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EP0483002A2 - Vorrichtung zur Entnahme von Suspensionsproben - Google Patents

Vorrichtung zur Entnahme von Suspensionsproben Download PDF

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Publication number
EP0483002A2
EP0483002A2 EP91402827A EP91402827A EP0483002A2 EP 0483002 A2 EP0483002 A2 EP 0483002A2 EP 91402827 A EP91402827 A EP 91402827A EP 91402827 A EP91402827 A EP 91402827A EP 0483002 A2 EP0483002 A2 EP 0483002A2
Authority
EP
European Patent Office
Prior art keywords
slurry
rotator
holes
blocks
sampling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP91402827A
Other languages
English (en)
French (fr)
Other versions
EP0483002A3 (en
EP0483002B1 (de
Inventor
Atsushi C/O Hiroshima Technical Institute Tatani
Naohiko C/O Hiroshima Technical Institute Ukawa
Susumu C/O Hiroshima Technical Institute Okino
Tooru C/O Hiroshima Technical Inst. Takashina
Tsumoru C/O Hiroshima Technical Inst. Nakamura
Tokuma C/O Mitsubishi Jukogyo K.K. Arai
Yoshihiro Shiraishi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Publication of EP0483002A2 publication Critical patent/EP0483002A2/de
Publication of EP0483002A3 publication Critical patent/EP0483002A3/xx
Application granted granted Critical
Publication of EP0483002B1 publication Critical patent/EP0483002B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
    • G01N35/10—Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices
    • G01N35/1095—Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices for supplying the samples to flow-through analysers
    • G01N35/1097—Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices for supplying the samples to flow-through analysers characterised by the valves
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/10—Devices for withdrawing samples in the liquid or fluent state
    • G01N1/20—Devices for withdrawing samples in the liquid or fluent state for flowing or falling materials
    • G01N1/2035—Devices for withdrawing samples in the liquid or fluent state for flowing or falling materials by deviating part of a fluid stream, e.g. by drawing-off or tapping

