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EP0181180B1 - Compositions détergentes - Google Patents

Compositions détergentes Download PDF

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Publication number
EP0181180B1
EP0181180B1 EP85307980A EP85307980A EP0181180B1 EP 0181180 B1 EP0181180 B1 EP 0181180B1 EP 85307980 A EP85307980 A EP 85307980A EP 85307980 A EP85307980 A EP 85307980A EP 0181180 B1 EP0181180 B1 EP 0181180B1
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EP
European Patent Office
Prior art keywords
composition according
sodium
aluminosilicate
acid
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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EP85307980A
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German (de)
English (en)
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EP0181180A2 (fr
EP0181180A3 (en
Inventor
Charles David Bragg
Stephen Anthony Johnson
Nigel John Kermode
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Procter and Gamble Ltd
Procter and Gamble Co
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Procter and Gamble Ltd
Procter and Gamble Co
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Priority to AT85307980T priority Critical patent/ATE90112T1/de
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Publication of EP0181180A3 publication Critical patent/EP0181180A3/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites

Definitions

  • the present invention relates to detergent compositions.
  • it relates to built laundry detergent compositions having reduced phosphate levels together with excellent cleaning, whiteness maintenance and stain-removal performance as well as improved bleach stability and fabric-care characteristics.
  • phosphate detergency builders as adjuncts for organic, water-soluble, synthetic detergents and their value in improving the overall performance of such detergents are well-known.
  • the use of high levels of phosphate builders, such as the tripolyphosphates has come under scrutiny because of the suspicion that soluble phosphate species accelerate the eutrophication or ageing process of water bodies.
  • detergency builders function to improve the detergency action of water-soluble organic detergent compounds is not precisely known, but appears to depend on a combination of such factors as water-softening action, soil suspension and anti-redeposition effects, clay swelling and peptization and pH adjustment. However, present theory does not allow the prediction of which compounds will serve as effective detergency builders.
  • zeolites Sodium aluminosilicates, commonly known as zeolites have been proposed for use as phosphate builder substitutes since they are able to soften water by removing calcium ions (see, for example, BE-A-814,874 and BE-A-813581). Zeolites are unable to duplicate the full range of builder functions demonstrated by phosphates, however.
  • One way of boosting the overall detergency of low-phosphate formulations is through the use of bleaching auxiliaries such as the inorganic or organic peroxy bleaches and organic bleach activators.
  • bleaching auxiliaries such as the inorganic or organic peroxy bleaches and organic bleach activators.
  • a granular detergent composition comprising by weight of the detergent composition:
  • compositions of the invention contain a specified detergent builder system and a bleach system.
  • the compositions will generally include an organic soap or synthetic detergent surfactant material.
  • Highly preferred compositions also contain defined levels of polycarboxylate polymers, alkali metal carbonate and alkali metal silicate designed to provide improved detergency and fabric appearance characteristics.
  • the builder system comprises three essential components, a water-insoluble aluminosilicate cation exchange material, an alkali metal salt of nitrilotriacetic acid, and a phosphate builder.
  • the aluminosilicate cation exchange material comprises from 6% to 18%, preferably from 7% to 16%, and more preferably from 8% to 14% by weight of the detergent composition.
  • the aluminosilicate can be crystalline or amorphous in character, preferred materials having the unit cell formula I M z [(AlO2) z (Si02) y ] xH20 I wherein M is a calcium-exchange cation, z and y are at least 6; the molar ratio of z to y is from 1.0 to 0.5 and x is at least 5, preferably from 7.5 to 276, more preferably from 10 to 264.
  • the aluminosilicate materials are in hydrated form and are preferably crystalline containing from 10% to 28%, more preferably from 18% to 22% water.
  • the aluminosilicate ion exchange materials are further characterized by a particle size diameter of from 0.1 ⁇ m to 10 ⁇ m, preferably from 0.2 ⁇ m to 4 ⁇ m.
  • particle size diameter herein represents the average particle size diameter of a given ion exchange material as determined by conventional analytical techniques such as, for example, microscopic determination utilizing a scanning electron microscope.
