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EP0722425A1 - The way of disposal of waste from olive oil production - Google Patents

The way of disposal of waste from olive oil production

Info

Publication number
EP0722425A1
EP0722425A1 EP95927616A EP95927616A EP0722425A1 EP 0722425 A1 EP0722425 A1 EP 0722425A1 EP 95927616 A EP95927616 A EP 95927616A EP 95927616 A EP95927616 A EP 95927616A EP 0722425 A1 EP0722425 A1 EP 0722425A1
Authority
EP
European Patent Office
Prior art keywords
waste
disposal
olive oil
oil production
way
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP95927616A
Other languages
German (de)
French (fr)
Inventor
Emil Hrusa
Ludvik Siegel
Jaroslav Podus Ka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
VODNI STAVBY PRAHA
Original Assignee
VODNI STAVBY PRAHA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by VODNI STAVBY PRAHA filed Critical VODNI STAVBY PRAHA
Publication of EP0722425A1 publication Critical patent/EP0722425A1/en
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F5/00Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/16Treatment of sludge; Devices therefor by de-watering, drying or thickening using drying or composting beds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
    • C02F2103/322Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters from vegetable oil production, e.g. olive oil production
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

Definitions

  • the invention deals with the way of disposal of waste from olive oil production.
  • Another method is used e.g. for the disposal of sludges resulting from wine clarification, so called blue sludges.
  • This method is based on calcination of the sludges at high temperatures, i.e. in principle on their pyrolitic decomposition.
  • Advantage is taken of the fact that the sludge contains certain amount of bentonite and the final product can be used as an additional raw material in the field of brickmaking, ceramics, cement and other industries. Neither this way of disposal is suitable for the purpose of this invention, since it assumes the proximity of a high temperature source and the presence of e.g. ferrocyanides, so that the process of calcination can occur.
  • Liquid phase of the waste whose density is between 800 to 1000 kg/m 3 , is continuously mixed, at a ratio of up to 300 kg of natural bentonite, to 1 m 3 of the liwuid phase of waste. After that a solid phase of waste is admixed and the mixture is inoculated and subject to forced aeration.
  • Waste from olive oil production was used containing 28.6 % (by weight) of olive press cake, 17.4 % (by weight) of olive sap after the oil separation - so called marga and 54 % (by weight) of vegetable waste.
  • Marga as the liqiud phase of waste with the density of 970 kg/ra 3 , was adjusted via mixing with natural bentonite, coming from the deposit Obrnice, at a ratio of 200 kg of bentonite to 1 m 3 of marga. The mixture was further mixed up with a solid phase, i.e. press cakes and with vegetable vaste while inoculation material was being added. Inoculation material was obtained as follows: 25 kg of the upper soil from the immediate vicinity of olive-trees was taken away and well mixed with 55 litres of untreated fresh-water water. After the sedimentation of insoluble parts the water portion was drawn off and immediately used.
  • the adjusted compost charge its temperature of 31 °C, was charged into the bioreactor equipped with a controlled aeration regime and measurement of carbon dioxide concentration on the bioreactor off-gas.
  • Appearance of the product shows unambiguously that the quality inter-reaction of original raw materials took place. Neither during the fermentation not after its completion the decomposition processes occurred which commonly accompany putrefaction of olive vaste with the release of undesirable and smelly compounds.

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Botany (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Processing Of Solid Wastes (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Fats And Perfumes (AREA)
  • Lubricants (AREA)
  • Fertilizers (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The way of disposal of waste from olive oil production using intensive grinding and mixing of effluent water with natural bentonite, which is thus activated. The solution is based on a continuous mixing of the liquid phase of waste, whose density is between 800 to 1000 kg/m<3>, at a ratio of up to 300 kg of natural bentonite, to 1 m<3> of the liquid phase of waste, followed by the admixture of solid phase of waste after which the mixture is inoculated and subject to forced aeration.

