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EP0783035A3 - Bleaching system containing Bis-and-Tris-(mu-oxo)-di-manganese complex salts - Google Patents

Bleaching system containing Bis-and-Tris-(mu-oxo)-di-manganese complex salts Download PDF

Info

Publication number
EP0783035A3
EP0783035A3 EP96120743A EP96120743A EP0783035A3 EP 0783035 A3 EP0783035 A3 EP 0783035A3 EP 96120743 A EP96120743 A EP 96120743A EP 96120743 A EP96120743 A EP 96120743A EP 0783035 A3 EP0783035 A3 EP 0783035A3
Authority
EP
European Patent Office
Prior art keywords
oxo
tris
complex salts
manganese complex
cycloalkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP96120743A
Other languages
German (de)
French (fr)
Other versions
EP0783035A2 (en
EP0783035B1 (en
Inventor
Ahmed Dr. Tafesh
Matthias Prof. Dr. Beller
Vera Friderichs
Gerd Dr. Reinhardt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Produkte Deutschland GmbH
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of EP0783035A2 publication Critical patent/EP0783035A2/en
Publication of EP0783035A3 publication Critical patent/EP0783035A3/en
Application granted granted Critical
Publication of EP0783035B1 publication Critical patent/EP0783035B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)

Abstract

Bleach systems contain bis- and tris-( mu -oxo)-di-manganese complex salts of formula (I) ÄLMn( mu -O)a( mu -OAc)bMnLÜ (x+) Ay; in which Ac = 2-8C acyl; a = 1-3; b = 0 if a = 2 or 3 or b = 2 if a = 1; x = 2 or 3; A = a mono- or di-valent anion; y = the equivalent amount of anion A to balance the positive charges; L = a ligand of formula R-N(Q)2 (II) or (Q)2N-(C(R<1>)2)g-N(Q)2 (III); Q = a group of formula (i); R = 1-12C alkyl, 5-10C cycloalkyl, phenyl, NH2, NHR<2>, N(R<2>)2, OH, OR<2> or COOH; R<1> = H, 1-12C alkyl, 5-10C cycloalkyl, NH2, NHR<2>, N(R<2>)2, OH, OR<2>, COOH, COOR<2>, Cl, Br, F or CN; R<2> = 1-12C alkyl or 5-10C cycloalkyl; g = 2 or 3; m, n = 0-4. Also claimed are washing agents and cleaning agents containing this bleach system.
EP96120743A 1996-01-04 1996-12-23 Bleaching system containing Bis-and-Tris-(mu-oxo)-di-manganese complex salts Expired - Lifetime EP0783035B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19600159A DE19600159A1 (en) 1996-01-04 1996-01-04 Bleaching agent systems containing bis- and tris (mu-oxo) -di-manganese complex salts
DE19600159 1996-01-04

Publications (3)

Publication Number Publication Date
EP0783035A2 EP0783035A2 (en) 1997-07-09
EP0783035A3 true EP0783035A3 (en) 1998-02-25
EP0783035B1 EP0783035B1 (en) 2003-09-24

Family

ID=7782152

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96120743A Expired - Lifetime EP0783035B1 (en) 1996-01-04 1996-12-23 Bleaching system containing Bis-and-Tris-(mu-oxo)-di-manganese complex salts

Country Status (7)

Country Link
US (1) US5942152A (en)
EP (1) EP0783035B1 (en)
JP (1) JPH09194886A (en)
AT (1) ATE250660T1 (en)
CA (1) CA2194342A1 (en)
DE (2) DE19600159A1 (en)
ES (1) ES2207663T3 (en)

Families Citing this family (19)

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Publication number Priority date Publication date Assignee Title
DE19605688A1 (en) * 1996-02-16 1997-08-21 Henkel Kgaa Transition metal complexes as activators for peroxygen compounds
AU6857996A (en) * 1996-08-26 1998-03-19 Procter & Gamble Company, The Cellulase activity control by a terminator
CA2248476A1 (en) * 1997-10-01 1999-04-01 Unilever Plc Bleach activation
US6274122B1 (en) * 1999-01-07 2001-08-14 Mclaughlin Gerald Device and method using dry mixtures for whitening teeth
US20040131561A1 (en) * 2001-03-14 2004-07-08 Mclaughlin Gerald Strips for treating teeth
GB2386616A (en) * 2002-03-21 2003-09-24 Unilever Plc Bleaching composition
JP2005194244A (en) * 2004-01-09 2005-07-21 Shigenobu Yano Zinc ion fluorescence sensor
AU2005222069B2 (en) 2004-03-05 2010-09-09 Gen-Probe Incorporated Reagents, methods and kits for use in deactivating nucleic acids
KR100647976B1 (en) * 2004-05-03 2006-11-23 애경산업(주) Macrocyclic Manganese Complexes as Bleaching Catalysts and Bleach and Bleach Detergent Containing the Same
WO2009124855A1 (en) 2008-04-09 2009-10-15 Basf Se Use of metal hydrazide complex compounds as oxidation catalysts
EP2304014A1 (en) * 2008-05-23 2011-04-06 Henkel AG & Co. KGaA Washing agent that is gentle on textiles
US8946140B2 (en) * 2009-05-14 2015-02-03 Ecolab Usa Inc. Compositions, systems and method for in situ generation of alkalinity
CN102958909B (en) 2010-06-28 2016-11-09 巴斯夫欧洲公司 Metal-free bleaching composition
CA2853315A1 (en) 2011-10-25 2013-05-02 Basf Se Use of acrylate copolymers as soil antiredeposition agents and soil release agents in laundry processes
IN2014CN03743A (en) 2011-10-25 2015-09-25 Basf Se
US10837949B1 (en) * 2012-03-22 2020-11-17 Piers Richard Warburton Peracetic acid sensor with filter to remove hydrogen peroxide
AU2014243274B2 (en) 2013-03-27 2017-10-12 Henkel Ag & Co. Kgaa Block copolymers as soil release agents in laundry processes
JP2016540075A (en) 2013-11-27 2016-12-22 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ Random copolymers as soil release agents in the laundry process.
WO2017186480A1 (en) 2016-04-26 2017-11-02 Basf Se Metal free bleaching composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0458398A2 (en) * 1990-05-21 1991-11-27 Unilever N.V. Bleach activation
WO1993025562A1 (en) * 1992-06-18 1993-12-23 Unilever Plc Synthesis of manganese oxidation catalyst
WO1995027773A1 (en) * 1994-04-07 1995-10-19 The Procter & Gamble Company Bleach compositions comprising bleach activators and bleach catalysts
WO1995028467A1 (en) * 1994-04-13 1995-10-26 The Procter & Gamble Company Detergents containing an enzyme and a delayed release peroxyacid bleaching system

