EP0154423A1 - Röntgenoskopisches kontrastierendes Umwindegarn - Google Patents
Röntgenoskopisches kontrastierendes Umwindegarn Download PDFInfo
- Publication number
- EP0154423A1 EP0154423A1 EP85300891A EP85300891A EP0154423A1 EP 0154423 A1 EP0154423 A1 EP 0154423A1 EP 85300891 A EP85300891 A EP 85300891A EP 85300891 A EP85300891 A EP 85300891A EP 0154423 A1 EP0154423 A1 EP 0154423A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- yarn
- radio opaque
- fibre
- opaque yarn
- filled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 18
- 229920000728 polyester Polymers 0.000 claims abstract description 6
- 239000004743 Polypropylene Substances 0.000 claims abstract description 4
- -1 polypropylene Polymers 0.000 claims abstract description 4
- 229920001155 polypropylene Polymers 0.000 claims abstract description 4
- 239000000835 fiber Substances 0.000 claims description 22
- 239000007822 coupling agent Substances 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 125000001589 carboacyl group Chemical group 0.000 claims description 2
- 238000009941 weaving Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- IEKHISJGRIEHRE-UHFFFAOYSA-N 16-methylheptadecanoic acid;propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)CCCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O IEKHISJGRIEHRE-UHFFFAOYSA-N 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000675 fabric finishing Substances 0.000 description 1
- 238000009962 finishing (textile) Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
Definitions
- This invention relates to radio opaque yarn such as that used in the manufacture of surgical swabs and dressings.
- Radio opaque fibres are disclosed in our European patent application No. 83304777.2. These fibres contain a high proportion of barium sulphate in order to provide the required degree of X-ray opacity. Such highly filled fibres tend to stretch due to fracture of the constituent filaments. Moreover the fractured filaments tend to run causing aggregations which may snarl-up during weaving.
- a radio opaque yarn comprises a bundle of filled fibres containing not less than 54% w /w of barium sulphate, the bundle being bound with up to 20% w /w of substantially unfilled binding fibre.
- Conventional wrapped yarns contain approximately 50% by weight of binding fibre.
- the present invention employs a higher proportion of filled fibres. This is important in the production of radio opaque yarns to optimise the opacity of the product.
- the unfilled, binding fibre may have a higher modulus and tensile strength than the filled fibres, increasing the strength and durability of the yarn. Furthermore the binding prevents running of any fractured filled fibres. This particularly facilitates narrow weaving or knitting where control of yarn tension is important.
- the binding fibres may be monofilament or multifilament.
- Preferred yarns in accordance with this invention comprise less than 5% w /w of binding fibre.
- the binding fibre preferably has a diameter of about 0.05 of the diameter of the bundle of filled fibre.
- the binding fibre may be wound at a preferred rate of 2 to 8 turns per cm, more preferably 4 to 6 turns per cm, most preferably 4 turns per cm. Yarn having less than 2 turns per cm of wrapping fibre tend to fragment during weaving, whereas yarn having more than 8 turns per cm is brittle and liable to break during cloth processing.
- the binding fibre preferably comprises a polyester although alternative materials which form fibres having a high modulus and tensile strength may be employed.
- the filled fibre preferably comprises polypropylene. Polyester fibres have also been found to be applicable. A maximum of 80% w /w of barium sulphate has been found to be appropriate although a maximum of 70% w /w may be preferred.
- a coupling agent may be employed, for example an alkanoyl triisostearoyl titanate or other of the coupling agents disclosed in European patent application No. 83304777.2.
- binding fibres may be employed although use of a single fibre is preferred because wrapping with a plurality of fibres has not been found to confer any additional advantages.
- the binding fibre may be textured, bulked, crimped or otherwise treated both to impart extensibility to the yarn and to improve the ability of the yarn to withstand wet and dry fabric finishing operations.
- a bundle of twenty filamens composed of polypropylene (melt flow index 12, 29.5% w /w), barium sulphate (particle size 0.5 ⁇ m, 70% w /w) and a coupling agent isopropyl triisostearoyl titanate (0.5% w /w) and a pigment (Cobalt Blue Med) having a weight of not less than 3000 decitex was wrapped with 4 turns per cm of a flat polyester fibre (24 filament, 74 decitex, no added lubricant).
