EP0426793A1 - Verfahren zum herstellen eines gegebenenfalls plattenförmigen kunstharz-druckformkörpers sowie vorprodukt zum einsatz bei einem solchen verfahren. - Google Patents
Verfahren zum herstellen eines gegebenenfalls plattenförmigen kunstharz-druckformkörpers sowie vorprodukt zum einsatz bei einem solchen verfahren.Info
- Publication number
- EP0426793A1 EP0426793A1 EP90906776A EP90906776A EP0426793A1 EP 0426793 A1 EP0426793 A1 EP 0426793A1 EP 90906776 A EP90906776 A EP 90906776A EP 90906776 A EP90906776 A EP 90906776A EP 0426793 A1 EP0426793 A1 EP 0426793A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- binder
- compressed
- layer structure
- layer
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 39
- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 11
- 239000000057 synthetic resin Substances 0.000 title claims abstract description 11
- 239000011230 binding agent Substances 0.000 claims abstract description 49
- 229920002522 Wood fibre Polymers 0.000 claims abstract description 24
- 229920005989 resin Polymers 0.000 claims abstract description 20
- 239000011347 resin Substances 0.000 claims abstract description 20
- 239000000835 fiber Substances 0.000 claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 239000000123 paper Substances 0.000 claims abstract description 10
- 229920002678 cellulose Polymers 0.000 claims abstract description 6
- 239000001913 cellulose Substances 0.000 claims abstract description 6
- 238000009833 condensation Methods 0.000 claims abstract description 6
- 230000005494 condensation Effects 0.000 claims abstract description 6
- 238000010924 continuous production Methods 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 5
- 239000002025 wood fiber Substances 0.000 claims description 23
- 239000012876 carrier material Substances 0.000 claims description 14
- 230000006835 compression Effects 0.000 claims description 10
- 238000007906 compression Methods 0.000 claims description 10
- 239000011148 porous material Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000748 compression moulding Methods 0.000 claims description 2
- 239000002657 fibrous material Substances 0.000 claims description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 239000013067 intermediate product Substances 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract description 6
- 229920001568 phenolic resin Polymers 0.000 abstract description 6
- 238000003825 pressing Methods 0.000 abstract description 4
- 239000005011 phenolic resin Substances 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 30
- 238000001035 drying Methods 0.000 description 3
- 239000012792 core layer Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/06—Making particle boards or fibreboards, with preformed covering layers, the particles or fibres being compressed with the layers to a board in one single pressing operation
Definitions
- the invention relates to a process for the production of a synthetic resin compression molding, in which cellulose-containing fibers such as wood fibers and a binder are mixed with a condensation resin or resin mixture based on phenols and / or amino compounds and aldehyde, such as formaldehyde, and optionally together with others Materials such as top layers and / or intermediate layers are hot pressed while the binder is curing.
- the invention further relates to a preliminary product which is suitable for being used in such a method.
- a method of the aforementioned type is known from EP 0081147 B1.
- This patent relates to a method for producing a decorative building board, in which an aqueous alkaline solution or dispersion of a phenol-formaldehyde resin is applied to wood fibers and the wood fibers resinated in this way are dried to a residual moisture content of 2 to 15%.
- a fiber mat is then formed from the resin-coated and dried wood fibers, the mat is mechanically pre-compressed and then hot-pressed in one or more layers arranged one above the other to form a core layer, the decorative layer being applied to the core layer at the same time as the pressing or after this .
- a building board is to be produced which has similar properties to the laminated boards which are produced in the customary manner Hot pressing of so-called "prepregs", which are papers impregnated with curable synthetic resins in a dry state, are produced.
- pregs papers impregnated with curable synthetic resins in a dry state
- the paper used is a material that is made from wood as a raw material using a relatively complex and environmentally harmful process.
- the invention is first of all based on the object of specifying a method of the type mentioned at the beginning, in which one does not require a special process step for resin coating the wood fibers and in which, according to an advantageous variant of the invention, using readily flowable condensation resin binders, the disadvantages mentioned of the known method described above can be avoided.
