EP0607402B1 - Mould for the production of mouldings containing liquid - Google Patents
Mould for the production of mouldings containing liquid Download PDFInfo
- Publication number
- EP0607402B1 EP0607402B1 EP93917716A EP93917716A EP0607402B1 EP 0607402 B1 EP0607402 B1 EP 0607402B1 EP 93917716 A EP93917716 A EP 93917716A EP 93917716 A EP93917716 A EP 93917716A EP 0607402 B1 EP0607402 B1 EP 0607402B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- sintered
- ceramic material
- pore
- foamed ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title abstract description 10
- 238000000465 moulding Methods 0.000 title abstract description 3
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 51
- 239000000463 material Substances 0.000 claims abstract description 26
- 239000011148 porous material Substances 0.000 claims abstract description 24
- 239000004927 clay Substances 0.000 claims abstract description 16
- 239000011381 foam concrete Substances 0.000 claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052593 corundum Inorganic materials 0.000 claims description 6
- 239000010431 corundum Substances 0.000 claims description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 6
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 5
- 229910001220 stainless steel Inorganic materials 0.000 claims description 5
- 239000010935 stainless steel Substances 0.000 claims description 5
- 239000010959 steel Substances 0.000 claims description 5
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 4
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052863 mullite Inorganic materials 0.000 claims description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 238000010894 electron beam technology Methods 0.000 claims description 2
- 238000005058 metal casting Methods 0.000 claims description 2
- 239000002923 metal particle Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 238000007569 slipcasting Methods 0.000 claims description 2
- 239000006261 foam material Substances 0.000 claims 1
- 230000002787 reinforcement Effects 0.000 claims 1
- 229910052602 gypsum Inorganic materials 0.000 abstract description 12
- 239000010440 gypsum Substances 0.000 abstract description 12
- 239000010410 layer Substances 0.000 description 52
- 239000011505 plaster Substances 0.000 description 11
- 239000011449 brick Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000005299 abrasion Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 238000003825 pressing Methods 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 238000011001 backwashing Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011268 mixed slurry Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/36—Linings or coatings, e.g. removable, absorbent linings, permanent anti-stick coatings; Linings becoming a non-permanent layer of the moulded article
- B28B7/368—Absorbent linings
Definitions
- the invention relates to a mold for the production of liquid-containing pressed parts, such as roof tiles made of clay, a clay-like or similar material.
- Roof tiles in the form of pressed roof tiles are usually made of clay, clay or similar material with a very specific water content; the clay or the clay-containing material is applied to a negative mold made of gypsum, which is accommodated in a steel frame and serves as the lower mold, and is finally pressed into a raw brick of the desired shape in a press by means of a negative mold made of gypsum which also serves as the upper mold .
- a negative mold made of gypsum which also serves as the upper mold.
- the top of the plaster mold serving as the lower mold is modeled on the surface of the underside of the bricks to be produced, while the downward-facing upper surface of the negative mold made of plaster serving as the upper mold corresponds to the visible outer surface of a brick.
- porous mold for the pressure casting of ceramic shaped pieces with a porous inner layer and a coarse-porous outer layer covering the back of the porous inner layer.
- the porous inner layer has an average pore diameter of at most 20 ⁇ m and a thickness of 5 to 40mm.
- an adhesive is applied, on which a porous Is applied outer layer, which consists of liquid resin and a filler with a grain size of 0.1 to 5mm and a thickness of 5 to 30mm and a pore diameter of at least 100 microns.
- This outer layer is sealed by a resin adhesive layer.
- EP-A-0 121 929 discloses a permeable mold for forming three-dimensional moldings, the inner layer of which is made from a mixed slurry which contains metallic grains, ceramic grains and a liquid binder with an evaporating or consumable component. A support layer of unsintered metal and ceramic powder is applied to this layer sintered in an oxidizing atmosphere. Due to the evaporating or consumable component of the liquid binder in the inner layer, openings with a porosity of 5 to 60% are created in the mold.
- the two known forms described above have in particular the disadvantage that they do not withstand the high contact pressure which is necessary when producing roof tiles in order to squeeze the liquid contained in the material to be pressed out of the clay, the clay-containing or similar material. Furthermore, the forms described above have the disadvantage that they have only a low resistance to abrasion.
- the negative molds made of gypsum used as the upper and lower mold undergo considerable abrasion, so that after an approximately known, not too high number of pressings, the wear, in particular on the negative mold made of gypsum as the upper mold, is so great due to the abrasion that the specified tolerances, in particular with regard to the permissible minimum thickness of the finished brick, can no longer be met.
- the plaster mold serving as the upper mold must therefore after about 600 to 800, at best 1000 brick pressings can be exchanged for a new, provided upper mold.
- the press must be replaced with a new, unused gypsum mold after half an hour at the latest, this process on average 5 to max. Takes 10min. Replacing the plaster mold serving as the upper mold takes 1 to 1.5 hours with a ten-hour shift, so that the brick press stops 10 to 15% of the time per shift.
- the old used gypsum molds are generally employed by three workers in each shift.
- the object of the invention is therefore to provide a mold for the production of liquid-containing pressed parts, such as clay roof tiles, a clay-containing or similar material, which has a very high wear resistance and durability. According to the invention, this is achieved in a mold for the production of liquid-containing pressed parts, such as roof tiles made of clay, a clay-containing or similar material, by the features in the characterizing part of claim 1 or 15. Advantageous further developments are the subject of to claim 1 or 15 directly or indirectly subordinate claims.
- a layer which comes into contact with the material to be pressed consists of fine-pored, sintered or foamed ceramic material, while the layer below is coarse-pored, sintered or foamed ceramic material or foamed concrete.
- the fine-pored, sintered or foamed ceramic material has a porosity of the order of 10 ⁇ (10. 10 -10 m) to 30 ⁇ m and the proportion of porosity is between 5 and 60% depending on the material to be pressed.
- additives such as corundum, mullite, silicon carbide, silicon nitride, zirconium dioxide and the like are added to the fine-pored, sintered or foamed ceramic material.