Description

The way of disposal of waste from olive oil production
The invention deals with the way of disposal of waste from olive oil production.
Production of olive oil mainly takes place at olive pressing shops, situated in the vicinity of live groves. The oil is pressed out of the olive pulp or olive cake or olive kernels. Waste originating during the process of olive oil production consists of pressed out matter of the pulp, husk, kernel shells, leaves and remnants of twigs and the sap remainig after separation of the oil. Disposal of this waste is currently carried out via burning of the solid portion at site while the sap, for which the term "marga" is used in the technology of olive oil production, is discharged into environment, because construction of the digester tank is regarded as expensive. Since the sap contains, apart from other components, considerable proportion of phosphatides, which tend to decompose via putrefactive processes, invironmental damages take place - spreading of bad smell, water and soil contamination.
Other possible ways of organic waste disposal have been published in the literature, e.g. inoculation with horned cattle sewage or sludge from sewage treatment plants, which should affect the proliferation of menthane-generating bacteria and hence the produciton of biogas. Because of the fact, that the rate of methane production is not constant and sometimes even falls to zero, inoculation with reticulum content or reticulum liquid extracted from the slaughtered fatstock has been tried. Thus, to some extent, it is possible to control the activity of bacteria, however, it is not possible to use this method as a routine method for disposal of waste with the above described composition and location. Also the chemical ways of disposal of similar wastes are known, e.g. using the acids and following neutralization. However, apart from being very expensive and complicated, these methods bring about the risk of overdosage and ensuing environmental damages.
Another method is used e.g. for the disposal of sludges resulting from wine clarification, so called blue sludges. This method is based on calcination of the sludges at high temperatures, i.e. in principle on their pyrolitic decomposition. Advantage is taken of the fact that the sludge contains certain amount of bentonite and the final product can be used as an additional raw material in the field of brickmaking, ceramics, cement and other industries. Neither this way of disposal is suitable for the purpose of this invention, since it assumes the proximity of a high temperature source and the presence of e.g. ferrocyanides, so that the process of calcination can occur.
The said shortcomings are in principle eliminated by the method of disposal of waste from olive oil production which is using an intensive grinding and mixing of the waste water with natural bentonite which is thus being activated.
Principle of the invention is as follows: Liquid phase of the waste, whose density is between 800 to 1000 kg/m3, is continuously mixed, at a ratio of up to 300 kg of natural bentonite, to 1 m3 of the liwuid phase of waste. After that a solid phase of waste is admixed and the mixture is inoculated and subject to forced aeration.
Advantage of this way of disposal of waste from olive oil production is a simple and cheap equipment which, for example, can only consist of the tank and grinding and mixing pump. Another advantage is the absence of chemicals and availability of all the necessary raw materials as well as energy and especially that of inoculation material. The latter can easily be prepared from the soil containing micro-organisms being for a long period modified via the acting of olive-tree products and thus provided with a specific biodegradation properties. Resulting product is a loose, lumpy mass suitable for exploitation in agriculture. The matter does not futher decompose neither smells bad even in a humid environment.
EXAMPLE
The method of waste disposal, as described in the invention, has been used under the field conditions.
Waste from olive oil production was used containing 28.6 % (by weight) of olive press cake, 17.4 % (by weight) of olive sap after the oil separation - so called marga and 54 % (by weight) of vegetable waste.
Marga, as the liqiud phase of waste with the density of 970 kg/ra3, was adjusted via mixing with natural bentonite, coming from the deposit Obrnice, at a ratio of 200 kg of bentonite to 1 m3 of marga. The mixture was further mixed up with a solid phase, i.e. press cakes and with vegetable vaste while inoculation material was being added. Inoculation material was obtained as follows: 25 kg of the upper soil from the immediate vicinity of olive-trees was taken away and well mixed with 55 litres of untreated fresh-water water. After the sedimentation of insoluble parts the water portion was drawn off and immediately used.
The adjusted compost charge, its temperature of 31 °C, was charged into the bioreactor equipped with a controlled aeration regime and measurement of carbon dioxide concentration on the bioreactor off-gas.
After 7 days the temperature of deposited waste reached its maximum of 65 °C and, simultaneously, the amount of carbon dioxide reached the maximum value throughout the whole course of the process. During the following 7 days values of both the measured parameters went down. In the final stage the temperature of composted material did not exceed 45 °C, which shows the accelerated disintegration of the biomass.
Appearance of the product shows unambiguously that the quality inter-reaction of original raw materials took place. Neither during the fermentation not after its completion the decomposition processes occurred which commonly accompany putrefaction of olive vaste with the release of undesirable and smelly compounds.

