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EP0336184A1 - Monoformylated 3,3'-diaminopropyl amine, process for its preparation and its use - Google Patents

Monoformylated 3,3'-diaminopropyl amine, process for its preparation and its use Download PDF

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Publication number
EP0336184A1
EP0336184A1 EP89104900A EP89104900A EP0336184A1 EP 0336184 A1 EP0336184 A1 EP 0336184A1 EP 89104900 A EP89104900 A EP 89104900A EP 89104900 A EP89104900 A EP 89104900A EP 0336184 A1 EP0336184 A1 EP 0336184A1
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EP
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Prior art keywords
formamide
monoformylated
acrylonitrile
mol
preparation
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EP89104900A
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German (de)
French (fr)
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EP0336184B1 (en
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Hans-Joachim Dr. Scholl
Helmut Dr. Reiff
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Bayer AG
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Bayer AG
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5006—Amines aliphatic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/34—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups
    • C07C233/35—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/36—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
    • C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
    • C08G18/0847—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of solvents for the polymers
    • C08G18/0852—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of solvents for the polymers the solvents being organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3228—Polyamines acyclic

Definitions

  • the present invention relates to new, monoformylated 3,3'-diaminodipropylamines or mixtures, a process for their preparation from acrylonitrile / formamide and subsequent hydrogenation and their use as chain extenders in the production of polyurethanes by the isocyanate polyaddition process.
  • a process for their preparation was also found, which is characterized in that acrylonitrile and formamide are added to the N, N-bis (2-cyanoethyl) formamide with the addition of a 4-aminopyridine derivative and subsequently to the monoformylated 3,3 '-Diaminopropylamine mixture of formula I and II hydrogenated.
  • N, N-bis (2-cyanoethyl) formamide is obtained from 2 moles of acrylonitrile and 1 mole of formamide with catalytic amounts of sodium.
  • DE-OS 3 520 982 describes reactions of acrylonitrile with formamide in the presence of a tertiary amine base to give 2- (N-formylamino) propionitrile. According to the statements made there, selectivity and yields are high. However, the bisadduct N, N-bis (2-cyanoethyl) formamide was not found.
  • N, N-bis (2-cyanoethyl) formamide is formed at all by the process according to the invention, especially in high yields, good selectivity and purity.
  • acrylonitrile Based on 1 mole of acrylonitrile, for example 0.5 to 10 moles of formamide can be used. The amount is preferably 0.5 to 2 mol.
  • Suitable 4-aminopyridine derivatives are those of the formula (III) in the R1 and R2 independently of one another are a monovalent C1- to C6-alkyl radical or R1 and R2 together represent a double-bonded C3- to C5-alkyl radical.
  • N, N-Dimethyl-4-aminopyridine or 4-pyrrolidinopyridine is preferably used.
  • the amount of this catalytically active base is not critical. In order to achieve a sufficiently rapid conversion, 0.5 to 10 mol% are usually used per mole of acrylonitrile.
  • Acrylonitrile is used as a technical product.
  • This product contains customary polymerization inhibitors in a small amount.
  • the process can be carried out without a solvent or preferably with the use of a solvent.
  • Polar solvents such as e.g. Tetrahydrofuran, dimethylacetamide or acetonitrile. Acetonitrile is particularly preferred.
  • Suitable reaction temperatures are, for example, those in the range from 0 to 120 ° C., preferably in the range from 20 to 100 ° C., the solvent-free variant in particular being preferably carried out at room temperature.
  • N, N-bis (2-cyanoethyl) formamide is obtained as a weakly colored liquid which is of customary intermediate product purity, so that further purification procedures can be dispensed with , because prohibitive contaminants of the prior art do not arise according to this procedure according to the invention.
  • the next stage of the process according to the invention consists in the known hydrogenation of the two nitrile groups of N, N-bis (2-cyanoethyl) formamide; for example in methanol / ammonia as a solvent using Raney nickel iron as a hydrogenation catalyst at temperatures of about 20 to 60 ° C and a hydrogen pressure of about 20 to 50 bar.
  • methanol / ammonia as a solvent using Raney nickel iron as a hydrogenation catalyst at temperatures of about 20 to 60 ° C and a hydrogen pressure of about 20 to 50 bar.
  • the monoformylated 3,3'-diaminodipropylamine mixture according to the invention is a substance which is low viscosity at room temperature and shows no tendency to crystallize.
  • the smell is only weakly aminic.
  • the inventive monoformylated 3,3'-diaminodipropylamine mixture is a novel, special chain extender for the production of Are polyurethane plastics by the isocyanate polyaddition process, in which a chain extension can first be carried out via the two amine groups and then, if necessary, further reactions of the N-CHO function are possible.
  • Possible implementations are oxidation, reduction or hydrolytic and / or thermal cleavage.
  • the diamine mixture according to the invention can be used, for example, to build up dissolved polyurethane polyureas by the solution polyaddition process.
  • an NCO prepolymer with an NCO content of 0.5-10% by weight is dissolved in a solvent and gradually extended with the diamine mixture according to the invention until the desired viscosity of approximately 5000 to approximately 70,000 mPas is reached.
  • the solids content is usually 20-40% by weight.
  • the solvents to be used belong to the prior art. They are, for example, dimethylformamide, dimethylacetamide, N-methylpyrrolidone but also aromatics / alcohol mixtures such as toluene-isopropanol.
  • the final properties of the polyurethaneureas can be specifically adjusted by, for example, next to the diamine mixture according to the invention additionally uses targeted monoamines (partial chain termination, viscosity reduction), diamines customary in PUR chemistry, optionally with salt groups (carboxyl and or sulfonate groups) or triamines (branching, viscosity increase, crosslinking).
  • targeted monoamines partial chain termination, viscosity reduction
  • diamines customary in PUR chemistry optionally with salt groups (carboxyl and or sulfonate groups) or triamines (branching, viscosity increase, crosslinking).
  • the diamine mixture according to the invention can furthermore be used particularly advantageously for the preparation of aq.
  • Polyurethane dispersions are used, such as those in Angew. Macromol. Chemie 26 , 1972, 85-106. In this case too, an additional reaction on the N-CHO group can be performed.
  • the diamine mixture according to the invention can also be used advantageously as an amine hardener for epoxides.
  • the hardener can be exchanged for the diamine mixture according to the invention, colorless, elasticized and very well adhering adhesives being formed.
  • the reaction solution was subsequently freed from low boilers (30-40 ° C./20 to 1 mbar) and the light yellow, clear crude solution was separated from remaining, lower boiling fractions under thin-film conditions (145 ° C. 0.1 mbar).
  • the light yellow, clear liquid thus obtained consists of 99% (GC) of N, N'-bis (2-cyanoethyl) formamide. Yield: 170 g, conversion: 59% (based on acrylonitrile) selectivity: 95% Analysis (%): C. H N found: 55.3 6.3 27.8 Theory: 55.6 6.0 27.8 (based on C7H9N3O)
  • N, N'-bis (2-cyanoethyl) formamide from Example 2 are mixed with 1000 ml of methanol, 500 ml of ammonia and 40 g of Raney nickel iron (Ni / Fe ratio: 85/15.
  • the mixture is stirred at 30 ° C. and 30 to 50 bar hydrogen pressure until the hydrogen uptake has ended, then the pressure is released, the catalyst is filtered off and the low-boiling fraction: ammonia and methanol are separated off.
  • Example 4 (Comparative Example to Example 3)
  • Example 3 255 g of Luprintan PFD are hydrogenated. 237 g (88% yield) of a dark-colored viscous amine mixture with a base N of 15.2% (theory 17.6%) are obtained. Analysis (%) C. H N found 51.8 9.9 25.6 theory 52.8 10.7 26.4 (based on C7H17N3O)