  • the aluminosilicate ion exchange materials herein are usually further characterised by their calcium ion exchange capacity, which is at least 200 mg. equivalent of CaC03 water hardness/g of aluminosilicate, calculated on an anhydrous basis, and which generally is in the range of from 300 mg eq./g to 352 mg eq./g.
  • the aluminosilicate ion exchange materials herein are still further characterized by their calcium ion exchange rate which is at least 130 mg equivalent of CaCO3/min/g of aluminosilicate (anhydrous basis) (2 grains Ca++/min/g) and generally lies within the range of from 130 mg equivalent of CaCO3/min/g (2 grains/min/g) to 390 mg equivalent of CaCO3/min/g (6 grains/min/g) based on calcium ion hardness.
  • Optimum aluminosilicates for builder purposes exhibit a calcium ion exchange rate of at least 260 mg equivalent of CaCO3/min/g (4 grains/min/g).
  • Aluminosilicate ion exchange materials useful in the practice of this invention are commercially available and can be naturally occurring aluminosilicates or synthetically derived. A method for producing aluminosilicate ion exchange materials is discussed in U.S.-A-3,985,669.
  • Preferred synthetic crystalline aluminosilicate ion exchange materials useful herein are available under the designations Zeolite A, Zeolite B, Zeolite X, Zeolite HS and mixtures thereof.
  • the crystalline aluminosilicate ion exchange material is Zeolite A and has the formula Na12[Al02)12 (SiO2)12] xH20 wherein x is from about 20 to about 30, especially about 27.
  • Zeolite X of formula Na86 [(AlO2)86(SiO2)106] .276 H2O is also suitable, as well as Zeolite HS of formula Na6 [(AlO2)6(SiO2)6] 7.5 H2O).
  • Suitable nitrilotriacetic acid salts for use herein are the trisodium and tripotassium salts of nitrilotriacetic acid.
  • the acid itself or the disodium or dipotassium salts of the acid can also be used as additive.
  • the nitrilotriacetic acid or salt will generally be converted into fully ionized form.
  • the nitrilotriacetic acid salt (measured in trisodium form) constitutes from 1% to 8%, preferably from 3% to 7% by weight of composition.
  • the percentage quantity (b) of nitrilotriacetic acid salt (again measured in trisodium form) and the percentage quantity (a) of aluminosilicate cation exchange material (measured in hydrated form) are such that the sum a + 2b is between 14 and 24, preferably between 16 and 21.
  • a further essential component of the compositions herein is from 6% to 14%, preferably from 8% to 12% of a dry mixed phosphate builder.
  • the phosphate builder is selected from sodium and potassium tripolyphosphates and hydrates thereof but is preferably substantially anhydrous or partly hydrated (i.e. to no more than about 60% of its hydration capacity). Phosphate builder content is measured on an anhydrous basis however.
  • the phosphate builder comprises less than 12% thereof, preferably less than 8% thereof of pyrophosphates. Highly preferred is a phosphate builder system which is admixed in dry crystalline form with the remainder of the detergent composition.
  • the detergent compositions of the invention also include a bleach system comprising an inorganic or organic peroxy bleaching agent, a heavy metal scavenging agent and in preferred compositions, an organic peroxy acid bleach precursor.
  • Suitable inorganic peroxygen bleaches include sodium perborate mono- and tetrahydrate, sodium percarbonate, sodium persilicate and urea-hydrogen peroxide addition products and the clathrate 4Na2SO4:2H202:1NaCl.
  • Suitable organic bleaches include peroxylauric acid, peroxyoctanoic acid, peroxynonanoic acid, peroxydecanoic acid, diperoxydodecanedioic acid, diperoxyazelaic acid, mono- and diperoxyphthalic acid and mono- and diperoxyisophthalic acid.
  • the bleaching agent is present in the compositions of the invention at a level of from 5% to 35% preferably from 10% to 25% by weight.
  • the heavy metal scavenging agent is preferably a water-soluble chelating agent.
  • Preferred are aminopolyacids having four or more acidic protons per molecule.
  • Suitable chelating agents include aminocarboxylate chelating agents such as ethylenediaminetetraacetic acid (EDTA), hydroxyethylethylenediaminetriacetic acid (HEEDTA), dihydroxyethylethylenediaminediacetic acid (DHEEDDA), diethylenetriaminepentaacetic acid (DETPA), 1,2-diaminocyclohexane-N,N,N',N'-tetraacetic acid (DCTA) and water-soluble salts thereof, and aminopolyphosphonate chelating agents such as ethylenediaminetetra(methylenephosphonic acid) (EDTMP), diethylenetriaminepenta(methylenephosphonic acid) (DETPMP), nitrilotri(methylenephosphonic acid) (NTMP),hexamethylenediamine
  • the heavy metal scavenging agent herein can also be represented by water-insoluble smectite-type clays selected from saponites, hectorites and sodium and calcium montmorillorites (sodium and calcium here designating the principal inorganic cation of the clay).