- the resultant yarn contained 68% w /w of barium sulphate and satisfied both the British Pharmacopea Index test (reference SDM XVII) and the U.S. pharmaceutical X-ray opacity requirements.
- the yarn was found to have a minimum breaking load greater than 500 cN and a breaking extension not less than 100% but not greater than 300%. The yarn could be woven without difficulty.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT85300891T ATE33997T1 (de) | 1984-02-11 | 1985-02-11 | Roentgenoskopisches kontrastierendes umwindegarn. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB848403656A GB8403656D0 (en) | 1984-02-11 | 1984-02-11 | Yarns |
GB8403656 | 1984-02-11 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0154423A1 true EP0154423A1 (de) | 1985-09-11 |
EP0154423B1 EP0154423B1 (de) | 1988-05-04 |
Family
ID=10556475
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85300891A Expired EP0154423B1 (de) | 1984-02-11 | 1985-02-11 | Röntgenoskopisches kontrastierendes Umwindegarn |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0154423B1 (de) |
AT (1) | ATE33997T1 (de) |
CA (1) | CA1262815A (de) |
DE (1) | DE3562494D1 (de) |
GB (2) | GB8403656D0 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0304311A1 (de) * | 1987-08-21 | 1989-02-22 | The Wellcome Foundation Limited | Komplexe von Polyethylenglycol mit Gewebeplasminogenaktivator |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8716243D0 (en) * | 1987-07-10 | 1987-08-19 | Courtaulds Plc | Yarns |
US6169045B1 (en) | 1993-11-16 | 2001-01-02 | Kimberly-Clark Worldwide, Inc. | Nonwoven filter media |
CN103741304A (zh) * | 2013-07-09 | 2014-04-23 | 浙江川本卫生材料有限公司 | 医用x光可探测缝纫线 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1188629A (fr) * | 1957-11-22 | 1959-09-24 | Vernon & Company Ltd | Perfectionnements apportés aux fils et pansements chirurgicaux décelables par les rayons chi. |
GB839718A (en) * | 1957-11-19 | 1960-06-29 | Robinson & Sons Ltd | Improvements in surgical dressings |
FR2125527A1 (de) * | 1971-02-17 | 1972-09-29 | Codman & Shurtleff |
-
1984
- 1984-02-11 GB GB848403656A patent/GB8403656D0/en active Pending
- 1984-11-30 GB GB08430257A patent/GB2153867B/en not_active Expired
-
1985
- 1985-02-11 DE DE8585300891T patent/DE3562494D1/de not_active Expired
- 1985-02-11 EP EP85300891A patent/EP0154423B1/de not_active Expired
- 1985-02-11 CA CA000474041A patent/CA1262815A/en not_active Expired
- 1985-02-11 AT AT85300891T patent/ATE33997T1/de active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB839718A (en) * | 1957-11-19 | 1960-06-29 | Robinson & Sons Ltd | Improvements in surgical dressings |
FR1188629A (fr) * | 1957-11-22 | 1959-09-24 | Vernon & Company Ltd | Perfectionnements apportés aux fils et pansements chirurgicaux décelables par les rayons chi. |
FR2125527A1 (de) * | 1971-02-17 | 1972-09-29 | Codman & Shurtleff |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0304311A1 (de) * | 1987-08-21 | 1989-02-22 | The Wellcome Foundation Limited | Komplexe von Polyethylenglycol mit Gewebeplasminogenaktivator |
Also Published As
Publication number | Publication date |
---|---|
GB8403656D0 (en) | 1984-03-14 |
GB8430257D0 (en) | 1985-01-09 |
GB2153867B (en) | 1986-12-03 |
DE3562494D1 (en) | 1988-06-09 |
ATE33997T1 (de) | 1988-05-15 |
GB2153867A (en) | 1985-08-29 |
CA1262815C (en) | 1989-11-14 |
EP0154423B1 (de) | 1988-05-04 |
CA1262815A (en) | 1989-11-14 |
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