- the fine-pored, sintered or foamed ceramic material consists of corundum, mullite, silicon carbide, silicon nitride or zirconium dioxide. Since zirconium dioxide is electrically conductive, if zirconium dioxide is added to the fine-pored, sintered or foamed ceramic material, demolding can be carried out more easily, or the adhesion between the mold and the pressed material is considerably reduced by the application of direct current.
- the same effect can also be achieved in that the surface of the layer of fine-pored, sintered or foamed material has a metallized or an oxidation layer.
- metal particles can be embedded in the fine-pored, sintered or foamed ceramic material to increase the conductivity.
- the layer of foamed ceramic material preferably has a thickness on the order of 0.1 to 2.0 mm.
- a Stainless steel mesh can be introduced.
- such a fabric made of stainless steel is accommodated in an area corresponding to the sealing labyrinth of the finished brick in the form of strip-shaped or web-like projections running in the longitudinal direction of a brick, which protrude outwards from the layer of fine-pored ceramic material; this largely prevents the web-like or strip-like projections in the layer of fine-pored, sintered or foamed material from breaking off.
- a mold according to the invention Because of the high abrasion resistance of fine-pored, sintered or foamed ceramic material, its wear during pressing is minimal compared to the abrasion with the plaster molds commonly used, so that a mold according to the invention has a service life of one depending on the material used for the production of roof tiles can have half to a year and more.
- the daily downtimes of the press in the order of 1 hour to 1.5 hours, which were previously required for spraying out used plaster molds and for inserting new, provided plaster molds, are thus eliminated. This means that the personnel involved in the manufacture, provision and spraying of new gypsum molds are no longer required, and the entire cost of gypsum is also eliminated.
- the layer consists of coarse-pored, sintered or foamed ceramic material, preferably of silicon carbide or corundum and, in order to enable backwashing with solvents or water, has a porosity that is 3 to 20 times greater than the porosity of the layer of fine-pored, sintered or foamed ceramic material.
- the layer of the layer arranged below is preferably made in the region facing away from the layer of fine-pored, sintered or foamed ceramic material coarse-pored, sintered or foamed ceramic material or foamed concrete a number of tubular channels for draining the liquid in the form of water are formed.
- cavities are formed in the layer of coarse-pore ceramic material or foamed concrete with supporting intermediate webs left between them.
- the cavities in the layer of large-pore, sintered or foamed ceramic material preferably have a cross-sectional area of the order of magnitude of 100 mm 2 , while the supporting intermediate webs have a thickness of 4 to 5 mm.
- the formation of the cavities in the layer of large-pore material saves a considerable amount of material, at the same time the distance and thus the time required for the liquid to be pressed out of the material to be processed in the form of water is reduced in order to keep the relatively thin layer thickness above the penetrate numerous cavities in the layer of coarse-pored, sintered or foamed ceramic material. Liquid entering the cavities can be sucked off through tubular channels running transversely thereto or, as was previously the case, by means of negative pressure.
- a porous connecting layer can be provided between the layer of fine-pored, sintered or foamed ceramic material and the layer of coarse-pored, sintered or foamed ceramic material to increase the adhesion.
- the mold according to the invention can also be used for slip casting or metal casting with and without vacuum application.
- the layer that comes into contact with the material to be pressed is a metal plate that has a large number of the finest Holes are penetrated, a layer of large-pore, sintered or foamed ceramic material or foamed concrete is again provided under this plate.
- the holes in the metal plate are flared to the underlying layer of coarse-pored, sintered or foamed ceramic material or foamed concrete, so that the water squeezed out of the clay reaches the underlying layer of foamed concrete or of coarse-pored, sintered or foamed ceramic material more quickly .
- the holes that widen conically to form a layer of coarse-pored, sintered or foamed ceramic material or foamed concrete run approximately perpendicular to the surface of the metal plate. If necessary, the holes are arranged in a different distribution density and / or with different diameters in different areas according to a further advantageous development of the invention.
- the conically widening holes are produced, for example, by means of laser or electron beam processes.
- FIG. 1 A first exemplary embodiment of a mold 1 according to the invention is shown schematically and to scale in FIG.
- An upper layer 10 in FIG. 1 consists of fine-pored, sintered or foamed ceramic material, while underneath another layer 11 of coarse-pored, sintered or foamed ceramic material or foamed concrete is provided.
- tubular channels 110 are provided, via which the liquid is drained from the clay, clayey or similar material in the form of water during the production of pressed roof tiles.
- Layer 10 preferably has a thickness of 1.5 mm. Furthermore, both layers 10 and 11 are preferably colored continuously, so that the appearance of the color of the underlying layer 11 alone is an indication that the layer 10 made of fine-pored, sintered or foamed ceramic material is used.
- protrusions 100 are shown on the upper side of the layer 10 made of fine-pored, sintered or foamed ceramic material in section outwards (upwards in FIG. 2), which in a direction perpendicular to the plane of the drawing are strip-shaped or web-like projections running parallel to one another, which in the negative form correspond to the sealing labyrinth provided in the lateral region of each roof tile.
- a steel mesh 20 made of preferably stainless steel is accommodated in the region of such projections 100 the sectional view of Figures 1 and 2 can only be seen as points.
- the steel mesh 20 is expediently also provided in the entire layer of fine-pored, sintered or foamed ceramic material.
- cavities 111 are formed in the layer 11 from coarse-pored, sintered or foamed ceramic material or from foamed concrete, between which supporting webs 112 have been left.
- the cavities 111 have a cross-sectional area on the order of 100 mm 2 , while the supporting intermediate webs 112 have a thickness on the order of preferably 4 to 5 mm.
- the provision of the cavities 111 in the layer 11 achieves considerable material savings and, at the same time, the liquid emerging from the layer 10 generally only has to penetrate a considerably thinner layer above the individual cavities in the form of water. The liquid which has escaped into the cavities can be drained from these, for example, through corresponding channels through the tubular channels 110 in FIG.
- FIG. 3 shows a modification of a mold 1 'according to the invention.
- a steel plate 30 is arranged over the layer 11 made of coarse-pored, sintered or foamed ceramic material or made of foamed concrete, which are penetrated by a large number of holes 300.