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Catalysts (AREA)

Abstract

Die vorliegende Erfindung betrifft neue, monoformylierte 3,3'-Diaminodipropylamine bzw. Gemische, ein Verfahren zu deren Herstellung aus Acrylnitril/Formamid und nachfolgender Hydrierung und deren Verwendung als Kettenverlängerungsmittel bei der Herstellung von Polyurethanen nach dem Isocyanat-Polyadditionsverfahren.The present invention relates to new, monoformylated 3,3'-diaminodipropylamines or mixtures, a process for their preparation from acrylonitrile / formamide and subsequent hydrogenation and their use as chain extenders in the production of polyurethanes by the isocyanate polyaddition process.

Description

Die vorliegende Erfindung betrifft neue, monoformylierte 3,3′-Diaminodipropylamine bzw. Gemische, ein Verfahren zu deren Herstellung aus Acrylnitril/Formamid und nach­folgender Hydrierung und deren Verwendung als Ketten­verlängerungsmittel bei der Herstellung von Polyure­thanen nach dem Isocyanat-Polyadditionsverfahren.The present invention relates to new, monoformylated 3,3'-diaminodipropylamines or mixtures, a process for their preparation from acrylonitrile / formamide and subsequent hydrogenation and their use as chain extenders in the production of polyurethanes by the isocyanate polyaddition process.

Es wurden die neuen, monoformylierten 3,3′-Diamo­dipropylamin-Gemische der Formel I und II gefunden

Figure imgb0001
The new, monoformylated 3,3'-diamodipropylamine mixtures of the formula I and II were found
Figure imgb0001

Es wurde weiterhin ein Verfahren zu ihrer Herstellung gefunden, das dadurch gekennzeichnet ist, daß man Acrylnitril und Formamid unter Zusatz eines 4-Amino­pyridin-Derivates zum N,N-Bis-(2-cyanethyl)-formamid umsetzt und nachfolgend zum monoformylierten 3,3′-­Diaminopropylamin-Gemisch der Formel I und II hydriert.A process for their preparation was also found, which is characterized in that acrylonitrile and formamide are added to the N, N-bis (2-cyanoethyl) formamide with the addition of a 4-aminopyridine derivative and subsequently to the monoformylated 3,3 '-Diaminopropylamine mixture of formula I and II hydrogenated.

Umsetzungen von Acrylnitril und Formamid in Gegenwart von Basen sind beschrieben worden:Reactions of acrylonitrile and formamide in the presence of bases have been described:

So erhält man nach DRP 735771 N,N-Bis-(2-cyanethyl)-­formamid aus 2 Mol Acrylnitril und 1 Mol Formamid mit katalystischen Mengen Natrium.According to DRP 735771, N, N-bis (2-cyanoethyl) formamide is obtained from 2 moles of acrylonitrile and 1 mole of formamide with catalytic amounts of sodium.

Nach den offenbarten, drastischen Herstellungsmethoden sind merkliche Anteile an Verunreinigungen zu erwarten, z.B. weitere Umsetzungen von N,N-Bis(2-cyanethyl)-­formamid mit Acrylnitril, deren Vorhandensein zur Rein­darstellung der erfindungsgemäßen Diamingemische I und II prohibitiv ist.According to the drastic manufacturing methods disclosed, noticeable levels of impurities are expected, e.g. further reactions of N, N-bis (2-cyanoethyl) formamide with acrylonitrile, the presence of which is prohibitive for the purification of the diamine mixtures I and II according to the invention.

Umsetzungen von Acrylnitril mit Formamid in Gegenwart einer tertiären Aminbase zu 2-(N-Formylamino)-­propionitril beschreibt die DE-OS 3 520 982. Selekti­vität und Ausbeuten sind nach den dort gemachten Angaben hoch. Das Bisaddukt N,N-Bis-(2-cyanethyl)-formamid wurde allerdings nicht gefunden.DE-OS 3 520 982 describes reactions of acrylonitrile with formamide in the presence of a tertiary amine base to give 2- (N-formylamino) propionitrile. According to the statements made there, selectivity and yields are high. However, the bisadduct N, N-bis (2-cyanoethyl) formamide was not found.