- the object underlying the invention is first in solved the method according to the invention, which is characterized in that for the continuous production of a pre-compact or a raw plate on a longitudinally moving web-shaped carrier material, a layer of a liquid binder is applied that to this fiber mass of cellulose-containing fibers such as wood fibers or bleached pulp of uniform thickness is applied in the form of a bed, a fiber cake or a mat, that if necessary a second web-shaped carrier material, to which a further layer of the liquid binder has previously been applied, is applied with the binder layer down onto the fiber mass, so that the layer structure thus formed continuously an average average density in the range between 600 and 1400 kg / m 3 , but advantageously between 800 and 1400 kg / m 3 , is compressed and heated to a higher temperature at which the viscosity of the binder is reduced so that the binder penetrates at least almost completely into the pore volume of the compressed fiber mass and is subsequently cured if necessary.
- fibrous materials such as paper
- the method according to the invention is characterized in that with a moisture content of the fiber mass used of at most 10% by weight, preferably at most 8% by weight, a condensation resin or resin mixture in liquid form is used as the binder for producing the binder layers which has a solid resin content of more than 80% by weight and a water content of at most 8% by weight, preferably at most 6% by weight, and the surcharge if appropriate contains substances such as color pigments.
- the layer structure is largely heated before it is compressed by means of electromagnetic high-frequency heating.
- the method according to the invention is characterized in that, at or after the end of the heating phase and the compression phase, the layer structure is compressed again briefly and its pore volume is reduced so much that the binder is practically uniformly distributed in the pore volume.
- This brief compression of the layer structure can advantageously take place in a calender.
- the method according to the invention is characterized in that the compressed layer structure passes through a cooling section after the end of the heating phase.
- the invention further relates to the compressed layer structure produced during the process according to the invention as a preliminary product, which can advantageously be used as a pre-compact in the further process steps for the production of synthetic resin compression molded articles.
- FIG. 1 in the figure is a schematic representation of a device for the continuous production of a pre-pressed ge shows.
- This device essentially consists - in the production direction (see arrow) of the manufacturing process one after the other - from a rolling device 1 for a first carrier material web 2, a belt conveyor 3 with a first binder application station 4 and a device 5 for producing and feeding a wood fiber cake, a take-off device 6 for a second carrier material web 7 with a second binder application station 8, a heatable belt press 10, as well as a cooled belt press 11 and a cutting device 12.
- the device 5 for producing and feeding a wood fiber cake consists of a wood fiber scattering device 13 with a belt conveyor 14, a compression belt 15, an isotope thickness measuring device 16 and a downstream transfer belt conveyor 17.
- a carrier material consisting of a sodium kraft paper with a weight per unit area of 200 g / m 2 , which is impregnated with 40% resin application - a phenol-formaldehyde resin,
- a binder consisting of a highly concentrated phenol-formaldehyde resin with a solid resin content of 86% and a water content of 5%.
- the solid resin content is determined by reweighing after drying in a drying cabinet for 60 min at 130 ° C.
- the water content of the resin is determined using the known Karl Fischer method.
- the viscosity of the binder at room temperature is approximately 45,000 mPa.s.
- the carrier material web 2 is continuously pulled off the unrolling device 1 and runs over a belt conveyor 3. From the first binder application station 4 arranged above the belt conveyor 3, the viscous phenolic resin binder 18 is used to form a binder layer 19 with a thickness of 0 , 5 mm applied.
- a wood fiber cake 20 is continuously produced, which is placed at 21 on the binder layer 19 applied to the open belt conveyor 3.
- 13 wood fibers in the form of a bed 22 with a bed height of 100 mm and a density of about 30 kg / m 3 are sprinkled with the aid of the scattering device.
- This bed 22 is then compressed to a thickness of approximately 60 mm by means of the circumferential compression belt 15.
- the basis weight of the wood fiber cake 20 thus produced is then kept constant with the aid of the isotope thickness measuring device and, for example, by controlling the spreading device.
- the second carrier material web 7 is continuously withdrawn from the take-off device 6, which has a supply roll 23, a support plate 24 and a plurality of deflection rollers 25, and as it slides over the support plate 24 from the second binder application station 8 - in an analogous manner to the first carrier material web 2 - provided with a 0.5 mm thick binder layer 26.