- the holes 300 shown in section are flared to the layer 11 provided there, made of foamed concrete or of coarse-pored, sintered or foamed ceramic material.
- the respective center axes are indicated by dash-dotted lines in the individual holes 300.
- the conical holes 300 have a diameter of 10 ⁇ m to 400 ⁇ m.
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Press-Shaping Or Shaping Using Conveyers (AREA)
- Moulds, Cores, Or Mandrels (AREA)
- Producing Shaped Articles From Materials (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
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- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Description
Die Erfindung betrifft eine Form zum Herstellen von flüssigkeitshaltigen Preßteilen, wie Dachziegeln aus Lehm, einem tonhaltigen oder ähnlichen Material.The invention relates to a mold for the production of liquid-containing pressed parts, such as roof tiles made of clay, a clay-like or similar material.
Dachziegel in Form von Preß-Dachziegeln werden üblicherweise aus Lehm, tonhaltigem oder ähnlichem Material mit einem ganz bestimmten Wassergehalt hergestellt; der Lehm oder das tonhaltige Material wird auf eine in einem Stahlrahmen untergebrachte, als Unterform dienende Negativform aus Gips in wohldosierter Menge aufgebracht und mittels einer ebenfalls in einem Stahlrahmen untergebrachten, als Oberform dienenden Negativform aus Gips in einer Presse letztendlich zu einem Rohziegel der gewünschten Form verpreßt. Hierbei ist die Oberseite der als Unterform dienenden Gipsform der Oberfläche der Unterseite der herzustellenden Ziegel nachgebildet, während die nach unten weisende Oberseite der als Oberform dienenden Negativform aus Gips der sichtbaren Außenfläche eines Ziegels entspricht.Roof tiles in the form of pressed roof tiles are usually made of clay, clay or similar material with a very specific water content; the clay or the clay-containing material is applied to a negative mold made of gypsum, which is accommodated in a steel frame and serves as the lower mold, and is finally pressed into a raw brick of the desired shape in a press by means of a negative mold made of gypsum which also serves as the upper mold . Here, the top of the plaster mold serving as the lower mold is modeled on the surface of the underside of the bricks to be produced, while the downward-facing upper surface of the negative mold made of plaster serving as the upper mold corresponds to the visible outer surface of a brick.
Aus FR-A-2 601 895 ist eine poröse Form für den Druckguß von keramischen Formstücken mit einer porösen Innenschicht und einer die Rückseite der porösen Innenschicht überdeckenden grobporösen Außenschicht bekannt. Die poröse Innenschicht weist einen mittleren Porendurchmesser von höchstens 20µm und eine Dicke von 5 bis 40mm auf.Auf der Rückseite der porösen Innenschicht ist ein Kleber aufgetragen, auf welchen eine poröse Außenschicht aufgebracht ist, die aus flüssigen Harz und einem Füllmaterial mit einer Korngröße von 0,1 bis 5mm besteht und eine Dicke von 5 bis 30mm und einen Porendurchmesser von wenigstens 100µm aufweist. Diese Außenschicht ist durch eine Harzkleberschicht abgedichtet.From FR-A-2 601 895 a porous mold for the pressure casting of ceramic shaped pieces with a porous inner layer and a coarse-porous outer layer covering the back of the porous inner layer is known. The porous inner layer has an average pore diameter of at most 20µm and a thickness of 5 to 40mm. On the back of the porous inner layer an adhesive is applied, on which a porous Is applied outer layer, which consists of liquid resin and a filler with a grain size of 0.1 to 5mm and a thickness of 5 to 30mm and a pore diameter of at least 100 microns. This outer layer is sealed by a resin adhesive layer.
Ferner ist aus EP-A-0 121 929 eine durchlässige Form zum Bilden von dreidimensionalen Formlingen bekannt, deren innere Schicht aus einer gemischten Schlämme hergestellt ist, die metallische Körner, keramische Körner und ein flüssiges Bindemittel mit einem verdampfenden oder verbrauchbaren Bestandteil enthält. Auf diese in oxidierender Atmosphäre gesinterte Schicht wird eine Stützschicht aus ungesintertem Metall- und Keramikpulver aufgebracht. Aufgrund des verdampfenden oder verbrauchbaren Bestandteils des flüssigen Bindemittels in der inneren Schicht entstehen in der Form Öffnungen mit einer Porosität von 5 bis 60%.Furthermore, EP-A-0 121 929 discloses a permeable mold for forming three-dimensional moldings, the inner layer of which is made from a mixed slurry which contains metallic grains, ceramic grains and a liquid binder with an evaporating or consumable component. A support layer of unsintered metal and ceramic powder is applied to this layer sintered in an oxidizing atmosphere. Due to the evaporating or consumable component of the liquid binder in the inner layer, openings with a porosity of 5 to 60% are created in the mold.
Die beiden vorstehend beschriebenen bekannten Formen weisen insbesondere den Nachteil auf, daß sie dem hohen Anpreßdruck, nicht standhalten, der beim Herstellen von Dachziegeln notwendig ist, um die in dem zu verpressenden Material enthaltene Flüssigkeit aus dem Lehm, dem tonhaltigen oder ähnlichem Material auszupressen. Ferner weisen die vorstehend beschriebenen Formen den Nachteil auf, daß sie nur eine geringe Abräsionsbeständigkeit haben.The two known forms described above have in particular the disadvantage that they do not withstand the high contact pressure which is necessary when producing roof tiles in order to squeeze the liquid contained in the material to be pressed out of the clay, the clay-containing or similar material. Furthermore, the forms described above have the disadvantage that they have only a low resistance to abrasion.