Es muß daher als äußerst überraschend angesehen werden, daß nach dem erfindungsgemäßen Verfahren N,N-Bis-(2-­cyanethyl)-formamid überhaupt entsteht, zumal in hohen Ausbeuten, guter Selektivität und Reinheit.It must therefore be regarded as extremely surprising that N, N-bis (2-cyanoethyl) formamide is formed at all by the process according to the invention, especially in high yields, good selectivity and purity.

Bezogen auf 1 Mol Acrylnitril können beispielsweise 0,5 bis 10 Mol Formamid eingesetzt werden. Vorzugsweise beträgt die Menge 0,5 bis 2 Mol.Based on 1 mole of acrylonitrile, for example 0.5 to 10 moles of formamide can be used. The amount is preferably 0.5 to 2 mol.

Als 4-Aminopyridin-Derivate kommen beispielsweise solche der Formel (III) in Frage

Figure imgb0002
in der
R₁ und R₂ unabhängig voneinander für einen einbindigen C₁- bis C₆-Alkylrest oder R₁ und R₂ gemeinsam für einen zweibindigen C₃- bis C₅-Alkylrest stehen.Examples of suitable 4-aminopyridine derivatives are those of the formula (III)
Figure imgb0002
 in the
R₁ and R₂ independently of one another are a monovalent C₁- to C₆-alkyl radical or R₁ and R₂ together represent a double-bonded C₃- to C₅-alkyl radical.

Bevorzugt wird N,N-Dimethyl-4-aminopyridin oder 4-­Pyrrolidinopyridin eingesetzt.N, N-Dimethyl-4-aminopyridine or 4-pyrrolidinopyridine is preferably used.

Die Einsatzmenge dieser katalytisch wirkenden Base ist nicht kritisch. Zur Erzielung eines hinreichend schnellen Umsatzes weren üblicherweise 0,5 bis 10 Mol-% pro Mol Acrylnitril verwendet.The amount of this catalytically active base is not critical. In order to achieve a sufficiently rapid conversion, 0.5 to 10 mol% are usually used per mole of acrylonitrile.

Acrylnitril kommt als technische Ware zum Einsatz. Diese Ware enthält in geringer Menge übliche Polymerisations­inhibitoren.Acrylonitrile is used as a technical product. This product contains customary polymerization inhibitors in a small amount.

Das Verfahren kann lösungsmittelfrei oder vorzugsweise unter Mitverwendung eines Lösungsmittels durchgeführt werden.The process can be carried out without a solvent or preferably with the use of a solvent.

Zur Erhöhung der Selektivität ist Lösungsmittelzusatz bei steigenden Reaktionstemperaturen zunehmend er­forderlich. Hierfür eignen sich polare Lösungsmittel wie z.B. Tetrahydrofuran, Dimethylacetamid oder Acetonitril. Acetonitril ist besonders bevorzugt.To increase the selectivity, it is increasingly necessary to add solvents as the reaction temperatures rise. Polar solvents such as e.g. Tetrahydrofuran, dimethylacetamide or acetonitrile. Acetonitrile is particularly preferred.

Geeignete Reaktionstemperaturen sind beispielsweise solche im Bereich von 0 bis 120°C, vorzugsweise im Bereich von 20 bis 100°C, wobei insbesondere die lösungsmittelfreie Variante vorzugsweise bei Raum­temperatur durchgeführt wird.Suitable reaction temperatures are, for example, those in the range from 0 to 120 ° C., preferably in the range from 20 to 100 ° C., the solvent-free variant in particular being preferably carried out at room temperature.

Das Arbeiten bei Normaldruck ist bevorzugt, jedoch kann auch unter erhöhten Druck gearbeitet werden.Working at normal pressure is preferred, but working under increased pressure is also possible.

Im übrigen erfordert das erfindungsgemäße Verfahren keine verfahrenstechnischen Besonderheiten. Das gleiche gilt für die Aufarbeitung. Nach Abtrennung der Niedrig­sieder, Formamid und des Katalysators (z.B. durch Destillation oder Dünnschichten) fällt N,N-Bis-(2-­cyanethyl)-formamid als schwach gefärbte Flüssigkeit an, die von üblicher Zwischenproduktreinheit ist, so daß auf weitere Reinigungsprozeduren verzichtet werden kann, weil prohibitive Verunreinigungen des Standes der Technik nach dieser erfindungsgemäßen Verfahrensweise nicht entstehen.Otherwise, the method according to the invention does not require any special procedural features. The same applies to the processing. After the low boilers, formamide and the catalyst have been separated off (for example by distillation or thin layers), N, N-bis (2-cyanoethyl) formamide is obtained as a weakly colored liquid which is of customary intermediate product purity, so that further purification procedures can be dispensed with , because prohibitive contaminants of the prior art do not arise according to this procedure according to the invention.

Die folgende Stufe des erfindungsgemäßen Verfahrens besteht in der an sich bekannten Hydrierung der beiden Nitrilgruppen des N,N-Bis-(2-cyanethyl)-formamids; beispielsweise in Methanol/Ammoniak als Lösungsmittel unter Verwendung von Raney-Nickel-Eisen als Hydrier­katalysator bei Temperaturen von etwa 20 bis 60°C und einem Wasserstoffdruck von etwa 20 bis 50 bar. Nach Abtrennung des Katalysators und der Niedrigsieder­anteile: Ammoniak/Methanol sind direkt in ausge­zeichneter Qualität die erfindungsgemäßen monoformy­lierten 3,3′-Diaminopropylamin-Gemische der Formel I und II erhältlich.The next stage of the process according to the invention consists in the known hydrogenation of the two nitrile groups of N, N-bis (2-cyanoethyl) formamide; for example in methanol / ammonia as a solvent using Raney nickel iron as a hydrogenation catalyst at temperatures of about 20 to 60 ° C and a hydrogen pressure of about 20 to 50 bar. After removal of the catalyst and the low-boiling fractions: ammonia / methanol, the monoformylated 3,3′-diaminopropylamine mixtures of the formulas I and II can be obtained directly in excellent quality.

