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EP0154367A3 - Process for phosphatizing metals - Google Patents

Process for phosphatizing metals Download PDF

Info

Publication number
EP0154367A3
EP0154367A3 EP85200192A EP85200192A EP0154367A3 EP 0154367 A3 EP0154367 A3 EP 0154367A3 EP 85200192 A EP85200192 A EP 85200192A EP 85200192 A EP85200192 A EP 85200192A EP 0154367 A3 EP0154367 A3 EP 0154367A3
Authority
EP
European Patent Office
Prior art keywords
phosphatizing
metals
coatings
phosphatizing metals
ethylenediamenetetraacetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP85200192A
Other languages
German (de)
Other versions
EP0154367A2 (en
EP0154367B1 (en
Inventor
Gerhard Muller
Werner Dr. Rausch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEA Group AG
Continentale Parker SA
Original Assignee
Metallgesellschaft AG
Continentale Parker SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metallgesellschaft AG, Continentale Parker SA filed Critical Metallgesellschaft AG
Priority to AT85200192T priority Critical patent/ATE37203T1/en
Publication of EP0154367A2 publication Critical patent/EP0154367A2/en
Publication of EP0154367A3 publication Critical patent/EP0154367A3/en
Application granted granted Critical
Publication of EP0154367B1 publication Critical patent/EP0154367B1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/23—Condensed phosphates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/12—Orthophosphates containing zinc cations
    • C23C22/17—Orthophosphates containing zinc cations containing also organic acids
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
    • C23C22/362—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also zinc cations

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Paints Or Removers (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Catalysts (AREA)
  • Glass Compositions (AREA)
  • Secondary Cells (AREA)
  • Materials For Medical Uses (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)

Abstract

The quality of coatings in a low zinc phosphating process is improved by including an activator of formate, nitrilotriacetate, trichloroacetate or ethylenediamenetetraacetate to produce more uniform coatings particularly desirable in advance of electrocoating.
EP85200192A 1984-03-09 1985-02-15 Process for phosphatizing metals Expired EP0154367B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT85200192T ATE37203T1 (en) 1984-03-09 1985-02-15 PROCESSES FOR THE PHOSPHATION OF METALS.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19843408577 DE3408577A1 (en) 1984-03-09 1984-03-09 METHOD FOR PHOSPHATING METALS
DE3408577 1984-03-09

Publications (3)

Publication Number Publication Date
EP0154367A2 EP0154367A2 (en) 1985-09-11
EP0154367A3 true EP0154367A3 (en) 1986-08-20
EP0154367B1 EP0154367B1 (en) 1988-09-14

Family

ID=6229954

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85200192A Expired EP0154367B1 (en) 1984-03-09 1985-02-15 Process for phosphatizing metals

Country Status (10)

Country Link
US (1) US4637838A (en)
EP (1) EP0154367B1 (en)
CN (1) CN85101297A (en)
AT (1) ATE37203T1 (en)
AU (1) AU575380B2 (en)
CA (1) CA1224121A (en)
DE (2) DE3408577A1 (en)
ES (1) ES541015A0 (en)
GB (1) GB2155960A (en)
ZA (1) ZA851761B (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8527833D0 (en) * 1985-11-12 1985-12-18 Pyrene Chemicals Services Ltd Phosphate coating of metals
DE3630246A1 (en) * 1986-09-05 1988-03-10 Metallgesellschaft Ag METHOD FOR PRODUCING PHOSPHATE COVER AND ITS APPLICATION
DE3871031D1 (en) * 1987-08-19 1992-06-17 Metallgesellschaft Ag METHOD FOR PHOSPHATING METALS.
JPH01100281A (en) * 1987-10-13 1989-04-18 Nippon Parkerizing Co Ltd Coating treatment liquid for metal surfaces
JPH0730455B2 (en) * 1988-09-27 1995-04-05 日本パーカライジング株式会社 Phosphate chemical treatment liquid
JP2781844B2 (en) * 1988-10-20 1998-07-30 日本ペイント株式会社 Undercoating agent for painting
JP2636919B2 (en) * 1989-01-26 1997-08-06 日本パーカライジング株式会社 Lubrication treatment method for cold plastic working of steel
DE3916498A1 (en) * 1989-05-20 1990-11-22 Kolbenschmidt Ag METHOD FOR APPLYING A PHOSPHATE RUNNING LAYER TO A BEARING METAL LAYER
DE4409306A1 (en) * 1994-03-18 1995-09-21 Basf Ag Process for modifying metal surfaces
DE4417965A1 (en) * 1994-05-21 1995-11-23 Henkel Kgaa Iron phosphating using substituted monocarboxylic acids
US6716192B1 (en) * 1997-09-30 2004-04-06 Charles F. Schroeder Medical needle having a visibly marked tip
US6551417B1 (en) 2000-09-20 2003-04-22 Ge Betz, Inc. Tri-cation zinc phosphate conversion coating and process of making the same
DE102005047424A1 (en) * 2005-09-30 2007-04-05 Henkel Kgaa Phosphating solution used as a pre-treatment for metal surfaces contains zinc irons, phosphate ions, hydrogen peroxide or an equivalent amount of a hydrogen peroxide-splitting substance and aliphatic chelate-forming carboxylic acid
CN102839374A (en) * 2012-09-05 2012-12-26 业纮企业股份有限公司 Surface treatment method for carbon steel ball for ball valve
CN103668149B (en) * 2013-12-19 2016-08-24 湖南金裕化工有限公司 Ordinary-temp fast bonderizing liquor and preparation method thereof
CN103695881B (en) * 2013-12-19 2016-08-24 湖南金裕化工有限公司 Room temperature is without slag fast bonderizing liquor and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1086955A (en) * 1952-08-28 1955-02-17 Parker Ste Continentale Improvements in metal coating
EP0015021A1 (en) * 1979-02-23 1980-09-03 Metallgesellschaft Ag Process for the pretreatment of metal surfaces for electrophoretic dip painting