Definitions

  • the present invention relates to a device for sampling for analysis a liquid in which precipitating solid particles are suspended (hereinafter referred to as a slurry) and which is kept in a column or tank of an exhaust gas cleaning apparatus or waste water treating apparatus or the like which uses such slurry, and to a method for sampling such slury for analysis.
  • a slurry a liquid in which precipitating solid particles are suspended
  • a wet lime exhaust gas desulfurizer functions to clean an exhaust gas containing SO2 or the like, such as boiler exhaust gas, through desulfurization with a slurry which is formed by suspending, for example, fine particles of lime-stone into water and which is kept in a column or tank.
  • the analysis for the composition of the slurry in such an apparatus has been carried out by quantitative and manual sampling of a small amount of sample required for the analysis with a pipet, and pouring it into an analyzer.
  • an object to be collected is a slurry in which precipitating solid particles are suspended, some solid particles precipitate and deposit in the sampling system, so that the following troubles have conventionally been observed.
  • the purpose of the present invention is to solve the above problems and provide an automatic sampling device and a method for sampling capable of preventing solid particles from precipitating and sedimenting when the slurry is sampled from a column or tank in an "on-line" fashion, so that stable feed of the slurry into an analyzer becomes possible over a long period of time, and so that composition data on the slurry can be obtained and utilized for controlling the slurry composition or for use as control signals.
  • the present invention provides a slurry sampling device for sampling a slurry in which solid particles are dispersed, which is characterized in that the device comprises an upper and lower blocks, and a rotator for collection which is rotatably held between the blocks, the rotator being provided with a plurality of through holes having a volume corresponding to the amount of sample to be collected, the upper and lower blocks being provided with a slurry conduit and a carrier conduit which can be communicated with the through holes so that slurry and carrier fluid can flow therethrough, and arc-shaped long grooves are provided on portions of the upper and lower blocks where an end of the slurry conduit comes into contact with the rotator, at least one of the through holes is thereby constantly in contact with the long grooves.
  • the present invention also provides a method for sampling slurry in which a part of slurry is partially bypassed from a slurry tank and resutrned to the slurry tank, the slurry is sampled intermittently from a bypassing line for the partially bypassed slurry and sent to an analyzer so that the composition of the slurry can be analyzed.
  • Figs. 1 (a) and (b) illustrate a principle block diagram for an embodiment of the automatic sampling device of the present invention
  • Fig. 2 illustrates a flow chart for the case in which slurry kept in a tank is sampled by an automatic sampling device and the sample thus obtained is introduced into an analyzer.
  • slurry kept in a slurry tank 1 is sampled by a slurry pump 2 and transferred to an automatic sampling device 3.
  • the amount of the slurry forwarded by the slurry pump 2 is overwhelmingly larger than that required for the analyzer 6, so that most of the slurry is continuously returned to the slurry tank 1 through a return pipe 4. Accordingly, the slurry is transferred as a uniformly dispersed slurry without the precipitation and sedimentation of the solid particles in the slurry.
  • a slurry introducing pipe 101 provided in the main body of the sampling device is connected to a conduit for the slurry forwarded by the slurry pump 2 in Fig. 2, as indicated by the arrow mark A in Fig. 1 (b).
  • the slurry flows into the main body from the lower part thereof for the removal of air bubbles in order to prevent precipitation in the slurry.
  • a slurry sampling rotator 102 is provided between an upper and lower blocks 105 and 109.
  • the slurry sampling rotator 102 can be rotated by a driving gear 103 which is rotated in turn by an external motor (not shown) and through a rotation gear 104 fitted to the outer circumference of the slurry sampling rotator 102.
  • a carrier introducing pipe 107 for the introduction of a carrier fluid 106 for analysis and a slurry discharging pipe 108 are connected to the upper block 105 of the main body.
  • a carrier exhausting pipe 110 for exhausting a mixture 11 of the carrier fluid for analysis and a sample liquid, and the slurry introducing pipe 101 are connected to the lower block 109 of the main body.
  • the rotator 102 for the collection of sample has a plurality of through holes 111, and is held between the upper block 105 and the lower bock 109, and can be rotated around a rotation axis 112.
  • Reference numeral 116 indicates a fixing nut for the rotation axis 112.
  • the slurry introducing pipe 101 and the slurry exhausting pipe 108, as well as the carrier introducing pipe 107 and the carrier exhausting pipe 110, are arranged on a vertical straight line, respectively.
  • a slurry inlet long groove 113 is provided on the surface where the opening of the slurry introducing pipe 101 in the lower block 109 comes into contact with the rotator 102 for the collection of sample
  • a slurry outlet long groove 114 is provided on the surface where the opening of the slurry exhausting pipe 108 of the main body of the upper block 105 comes into contact with the rotator 102, so that the arrangement of these long grooves is symmetrical with respect to the rotator 102 for the collection of sample.
  • the long groove angle ⁇ is set to be identical with the angle ⁇ between through holes, so that one of the through holes 111 is always within the range of the long grooves.
  • the long grooves 113 and 114 are provided in the half portions on the side of the slurry inlet and outlet, if two or three through holes are provided as shown in Figs. 4 and 5.
  • the slurry stored in the through holes 111 is carried by an analytical carrier fluid to be sent to the analyzer 6 through the carrier fluid exhausting pipe 110.
  • the rotator 102 for the collection of sample may comprise a plurality of through holes which are suitably arranged, and an angle between the through holes should be set to a suitable value.
  • the rotator may have at least two through holes as shown in Fig. 4, and three through holes as shown in Fig. 5.
  • the flow rate of the slurry which flows through the slurry inlet long groove 113 and the through holes 111 and the slurry outlet long groove 114 and the slurry exhausting pipe 108 via the slurry introducing pipe 101, to a flow rate value of 0.2 m/sec or more, so that the precipitation and deposition of the solid particles may be prevented.
  • the slurry was automatically sampled from the slurry tank 1 containing the absorbent slurry through the slurry pump 2 by means of the automatic sampling device 3, and the excess amount of the slurry was returned to the slurry tank 1 through the return pipe 4. Simultaneously, the collected sample was forwarded to the carbonate analyzer 6 together with the analytical carrier fluid 5, and the concentration of CaCO3 particles contained in the absorbent slurry could be detected stably and with high accuracy over a long period of time. Using the signals thus obtained for the process control of the exhaust gas desulfurizer, it was possible to obtain excellent operation results without troubles.

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  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Hydrology & Water Resources (AREA)
  • Sampling And Sample Adjustment (AREA)
EP91402827A 1990-10-24 1991-10-23 Vorrichtung zur Entnahme von Suspensionsproben Expired - Lifetime EP0483002B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP110481/90 1990-10-24
JP1990110481U JP2527276Y2 (ja) 1990-10-24 1990-10-24 スラリーのサンプリング装置

Publications (3)

Publication Number Publication Date
EP0483002A2 true EP0483002A2 (de) 1992-04-29
EP0483002A3 EP0483002A3 (en) 1992-09-23
EP0483002B1 EP0483002B1 (de) 1996-02-21

Family

ID=14536819

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91402827A Expired - Lifetime EP0483002B1 (de) 1990-10-24 1991-10-23 Vorrichtung zur Entnahme von Suspensionsproben

Country Status (7)