Der erfindungswesentliche Punkt ist darin zu sehen, daß erst aufgrund des erfindungsgemäßen Verfahrens zur Her­stellung von N,N-Bis(2-cyanethyl)-formamid ein genügend reines Ausgangsprodukt zur Verfügung steht, das die Herstellung der erfindungsgemäßen monoformylierten Diamine I und II in einfacher Weise und guter Qualität nach an sich bekannten Hydriertechniken ermöglicht.The point essential to the invention can be seen in the fact that only because of the process according to the invention for the preparation of N, N-bis (2-cyanoethyl) formamide is a sufficiently pure starting product available that can be used to prepare the monoformylated diamines I and II according to the invention in a simple manner and good quality according to known hydrogenation techniques.

Das erfindungsgemäße monoformylierte 3,3′-Diamino­dipropylamin-Gemisch ist eine bei Raumtemperatur dünnflüssige Substanz, die keinerlei Kristallisations­neigung erkennen läßt. Der Geruch ist nur schwach aminisch.The monoformylated 3,3'-diaminodipropylamine mixture according to the invention is a substance which is low viscosity at room temperature and shows no tendency to crystallize. The smell is only weakly aminic.

Das erfindungsgemäße, monoformylierte 3,3′-Diamino­dipropylamin-Gemisch stellt ein neuartiges, spezielles Kettenverlängerungsmittel für die Herstellung von Polyurethankunststoffen nach dem Isocyanat-Poly­additionsverfahren dar, in dem zunächst eine Ketten­verlängerung über die beiden Amingruppen vorgenommen werden kann und nachfolgend gegebenenfalls weitere Umsetzungen der

Figure imgb0003
N-CHO-Funktion möglich sind.The inventive monoformylated 3,3'-diaminodipropylamine mixture is a novel, special chain extender for the production of Are polyurethane plastics by the isocyanate polyaddition process, in which a chain extension can first be carried out via the two amine groups and then, if necessary, further reactions of the
Figure imgb0003
N-CHO function are possible.

Mögliche Umsetzungen sind Oxidation, Reduktion oder hydrolyt- und/oder thermische Spaltung.Possible implementations are oxidation, reduction or hydrolytic and / or thermal cleavage.

Das erfindungsgemäße Diamingemisch kann beispielsweise zu Aufbau von gelösten Polyurethanpolyharnstoffen nach dem Lösungspolyadditionsverfahren verwendet werden. Dazu wird ein NCO-Prepolymer mit einem NCO-Gehalt von 0,5 - 10 Gew.-% in einem Lösungsmittel gelöst und schrittweise mit dem erfindungsgemäßen Diamingemisch verlängert bis die gewünschte Viskosität von ca. 5000 bis ca. 70 000 mPas erreicht wird. Der Feststoffgehalt beträgt üblicherweise 20 - 40 Gew.-%. Man kann auch vorteilhaft so verfahren, daß das erfindungsgemäße Diamingemisch vorgelegt wird und die Polyaddition durch Zugabe der NCO-Prepolymerlösung durchgeführt wird.The diamine mixture according to the invention can be used, for example, to build up dissolved polyurethane polyureas by the solution polyaddition process. For this purpose, an NCO prepolymer with an NCO content of 0.5-10% by weight is dissolved in a solvent and gradually extended with the diamine mixture according to the invention until the desired viscosity of approximately 5000 to approximately 70,000 mPas is reached. The solids content is usually 20-40% by weight. One can also advantageously proceed in such a way that the diamine mixture according to the invention is initially introduced and the polyaddition is carried out by adding the NCO prepolymer solution.

Die zu verwendenden Lösungsmittel gehören zum Stand der Technik. Es sind beispielsweise Dimethylformamid, Dimethylacetamid, N-Methylpyrrolidon aber auch Aro­maten/Alkohol-Gemische wie etwa Toluol-Isopropanol.The solvents to be used belong to the prior art. They are, for example, dimethylformamide, dimethylacetamide, N-methylpyrrolidone but also aromatics / alcohol mixtures such as toluene-isopropanol.

Die Endeigenschaften der Polyurethanharnstoffe lassen sich gezielt einstellen, indem man beispielsweise neben dem erfindungsgemäßen Diamingemisch zusätzlich gezielt Monoamine (partieller Kettenabbruch, Viskositätsver­minderung), in der PUR-Chemie übliche Diamine, ge­gebenenfalls mit Salzgruppen (Carboxyl- und oder Sulfonatgruppen) oder aber Triamine (Verzweigung, Viskositätssteigerung, Vernetzung) einsetzt.The final properties of the polyurethaneureas can be specifically adjusted by, for example, next to the diamine mixture according to the invention additionally uses targeted monoamines (partial chain termination, viscosity reduction), diamines customary in PUR chemistry, optionally with salt groups (carboxyl and or sulfonate groups) or triamines (branching, viscosity increase, crosslinking).

Das erfindungsgemäße Diamingemisch kann weiterhin an­stelle üblicher Diamine besonders vorteilhaft zur Her­stellung wäßr. Polyurethandispersionen verwendet werden wie sie beispielsweise in Angew. Makromol. Chemie 26, 1972, 85 - 106 beschrieben sind. Auch in diesem Fall kann gegebenenfalls eine zusätzliche Reaktion an der

Figure imgb0004
N-CHO-Gruppe durchgeführt werden.The diamine mixture according to the invention can furthermore be used particularly advantageously for the preparation of aq. Polyurethane dispersions are used, such as those in Angew. Macromol. Chemie 26 , 1972, 85-106. In this case too, an additional reaction on the
Figure imgb0004
N-CHO group can be performed.

Auch als aminischer Härter für Epoxide kann das er­findungsgemäße Diamingemisch vorteilhaft verwendet werden. So kann beispielsweise in gängigen 2-Kompo­nenten-Epoxid-Klebern der Härter gegen das erfin­dungsgemäße Diamingemisch ausgetauscht werden, wobei farblose, elastifizierte und sehr gut haftende Kleb­stoffe gebildet werden.The diamine mixture according to the invention can also be used advantageously as an amine hardener for epoxides. For example, in common 2-component epoxy adhesives, the hardener can be exchanged for the diamine mixture according to the invention, colorless, elasticized and very well adhering adhesives being formed.