  • smectite-type clays While any of the above smectite-type clays can be incorporated in the compositions of the invention, particularly preferred smectite-type clays have ion-exchange capacities of at least 50 meq/100g clay, more preferably at least 70 meq/100g (measured, for instance, as described in "The Chemistry and Physics of Clays", p.p. 264-265, Interscience (1979)). Especially preferred materials are as follows:-
  • Barasym LIH 200 When present, the above clays are generally added at a level of from 1% to 20%, more preferably from 2% to 10% by weight of composition. Such clays also provide a fabric softening benefit to the compositions.
  • Another suitable heavy metal scavenging agent is water-insoluble, preferably colloidal magnesium silicate or a water-soluble magnesium salt forming magnesium silicate in the aqueous slurry crutcher mix prior to spray-drying.
  • the magnesium silicate or salt is generally added at a level in the range from 0.015% to 0.2%, preferably from 0.03% to 0.15%, more preferably from 0.05% to 0.12% by weight (magnesium basis).
  • Suitable magnesium salts include magnesium sulfate, magnesium sulfate heptahydrate, magnesium chloride and magnesium chloride hexahydrate.
  • compositions of the invention preferably also contain an organic peroxy acid bleach precursor at a level of from 0.5% to 10%, preferably from 1% to 6% by weight.
  • Suitable bleach precursors are disclosed in UK-A-2040983, and include for example, the peracetic acid bleach precursors such as tetraacetylethylenediamine, tetraacetylmethylenediamine, tetraacetylhexylenediamine, sodium p-acetoxybenzene sulphonate, tetraacetylglycouril, pentaacetylglucose, octaacetyllactose, and methyl o-acetoxy benzoate.
  • R is an alkyl group containing from 6 to 12 carbon atoms wherein the longest linear alkyl chain extending from and including the carboxyl carbon contains from 5 to 10 carbon atoms and L is a leaving group, the conjugate acid of which has a pK a in the range from 6 to 13.
  • the alkyl group, R can be either linear or branched and, in preferred embodiments, it contains from 7 to 9 carbon atoms.
  • Preferred leaving groups L have a pK a in the range from about 7 to about 11, more preferably from about 8 to about 10. Examples of leaving groups are those having the formula
  • the preferred leaving group L has the formula (a) in which Z is H, x is 0 and Y is sulfonate, carboxylate or dimethylamine oxide radical.
  • Highly preferred materials are sodium 3,5,5,-trimethylhexanoyloxybenzene sulfonate, sodium 3,5,5-trimethylhexanoyloxybenzoate, sodium 2-ethylhexanoyl oxybenzenesulfonate, sodium nonanoyl oxybenzene sulfonate and sodium octanoyl oxybenzenesulfonate, the acyloxy group in each instance preferably being p-substituted.
  • the bleach activator herein will normally be added in the form of particles comprising finely-divided bleach activator and a binder
  • the binder is generally selected from nonionic surfactants such as the ethoxylated tallow alcohols, polyethylene glycols, anionic surfactants, film forming polymers, fatty acids and mixtures thereof. Highly preferred are nonionic surfactant binders, the bleach activator being admixed with the binder and extruded in the form of elongated particles through a radial extruder as described in EP-A-62523.
  • the bleach activator particles can be prepared by spray drying as described in EP-A-0174132.
  • the detergent compositions herein preferably contain from 5% to 60%, more preferably from 8% to 30% by weight of an organic surfactant selected from anionic, nonionic, zwitterionic, ampholytic and cationic surfactants, and mixtures thereof.
  • organic surfactant selected from anionic, nonionic, zwitterionic, ampholytic and cationic surfactants, and mixtures thereof.
  • Surfactants useful herein are listed in US-A-4,222,905 and US-A-4,239,659.
  • the anionic surfactant can be any one or more of the materials used conventionally in laundry detergents.
  • Suitable synthetic anionic surfactants are water-soluble salts of alkyl benzene sulphonates, alkyl sulphates, alkyl polyethoxy ether sulphates, paraffin sulphonates, alpha-olefin sulphonates, alpha-sulpho-carboxylates and their esters, alkyl glyceryl ether sulphonates, fatty acid monoglyceride sulphates and sulphonates, alkyl phenol polyethoxy ether sulphates, 2-acyloxy alkane-1-sulphonate, and beta-alkyloxy alkane sulphonate.
  • a particularly suitable class of anionic surfactants includes water-soluble salts, particularly the alkali metal, ammonium and alkanolammonium salts or organic sulphuric reaction products having in their molecular structure an alkyl or alkaryl group containing from about 8 to about 22, especially from about 10 to about 20 carbon atoms and a sulphonic acid or sulphuric acid ester group.
  • alkyl is the alkyl portion of acyl groups).
