EP0685014B1 - Stratifie - Google Patents
Stratifie Download PDFInfo
- Publication number
- EP0685014B1 EP0685014B1 EP94906990A EP94906990A EP0685014B1 EP 0685014 B1 EP0685014 B1 EP 0685014B1 EP 94906990 A EP94906990 A EP 94906990A EP 94906990 A EP94906990 A EP 94906990A EP 0685014 B1 EP0685014 B1 EP 0685014B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- adhesive
- appliqué
- fibres
- layer
- base layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
- D06Q1/12—Decorating textiles by transferring a chemical agent or a metallic or non-metallic material in particulate or other form, from a solid temporary carrier to the textile
- D06Q1/14—Decorating textiles by transferring a chemical agent or a metallic or non-metallic material in particulate or other form, from a solid temporary carrier to the textile by transferring fibres, or adhesives for fibres, to the textile
Definitions
- the invention relates to laminated articles and in particular to an appliqué for applying to fabric garments and other textile substrates.
- GB-A-2,010,123 describes a lining material, particularly for the interior lining of motor vehicle roofs and accessories.
- the roof lining material comprises a PVC calendered sheet, a layer of adhesive applied to an upper surface of the calendered sheet and fibres which may be flocked onto the adhesive.
- US-A-5,059,452 describes a flocked polyurethane fabric, wherein the possibility of selectively applying fibers of dissimilar colors to achieve consistency in color on flocked fabric is disclosed.
- FR-A-2659094 describes an appliqué comprising an adhesive polyvinylchloride material laminated onto a paper backing sheet which is then fully flocked in a single colour flock material. The sheet and flock is then cut up into individual badges or motifs for application by high frequency welding to a textile substrate.
- the flock fibres may be screen printed, in the case of a multicoloured article, with desired colours to form a required badge or motif.
- the main difficulty is the processing difficulty involved in screen printing a desired image onto the flock material.
- Different coloured inks are required which must be applied in a number of different stages and the badge thus formed must be cured at high temperature.
- the flock fibres are of rayon viscose (1.7 DTEX) 0.5mm flock which is adapted to receive the necessary screen printing ink.
- the abrasion resistance of the badge thus formed is often not satisfactory.
- the colours in the badge are often not sufficiently stable in repeated machine washing of the garment to which the badge is applied.
- the fibres have a relatively rough feel and consequently often detract from the feel of the garment to which they are applied.
- the applied print has a stiff mounting handle on the fabric which also detracts from the product.
- This invention is directed towards providing an appliqué which will overcome at least some of these difficulties.
- an appliqué comprising:-
- the flock fibres are of synthetic fibre, preferably polyamide fibre, most preferably of polyamide fibres (3.3 DTEX) 1mm. These fibres give a partially plush finish.
- at least two and possibly several different coloured flock fibres are flocked onto the adhesive.
- flock fibres of different colours are applied in sequential flocking steps.
- the fibres are flocked onto the adhesive in a desired motif or pattern through separate screens.
- the appliqué includes a support layer on which the base layer is supported. This assists in achieving dimensional stability. For ease of removal, preferably the base layer is peelably attached to the support layer.
- the support layer is of stiff paper material or similarly adapted substrate.
- the adhesive is applied to the base layer only in the region to which the flock fibres are to be flocked.
- the adhesive is applied to the base layer through a screen.
- the flock receiving adhesive is selected to be compatible with both the flock fibres and the base material. Typically the adhesive is compatible with the polyamide fibres and polyvinylchloride film material.
- the base layer is of polyvinylchloride film material which is suitable for fixing to a fabric by high frequency welding.
- the invention also provides a method of forming an appliqué carrying a motif or badge to be applied to a fabric comprising the steps of:-
- the method includes flocking flock fibres of at least several colour flock fibres onto the adhesive in a desired sequence to form a desired coloured motif.
- the adhesive is applied to the base layer only in the region to which the fibres are to be flocked.