Die vorliegende Erfindung soll anhand der folgenden Beispiele näher erläutert werden (%-Angaben beziehen sich auf Gew.-%).The following examples are intended to illustrate the present invention (% figures relate to% by weight).

BeispieleExamples Beispiel 1 (Herstellung von N,N′-Bis-(2-cyanethyl-­formamid) Example 1 (Preparation of N, N'-bis (2-cyanoethyl-formamide)

In eine Lösung aus 212 g Acrylnitril, 212 g Acetonitril und 180 g Formamid werden bei Raumtemperatur unter Rühren 14,7 g N,N-Dimethyl-4-aminopyridin eingetragen. Die klare Lösung wird 21 Stunden unter Rückflußbe­dingungen erhitzt, wobei die Innentemperatur von 86°C auf ca. 92°C anstieg.14.7 g of N, N-dimethyl-4-aminopyridine are introduced into a solution of 212 g of acrylonitrile, 212 g of acetonitrile and 180 g of formamide at room temperature with stirring. The clear solution is heated under reflux conditions for 21 hours, the internal temperature rising from 86 ° C. to approx. 92 ° C.

Die Reaktionslösung wurde nachfolgend von Niedrigsiedern befreit (30 - 40°C/20 bis 1 mbar) und die hellgelbe, klare Rohlösung unter Dünnschichtbedingungen (145°C 0,1 mbar) von restlichen, niedriger siedenden Anteilen abgetrennt. Die so erhaltende hellgelbe, klare Flüssig­keit besteht zu 99 % (GC) aus N,N′-Bis-(2-cyanethyl)-­formamid.
Ausbeute: 170 g, Umsatz: 59 % (bezogen auf Acrylnitril) Selektivität: 95% Analyse (%): C H N gefunden: 55,3 6,3 27,8 Theorie: 55,6 6,0 27,8 (bezogen auf C₇H₉N₃O) The reaction solution was subsequently freed from low boilers (30-40 ° C./20 to 1 mbar) and the light yellow, clear crude solution was separated from remaining, lower boiling fractions under thin-film conditions (145 ° C. 0.1 mbar). The light yellow, clear liquid thus obtained consists of 99% (GC) of N, N'-bis (2-cyanoethyl) formamide.
Yield: 170 g, conversion: 59% (based on acrylonitrile) selectivity: 95% Analysis (%): C. H N found: 55.3 6.3 27.8 Theory: 55.6 6.0 27.8 (based on C₇H₉N₃O)

Beispiel 2 (Herstellung von N,N′-Bis-(2-cyanethyl)-­formamid Example 2 (Preparation of N, N'-bis (2-cyanoethyl) formamide

In eine Lösung aus 770 g Acrylnitril und 433 g Formamid werden bei Raumtemperatur unter Rühren 27,5 g N,N′-Di­methyl-4-aminopyridin eingetragen. Man läßt die klare Lösung 4 Tage bei Raumtemperatur stehen, befreit die Reaktionslösung von Niedrigsiedern (Raumtemperautr/20 bis 1 mbar) und trennt restliche Siedeanteile unter Dünnschichtbedingungen (145°C/0,1 mbar) ab. Die so erhaltene Sumpf-Flüssigkeit ist praktisch farblos und klar.
Ausbeute: 621 g N,N′-Bis-(2-cyanethyl)-formamid
Reinheit: 98 % (GC)
Umsatz: 53 % (bezogen auf Acrylnitril
Selektivität: 96 %27.5 g of N, N'-dimethyl-4-aminopyridine are introduced into a solution of 770 g of acrylonitrile and 433 g of formamide at room temperature with stirring. The clear solution is left to stand for 4 days at room temperature, the reaction solution is freed from low boilers (room temperature / 20 to 1 mbar) and residual boiling components are separated off under thin-film conditions (145 ° C./0.1 mbar). The bottom liquid thus obtained is practically colorless and clear.
Yield: 621 g of N, N'-bis (2-cyanoethyl) formamide
Purity: 98% (GC)
Sales: 53% (based on acrylonitrile
Selectivity: 96%

Beispiel 3 (Herstellung monoformylierter 3,3′-Diamino­dipropylamin-Gemische der Formel I und II Example 3 (Preparation of monoformylated 3,3'-diaminodipropylamine mixtures of the formula I and II

In einem Rührautoklav werden 255 g N,N′-Bis-(2-cyan­ethyl)-formamid aus Beispiel 2 mit 1000 ml Methanol, 500 ml Ammoniak und 40 g Raney-Nickel-Eisen (Ni/Fe Verhältnis: 85/15 versetzt. Bei 30°C und 30 bis 50 bar Wasserstoffdruck wird bis zum Ende der Wasserstoff­aufnahme gerührt. Anschließend wird entspannt, vom Katalysator abfiltriert und der Niedrigsiederanteil: Ammoniak und Methanol abgetrennt.In a stirred autoclave, 255 g of N, N'-bis (2-cyanoethyl) formamide from Example 2 are mixed with 1000 ml of methanol, 500 ml of ammonia and 40 g of Raney nickel iron (Ni / Fe ratio: 85/15. The mixture is stirred at 30 ° C. and 30 to 50 bar hydrogen pressure until the hydrogen uptake has ended, then the pressure is released, the catalyst is filtered off and the low-boiling fraction: ammonia and methanol are separated off.