  • Examples of this group of synthetic detergents which form part of the detergent compositions of the present invention are the sodium and potassium alkyl sulphates, especially those obtained by sulphating the higher alcohols (C8 ⁇ 18) carbon atoms produced by reducing the glycerides of tallow or coconut oil and sodium and potassium alkyl benzene sulphonates, in which the alkyl group contains from about 9 to about 15, especially about 11 to about 13, carbon atoms, in straight chain or branched chain configuration, e.g.
  • anionic detergent compounds herein include the sodium C10 ⁇ 18 alkyl glyceryl ether sulphonates, especially those ethers of higher alcohols derived from tallow and coconut oil; sodium coconut oil fatty acid monoglyceride sulphonates and sulphates; and sodium or potassium salts of alkyl phenol ethylene oxide ether sulphate containing about 1 to about 10 units of ethylene oxide per molecule and wherein the alkyl groups contain about 8 to about 12 carbon atoms.
  • Other useful anionic detergent compounds herein include the water-soluble salts or esters of alpha-sulphonated fatty acids containing from about 6 to 20 carbon atoms in the fatty acid group and from about 1 to 10 carbon atoms in the ester group; water-soluble salts of 2-acyloxy-alkane-1-sulphonic acids containing from about 2 to 9 carbon atoms in the acyl group and from about 9 to about 23 carbon atoms in the alkane moiety; alkyl ether sulphates containing from about 10 to 18, especially about 12 to 16, carbon atoms in the alkyl group and from about 1 to 12, especially 1 to 6, more especially 1 to 4 moles of ethylene oxide; water-soluble salts of olefin sulphonates containing from about 12 to 24, preferably aout 14 to 16, carbon atoms, especially those made by reaction with sulphur trioxide followed by neutralization under conditions such that any sultones present are hydrolysed to the corresponding hydroxy alkane sulphonates;
  • alkane chains of the foregoing non-soap anionic surfactants can be derived from natural sources such as coconut oil or tallow, or can be made synthetically as for example using the Ziegler or Oxo processes. Water solubility can be achieved by using alkali metal, ammonium or alkanolammonium cations; sodium is preferred. Suitable fatty acid soaps can be selected from the ordinary alkali metal (sodium, potassium), ammonium, and alkylolammonium salts of higher fatty acids containing from about 8 to about 24, preferably from about 10 to about 22 and especially from about 16 to about 22 carbon atoms in the alkyl chain.
  • Suitable fatty acids can be obtained from natural sources such as, for instance, from soybean oil, castor oil, tallow, whale and fish oils, grease, lard and mixtures thereof).
  • the fatty acids also can be synthetically prepared (e.g., by the oxidation of petroleum, or by hydrogenation of carbon monoxide by the Fischer-Tropsch process).
  • Resin acids are suitable such as rosin and those resin acids in tall oil.
  • Napthenic acids are also suitable.
  • Sodium and potassium soaps can be made by direct saponification of the fats and oils or by the neutralization of the free fatty acids which are prepared in a separate manufacturing process. Particularly useful are the sodium and potassium salts of the mixtures of fatty acids derived from tallow and hydrogenated fish oil.
  • Mixtures of anionic surfactants are particularly suitable herein, especially mixtures of sulfonate and sulfate surfactants in a weight ratio of from about 5:1 to about 1:5, preferably from about 5:1 to about 1:1, more preferably from about 5:1 to about 1.5:1.
  • an alkyl benzene sulfonate having from 9 to 15, especially 11 to 13 carbon atoms in the alkyl radical, the cation being an alkali metal, preferably sodium; and either an alkyl sulfate having from 10 to 20, preferably 12 to 18 carbon atoms in the alkyl radical or an ethoxy sulfate having from 10 to 20, preferably 10 to 16 carbon atoms in the alkyl radical and an average degree of ethoxylation of 1 to 6, having an alkali metal cation, preferably sodium.
  • the nonionic surfactants useful in the present invention are condensates of ethylene oxide with a hydrophobic moiety to provide a surfactant having an average hydrophilic-lipophilic balance (HLB) in the range from about 8 to 17, preferably from about 9.5 to 13.5, more preferably from about 10 to about 12.5.
  • HLB hydrophilic-lipophilic balance
  • the hydrophobic moiety may be aliphatic or aromatic in nature and the length of the polyoxyethylene group which is condensed with any particular hydrophobic group can be readily adjusted to yield a water-soluble compound having the desired degree of balance between hydrophilic and hydrophobic elements.
  • Suitable nonionic surfactants include:
  • the compounds formed by condensing ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol generally falls in the range of about 1500 to 1800.