- the carrier material web 7 coated in this way is then continuously pressed onto the wood fiber cake 20, with the binder layer 26 facing downward, so that a layer structure 27 now results, which consists of the wood fiber cake 20, which is provided on both sides by carrier material webs 2 provided with binder layers 19, 26 , 7 is covered.
- This layer structure 27 now passes through the radio frequency Heater 9, in which it is heated to a temperature of 80-140 ° C. At these temperatures, the viscosity of the binder drops to viscosity values of 100 to 300 mPa.s.
- the layer structure 27 heated in this way is fed to the entrance of the heated belt press 10 and compressed to a density of approximately 300 kg / m 3 in its feed area.
- the binder penetrates into the pore volume of the compressed wood fiber cake due to its reduced viscosity due to the heating, with a long residence time in the belt press 10 of 3 min Uniformity of the binder distribution over the pore volume is achieved.
- the compressed layer structure 27 ' after leaving the belt press 10, passes through an infrared heating device and then through a calender in which the layer structure 27' which has already been compressed is briefly further strongly compacted.
- the pore volume in the layer structure is reduced to such an extent that it is practically completely filled by the amount of binder and the binder is thus uniformly wetted on the surface of the wood fibers. This can cause any unequal moderate in the distribution of the binder within the wood fiber mass, which still exist in the layer structure 27 'when leaving the belt press 10, can be further compensated in an advantageous manner.
- the plate-shaped high-pressure molded body which was removed from the press after cooling and cooled down has a flexural strength of 140 N / mm 2 , a tensile strength of 70 N / mm 2 and a water absorption of approximately 0.8%.
- the method for producing a pre-compact described with reference to the figure, which is used in the production of a plate-shaped high-pressure molded body, can, with corresponding modifications, also be used directly for producing high-pressure molded bodies.
- This is then realized, for example, by increasing the pressing pressure in the belt press 10, for example to 70 bar and the pressing temperature to 150 ° C., and extending the dwell time of the layer structure, for example to 6 minutes, so that the synthetic resin binder contained in the layer structure initially flows well and then hardens.
- a raw plate is then removed from the belt press 10 and is cooled to 30 ° C. in the downstream cooled belt press 11. The raw plate is then cut to length and decorative lacquered or coated for further use in a known manner.
- the molded articles produced by the process according to the invention can largely be used in the same field of application as the conventional decorative synthetic resin high-pressure laminates of greater thickness (e.g. between 3 and 15 mm thick), e.g. So for the production of self-supporting components or as weatherproof panels for outdoor use.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Printing Methods (AREA)
- Moulding By Coating Moulds (AREA)
- Paper (AREA)
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT1061/89A AT392758B (de) | 1989-05-03 | 1989-05-03 | Verfahren zum herstellen eines gegebenenfalls plattenfoermigen kunstharz-druckformkoerpers sowie vorprodukt zum einsatz bei einem solchen verfahren |
AT1061/89 | 1989-05-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0426793A1 true EP0426793A1 (de) | 1991-05-15 |
EP0426793B1 EP0426793B1 (de) | 1993-08-04 |
Family
ID=3505743