Man erhält 262 g (98 % Ausbeute) fast farbloses, klares, dünnflüssiges Amingemisch der Formel I und II, das nach 1 H-NMR-Untersuchungen im molaren Verhältnis von ca. 50:50 % vorliegt. Analyse (%): C H N gefunden 53,0 10,5 26,4 Theorie 52,8 10,7 26,4 (bezogen auf C₇H₁₇N₃O) Der Basen-N betrug 17,4 % (Theorie 17,6 %)This gives 262 g (98% yield) of an almost colorless, clear, low viscosity amine mixture of the formulas I and II which, according to 1 H-NMR investigations, is in a molar ratio of approx. 50:50%. Analysis (%): C. H N found 53.0 10.5 26.4 theory 52.8 10.7 26.4 (based on C₇H₁₇N₃O) The base N was 17.4% (theory 17.6%)

Beispiel 4 (Vergleichsbeispiel zu Beispiel 3) Example 4 (Comparative Example to Example 3)

®Luprintan PFD (Fa. BASF), ein N,N′-Bis-(2-cyanethyl)-­formamid nach dem bisherigen Stand der Technik wird nachfolgend vergleichweise untersucht:®Luprintan PFD (from BASF), an N, N′-bis (2-cyanoethyl) formamide according to the prior art is examined in the following in comparison:

Entsprechend Beispiel 3 werden 255 g Luprintan PFD hydriert. Man erhält 237 g (88 % Ausbeute) eines dunkel gefärbten dickflüssigen Amingemisches mit einem Basen-N von 15,2 % (Theorie 17,6 %). Analyse (%) C H N gefunden 51,8 9,9 25,6 Theorie 52,8 10,7 26,4 (bezogen auf C₇H₁₇N₃O) According to Example 3, 255 g of Luprintan PFD are hydrogenated. 237 g (88% yield) of a dark-colored viscous amine mixture with a base N of 15.2% (theory 17.6%) are obtained. Analysis (%) C. H N found 51.8 9.9 25.6 theory 52.8 10.7 26.4 (based on C₇H₁₇N₃O)

Die vorliegenden Daten weisen dieses Produkt von ver­gleichsweise minderer Qualität aus.The available data identify this product of comparatively poor quality.

Die nachfolgenden Beispiele behandeln Verwendungs-­möglichkeiten der erfindungsgemäßen monoformylierten Amingemische (I) und (II):The following examples deal with possible uses of the monoformylated amine mixtures (I) and (II) according to the invention:

NCO-Prepolymer 1:NCO prepolymer 1:

830,5 g (0,489 mol) Polyester aus Adipinsäure, 1,6-­Hexandiol und Neopentylglykol vom Molekulargewicht 1700 und 28,3 (0,013 mol) eines monofunktionellen auf n-­Butanol gestartetem Ethylenoxid/Propylenoxidpolyethers vom Molgewicht 2150 werden bei 110°C 30 min im Vakuum entwässert. Nach Abkühlen auf 55 - 60°C wird eine Mischung aus 122 g (0,55 mol) 1-Isocyanatomethyl-5-­isocyanato-1,3,3-trimethylcyclohexan und 92,5 g (0,55 mol) 1,6-Diisocyanatohexan zugegeben. Nach 15 Minuten wird auf 120°C erwärmt und 2 h bei dieser Temperatur nachgerührt. Nun wird mit 340 ml Aceton zu einem Feststoffgehalt von 80 % gelöst. Der NCO-Gehalt der Lösung beträgt 3,3 % (Theorie 3,7 %).830.5 g (0.489 mol) of polyester from adipic acid, 1,6-hexanediol and neopentyl glycol of molecular weight 1700 and 28.3 (0.013 mol) of a monofunctional ethylene oxide / propylene oxide polyether started on n-butanol with a molecular weight of 2150 are at 110 ° C for 30 min dewatered in a vacuum. After cooling to 55-60 ° C., a mixture of 122 g (0.55 mol) of 1-isocyanatomethyl-5-isocyanato-1,3,3-trimethylcyclohexane and 92.5 g (0.55 mol) of 1.6- Diisocyanatohexane added. After 15 minutes, the mixture is warmed to 120 ° C. and stirred at this temperature for 2 h. Now is dissolved with 340 ml of acetone to a solids content of 80%. The NCO content of the solution is 3.3% (theory 3.7%).

NCO-Prepolymer 2:NCO prepolymer 2:

403,7 g (0,238 mol) eines Polyesters aus Adipinsäure, 1,6-Hexandiol und Neopentylglykol vom Molgewicht 1700 werden bei 110°C 30 min im Wasserstrahvakuum entwässert. Nach Abkühlen auf 60 - 70°C setzt man 96,3 g (0,434 mol) 1-Isocyanatomethyl-5-isocyanato-1,3,3-trimethylcyclo­hexan zu und erwärmt nach ca. 15 min auf 110°C. Nach 1,5 h löst man 70 %ig in Toluol ein. Der NCO-Gehalt der Lösung beträgt 1,8 % (Theorie 2,3 %).403.7 g (0.238 mol) of a polyester made from adipic acid, 1,6-hexanediol and neopentyl glycol with a molecular weight of 1700 are dewatered at 110 ° C. in a water jet vacuum for 30 min. After cooling to 60-70 ° C., 96.3 g (0.434 mol) of 1-isocyanatomethyl-5-isocyanato-1,3,3-trimethylcyclohexane are added and the mixture is heated to 110 ° C. after about 15 minutes. After 1.5 h, 70% strength is dissolved in toluene. The NCO content of the solution is 1.8% (theory 2.3%).