  • Such synthetic nonionic detergents are available on the market under the Trade Name of "Pluronic (RTM)" supplied by Wyandotte Chemicals Corporation.
  • Especially preferred nonionic surfactants for use herein are the C9-C15 primary alcohol ethoxylates containing 3-8 moles of ethylene oxide per mole of alcohol, particularly the C12-C15 primary alcohols containing 6-8 moles of ethylene oxide per mole of alcohol.
  • Cationic surfactants suitable for use herein include quaternary ammonium surfactants and surfactants of a semi-polar nature, for example amine oxides.
  • Suitable surfactants of the amine oxide class have the general formula V wherein R5 is a linear or branched alkyl or alkenyl group having 8 to 20 carbon atoms, each R6 is independently selected from C1 ⁇ 4 alkyl and -(C n H 2n 0) m H where i is an integer from 1 to 6, j is 0 or 1, n is 2 or 3 and m is from 1 to 7, the sum total of C n H 2n 0 groups in a molecule being no more than 7.
  • R5 has from 10 to 14 carbon atoms and each R6 is independently selected from methyl and -(C n H 2n 0) m H wherein m is from 1 to 3 and the sum total of C n H 2n 0 groups in a molecule is no more than 5, preferably no more than 3.
  • j is O and each R6 is methyl, and R5 is C12-C14 alkyl.
  • Another suitable class of amine oxide species is represented by bis-amine oxides having the following substituents.
  • Suitable quaternary ammonium surfactants for use in the present composition can be defined by the general formula VI: wherein R7 is a linear or branched alkyl, alkenyl or alkaryl group having 8 to 16 carbon atoms and each R8 is independently selected from C1 ⁇ 4 alkyl, C1 ⁇ 4 alkaryl and -(C n H 2n 0) m wherein i is an integer from 1 to 6, j is 0 or 1, n is 2 or 3 and m is from 1 to 7, the sum total of C n H 2n 0 groups in a molecule being no more than 7, and wherein Z represents counteranion in number to give electrical neutrality.
  • R7 has from 10 to 14 carbon atoms and each R8 is independently selected from methyl and (C n H 2n 0) m H wherein m is from 1 to 3 and the sum total of C n H 2n 0 groups in a molecule is no more than 5, preferably no more than 3.
  • j is 0, R8 is selected from methyl, hydroxyethyl and hydroxypropyl and R7 is C12-C14 alkyl.
  • Particularly preferred surfactants of this class include C12 alkyl trimethylammonium salts, C14 alkyltrimethylammonium salts, coconutalkyltrimethylammonium salts, coconutalkyldimethyl-hydroxyethylammonium salts, coconutalkyldimethylhydroxy-propylammonium salts, and C12 alkyldihydroxyethylmethyl ammonium salts.
  • Another group of useful cationic compounds are the diammonium salts of formula VI in which j is 1, R7 is C12-C14 alkyl, each R8 is methyl, hydroxyethyl or hydroxypropyl and i is 2 or 3.
  • R7 is coconut alkyl
  • R8 is methyl
  • i is 3.
  • the builder system herein is supplemented by three additional components, polycarboxylate polymers, alkali metal carbonates and alkali metal silicates.
  • the polycarboxylate polymers herein are preferably selected from co-polymeric polycarboxylic acids and their salts derived from an unsaturated polycarboxylic acid such as maleic acid, citraconic acid, itaconic acid or mesaconic acid as a first monomer and ethylene, methylvinyl ether, acrylic acid or methacrylic acid as a second monomer, the copolymer comprising at least about 10 mole %, preferably at least about 20 mole % of polycarboxylic acid units and having a weight-average molecular weight of at least about 12,000, preferably at least about 30,000; homopolyacrylates and homopolymethacrylates having a weight-average molecular weight of from about 1000 to about 20,000, preferably from about 1000 to about 10,000; and mixtures thereof.
  • an unsaturated polycarboxylic acid such as maleic acid, citraconic acid, itaconic acid or mesaconic acid as a first monomer and ethylene, methylviny
  • Mixtures are highly preferred in the context of providing excellent bleach stability, detergency and anti-incrustation performance in the context of the low-phosphorous, low aluminosilicate/NTA formulations disclosed herein.
  • Suitable mixtures have a copolymer: homopolymer ratio of from about 1:2 to about 5:1, preferably from about 1:1 to about 5:1, more preferably about 1:1 to 2:1.
  • the total level of polycarboxylate polymer in final product is preferably from 0.5% to 5%, more preferably from 2% to 4%.
  • Weight-average polymer molecular weights can be determined herein by light scattering or by gel permeation chromotography using Waters ⁇ Porasil (RTM) GPC 60 A2 and ⁇ Bondagel (RTM) E-125, E-500 and E-1000 in series, temperature-controlled columns at 40°C against sodium polystyrene sulphonate polymer standards, available from Polymer Laboratories Ltd., Shropshire, UK, the polymer standards being calibrated as their sodium salts, and the eluant being 0.15M sodium dihydrogen phosphate and 0.02M tetramethyl ammonium hydroxide at pH 7.0 in 80/20 water/acetonitrile.