- the adhesive is applied to the base layer through a screen.
- the flock fibres are applied to the adhesive through a screen.
- the coloured flock fibres are applied to the adhesive in sequential flocking steps.
- Most preferably the coloured flock fibres are flocked onto the adhesive through separate screens.
- the method includes the step prior to applying the adhesive, of providing a support layer for the thermoplastic base layer.
- the adhesive is cured after application of the flock fibres.
- the invention further provides a method of applying an appliqué according to the invention to a fabric support comprising the step of:- removing the support layer, if present, and welding the appliqué to the fabric support by high frequency welding.
- the method further includes the step, prior to welding, of interposing a layer of foam or the like material between the base layer of the appliqué and the fabric support.
- a high frequency weldable plastics such as polyvinylchloride sheet or film having a thickness of between 0.15mm and 0.30 mm forming a base layer is applied onto a support layer, preferably by a flow process in which the PVC in a liquid form is applied to the support layer.
- the support layer in the preferred arrangement is of a stiff paper material which allows the plastics film to be easily peeled off the support layer after processing.
- the application of the PVC onto a support layer facilitates the subsequent processing of the product whilst maintaining the dimensional stability of the PVC when subjected to heating.
- a layer of permanent adhesive is applied to the upper side of the base layer of polyvinylchloride film material.
- the adhesive is applied through a screen only to the area of the base layer on which a desired motif or badge is required.
- the adhesive is compatible with both polyamide fibres and PVC.
- Polyamide fibres of (3.3. DTEX) 1mm are flocked onto the adhesive using conventional flocking techniques.
- the fibres are flocked onto the adhesive to produce a desired motif or badge on the polyvinylchloride base film.
- a desired motif or badge the fibres are flocked onto the adhesive in a desired sequence using separate screens for each colour.
- the appliqué thus formed is then treated, typically at 160°C for approximately three minutes to cure the adhesive and to ensure permanent adhesion of the flock fibres to the base polyvinylchloride adhesive.
- the sheet of flocked film material thus formed has a plurality of appliqué badges or motifs spaced-apart therealong. This sheet is then cut up into individual appliqués which may be applied to textiles or other substrates, after removal of the backing paper using conventional high frequency welding techniques. If an additional three dimensional effect is required a layer of polyurethane foam may be interposed between the PVC film and the fabric to which the appliqué is to be attached.
- Fig. 1 there is illustrated an appliqué according to the invention and indicated generally by the reference numeral 1.
- the appliqué 1 comprises a support layer 2 of paper material coated with a release agent.
- a PVC base layer 3 which is typically 0.15 to 0.3 mm thick is applied, for example in a liquid form, onto the paper support sheet 2.
- An adhesive 4 which is compatible with the PVC sheet and with polyamide flock fibres 5 is then applied onto the PVC sheet 3 through a screen 20.
- the adhesive is a plastisol polyvinyl chloride based adhesive, made up of a PVC resin, with an appropriate plasticizer blend, and corresponding curing agents and stabilizer.
- the polyamide flock fibres 5 are typically 1 mm (3.3 DTEX) and are electrostatically flocked in one or more colours, in sequence, onto the pattern of the adhesive 4.
- the fibres are flocked onto the adhesive using a screen to achieve a desired motif or badge.
- the fibres are applied sequentially through different screens for each colour fibre.
- each sheet After flocking in sheet form and heat curing, each sheet is cut up into individual appliques.
- the paper base layer 2 is peeled off and the PVC sheet 3 is placed directly onto a textile fabric 10.
- the PVC is welded to the fabric by conventional high frequency welding techniques using a metal die 13.
- a layer 12 of PVC foam material may be sandwiched between the textile substrate 10 and the PVC sheet 3 to achieve a three dimensional effect.
- the appliqué according to the invention is readily formed and applied and has improved colour fastness and stability after repeated machine washings of the garment to which it is applied. Further, the appliqué has superior tactile properties to conventional appliqués.
