T3/en not_active Expired - Lifetime
- 1996-01-19 US US08/875,691 patent/US5985087A/en not_active Expired - Fee Related
- 1996-01-19 CA CA002212255A patent/CA2212255C/en not_active Expired - Fee Related
- 1996-01-19 JP JP8523204A patent/JPH10513004A/en not_active Ceased
- 1996-01-19 BR BR9607580A patent/BR9607580A/en active Search and Examination
- 1996-01-19 EP EP96901742A patent/EP0807310B1/en not_active Revoked
- 1996-01-19 WO PCT/EP1996/000226 patent/WO1996024144A1/en not_active Application Discontinuation
- 1996-01-19 CN CN96191727A patent/CN1089936C/en not_active Expired - Fee Related
- 1996-01-19 AT AT96901742T patent/ATE172321T1/en not_active IP Right Cessation
- 1996-01-19 CZ CZ19972420A patent/CZ289279B6/en not_active IP Right Cessation
- 1996-01-19 DE DE59600669T patent/DE59600669D1/en not_active Expired - Fee Related
- 1996-01-19 PL PL96321681A patent/PL178732B1/en not_active IP Right Cessation
- 1996-01-31 FI FI960446A patent/FI960446L/en not_active IP Right Cessation
- 1996-01-31 IL IL11697996A patent/IL116979A/en not_active IP Right Cessation
- 1996-02-01 ZA ZA96775A patent/ZA96775B/en unknown
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FI960446A0 (en) | 1996-01-31 |
PL321681A1 (en) | 1997-12-22 |
ZA96775B (en) | 1996-08-12 |
JPH10513004A (en) | 1998-12-08 |
PL178732B1 (en) | 2000-06-30 |
CN1089936C (en) | 2002-08-28 |
DE59600669D1 (en) | 1998-11-19 |
DE19503324A1 (en) | 1996-08-08 |
WO1996024144A1 (en) | 1996-08-08 |
BR9607580A (en) | 1998-07-07 |
IL116979A0 (en) | 1996-05-14 |
CZ242097A3 (en) | 1997-11-12 |
ATE172321T1 (en) | 1998-10-15 |
FI960446L (en) | 1996-08-03 |
IL116979A (en) | 2000-07-16 |
CA2212255A1 (en) | 1996-08-08 |
US5985087A (en) | 1999-11-16 |
CZ289279B6 (en) | 2001-12-12 |
ES2122783T3 (en) | 1998-12-16 |
CA2212255C (en) | 2004-10-26 |
CN1172546A (en) | 1998-02-04 |
EP0807310A1 (en) | 1997-11-19 |
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