  • RTM Waters ⁇ Porasil
  • RTM Bondagel
  • Alkali metal carbonate is important herein for providing the appropriate in-use solution pH for optimum detergency (from about pH 10 to pH 11, preferably from about pH 10.4 to about pH 10.6, measured as 1% solution).
  • the compositions of the invention include from 5% to 30%, preferably from 10% to 25% alkali metal carbonate (anhydrous basis).
  • Alkali metal silicate is preferably included in the compositions of the invention at a level in the range from 1% to 4%, more preferably from 1.5% to 2.5%. At lower levels, bleaching performance is found to be increasingly degraded; at higher levels, on the other hand, aluminosilicate performance and fabric appearance is detrimentally effected by aluminosilicate particle aggregation.
  • compositions of the invention can be supplemented by all manner of detergent and laundering components, inclusive of suds suppressors, enzymes, fluorescers, photoactivators, bleach catalysts, soil suspending agents, anti-caking agents, pigments, perfumes, fabric conditioning agents etc.
  • Suds suppressors are represented by materials of the silicone, wax, vegetable and hydrocarbon oil and phosphate ester varieties.
  • Suitable silicone suds controlling agents include polydimethylsiloxanes having a molecular weight in the range from about 200 to about 200,000 and a kinematic viscosity in the range from about 20 to about 2,000,000 mm2/s, preferably from about 3000 to about 30,000 mm2/s, and mixtures of siloxanes and hydrophobic silanated (preferably trimethylsilanated) silica having a particle size in the range from about 10 nm to about 20 nm and a specific surface area above about 50 m2/g.
  • Suitable waxes include microcrystalline waxes having a melting point in the range from about 65 o C to about 100 o C, a molecular weight in the range from about 400-1000, and a penetration value of at least 6, measured at 25°C (77 o F) by ASTM-D1321, and also paraffin waxes, synthetic waxes and natural waxes.
  • Suitable phosphate esters include mono- and/or di-C16-C22 alkyl or alkenyl phosphate esters, and the corresponding mono- and/or di alkyl or alkenyl ether phosphates containing up to 6 ethoxy groups per molecule.
  • Enzymes suitable for use herein include those discussed in US-A-3,519,570 and US-A-3,533,139 to McCarty and McCarty et al issued July 7, 1970 and January 5, 1971, respectively.
  • Suitable fluorescers include Blankophor MBBH (Bayer AG) and Tinopal CBS and EMS (Ciba Geigy).
  • Photoactivators are discussed in EP-A-57088, highly preferred materials being zinc phthalocyanine tri- and tetra-sulfonates.
  • Suitable fabric conditioning agents include di-C12-C24 alkyl or alkenyl amines and ammonium and quaternary ammonium salts.
  • Suitable bleach catalysts are discussed in EP-A-72166 and EP-A-0124341.
  • Antiredeposition and soil suspension agents suitable herein include cellulose derivatives such as methylcellulose, carboxymethylcellulose and hydroxyethylcellulose.
  • compositions of the invention are preferably prepared by spray-drying an aqueous slurry comprising the aluminosilicate and, where present, alkali metal silicate and anionic surfactant.
  • the nitrilotriacetate can also be spray-dried or added separately to the spray-dried base granules.
  • Tripolyphosphate builder and, where present, carbonate, are also separately dry-mixed with the spray-dried base granules.
  • the aqueous slurry is mixed at a temperature in the range from about 45-90 o C and the water-content of the slurry adjusted to a range of about 25% to about 50%.
  • Spray drying is undertaken with a drying gas inlet temperature of from about 250-390 o C, preferably about 275-350 o C, providing a final moisture content in the range of from about 8% to 14% by weight.
  • Granular detergent compositions are prepared as follows.
  • a base powder composition is first prepared by mixing all components except Dobanol 45E7, bleach, bleach activator, enzyme, suds suppressor, phosphate and carbonate in a crutcher as an aqueous slurry at a temperature of about 55°C and containing about 35% water.
  • the slurry is then spray dried at a gas inlet temperature of about 330°C to form base powder granules.
  • the bleach activator where present, is then admixed with TAE25 as binder and extruded in the form of elongate particles through a radial extruder as described in European Patent Application Number 62523.
  • the bleach activator noodles, bleach, enzyme, suds suppressor, phosphate and carbonate are then dry-mixed with the base powder composition and finally Dobanol 45E7 is sprayed into the final mixture.
  • compositions are low phosphate detergent compositions displaying excellent bleach stability, fabric care and detergency performance across the range of wash temperatures with particularly outstanding performance in the case of Examples I to IV on greasy and particulate soils at low wash temperatures.