Bei jeder Pressung erfahren die als Ober- und Unterform verwendeten Negativformen aus Gips einen beachtlichen Abrieb, so daß nach einer in etwa bekannten, nicht zu hohen Anzahl von Pressungen der Verschleiß, insbesondere an der als Oberform dienenden Negativform aus Gips durch den Abrieb so groß ist, daß die vorgegebenen Toleranzen insbesondere hinsichtlich der zulässigen minimalen Dicke der fertigen Ziegel nicht mehr einzuhalten sind. Insbesondere die als Oberform dienende Gipsform muß daher nach etwa 600 bis 800, günstigstenfalls 1000 Ziegelpressungen gegen eine neue, bereitgestellte Oberform ausgetauscht werden.With each pressing, the negative molds made of gypsum used as the upper and lower mold undergo considerable abrasion, so that after an approximately known, not too high number of pressings, the wear, in particular on the negative mold made of gypsum as the upper mold, is so great due to the abrasion that the specified tolerances, in particular with regard to the permissible minimum thickness of the finished brick, can no longer be met. In particular, the plaster mold serving as the upper mold must therefore after about 600 to 800, at best 1000 brick pressings can be exchanged for a new, provided upper mold.
Hierzu muß die Presse in Abhängigkeit von dem verwendeten, zu verpressenden Material jeweils nach einer halben bis spätestens einer Stunde gegen eine neue, unverbrauchte Gipsform ausgewechselt werden, wobei dieser Vorgang im Durchschnitt 5 bis max. 10min dauert. Allein das Auswechseln der als Oberform dienenden Gipsform nimmt bei einer zehnstündigen Schichtdauer 1 bis 1,5h in Anspruch, sodaß die Ziegelpresse pro Schicht 10 bis 15% der Dauer stillsteht.For this purpose, depending on the material to be pressed, the press must be replaced with a new, unused gypsum mold after half an hour at the latest, this process on average 5 to max. Takes 10min. Replacing the plaster mold serving as the upper mold takes 1 to 1.5 hours with a ten-hour shift, so that the brick press stops 10 to 15% of the time per shift.
Ferner sind mit dem Vorbereiten und Herstellen neuer Gipsformen und mit dem Auswechseln dieser Gipsformen die alten verbrauchten Gipsformen in jeder Schicht im allgemeinen drei Arbeiter beschäftigt.Furthermore, in preparing and manufacturing new gypsum molds and replacing these gypsum molds, the old used gypsum molds are generally employed by three workers in each shift.
Somit ist nicht nur die Vorbereitung und Bereitstellung neuer und einwandfreier Gipsformen und deren Austausch gegen verbrauchte Gipsformen insgesamt sehr zeitaufwendig und kostenintensiv, sondern auch die sich aufsummierenden Stillstandszeiten zum Ersetzen verbrauchter Formen und zum Einsetzen neuer Formen sowie die benötigten Gipsmengen und das beim Ausspritzen der Gipsformen verbrauchte Wasser stellen einen beachtlichen Kostenfaktor dar. Weitere Kosten entstehen durch das Besorgen und Entsorgen der beachtlichen Mengen an Gips.Thus, not only is the preparation and provision of new and perfect plaster molds and their replacement for used plaster molds overall very time-consuming and cost-intensive, but also the cumulative downtimes for replacing used molds and for inserting new molds, as well as the plaster quantities required and the amount used when spraying out the plaster molds Water is a considerable cost factor. Additional costs arise from getting and disposing of the considerable amounts of gypsum.
Aufgabe der Erfindung ist es daher, eine Form zum Herstellen von flüssigkeitshaltigen Preßteilen, wie Dachziegeln aus Lehm, einem tonhaltigen oder ähnlichen Material zu schaffen, die eine sehr hohe Verschleißfestigkeit und Haltbarkeit aufweist. Gemäß der Erfindung ist dies bei einer Form zum Herstellen von flüssigkeitshaltigen Preßteilen, wie Dachziegeln aus Lehm, einem tonhaltigen oder ähnlichen Material durch die Merkmale im kennzeichnenden Teil des Anspruchs 1 oder 15 erreicht. Vorteilhafte Weiterbildungen sind Gegenstand der auf den Anspruch 1 oder 15 unmittelbar oder mittelbar rückbezogenen Unteransprüche.The object of the invention is therefore to provide a mold for the production of liquid-containing pressed parts, such as clay roof tiles, a clay-containing or similar material, which has a very high wear resistance and durability. According to the invention, this is achieved in a mold for the production of liquid-containing pressed parts, such as roof tiles made of clay, a clay-containing or similar material, by the features in the characterizing part of
Bei der erfindungsgemäßen Form besteht eine mit dem zu verpressenden Material in Kontakt kommende Schicht aus feinporigem, gesintertem oder geschäumtem Keramikmaterial, während die Schicht darunter grobporiges, gesintertes oder geschäumtes Keramikmaterial oder geschäumter Beton ist.In the form according to the invention, a layer which comes into contact with the material to be pressed consists of fine-pored, sintered or foamed ceramic material, while the layer below is coarse-pored, sintered or foamed ceramic material or foamed concrete.
Hierbei hat das feinporige, gesinterte oder geschäumte Keramikmaterial eine Porosität in der Größenordnung von 10 Å (10 . 10-10m) bis 30µm und der Porositätsanteil liegt in Abhängigkeit von dem zu verpressenden Material zwischen 5 bis 60%.The fine-pored, sintered or foamed ceramic material has a porosity of the order of 10 Å (10. 10 -10 m) to 30 µm and the proportion of porosity is between 5 and 60% depending on the material to be pressed.