VerwendungsbeispieleExamples of use A Polyurethanharnstoffe durch LösungspolyadditionA polyurethane ureas by solution polyaddition

  • A 1) Zu einer Lösung aus 3,81 g (23,7 mmol) des er­findungsgemäßen Diamingemisches aus Beispiel 3 und 1,6 (5,4 mmol) Oktadecylisocyanat in einer Mischung aus 80 g Toluol, 80 g Isopropanol und 32 g Ethylen­glykolmonoethylether tropft man portionsweise langsam 100 g Prepolymerlösung 2. Man erhält eine blaß-gelbe, klare Lösung mit einem Feststoff von 25,5 % und einer Viskosität (23°C) von 7500 mPas.
    Glasplatten und Aluminiumfolien werden mit der Lösung beschichtet und das Lösungsmittel bei 130°C verdampft. man erhält eine optisch klare, weiche aber klebfreie Beschichtung. Der Polyurethanharn­stoffilm ist sehr elastisch und zeigt auf Aluminium eine ausgezeichnete Haftung.    A 1) Dropwise to a solution of 3.81 g (23.7 mmol) of the diamine mixture according to the invention from Example 3 and 1.6 (5.4 mmol) of octadecyl isocyanate in a mixture of 80 g of toluene, 80 g of isopropanol and 32 g of ethylene glycol monoethyl ether 100 g of prepolymer solution 2 are slowly added in portions. A pale yellow, clear solution having a solid of 25.5% and a viscosity (23 ° C.) of 7500 mPas is obtained.
    Glass plates and aluminum foils are coated with the solution and the solvent is evaporated at 130 ° C. an optically clear, soft but tack-free coating is obtained. The polyurethane urea film is very elastic and shows excellent adhesion to aluminum.
  • A 2) Zu einer Lösung von 3,81 g (0,024 mol) des er­findungsgemäßen Amingemisches gemäß Beispiel 3 in 192 g N,N-Dimethylformamid tropft man bei 50°C eine Mischung aus 100 g Prepolymerlösung 2 und 1,8 g Octadecylisocyanat innerhalb 2 Stunden zu. Nach Abkühlen auf Raumtemperatur erhält man eine leicht gelbe, klare Lösung mit einem Feststoffgehalt von 25 % und einer Viskosität von 11,000 mPas. Der bei 130°C erzeugte Film ist farblos und klar.A 2) A solution of 100 g of prepolymer solution 2 and 1.8 g of octadecyl isocyanate is added dropwise at 50 ° C. to a solution of 3.81 g (0.024 mol) of the amine mixture according to the invention according to Example 3 in 192 g of N, N-dimethylformamide Hours too. After cooling to room temperature, a slightly yellow, clear solution with a solids content of 25% and a viscosity of 11,000 mPas is obtained. The film produced at 130 ° C is colorless and clear.
  • A 3) Man arbeitet völlig analog A 2, setzt jedoch das Amingemisch gemäß Beispiel 4 ein. Die erhaltene Polymerlösung ist braun und leicht opak, die Viskosität beträgt lediglich 1000 mPas. Die ent­sprechenden Filmeigenschaften sind ähnlich.A 3) The procedure is completely analogous to A 2, but the amine mixture according to Example 4 is used. The polymer solution obtained is brown and slightly opaque, the viscosity is only 1000 mPas. The corresponding film properties are similar.
B Herstellung von Polyurethanharnstoffdispersionen in WasserB Preparation of polyurethane urea dispersions in water

  • B 1) 250 g Prepolymerlösung 1 werden mit 450 ml Aceton auf 33 % Feststoffgehalt verdünnt und bei 50 - 55°C mit einer Mischung aus 4,15 g (0,011 mol) 50 %iger wäßriger Lösung des 2-Aminoethyl-β-aminoethan­sulfonsäure-natriumsalzes, 0,71 g (0,014 mol) Hydrazinhydrat und 6,8 g (0,04 mol) des erfindungs­gemäßen Amingemisches nach Beispiel 3 in 50 ml entsalztem Wasser, versetzt. Nach 15 Minuten wird mit 440 ml entsalztem Wasser in 6 min dispergiert. Nach dem Abdestillieren des Acetone im Wasser­strahlvakuum erhält man eine feinteilige Dispersion mit einem Feststoffgehalt von 33,8 %. Der bei 120°C erzeugte Film ist optisch klar und farblos.B 1) 250 g of prepolymer solution 1 are diluted to a solids content of 33% with 450 ml of acetone and at 50-55 ° C. with a mixture of 4.15 g (0.011 mol) of a 50% aqueous solution of 2-aminoethyl-β-aminoethanesulfonic acid. sodium salt, 0.71 g (0.014 mol) of hydrazine hydrate and 6.8 g (0.04 mol) of the amine mixture according to the invention from Example 3 in 50 ml of deionized water. After 15 minutes, the mixture is dispersed with 440 ml of deionized water in 6 minutes. After distilling off the acetone in a water jet vacuum, a finely divided dispersion with a solids content of 33.8% is obtained. The film produced at 120 ° C is optically clear and colorless.
  • B 2) Man verfährt völlig analog Beispiel A, setzt jedoch anstelle des gemäß Beispiel 3 hergestellten Amins nunmehr 6.8 g (0,04 mol) Amin aus Vergleichsbei­spiel 4 ein. Die aus dem Versuch resultierende Dispersion ist ebenfalls feinteilig, es setzt sich jedoch über Nacht wenig dunkelbraunes Sediment ab.B 2) The procedure is completely analogous to Example A, but now 6.8 g (0.04 mol) of amine from Comparative Example 4 is used instead of the amine prepared according to Example 3. The dispersion resulting from the experiment is also finely divided, but little dark brown sediment settles out overnight.
  • B 3) Als Vergleichsbeispiel zu Beispiel A und B anstelle der beiden erfindungsgemäßen Amine 7,22 g (0,043 mol) 1-Aminomethyl-5-amino-1,3,3-trimethylcyclo­hexan (Isophorondiamin eingesetzt. Man erhält eine grobteilige Dispersion mit einem Feststoffgehalt von 34 %. Der bei 120°C erzeugte Film zeigt ein opakes Aussehen, was auf Inhomogenitäten hinweist.B 3) 7.22 g (0.043 mol) of 1-aminomethyl-5-amino-1,3,3-trimethylcyclohexane (isophoronediamine) is used as a comparative example to Examples A and B instead of the two amines according to the invention. A coarse dispersion with a solids content is obtained The film produced at 120 ° C. has an opaque appearance, which indicates inhomogeneities.