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Claims (12)

  1. Composition détergente granulaire, comprenant, en poids de la composition détergente :
    (a) de 6% à 18% (sur la base de la forme hydratée) d'une matière échangeuse de cations de type aluminosilicate insoluble dans l'eau,
    (b) de 1% à 8% (sur la base de la forme trisodique) d'un sel de métal alcalin d'acide nitrilotriacétique;
    (c) de 6% à 14% (sur une base anhydre) d'adjuvant phosphate mélangé à sec, l'adjuvant phosphate étant choisi parmi les tripolyphosphates de sodium et de potassium et comprenant moins de 12% de pyrophosphate,
    (d) de 5% à 35% d'un agent de blanchiment peroxydé minéral ou organique,
    (e) de 0% à 10% d'un précurseur d'agent de blanchiment peracide organique, et
    (f) un agent piégeur de métaux lourds,
    dans laquelle la somme (a) + 2 (b) des quantités de (a) et de (b), en pourcentages, indiquées ci-dessus est comprise entre 14 et 24.
  2. Composition selon la revendication 1, dans laquelle la somme (a) + 2 (b) des quantités de (a) et de (b), en pourcentages, est comprise entre 16 et 21.
  3. Composition selon la revendication 1 ou 2, comprenant de 7% à 16%, de préférence de 8% à 14%, de matière échangeuse de cations de type aluminosilicate insoluble dans l'eau.
  4. Composition selon l'une quelconque des revendications 1 à 3, dans laquelle la matière échangeuse de cations répond à la formule générale I :