Gemäß einer weiteren vorteilhaften Weiterbildung der Erfindung werden dem feinporigen, gesinterten oder geschäumten Keramikmaterial Zusätze, wie Korund, Mullit, Siliziumcarbid, Siliziumnitrid, Zirkondioxid u.ä. beigemengt. Ferner besteht das feinporige, gesinterte oder geschäumte Keramikmaterial aus Korund, Mullit, Siliziumcarbid, Siliziumnitrid oder Zirkondioxid. Da Zirkondioxid elektrisch leitend ist, läßt sich bei einer Beimengung von Zirkondioxid zu dem feinporigen, gesinterten oder geschäumten Keramikmaterial eine Entformung leichter vornehmen bzw. es wird durch das Beaufschlagen mit Gleichstrom die Adhäsion zwischen der Form und dem verpreßten Material beträchtlich verringert. Dieselbe Wirkung kann auch damit erreicht werden, dadurch daß die Oberfläche der Schicht aus feinporigem, gesintertem oder geschäumtem Material eine metallisierte bzw. eine Oxidationsschicht aufweist. Ferner können gemäß einer weiteren vorteilhaften Weiterbildung der Erfindung zur Erhöhung der Leitfähigkeit Metallpartikel in das feinporige, gesinterte oder geschäumte Keramikmaterial eingelagert werden.According to a further advantageous development of the invention, additives such as corundum, mullite, silicon carbide, silicon nitride, zirconium dioxide and the like are added to the fine-pored, sintered or foamed ceramic material. added. Furthermore, the fine-pored, sintered or foamed ceramic material consists of corundum, mullite, silicon carbide, silicon nitride or zirconium dioxide. Since zirconium dioxide is electrically conductive, if zirconium dioxide is added to the fine-pored, sintered or foamed ceramic material, demolding can be carried out more easily, or the adhesion between the mold and the pressed material is considerably reduced by the application of direct current. The same effect can also be achieved in that the surface of the layer of fine-pored, sintered or foamed material has a metallized or an oxidation layer. Furthermore, according to a further advantageous development of the invention, metal particles can be embedded in the fine-pored, sintered or foamed ceramic material to increase the conductivity.
Ferner hat die Schicht aus geschäumtem Keramikmaterial vorzugsweise eine Dicke in der Größenordnung von 0,1 bis 2,0mm. Zur Verstärkung der dünnen Schicht aus feinporigem, gesinterten oder geschäumtem Keramikmaterial kann in dieser ein Gewebe aus rostfreiem Stahl eingebracht werden. Insbesondere ist ein solches Gewebe aus rostfreiem Stahl in einem dem Dichtlabyrinth des fertigen Ziegels entsprechenden Bereich in Form von in Längsrichtung eines Ziegels verlaufenden, leistenförmigen oder stegartigen Vorsprüngen untergebracht, welche von der Schicht aus feinporigem Keramikmaterial nach außen vorstehen; hierdurch ist ein Abbrechen der stegartigen oder leistenförmigen Vorsprünge in der Schicht aus feinporigem, gesintertem oder geschäumtem Material weitestgehend unterbunden.Furthermore, the layer of foamed ceramic material preferably has a thickness on the order of 0.1 to 2.0 mm. To reinforce the thin layer of fine-pored, sintered or foamed ceramic material, a Stainless steel mesh can be introduced. In particular, such a fabric made of stainless steel is accommodated in an area corresponding to the sealing labyrinth of the finished brick in the form of strip-shaped or web-like projections running in the longitudinal direction of a brick, which protrude outwards from the layer of fine-pored ceramic material; this largely prevents the web-like or strip-like projections in the layer of fine-pored, sintered or foamed material from breaking off.
Aufgrund der hohen Abriebfestigkeit von feinporigem, gesintertem oder geschäumtem Keramikmaterial ist dessen Abnutzung bei einer Pressung im Vergleich zu dem Abrieb bei den üblicherweise verwendeten Gipsformen minimal, so daß eine Form gemäß der Erfindung in Abhängigkeit von dem zur Herstellung von Dachziegeln verwendeten Material eine Lebensdauer von einem halben bis zu einem Jahr und mehr haben kann. Bei Benutzung der erfindungsgemäßen Form entfallen somit insbesondere die täglichen Stillstandszeiten der Presse in der Größenordnung von 1h bis 1,5h, die bisher zum Ausspritzen verbrauchter Gipsformen und zum Einsetzen neuer, bereitgestellter Gips formen erforderlich waren. Damit wird auch das mit dem Herstellen, Bereitstellen und Ausspritzen neuer Gipsformen beschäftigte Personal nicht mehr benötigt, und es entfallen obendrein die gesamten Kosten für Gips.Because of the high abrasion resistance of fine-pored, sintered or foamed ceramic material, its wear during pressing is minimal compared to the abrasion with the plaster molds commonly used, so that a mold according to the invention has a service life of one depending on the material used for the production of roof tiles can have half to a year and more. When using the mold according to the invention, the daily downtimes of the press in the order of 1 hour to 1.5 hours, which were previously required for spraying out used plaster molds and for inserting new, provided plaster molds, are thus eliminated. This means that the personnel involved in the manufacture, provision and spraying of new gypsum molds are no longer required, and the entire cost of gypsum is also eliminated.
Gemäß einer weiteren vorteilhaften Ausbildung der erfindungsgemäßen Form besteht die Schicht aus grobporigem, gesintertem oder geschäumtem Keramikmaterial, vorzugsweise aus Siliziumcarbid oder Korund und weist, um eine Rückspülung mit Lösungsmitteln oder Wasser zu ermöglichen, eine Porosität auf, die um einen Faktor 3 bis 20 größer ist als die Porosität der Schicht aus feinporigem, gesintertem oder geschäumtem Keramikmaterial. Ferner sind vorzugsweise bei einer vorteilhaften Weiterbildung in dem der Schicht aus feinporigem, gesintertem oder geschäumtem Keramikmaterial abgewandten Bereich der darunter angeordneten Schicht aus grobporigem, gesintertem oder geschäumtem Keramikmaterial oder geschäumtem Beton eine Anzahl rohrförmiger Kanäle zum Ableiten der Flüssigkeit in Form von Wasser ausgebildet.According to a further advantageous embodiment of the mold according to the invention, the layer consists of coarse-pored, sintered or foamed ceramic material, preferably of silicon carbide or corundum and, in order to enable backwashing with solvents or water, has a porosity that is 3 to 20 times greater than the porosity of the layer of fine-pored, sintered or foamed ceramic material. Furthermore, in an advantageous development, the layer of the layer arranged below is preferably made in the region facing away from the layer of fine-pored, sintered or foamed ceramic material coarse-pored, sintered or foamed ceramic material or foamed concrete a number of tubular channels for draining the liquid in the form of water are formed.