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90906776A Expired - Lifetime EP0426793B1 (de) | 1989-05-03 | 1990-04-27 | Verfahren zum herstellen eines gegebenenfalls plattenförmigen kunstharz-druckformkörpers sowie vorprodukt zum einsatz bei einem solchen verfahren |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0426793B1 (de) |
JP (1) | JPH03506001A (de) |
AT (2) | AT392758B (de) |
AU (1) | AU632811B2 (de) |
BR (1) | BR9006755A (de) |
CA (1) | CA2032170A1 (de) |
WO (1) | WO1990013403A1 (de) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT397805B (de) * | 1992-03-04 | 1994-07-25 | Isovolta | Verfahren zur herstellung eines kunstharz-druckformkörpers |
ES2140695T3 (es) * | 1994-08-01 | 2000-03-01 | Tarkett Sommer Sa | Procedimiento de fabricacion de un revestimiento de suelo con paramento de madera natural o sintetica, y productos obtenidos. |
NL1007314C2 (nl) * | 1997-10-20 | 1999-04-21 | Syntech Holdings Bv | Vormdeel, in het bijzonder in de vorm van een plaat, dat een samengeperst mengsel van polyurethan, bindmiddel en vulmiddel omvat, werkwijze en inrichting voor het vervaardigen van een dergelijk vormdeel, alsmede vloerplaten, een sporthal voorzien van dergelijke vloerplaten, relatiegeschenken en meubels. |
CN1136084C (zh) * | 1997-10-20 | 2004-01-28 | 合成技术控股有限公司 | 一种模制件及其制造方法 |
NL1008899C2 (nl) * | 1998-04-16 | 1999-10-19 | Syntech Holdings Bv | Vormdeel, in het bijzonder in de vorm van een plaat, dat een samengeperst mengsel van bindmiddel en vulmiddel omvat, werkwijze en inrichting voor het vervaardigen van een dergelijk vormdeel, alsmede vloerplaten, een sporthal voorzien van dergelijke vloerplaten, plafondplaten, relatiegeschenken, kunstvoorwerpen en meubels. |
CN101758540B (zh) * | 2010-01-25 | 2013-03-20 | 西北农林科技大学 | 一种重组材板坯铺装机 |
HUE050762T2 (hu) * | 2015-12-16 | 2021-01-28 | SWISS KRONO Tec AG | Eljárás egy sima felületû OSB lemez elõállítására |
CN106003275B (zh) * | 2016-07-01 | 2018-01-05 | 鄂尔多斯市华林沙柳科技有限公司 | 一种以灌木为原料制造木基型材的自动生产设备及方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2831794A (en) * | 1958-04-22 | Process for manufacturing veneer panels | ||
BE500838A (de) * | 1950-01-27 | |||
FR1099184A (fr) * | 1953-02-19 | 1955-08-31 | Abitibi Power & Paper Co | Planches artificielles |
FR1283609A (fr) * | 1961-03-13 | 1962-02-02 | Svenska Cellulosa Ab | Procédé de préparation d'articles moulés durs ou demi-durs en fibre de bois, et notamment de panneaux en fibre de bois possédant une surface de recouvrement résistante |
DE1453390A1 (de) * | 1962-05-26 | 1969-03-06 | Holztechnik Anstalt | Verfahren zur Oberflaechenveredelung von Pressplatten |
DE1653237B1 (de) * | 1967-12-23 | 1971-05-13 | Hombak Maschinenfab Kg | Verfahren und Vorrichtung zum Kalibrieren und zur gleichzeitigen Quellungsverguetung von Holzwerkstoffplatten |
DE1703076A1 (de) * | 1968-03-28 | 1972-01-05 | Teutoburger Sperrholzwerk Geor | Spanplatte sowie Verfahren zu ihrer Herstellung |
-
1989
- 1989-05-03 AT AT1061/89A patent/AT392758B/de not_active IP Right Cessation
-
1990
- 1990-04-27 AT AT90906776T patent/ATE92393T1/de active
- 1990-04-27 JP JP2506510A patent/JPH03506001A/ja active Pending
- 1990-04-27 WO PCT/AT1990/000042 patent/WO1990013403A1/de active IP Right Grant
- 1990-04-27 AU AU55505/90A patent/AU632811B2/en not_active Ceased
- 1990-04-27 EP EP90906776A patent/EP0426793B1/de not_active Expired - Lifetime
- 1990-04-27 BR BR909006755A patent/BR9006755A/pt unknown
- 1990-04-27 CA CA002032170A patent/CA2032170A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of WO9013403A1 * |
Also Published As
Publication number | Publication date |
---|---|
ATA106189A (de) | 1990-11-15 |
JPH03506001A (ja) | 1991-12-26 |
AU5550590A (en) | 1990-11-29 |
CA2032170A1 (en) | 1990-11-04 |
ATE92393T1 (de) | 1993-08-15 |
EP0426793B1 (de) | 1993-08-04 |
AU632811B2 (en) | 1993-01-14 |
BR9006755A (pt) | 1991-08-06 |
WO1990013403A1 (de) | 1990-11-15 |
AT392758B (de) | 1991-06-10 |
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