            Mz[(AlO₂)z(SiO₂)y],xH₂O   I



    dans laquelle M est un cation échangeur de calcium, z et y sont au moins égaux à 6; le rapport molaire de z à y est dans la gamme de 1,0 à 0,5; et x a une valeur de 10 à 264; l'aluminosilicate ayant une capacité d'échange d'ions calcium d'au moins 200 milliéquivalents-g de dureté d'eau en CaCO₃/g d'aluminosilicate, calculée sur une base anhydre, une vitesse d'échange des ions calcium d'au moins 130 milliéquivalents-g de CaCO₃/min/g d'aluminosilicate (2 grains de Ca²⁺/min/g) et un diamètre de particule de 0,1 µm à 10 µm.
  5. Composition selon l'une quelconque des revendications 1 à 4, comprenant de 3% à 7% du sel d'acide nitrilotriacétique.
  6. Composition selon l'une quelconque des revendications 1 à 5, comprenant de 8% à 12% de l'adjuvant phosphate et dans laquelle l'adjuvant phosphate comprend moins de 8% de pyrophosphate.
  7. Composition selon l'une quelconque des revendications 1 à 6, comprenant au moins 0,5% de précurseur d'agent de blanchiment peracide organique.
  8. Composition selon la revendication 7, dans laquelle le précurseur d'agent de blanchiment peracide organique répond à la formule générale II
    Figure imgb0010
     xdans laquelle R est un groupe alkyle contenant de 6 à 12 atomes de carbone, dans laquelle la chaîne alkyle linéaire la plus longue s'étendant depuis l'atome de carbone du carboxyle et incluant cet atome contient de 5 à 10 atomes de carbone et L est un groupe partant, dont l'acide conjugué a un pKa dans la gamme de 6 à 13.
  9. Composition selon l'une quelconque des revendications 1 à 8, dans laquelle l'agent piégeur de métaux lourds est choisi parmi les aminopolycarboxylates et les aminopolyphosphonates hydrosolubles comportant au moins quatre protons acides par molécule, ou une argile de type smectite insoluble dans l'eau, choisie parmi les saponites, les hectorites, et les montmorillonites de sodium et de calcium.
  10. Composition selon l'une quelconque des revendications 1 à 9, comprenant en outre de 0,5% à 5% de polymère polycarboxylate.
  11. Composition selon l'une quelconque des revendications 1 à 10, comprenant en outre de 1% à 4% de silicate de métal alcalin.
  12. Composition selon l'une quelconque des revendications 1 à 11, comprenant de 5% à 60% de tensioactif organique choisi parmi les tensioactifs anioniques, non ioniques, zwittérioniques, ampholytes et cationiques, et leurs mélanges.
EP85307980A 1984-11-03 1985-11-04 Compositions détergentes Revoked EP0181180B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT85307980T ATE90112T1 (de) 1984-11-03 1985-11-04 Detergenszusammensetzungen.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB848427855A GB8427855D0 (en) 1984-11-03 1984-11-03 Detergent compositions
GB8427855 1984-11-03

Publications (3)

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EP0181180A2 EP0181180A2 (fr) 1986-05-14
EP0181180A3 EP0181180A3 (en) 1990-01-17
EP0181180B1 true EP0181180B1 (fr) 1993-06-02

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EP85307980A Revoked EP0181180B1 (fr) 1984-11-03 1985-11-04 Compositions détergentes

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EP (1) EP0181180B1 (fr)
AT (1) ATE90112T1 (fr)
CA (1) CA1279801C (fr)
DE (1) DE3587382T2 (fr)
DK (1) DK164706C (fr)
FI (1) FI80068C (fr)
GB (1) GB8427855D0 (fr)
GR (1) GR852653B (fr)
IE (1) IE60527B1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0660873B2 (fr) † 1992-09-01 2006-05-31 The Procter & Gamble Company Detergent en poudre de haute densite

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT330930B (de) * 1973-04-13 1976-07-26 Henkel & Cie Gmbh Verfahren zur herstellung von festen, schuttfahigen wasch- oder reinigungsmitteln mit einem gehalt an calcium bindenden substanzen
FI822428L (fi) * 1981-07-15 1983-01-16 Unilever Nv Rengoeringsblandning
US4412934A (en) * 1982-06-30 1983-11-01 The Procter & Gamble Company Bleaching compositions

Also Published As

Publication number Publication date
IE60527B1 (en) 1994-07-27
EP0181180A2 (fr) 1986-05-14
DK164706B (da) 1992-08-03
FI80068B (fi) 1989-12-29
DK506285A (da) 1986-05-04
GR852653B (fr) 1986-02-03
FI854297A0 (fi) 1985-11-01
FI80068C (fi) 1990-04-10
DE3587382T2 (de) 1993-12-16
GB8427855D0 (en) 1984-12-12
IE852715L (en) 1986-05-03
CA1279801C (fr) 1991-02-05
DK506285D0 (da) 1985-11-01
FI854297A (fi) 1986-05-04
DK164706C (da) 1992-12-21
EP0181180A3 (en) 1990-01-17
ATE90112T1 (de) 1993-06-15
DE3587382D1 (de) 1993-07-08

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