Gemäß einer vorteilhaften Ausbildung der erfindungsgemäßen Form sind in der Schicht aus grobporigem Keramikmaterial oder geschäumtem Beton Hohlräume mit dazwischen stehen gelassenen, stützenden Zwischenstegen ausgebildet. Vorzungsweise weisen die Hohlräume in der Schicht aus großporigem, gesintertem oder geschäumtem Keramikmaterial eine Querschnittsfläche in der Größenordnung von 100mm2 auf, während die stütenden Zwischenstege ein Dicke von 4 bis 5mm haben.According to an advantageous embodiment of the mold according to the invention, cavities are formed in the layer of coarse-pore ceramic material or foamed concrete with supporting intermediate webs left between them. The cavities in the layer of large-pore, sintered or foamed ceramic material preferably have a cross-sectional area of the order of magnitude of 100 mm 2 , while the supporting intermediate webs have a thickness of 4 to 5 mm.
Durch die Ausbildung der Hohlräume in der Schicht aus großporigem Material ist eine beachtliche Materialersparnis erreicht, gleichzeitig ist die Strecke und damit die Zeit erheblich verkürzt, welche die aus dem zu verarbeitenden Material herausgepreßte Flüssigkeit in Form von Wasser benötigt, um die verhältnismäßig dünne Schichtstärke über den zahlreichen Hohlräumen in der Schicht aus grobporigem, gesintertem oder geschäumtem Keramikmaterial zu durchdringen. In die Hohlräume gelangende Flüssigkeit kann durch quer dazu verlaufende, rohrförmige Kanäle oder auch, wie bisher schon üblich, durch Unterdruck abgesaugt werden.The formation of the cavities in the layer of large-pore material saves a considerable amount of material, at the same time the distance and thus the time required for the liquid to be pressed out of the material to be processed in the form of water is reduced in order to keep the relatively thin layer thickness above the penetrate numerous cavities in the layer of coarse-pored, sintered or foamed ceramic material. Liquid entering the cavities can be sucked off through tubular channels running transversely thereto or, as was previously the case, by means of negative pressure.
Ferner kann zur Erhöhung der Haftung eine poröse Verbindungsschicht zwischen der Schicht aus feinporigem, gesintertem oder geschäumtem Keramikmaterial und der Schicht aus grobporigem, gesintertem oder geschäumtem Keramikmaterial vorgesehen werden.Furthermore, a porous connecting layer can be provided between the layer of fine-pored, sintered or foamed ceramic material and the layer of coarse-pored, sintered or foamed ceramic material to increase the adhesion.
In vorteilhafter Weise kann die erfindungsgemäße Form auch bei Schlickerguß oder Metallguß mit und ohne Vakuumbeaufschlagung verwendet werden.Advantageously, the mold according to the invention can also be used for slip casting or metal casting with and without vacuum application.
Gemäß einer Modifikation der Erfindung ist in der Form die mit dem zu verpressenden Material in Kontakt kommende Schicht eine Metallplatte, die von einer großen Anzahl feinster Löcher durchdrungen ist, unter dieser Platte ist wiederum eine Schicht aus großporigem, gesintertem oder geschäumtem Keramikmaterial oder aus geschäumtem Beton vorgesehen. Die Löcher in der Metallplatte sind zu der darunter befindlichen Schicht aus grobporigem, gestintertem oder geschäumtem Keramikmaterial oder geschäumtem Beton konisch aufgeweitet, damit das aus dem Lehm herausgepreßte Wasser schneller in die darunter befindliche Schicht aus geschäumtem Beton bzw. aus grobporigem, gesintertem oder geschäumtem Keramikmaterial gelangt.According to a modification of the invention, the layer that comes into contact with the material to be pressed is a metal plate that has a large number of the finest Holes are penetrated, a layer of large-pore, sintered or foamed ceramic material or foamed concrete is again provided under this plate. The holes in the metal plate are flared to the underlying layer of coarse-pored, sintered or foamed ceramic material or foamed concrete, so that the water squeezed out of the clay reaches the underlying layer of foamed concrete or of coarse-pored, sintered or foamed ceramic material more quickly .
Hierbei verlaufen die sich zur Schicht aus grobporigem, gesintertem oder geschäumtem Keramikmaterial oder geschäumtem Beton konisch erweiterenden Löcher etwa senkrecht zur Oberfläche der Metallplatte. Erforderlichenfalls sind in verschiedenen Bereichen gemaß einer weiteren vorteilhaften Weiterbildung der Erfindung die Löcher in einer unterschiedlichen Verteilungsdichte und/oder mit unterschiedlichen Durchmessern angeordnet. Die sich konisch erweiternden Löcher werden beispielsweise mittels Laser- oder Elektronenstrahlverfahren hergestellt.The holes that widen conically to form a layer of coarse-pored, sintered or foamed ceramic material or foamed concrete run approximately perpendicular to the surface of the metal plate. If necessary, the holes are arranged in a different distribution density and / or with different diameters in different areas according to a further advantageous development of the invention. The conically widening holes are produced, for example, by means of laser or electron beam processes.
Nachfolgend wird die Erfindung anhand von bevorzugten Ausführungsformen unter Bezugnahme auf die anliegende Zeichnung im einzelnen erläutert. Es zeigen:
- Fig.1
- schematisch in einer stark vergrößerten, unmaßstäblichen Darstellung einen Teil einer Schnittansicht durch eine Form gemäß der Erfindung;
- Fig.2
- eine ebenfalls schematische, unmaßstäbliche Darstellung einer Schnittansicht eines anderen Teilbereichs der Ausführungsform nach Fig.1, und
- Fig.3
- ebenfalls wieder schematisch in einer unmaßstäblichen Darstellung einen Teil einer Schnittansicht einer modifizierten Ausführung der erfindungsgemäßen Form.
- Fig. 1
- schematically in a greatly enlarged, scale representation, part of a sectional view through a mold according to the invention;
- Fig. 2
- a likewise schematic, not to scale representation of a sectional view of another partial area of the embodiment according to FIG. 1, and
- Fig. 3
- again schematically in an out of scale Representation of part of a sectional view of a modified embodiment of the mold according to the invention.