- polyamide fibres pre-dyed by conventional techniques gives the substantial advantages mentioned above.
- the fibres have improved light fastness, wet and dry rubbing fastness and improved abrasion resistance.
- the use of these fibres represents in particular a substantial improvement over fibres which are screen printed after application.
- the appliqués of the invention may be used in high specification applications such as in the motor vehicle industry.
- Conventional appliqués have not heretofore been used in such industries because of the disadvantages of conventional products and processes.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Decoration Of Textiles (AREA)
- Laminated Bodies (AREA)
- Glass Compositions (AREA)
Claims (21)
- Appliqué comprenant:une couche de base d'une matière plastique en feuilles;un adhésif appliqué sur un côté de la couche de base; et une couche de fibres floquées sur l'adhésif;caractérisé en ce que ladite couche de fibres floquées est une couche de fibres de floc préteintées qui sont floquées sur l'adhésif à travers un cadre qui présente des ouvertures destinées aux fibres de floc correspondant à au moins une partie d'un motif ou dessin désiré.
- Appliqué tel que revendiqué à la revendication 1, dans lequel des fibres de floc d'au moins deux couleurs différentes sont floquées sur l'adhésif.
- Appliqué tel que revendiqué à la revendication 2, dans lequel les fibres de floc de couleurs différentes sont appliquées dans des étapes de flocage séquentielles.
- Appliqué tel que revendiqué à la revendication 2 ou 3, dans lequel les fibres sont floquées sur l'adhésif selon un motif ou dessin désiré à travers des cadres séparés.
- Appliqué tel que revendiqué dans l'une quelconque des revendications précédentes, dans lequel les fibres de floc sont en une matière de fibre synthétique, de préférence une fibre de polyamide, de préférence de 1 mm (3,3 DTEX).
- Appliqué tel que revendiqué dans l'une quelconque des revendications précédentes, dans lequel l'adhésif est appliqué sur la couche de base seulement dans la région sur laquelle les fibres de floc doivent être floquées.
- Appliqué tel que revendiqué à la revendication 6, dans lequel l'adhésif est appliqué sur la couche de base à travers un cadre.
- Appliqué tel que revendiqué dans l'une quelconque des revendications précédentes, dans lequel l'adhésif recevant le floc est un adhésif qui est compatible à la fois avec les fibres de floc et avec la matière de base, de préférence l'adhésif est compatible à la fois avec les fibres de polyamide et avec une matière de film de polyvinylchlorure.
- Appliqué tel que revendiqué dans l'une quelconque des revendications précédentes, dans lequel la couche de base est un film de polyvinylchlorure.
- Appliqué tel que revendiqué dans l'une quelconque des revendications précédentes, dans lequel l'appliqué comporte une couche de support sur lequel la couche de base est supportée.
- Appliqué tel que revendiqué à la revendication 10, dans lequel la couche de base est fixée de manière décollable sur la couche de support, de préférence la couche de support est une matière de papier rigide.
- Procédé de formation d'un appliqué portant un motif ou un badge à appliquer sur un tissu comprenant les étapes:-d'application d'un adhésif sur une couche de base d'une matière plastique en feuilles; etde flocage de fibres de floc préteintées sur l'adhésif à travers un cadre qui présente des ouvertures destinées aux fibres de floc correspondant à au moins une partie d'un motif ou dessin désiré.
- Procédé tel que revendiqué à la revendication 12, dans lequel il existe des fibres de floc d'au moins deux couleurs différentes et le procédé comporte le flocage de fibres de floc d'une deuxième couleur sur l'adhésif pour former un motif coloré désiré.
- Procédé tel que revendiqué à la revendication 12 ou 13, dans lequel l'adhésif est appliqué sur la couche de base uniquement dans la région sur laquelle les fibres doivent être floquées.
- Procédé tel que revendiqué à la revendication 14, dans lequel l'adhésif est appliqué sur la couche de base à travers un cadre.