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2884351A (en) * 1956-01-25 1959-04-28 Parker Rust Proof Co Method of cold rolling ferrous strip stock
GB865497A (en) * 1958-10-03 1961-04-19 Pyrene Co Ltd Improvements relating to the cleaning and phosphate coating of metallic surfaces
GB1414484A (en) * 1972-05-03 1975-11-19 Pyrene Chemical Services Ltd Treatment of zinc surfaces
SU800240A1 (en) * 1977-03-05 1981-01-30 Научно-Исследовательский Институтхимии Саратовского Государственногоордена Трудового Красного Знамениуниверситета Им.H.Г.Чернышевского Solution for cadmium parkerizing
GB1591039A (en) * 1977-05-03 1981-06-10 Pyrene Chemical Services Ltd Processes and compositions for coating metal surfaces
JPS5811513B2 (en) * 1979-02-13 1983-03-03 日本ペイント株式会社 How to protect metal surfaces
GB2072225B (en) * 1980-03-21 1983-11-02 Pyrene Chemical Services Ltd Process and composition for coating metal surfaces
DE3016576A1 (en) * 1980-04-30 1981-11-05 Metallgesellschaft Ag, 6000 Frankfurt METHOD FOR PHOSPHATING METAL SURFACES AND THE USE THEREOF
DE3118375A1 (en) * 1981-05-09 1982-11-25 Metallgesellschaft Ag, 6000 Frankfurt METHOD FOR PHOSPHATING METALS AND ITS APPLICATION FOR PRE-TREATMENT FOR ELECTRO DIP PAINTING
US4498935A (en) * 1981-07-13 1985-02-12 Parker Chemical Company Zinc phosphate conversion coating composition
US4486241A (en) * 1981-09-17 1984-12-04 Amchem Products, Inc. Composition and process for treating steel
JPS58144477A (en) * 1982-02-20 1983-08-27 Nippon Paint Co Ltd Phosphating process of metal surface
DE3311738A1 (en) * 1983-03-31 1984-10-04 Metallgesellschaft Ag, 6000 Frankfurt METHOD FOR PHOSPHATING METAL SURFACES

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1086955A (en) * 1952-08-28 1955-02-17 Parker Ste Continentale Improvements in metal coating
EP0015021A1 (en) * 1979-02-23 1980-09-03 Metallgesellschaft Ag Process for the pretreatment of metal surfaces for electrophoretic dip painting

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, Band 94, Nr. 22, Juni 1981, Seite 280, Nr. 179325a, Columbus, Ohio, US; & SU - A - 800 240 (SARATOV STATE UNIVERSITY) 23-01-1981 *
CHEMICAL ABSTRACTS, Band 99, Nr. 26, Dezember 1983, Seite 273, Nr. 216843u, Columbus, Ohio, US; & JP - A - 58 144 477 (NIPPON PAINT CO., LTD.) 27-08-1983 *

Also Published As

Publication number Publication date
EP0154367A2 (en) 1985-09-11
CA1224121A (en) 1987-07-14
ATE37203T1 (en) 1988-09-15
ES8602152A1 (en) 1985-12-01
AU575380B2 (en) 1988-07-28
EP0154367B1 (en) 1988-09-14
AU3957485A (en) 1985-09-12
GB8506049D0 (en) 1985-04-11
CN85101297A (en) 1987-01-24
ES541015A0 (en) 1985-12-01
GB2155960A (en) 1985-10-02
DE3408577A1 (en) 1985-09-12
ZA851761B (en) 1985-11-27
US4637838A (en) 1987-01-20
DE3564967D1 (en) 1988-10-20

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