In Fig.1 ist schematisch und unmaßstäblich ein erstes Ausführungsbeispiel einer Form 1 gemäß der Erfindung dargestellt. Eine in Fig.1 obere Schicht 10 besteht aus feinporigem, gesintertem oder geschäumtem Keramikmaterial, während darunter eine weitere Schicht 11 aus grobporigem, gesintertem oder geschäumtem Keramikmaterial oder geschäumtem Beton vorgesehen ist. In dem in Fig.1 unteren Bereich der Schicht 11 sind rohrförmig ausgebildete Kanäle 110 vorgesehen, über welche bei der Herstellung von Preß-Dachziegeln die Flüssigkeit im wesentlichen in Form von Wasser aus dem Lehm, tonhaltigem oder ähnlichem Material abgeleitet wird.A first exemplary embodiment of a
Die Schicht 10 hat vorzugsweise eine Dicke von 1,5mm. Ferner sind vorzugsweise beide Schichten 10 und 11 durchgehend eingefärbt, so daß allein schon das Aufscheinen der Farbe der darunterliegenden Schicht 11 ein Hinweis dafür ist, daß die Schicht 10 aus feinporigem, gesintertem oder geschäumtem Keramikmaterial auf gebraucht ist.
In Fig.2 sind im Unterschied zu Fig.1 an der Oberseite der Schicht 10 aus feinporigem, gesintertem oder geschäumtem Keramikmaterial im Schnitt nach außen (in Fig.2 nach oben) vorstehende Vorsprünge 100 dargestellt, die in einer zur Zeichenebene senkrechten Richtung als leistenförmige bzw. stegartige, parallel zueinander verlaufende Vorsprünge ausgebildet sind, welche in der Negativform den im seitlichen Bereich jedes Dachziegels vorgesehenen Dichtlabyrinths entsprechen.In FIG. 2, in contrast to FIG. 1,
Um die Bruchsicherheit dieser aus feinporigem, gesintertem oder geschäumtem Keramikmaterial bestehenden Vorsprünge 100 zu erhöhen bzw. ein Abbrechen im wesentlichen auszuschließen, ist im Bereich solcher Vorsprünge 100 ein Stahlgewebe 20 aus vorzugsweise rostfreiem Stahl untergebracht, das in der Schnittdarstellung der Fig.1 und 2 lediglich als Punkte zu erkennen ist. Wie aus Fig.1 zu ersehen ist, ist das Stahlgewebe 20 zweckmäßigerweise auch in der gesamten Schicht aus feinporigem, gesintertem oder geschäumtem Keramikmaterial vorgesehen.In order to increase the fracture resistance of these
Wie aus Fig.2 zu ersehen ist, sind in der Schicht 11 aus grobporigem, gesintertem oder geschäumtem Keramikmaterial oder aus geschäumtem Beton Hohlräume 111 ausgebildet, zwischen welchen stützende Stege 112 stehengelassen worden sind. Die Hohlräume 111 haben eine Querschnittsfläche in der Größenordnung von 100mm2, während die stützenden Zwischenstege 112 eine Dicke in der Größenordnung von vorzugsweise 4 bis 5mm aufweisen. Durch das Vorsehen der Hohlräume 111 in der Schicht 11 ist eine beachtliche Materialersparnis erreicht und gleichzeitig muß die aus der Schicht 10 austretende Flüssigkeit im allgemeinen in Form von Wasser nur eine erheblich dünnere Schicht über den einzelnen Hohlräumen durchdringen. Die in die Hohlräume ausgetretene Flüssigkeit kann aus diesen beispielsweise durch den rohrförmigen Kanälen 110 in Fig.1 entsprechende Kanäle abgeleitet, oder auch wie bisher bei der Ziegelherstellung bereits üblich, mittels Unterdruck abgesaugt werden.As can be seen from FIG. 2,
In Fig.3 ist eine Modifikation einer Form 1' gemäß der Erfindung dargestellt. Bei dieser Ausführung ist über der Schicht 11 aus grobporigem, gesintertem oder geschäumtem Keramikmaterial oder aus geschäumtem Beton eine Stahlplatte 30 angeordnet, die von einer großen Anzahl Löcher 300 durchdrungen sind. In Fig.3 sind die im Schnitt wiedergegebenen Löcher 300 zu der dort vorgesehenen Schicht 11, aus geschäumtem Beton oder aus grobporigem, gesintertem oder geschäumtem Keramikmaterial konisch erweitert. Hierbei sind durch strichpunktierte Linien in den einzelnen Löchern 300 die jeweiligen Mittenachsen angedeutet. Die konischen Löcher 300 weisen einen Durchmesser 10µm bis 400µm auf.3 shows a modification of a mold 1 'according to the invention. In this embodiment, a
Claims (19)
- Mould for producing liquid-containing moulded articles, such as roof tiles of clay, a loamy or similar material, characterized in that a layer (10) of the mould (1) coming into contact with the material to be pressed consists of fine-pore, sintered or foamed ceramic material having a porosity of the order of magnitude of 10 Å (10 · 10-10 m) to 30µm, a porosity proportion between 5 to 60% depending on the material to be pressed and a layer thickness of the order of magnitude of 0.1 to 2.0mm, and
that the layer (11) therebelow is coarse-pore, sintered or foamed ceramic material or foamed concrete, having a porosity which is a factor of 3 to 20 times greater than the porosity of the fine-pore layer (10). - Mould according to claim 1, characterized in that the fine-pore, sintered or foamed ceramic material of the layer (10) consists of corundum, mullite, silicon carbide, silicon nitride or zirconium dioxide.
- Mould according to claim 1, characterized in that additives such as corundum, mullite, silicon carbide, silicon nitride, zirconium dioxide, are added to the fine-pore sintered or foamed ceramic material of the layer (10).
- Mould according to any one of claims 1 to 3, characterized in that the surface of the layer (10) of fine-pore, sintered or foamed ceramic material has a metallized layer.
- Mould according to any one of claims 1 to 3, characterized in that the surface of the layer (10) of fine-pore, sintered or foam material has an oxidation layer.