- Procédé tel que revendiqué dans l'une quelconque des revendications 12 à 15, dans lequel il existe des fibres de floc d'au moins deux couleurs différentes qui sont appliquées sur l'adhésif dans des étapes de flocage séquentielles.
- Procédé tel que revendiqué à la revendication 16, dans lequel les fibres de floc colorées sont floquées sur l'adhésif à travers des cadres séparés.
- Procédé tel que revendiqué dans l'une quelconque des revendications 12 à 17, comportant l'étape, avant l'application de l'adhésif, de fourniture d'une couche de support pour la couche de base en plastique.
- Procédé tel que revendiqué dans l'une quelconque des revendications 12 à 18, comportant l'étape de cuisson de l'adhésif après l'application des fibres de floc.
- Procédé d'application d'un appliqué tel que revendiqué dans l'une quelconque des revendications 1 à 11 sur un support de tissu se composant de l'étape:-
de retrait de la couche de support, si elle existe, et de soudure de l'appliqué au support de tissu par soudage à haute fréquence. - Procédé tel que revendiqué à la revendication 20, comportant l'étape, avant le soudage, d'interposition d'une couche de mousse ou de matériau semblable entre la couche de base de l'appliqué et le support de tissu.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IE930122 | 1993-02-22 | ||
| IE930122 | 1993-02-22 | ||
| PCT/IE1994/000008 WO1994019530A1 (fr) | 1993-02-22 | 1994-02-22 | Stratifie |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0685014A1 EP0685014A1 (fr) | 1995-12-06 |
| EP0685014B1 true EP0685014B1 (fr) | 1997-05-21 |
Family
ID=11039882
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94906990A Expired - Lifetime EP0685014B1 (fr) | 1993-02-22 | 1994-02-22 | Stratifie |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0685014B1 (fr) |
| AT (1) | ATE153397T1 (fr) |
| AU (1) | AU6043194A (fr) |
| DE (1) | DE69403323T2 (fr) |
| WO (1) | WO1994019530A1 (fr) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6929771B1 (en) | 2000-07-31 | 2005-08-16 | High Voltage Graphics, Inc. | Method of decorating a molded article |
| US6977023B2 (en) | 2001-10-05 | 2005-12-20 | High Voltage Graphics, Inc. | Screen printed resin film applique or transfer made from liquid plastic dispersion |
| US7338697B2 (en) | 2000-07-24 | 2008-03-04 | High Voltage Graphics, Inc. | Co-molded direct flock and flock transfer and methods of making same |
| US7344769B1 (en) | 2000-07-24 | 2008-03-18 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the flocked transfer |
| US7351368B2 (en) | 2002-07-03 | 2008-04-01 | High Voltage Graphics, Inc. | Flocked articles and methods of making same |
| US7364782B2 (en) | 2000-07-24 | 2008-04-29 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
| US7393576B2 (en) | 2004-01-16 | 2008-07-01 | High Voltage Graphics, Inc. | Process for printing and molding a flocked article |
| US7410682B2 (en) | 2002-07-03 | 2008-08-12 | High Voltage Graphics, Inc. | Flocked stretchable design or transfer |
| US7413581B2 (en) | 2002-07-03 | 2008-08-19 | High Voltage Graphics, Inc. | Process for printing and molding a flocked article |
| US7465485B2 (en) | 2003-12-23 | 2008-12-16 | High Voltage Graphics, Inc. | Process for dimensionalizing flocked articles or wear, wash and abrasion resistant flocked articles |
| US7749589B2 (en) | 2005-09-20 | 2010-07-06 | High Voltage Graphics, Inc. | Flocked elastomeric articles |
| US7799164B2 (en) | 2005-07-28 | 2010-09-21 | High Voltage Graphics, Inc. | Flocked articles having noncompatible insert and porous film |