Claims

The way of disposal of waste from olive oil production using intensive grinding and mixing of effluent water with natural bentonite, which is thus activated, c h a r a c t e r i z e d by continuous mixing of the liquid phase of waste, whose density is between 800 to 1000 kg/m3, at a ratio of up to 300 kg of natural bentonite, to 1 m3 of the liquid phase of waste, followed by the admixture of solid phase of waste after which the mixture is inoculated and subject to forced aeration.
EP95927616A 1994-08-08 1995-08-03 The way of disposal of waste from olive oil production Ceased EP0722425A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CZ941911A CZ280400B6 (en) 1994-08-08 1994-08-08 Process of disposing waste from the production of olive oil
CZ191194 1994-08-08
PCT/CZ1995/000016 WO1996005145A2 (en) 1994-08-08 1995-08-03 Disposal of waste from olive oil production

Publications (1)

Publication Number Publication Date
EP0722425A1 true EP0722425A1 (en) 1996-07-24

Family

ID=5464027

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95927616A Ceased EP0722425A1 (en) 1994-08-08 1995-08-03 The way of disposal of waste from olive oil production

Country Status (3)

Country Link
EP (1) EP0722425A1 (en)
CZ (1) CZ280400B6 (en)
WO (1) WO1996005145A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1035091A1 (en) * 1999-03-08 2000-09-13 STOCKHAUSEN GmbH & CO. KG Vegetal waste composition from oil production stable during storage and transport
CN102718312A (en) * 2012-07-14 2012-10-10 哈尔滨工业大学 Preparation and regeneration methods of iron-based activated sludge and method for treating domestic sewage by regenerated iron-based activated sludge
EP2789598A1 (en) 2013-04-12 2014-10-15 Manios, Thrassyvoulos Process for obtaining compost from wastewaters produced by olive oil mills

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2640156A1 (en) * 1976-09-07 1978-03-16 Erich Dr Asendorf Food industry wastes clarification esp. for olive oil prodn. - comprises two aeration stages with dilution by recycled activated sludge water
FR2607490B1 (en) * 1986-11-28 1990-04-27 Brun Christian BIOLOGICAL PROCESS FOR THE TREATMENT OF VEGETABLE AND ANIMAL FAT BY BACTERIA IN PURIFICATION PLANTS AND THE IMPLEMENTATION OF SAID PROCESS
IT1239280B (en) * 1989-10-04 1993-10-19 Achille Poglio ENERGY RECOVERY OF WASTEWATER FROM OLIVE OIL MILLS THROUGH TREATMENT OF THE SAME WATER WITH SPECIAL CATALYSTS AND POLYENZYMATIC MIXTURE FOR FINAL PRODUCTION OF HUMIC EXTRACTS IN AQUEOUS SOLUTION, OR AMENDERS IN AQUEOUS SOLUTION, OR ANTI-WASTEWATER AM;
IT1240759B (en) * 1990-02-09 1993-12-17 S.I.B.E. Societa' Ingegneria Bernardini Ernesto PROCEDURE TO REDUCE POLLUTION IN WATERS ARISING FROM OLIVE PROCESSING PLANTS AND RELATED PLANT.

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9605145A2 *

Also Published As

Publication number Publication date
CZ191194A3 (en) 1996-01-17
WO1996005145A3 (en) 1996-04-25
CZ280400B6 (en) 1996-01-17
WO1996005145A2 (en) 1996-02-22

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