- Mould according to any one of claims 1 to 3, characterized in that to increase the conductivity metal particles are intercalated into the fine-pore, sintered or foamed ceramic material.
- Mould according to any one of the preceding claims, characterized in that for reinforcement a fabric of stainless steel is inserted into the thin layer (10) of fine-pore, sintered or foamed ceramic material.
- Mould according to claim 7, characterized in that in particular strip-like or web-like projections (100) extending parallel to each other and projecting outwardly from the layer (10) of fine-pore sintered or foamed ceramic material are reinforced by the steel fabric (20) of stainless steel.
- Mould according to any one of the preceding claims characterized in that the layer (11) of coarse-pore, sintered or foamed ceramic material consists of silicon carbide or corundum.
- Mould according to any one of the preceding claims, characterized in that a plurality of tubular passages (110) for draining the liquid are formed in the region of the layer (11) of coarse-pore sintered or foamed ceramic material or foamed concrete remote from the layer (10) of fine-pore, sintered or foamed ceramic material.
- Mould according to any one of the preceding claims, characterized in that in the layer (11) of coarse-pore, sintered or foamed ceramic material or foamed concrete cavities (111) having supporting intermediate webs (112) are formed.
- Mould according to claim 11, characterized in that the cavities (111) in the layer (11) have a cross-sectional area of the order of magnitude of 100mm2 and the supporting intermediate webs (112) a thickness of the order of magnitude of 4 to 5 mm,
- Mould according to claim 1, characterized in that to increase the bonding a porous bonding layer in provided between the layer (10) of fine-pore, sintered or foamed ceramic material and the layer (11) of coarse-pore sintered or foamed ceramic material.
- Use of the mould according to claims 1 to 13 in slip casting or metal casting with or without vacuum,
- Mould for producing liquid-containing press moulded articles, such as roof tiles of clay, a loamy or similar material, characterized in that a layer (10) of the mould (1) coming into contact with the material to be pressed is a metal plate (30) which is perforated by a large number of extremely fine holes (300) having a diameter between 10µm and 400µm, and that the layer (11) therebelow is coarse-pore, sintered or foamed ceramic material or foamed concrete.
- Mould according to claim 15 characterized in that the holes (300) in the metal plate (30) are conically widened.
- Mould according to any one of claims 15 or 16, characterized in that the holes (300) extend substantially perpendicularly to the metal plate surface (30a).
- Mould according to any one of claims 15 to 17, characterized in that the holes (300) are arranged in various regions in a different distribution density and/or with different diameters.
- Mould according to any one of claims 15 to 18, characterized in that the holes (300) are made by laser or electron beam methods.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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DE4225412 | 1992-07-31 | ||
DE4225412A DE4225412C1 (en) | 1992-07-31 | 1992-07-31 | |
PCT/EP1993/002048 WO1994003313A1 (en) | 1992-07-31 | 1993-07-30 | Mould for the production of mouldings containing liquid |
Publications (2)
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EP0607402A1 EP0607402A1 (en) | 1994-07-27 |
EP0607402B1 true EP0607402B1 (en) | 1997-11-12 |
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EP93917716A Expired - Lifetime EP0607402B1 (en) | 1992-07-31 | 1993-07-30 | Mould for the production of mouldings containing liquid |
Country Status (9)
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EP (1) | EP0607402B1 (en) |
CN (1) | CN1088150A (en) |
AT (1) | ATE160105T1 (en) |
AU (1) | AU666968B2 (en) |
CA (1) | CA2120157A1 (en) |
DE (1) | DE4225412C1 (en) |
TR (1) | TR28181A (en) |
WO (1) | WO1994003313A1 (en) |
ZA (1) | ZA935514B (en) |
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JPS6331710A (en) * | 1986-07-26 | 1988-02-10 | 東陶機器株式会社 | Manufacture of porous mold for pressure-molding pottery |
FR2602708B1 (en) * | 1986-08-05 | 1990-08-24 | Elmetherm Sa | PROCESS FOR THE MANUFACTURE OF MOLDS FOR THE PRODUCTION OF CERAMIC MATERIALS |
FR2602504B1 (en) * | 1986-08-07 | 1992-02-14 | Desmarquest Ceramiques Tech | PROCESS FOR PRODUCING OPEN POROSITY SILICON NITRIDE MATERIALS AND APPLICATION TO POROUS MOLDS |
JPH03290202A (en) * | 1990-04-06 | 1991-12-19 | Kawasaki Steel Corp | Wet molding tool |
FR2674172B1 (en) * | 1991-03-21 | 1993-06-18 | Ind Regionale Batiment | PRESSING MOLD FOR PRODUCING ARTICLES OBTAINED FROM A MOLDABLE MATERIAL IN THE FORM OF WET PULP. |
-
1992
- 1992-07-31 DE DE4225412A patent/DE4225412C1/de not_active Expired - Fee Related
-
1993
- 1993-07-30 CA CA002120157A patent/CA2120157A1/en not_active Abandoned
- 1993-07-30 AT AT93917716T patent/ATE160105T1/en not_active IP Right Cessation
- 1993-07-30 TR TR00681/93A patent/TR28181A/en unknown
- 1993-07-30 WO PCT/EP1993/002048 patent/WO1994003313A1/en active IP Right Grant
- 1993-07-30 ZA ZA935514A patent/ZA935514B/en unknown
- 1993-07-30 EP EP93917716A patent/EP0607402B1/en not_active Expired - Lifetime
- 1993-07-30 AU AU47056/93A patent/AU666968B2/en not_active Ceased
- 1993-07-31 CN CN93117645A patent/CN1088150A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
AU4705693A (en) | 1994-03-03 |
CN1088150A (en) | 1994-06-22 |
ATE160105T1 (en) | 1997-11-15 |
EP0607402A1 (en) | 1994-07-27 |
WO1994003313A1 (en) | 1994-02-17 |
ZA935514B (en) | 1994-09-20 |
TR28181A (en) | 1996-02-06 |
AU666968B2 (en) | 1996-02-29 |
DE4225412C1 (en) | 1993-04-29 |
CA2120157A1 (en) | 1994-02-17 |
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