| US8007889B2 (en) | 2005-04-28 | 2011-08-30 | High Voltage Graphics, Inc. | Flocked multi-colored adhesive article with bright lustered flock and methods for making the same |
| US8206800B2 (en) | 2006-11-02 | 2012-06-26 | Louis Brown Abrams | Flocked adhesive article having multi-component adhesive film |
| US8354050B2 (en) | 2000-07-24 | 2013-01-15 | High Voltage Graphics, Inc. | Co-molded direct flock and flock transfer and methods of making same |
| US8475905B2 (en) | 2007-02-14 | 2013-07-02 | High Voltage Graphics, Inc | Sublimation dye printed textile |
| WO2015099619A1 (fr) * | 2013-12-27 | 2015-07-02 | Flokser Tekstil San. Ve Tic. A.S. | Procédé de flocage appliqué à un matériau de revêtement membranaire/en feuille en pvc ayant des propriétés thermoplastiques et produit semi-fini floqué obtenu à l'aide dudit procédé |
| US9193214B2 (en) | 2012-10-12 | 2015-11-24 | High Voltage Graphics, Inc. | Flexible heat sealable decorative articles and method for making the same |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5796726A (en) * | 1996-04-08 | 1998-08-18 | Ericsson Inc. | Systems and methods for random access in time division multiple access satellite radiotelephone communications |
| DE69929342D1 (de) | 1998-07-21 | 2006-03-30 | Tachyon Inc | Verfahren und gerät für mehrfachzugriff in einem kommunikationssystem |
| US6982969B1 (en) | 1999-09-28 | 2006-01-03 | Tachyon, Inc. | Method and system for frequency spectrum resource allocation |
| DE102008045457A1 (de) * | 2008-09-02 | 2010-03-04 | Branko Stahl | Verfahren zur Applizierung von feinen Volumenmotiven auf rauhen bzw. grob gegliederten Oberflächen von Trägermaterialien |
| CA2748040C (fr) * | 2008-12-22 | 2014-12-02 | Illinois Tool Works Inc. | Application d'un dessin sur une etoffe |
| WO2010094044A1 (fr) | 2009-02-16 | 2010-08-19 | High Voltage Graphics, Inc. | Dessin ou transfert étirable floqué comprenant un film thermoplastique et son procédé de fabrication |
| WO2011112936A1 (fr) | 2010-03-12 | 2011-09-15 | High Voltage Graphics, Inc. | Articles floqués offrant une résistance à la déchirure et procédés pour fabriquer ceux-ci |
| US12138902B2 (en) * | 2019-02-11 | 2024-11-12 | Fiberlok Technologies | Light retroreflective graphic textile |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2010123A (en) * | 1977-12-15 | 1979-06-27 | Comind Spa | A lining material, a manufacturing process therefor and products lined with the material, particularly sun screens for motorcars |
| DE3502990C1 (de) * | 1985-01-30 | 1986-06-05 | Volker 5600 Wuppertal Mau | Mehrschichtiger Flocktransferfolien-Zuschnitt |
| US5059452A (en) * | 1989-04-03 | 1991-10-22 | Squires William J | Flocked foam fabric with flattened fibers which are color printed |
| FR2659094B1 (fr) * | 1990-03-02 | 1994-05-13 | Enduction Flockage | Procede de fabrication d'un produit flocke et produit flocke obtenu. |
| GB2245220B (en) * | 1990-06-22 | 1993-11-03 | Electroscope Limited | A transfer sheet |
-
1994
- 1994-02-22 DE DE69403323T patent/DE69403323T2/de not_active Expired - Fee Related
- 1994-02-22 EP EP94906990A patent/EP0685014B1/fr not_active Expired - Lifetime
- 1994-02-22 WO PCT/IE1994/000008 patent/WO1994019530A1/fr not_active Ceased
- 1994-02-22 AU AU60431/94A patent/AU6043194A/en not_active Abandoned
- 1994-02-22 AT AT94906990T patent/ATE153397T1/de not_active IP Right Cessation
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7381284B2 (en) | 2000-07-24 | 2008-06-03 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