Für die Dispersionen B 1 - B 3 werden folgende Daten bestimmt: B 1 B 2 B 3 Feststoffgehalt 33,8 % 34,2 % 34,0 % pH-Wert 7 - 8 7 - 8 7 - 8 Sulfongehalt 0,42 % 0,42 % 0,42 % Teilchengröße (nm) 95 240 220,800 Verteilung eng, monomodal wenig braunes Sediment bimodal The following data are determined for the dispersions B 1 - B 3: B 1 B 2 B 3 Solids content 33.8% 34.2% 34.0% PH value 7-8 7-8 7-8 Sulfone content 0.42% 0.42% 0.42% Particle size (nm) 95 240 220,800 distribution narrow, monomodal little brown sediment bimodal

C) Verwendung des erfindungsgemäßen Diamingemisches als Härter für EpoxidharzeC) Use of the diamine mixture according to the invention as a hardener for epoxy resins

1 g eines käuflichen Epoxidharzes (Uhu 300 Binder, Fa. Uhu, D 7580, Bühl) wird mit 0,34 g des erfindungsgemäßen Diamingemisches gemäß Beispiel 3 innig vermischt. Das Produkt ist nach 10 Minuten bei 100°C ausgehärtet. Der Film aus dem 2-Komponentenkleber ist kratzfest, Farblos und optisch klar.1 g of a commercially available epoxy resin (Uhu 300 Binder, Uhu, D 7580, Bühl) is intimately mixed with 0.34 g of the diamine mixture according to the invention according to Example 3. The product is cured after 10 minutes at 100 ° C. The film made of 2-component adhesive is scratch-resistant, colorless and optically clear.

Wiederholt man den Versuch mit 0,35 g des Diaminge­misches gemäß Vgl.-Beispiel 4, so erhält man bei sonst völlig analogem Befund einen gelb-braunen statt völlig farblosen Film.If the test is repeated with 0.35 g of the diamine mixture according to Example 4, a yellow-brown instead of completely colorless film is obtained with an otherwise completely analogous finding.

Die Aushärtung ist auch über Nacht bei Raumtemperatur möglich. Die Ergebnisse sind identisch.Curing is also possible overnight at room temperature. The results are identical.

Claims (6)

1.
Figure imgb0005
 1.
Figure imgb0005
 2. Monoformylierte 3,3′-Diaminodipropylamin-Gemische der Formel I und II im Verhältnis 1:99 bis 99:1, vorzugsweise 20:80 bis 80:20 Mol-%
Figure imgb0006
 2. Monoformylated 3,3'-diaminodipropylamine mixtures of the formulas I and II in a ratio of 1:99 to 99: 1, preferably 20:80 to 80:20 mol%
Figure imgb0006
 3. Verfahren zur Herstellung von monoformylierten 3,3′-Diaminodipropylamin-Gemischen nach Anspruch 2, dadurch gekennzeichnet, daß man Acrylnitril und Formamid unter Zusatz eines 4-Aminopyridin-­Derivates umsetzt und das so erhältliche N,N′-Bis-­(2-cyanethyl)-formamid anschließend hydriert.3. A process for the preparation of monoformylated 3,3'-diaminodipropylamine mixtures according to claim 2, characterized in that acrylonitrile and formamide are reacted with the addition of a 4-aminopyridine derivative and the N, N'-bis- (2- cyanethyl) formamide then hydrogenated. 4. Verfahren nach Anspruch 3, dadurch gekennzeichnet, daß man ein 4-Aminopyridin-Derivat der Formel
Figure imgb0007
 einsetzt, in der
R₁ und R₂ unabhängig voneinander für einen ein­bindigen C₁- bis C₆-Alkylrest oder R₁ und R₂ gemeinsam für einen zweibindigen C₃- bis C₅-Al­kylrest stehen.4. The method according to claim 3, characterized in that a 4-aminopyridine derivative of the formula
Figure imgb0007
 uses in the
R₁ and R₂ independently of one another are a monovalent C₁- to C₆-alkyl radical or R₁ and R₂ together represent a double-bonded C₃- to C₅-alkyl radical. 5. Verfahren nach einem der Ansprüche 3 oder 4, da­durch gekennzeichnet, daß bezogen auf Acrylnitril 0,5 bis 10 Mol-% eines 4-Aminopyridin-Derivates zum Einsatz kommen.5. The method according to any one of claims 3 or 4, characterized in that based on acrylonitrile 0.5 to 10 mol% of a 4-aminopyridine derivative are used. 6. Verwendung von monoformylierten 3,3′-Diaminodi­propylamin-Gemischen nach Anspruch 1 oder 2 als alleiniges oder anteiliges Kettenverlängerungs­mittel bei der Herstellung von Polyurethankunst­stoffen nach dem Isocyanat-Polyadditionsverfahren.6. Use of monoformylated 3,3'-diaminodipropylamine mixtures according to claim 1 or 2 as the sole or partial chain extender in the production of polyurethane plastics by the isocyanate polyaddition process.
EP89104900A 1988-04-02 1989-03-18 Monoformylated 3,3'-diaminopropyl amine, process for its preparation and its use Expired - Lifetime EP0336184B1 (en)

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CN109679051A (en) * 2018-12-26 2019-04-26 山东一诺威聚氨酯股份有限公司 Thermoplastic polyurethane elastomer and preparation method thereof containing key function
CN115869960A (en) * 2022-12-16 2023-03-31 南京红宝丽醇胺化学有限公司 Ni-Co-Ce-Cr catalyst and preparation method and application thereof

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CN113416140B (en) * 2021-06-03 2023-01-13 万华化学集团股份有限公司 Method for preparing 2-methyl pentanediamine

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DE2523633A1 (en) * 1975-05-28 1976-12-16 Bayer Ag NON-INSTALLABLE, ODORLESS CATALYSTS FOR POLYURETHANE SYNTHESIS
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CN109679051A (en) * 2018-12-26 2019-04-26 山东一诺威聚氨酯股份有限公司 Thermoplastic polyurethane elastomer and preparation method thereof containing key function
CN115869960A (en) * 2022-12-16 2023-03-31 南京红宝丽醇胺化学有限公司 Ni-Co-Ce-Cr catalyst and preparation method and application thereof

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