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US1246339A (en) 1916-08-21 1917-11-13 Isaac J Smit Self-illuminating depresser for dental and surgical work.
NL209345A (en) 1955-07-27
GB864798A (en) 1958-03-20 1961-04-06 Unilever Ltd Bleaching processes and compositions
NL97449C (en) 1959-06-19
US3156654A (en) 1961-06-19 1964-11-10 Shell Oil Co Bleaching
GB1003310A (en) 1963-01-15 1965-09-02 Unilever Ltd Bleaching processes and compositions
US3332882A (en) 1964-12-18 1967-07-25 Fmc Corp Peroxygen compositions
GB1182143A (en) 1966-03-01 1970-02-25 United States Borax Chem Bleaching Compositions and Methods.
GB1519351A (en) 1975-01-29 1978-07-26 Unilever Ltd Preparation of acetoxy arylene sulphonates
US4128494A (en) 1976-09-01 1978-12-05 Produits Chimiques Ugine Kuhlmann Activators for percompounds
US4397757A (en) 1979-11-16 1983-08-09 Lever Brothers Company Bleaching compositions having quarternary ammonium activators
GR76237B (en) 1981-08-08 1984-08-04 Procter & Gamble
EP0091159B1 (en) 1982-04-02 1985-09-11 Unilever N.V. Process for preparing sugar acetates
US4412934A (en) 1982-06-30 1983-11-01 The Procter & Gamble Company Bleaching compositions
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GB8304990D0 (en) 1983-02-23 1983-03-30 Procter & Gamble Detergent ingredients
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US4751015A (en) 1987-03-17 1988-06-14 Lever Brothers Company Quaternary ammonium or phosphonium substituted peroxy carbonic acid precursors and their use in detergent bleach compositions
US4933103A (en) 1987-03-23 1990-06-12 Kao Corporation Bleaching composition
US4915863A (en) 1987-08-14 1990-04-10 Kao Corporation Bleaching composition
GB8720863D0 (en) 1987-09-04 1987-10-14 Unilever Plc Metalloporphyrins
EP0331229B1 (en) 1988-03-01 1993-08-18 Unilever N.V. Quaternary ammonium compounds for use in bleaching systems
GB8908416D0 (en) * 1989-04-13 1989-06-01 Unilever Plc Bleach activation
GB8915781D0 (en) 1989-07-10 1989-08-31 Unilever Plc Bleach activation
US5114688A (en) 1990-01-23 1992-05-19 L'air Liquide, Societe Anonyme Pour L'etude Et Exploitation Des Procedes Georges Claude Binuclear metal macrocyclic and macrobicyclic complexes for oxygen separation and transport
GB9003741D0 (en) 1990-02-19 1990-04-18 Unilever Plc Bleach activation
US5194416A (en) 1991-11-26 1993-03-16 Lever Brothers Company, Division Of Conopco, Inc. Manganese catalyst for activating hydrogen peroxide bleaching
US5686014A (en) * 1994-04-07 1997-11-11 The Procter & Gamble Company Bleach compositions comprising manganese-containing bleach catalysts
US5720897A (en) * 1995-01-25 1998-02-24 University Of Florida Transition metal bleach activators for bleaching agents and detergent-bleach compositions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0458398A2 (en) * 1990-05-21 1991-11-27 Unilever N.V. Bleach activation
WO1993025562A1 (en) * 1992-06-18 1993-12-23 Unilever Plc Synthesis of manganese oxidation catalyst
WO1995027773A1 (en) * 1994-04-07 1995-10-19 The Procter & Gamble Company Bleach compositions comprising bleach activators and bleach catalysts
WO1995028467A1 (en) * 1994-04-13 1995-10-26 The Procter & Gamble Company Detergents containing an enzyme and a delayed release peroxyacid bleaching system

Also Published As

Publication number Publication date
ATE250660T1 (en) 2003-10-15
US5942152A (en) 1999-08-24
EP0783035A2 (en) 1997-07-09
DE59610733D1 (en) 2003-10-30
CA2194342A1 (en) 1997-07-05
DE19600159A1 (en) 1997-07-10
EP0783035B1 (en) 2003-09-24
JPH09194886A (en) 1997-07-29
ES2207663T3 (en) 2004-06-01

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