| US7338697B2 (en) | 2000-07-24 | 2008-03-04 | High Voltage Graphics, Inc. | Co-molded direct flock and flock transfer and methods of making same |
| US7344769B1 (en) | 2000-07-24 | 2008-03-18 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the flocked transfer |
| US7364782B2 (en) | 2000-07-24 | 2008-04-29 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
| US7632371B2 (en) | 2000-07-24 | 2009-12-15 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
| US7390552B2 (en) | 2000-07-24 | 2008-06-24 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacturing including the flocked transfer |
| US8354050B2 (en) | 2000-07-24 | 2013-01-15 | High Voltage Graphics, Inc. | Co-molded direct flock and flock transfer and methods of making same |
| US7402222B2 (en) | 2000-07-24 | 2008-07-22 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the flocked transfer |
| US6929771B1 (en) | 2000-07-31 | 2005-08-16 | High Voltage Graphics, Inc. | Method of decorating a molded article |
| US6977023B2 (en) | 2001-10-05 | 2005-12-20 | High Voltage Graphics, Inc. | Screen printed resin film applique or transfer made from liquid plastic dispersion |
| US7351368B2 (en) | 2002-07-03 | 2008-04-01 | High Voltage Graphics, Inc. | Flocked articles and methods of making same |
| US7410682B2 (en) | 2002-07-03 | 2008-08-12 | High Voltage Graphics, Inc. | Flocked stretchable design or transfer |
| US7413581B2 (en) | 2002-07-03 | 2008-08-19 | High Voltage Graphics, Inc. | Process for printing and molding a flocked article |
| US7465485B2 (en) | 2003-12-23 | 2008-12-16 | High Voltage Graphics, Inc. | Process for dimensionalizing flocked articles or wear, wash and abrasion resistant flocked articles |
| US7393576B2 (en) | 2004-01-16 | 2008-07-01 | High Voltage Graphics, Inc. | Process for printing and molding a flocked article |
| US8007889B2 (en) | 2005-04-28 | 2011-08-30 | High Voltage Graphics, Inc. | Flocked multi-colored adhesive article with bright lustered flock and methods for making the same |
| US7799164B2 (en) | 2005-07-28 | 2010-09-21 | High Voltage Graphics, Inc. | Flocked articles having noncompatible insert and porous film |
| USRE45802E1 (en) | 2005-07-28 | 2015-11-17 | High Voltage Graphics, Inc. | Flocked articles having noncompatible insert and porous film |
| US7749589B2 (en) | 2005-09-20 | 2010-07-06 | High Voltage Graphics, Inc. | Flocked elastomeric articles |
| US8168262B2 (en) | 2005-09-20 | 2012-05-01 | High Voltage Graphics, Inc. | Flocked elastomeric articles |
| US8206800B2 (en) | 2006-11-02 | 2012-06-26 | Louis Brown Abrams | Flocked adhesive article having multi-component adhesive film |
| US8475905B2 (en) | 2007-02-14 | 2013-07-02 | High Voltage Graphics, Inc | Sublimation dye printed textile |
| US9193214B2 (en) | 2012-10-12 | 2015-11-24 | High Voltage Graphics, Inc. | Flexible heat sealable decorative articles and method for making the same |
| WO2015099619A1 (fr) * | 2013-12-27 | 2015-07-02 | Flokser Tekstil San. Ve Tic. A.S. | Procédé de flocage appliqué à un matériau de revêtement membranaire/en feuille en pvc ayant des propriétés thermoplastiques et produit semi-fini floqué obtenu à l'aide dudit procédé |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69403323T2 (de) | 1997-11-20 |
| ATE153397T1 (de) | 1997-06-15 |
| EP0685014A1 (fr) | 1995-12-06 |
| AU6043194A (en) | 1994-09-14 |
| DE69403323D1 (de) | 1997-06-26 |
| WO1994019530A1 (fr) | 1994-09-01 |
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