Country Link
US (1) US5295400A (de)
EP (1) EP0483002B1 (de)
JP (1) JP2527276Y2 (de)
CN (1) CN1023256C (de)
DE (1) DE69117246T2 (de)
DK (1) DK0483002T3 (de)
FI (1) FI102323B (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5345828A (en) * 1992-07-13 1994-09-13 Pmmi Process plant sample collection system and method
US6966336B1 (en) * 2003-01-24 2005-11-22 Sandia National Laboratories Fluid injection microvalve
US6912909B1 (en) 2004-07-22 2005-07-05 Appcor At Prindle Station Diaphragm-type pressure sensors for slurries and similar flows
JP4670590B2 (ja) * 2005-10-28 2011-04-13 株式会社島津製作所 流路切換バルブ及びそれを用いた高速液体クロマトグラフ
EP2021747B1 (de) * 2006-04-26 2018-08-01 Halliburton Energy Services, Inc. Faseroptischer seismischer mems-sensor mit von schwenkbalken getragener masse
US8397592B2 (en) 2010-02-19 2013-03-19 Vertex Pharmaceuticals, Inc. Systems and methods for inline sampling
US11035480B2 (en) * 2016-02-24 2021-06-15 Leanna Levine and Aline, Inc. Mechanically driven sequencing manifold
CN110360340B (zh) * 2018-09-07 2025-01-28 上海北昂医药科技股份有限公司 电动分配定量装置
CN113203597B (zh) * 2021-04-21 2023-04-11 华能伊敏煤电有限责任公司汇流河热电分公司 一种热电厂用脱硫塔取样装置

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2141877A1 (de) * 1971-06-18 1973-01-26 Boehringer Mannheim Gmbh
FR2250111A1 (en) * 1973-11-07 1975-05-30 Alsacienne Services Ind Presampling device for liquids - removes samples required for quality control analysis from continuously flowing liquid
EP0019052A1 (de) * 1979-05-10 1980-11-26 RHE Händel Engineering GmbH Vorrichtung zum Entnehmen von Proben aus zähflüssigen Kunstharzen aus einem Behälter
US4346610A (en) * 1979-04-28 1982-08-31 Japan Spectroscopic Co., Ltd. Device for introducing micro amount of sample into an analyzing apparatus

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB855234A (en) * 1956-02-27 1960-11-30 Perkin Elmer Corp Sampling devices
JPS5111880Y2 (de) * 1971-08-11 1976-03-31
US4068528A (en) * 1976-01-19 1978-01-17 Rheodyne Incorporated Two position rotary valve for injecting sample liquids into an analysis system
US4152391A (en) * 1977-12-16 1979-05-01 Coulter Electronics, Inc. Liquid transfer valve
US4167117A (en) * 1978-07-10 1979-09-11 Exxon Production Research Company Apparatus and method for sampling flowing fluids and slurries
US4444066A (en) * 1981-06-29 1984-04-24 Beckman Instruments, Inc. High pressure sample injector valve
US4506558A (en) * 1983-03-03 1985-03-26 Rheodyne Incorporated Injector with minimal flow-interrupt transient
US4702889A (en) * 1986-01-16 1987-10-27 Coulter Electronics Inc. Liquid sampling valve
US4823622A (en) * 1986-12-16 1989-04-25 Spectra Physics Sample metering valve for a sample preparation system
FI79196C (fi) * 1987-04-23 1989-11-10 Outokumpu Oy Anordning foer provtagning ur substans innehaollande fast aemne.
US4957008A (en) * 1988-12-28 1990-09-18 Coulter Electronics, Inc. Fluid sampling and transfer valve assembly
US4948565A (en) * 1989-04-25 1990-08-14 Fisher Scientific Company Analytical system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2141877A1 (de) * 1971-06-18 1973-01-26 Boehringer Mannheim Gmbh
FR2250111A1 (en) * 1973-11-07 1975-05-30 Alsacienne Services Ind Presampling device for liquids - removes samples required for quality control analysis from continuously flowing liquid
US4346610A (en) * 1979-04-28 1982-08-31 Japan Spectroscopic Co., Ltd. Device for introducing micro amount of sample into an analyzing apparatus
EP0019052A1 (de) * 1979-05-10 1980-11-26 RHE Händel Engineering GmbH Vorrichtung zum Entnehmen von Proben aus zähflüssigen Kunstharzen aus einem Behälter

Also Published As

Publication number Publication date
JPH0469751U (de) 1992-06-19
FI102323B1 (fi) 1998-11-13
EP0483002A3 (en) 1992-09-23
EP0483002B1 (de) 1996-02-21
DE69117246T2 (de) 1996-07-11
DE69117246D1 (de) 1996-03-28
US5295400A (en) 1994-03-22
JP2527276Y2 (ja) 1997-02-26
FI914859A (fi) 1992-04-25
CN1061094A (zh) 1992-05-13
FI102323B (fi) 1998-11-13
DK0483002T3 (da) 1996-03-18
CN1023256C (zh) 1993-12-22
FI914859A0 (fi) 1991-10-15

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