EP0151106A1 - Zwei komponenten abbindende zusammensetzung und anwendung dieser zusammensetzung für isophone und isotherme überzüge - Google Patents
Zwei komponenten abbindende zusammensetzung und anwendung dieser zusammensetzung für isophone und isotherme überzügeInfo
- Publication number
- EP0151106A1 EP0151106A1 EP19830902104 EP83902104A EP0151106A1 EP 0151106 A1 EP0151106 A1 EP 0151106A1 EP 19830902104 EP19830902104 EP 19830902104 EP 83902104 A EP83902104 A EP 83902104A EP 0151106 A1 EP0151106 A1 EP 0151106A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- plasticizer
- solid
- resin
- approximately
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 37
- 238000000576 coating method Methods 0.000 title claims abstract description 10
- 239000011248 coating agent Substances 0.000 title claims abstract description 9
- 239000000470 constituent Substances 0.000 title claims description 13
- 230000009977 dual effect Effects 0.000 title 1
- 239000007787 solid Substances 0.000 claims abstract description 24
- 239000007788 liquid Substances 0.000 claims abstract description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004014 plasticizer Substances 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 239000011505 plaster Substances 0.000 claims abstract description 9
- 229920006243 acrylic copolymer Polymers 0.000 claims abstract description 7
- 239000004568 cement Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000725 suspension Substances 0.000 claims abstract description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000945 filler Substances 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical group 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims 1
- 238000009413 insulation Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000002353 algacidal effect Effects 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000000088 plastic resin Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- DGSDBJMBHCQYGN-UHFFFAOYSA-M sodium;2-ethylhexyl sulfate Chemical group [Na+].CCCCC(CC)COS([O-])(=O)=O DGSDBJMBHCQYGN-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
Definitions
- the invention relates to a curable composition with two constituents, one liquid and the other solid in the form of particles, in particular powders, which are mixed at the time of use.
- the invention also relates to the use of such a composition as isophonic and isothermal coating and resistant to corrosion and to chemical agents.
- the liquid phase comprises, on the one hand, a plastic resin in solution or in suspension in water and, on the other hand, an anionic agent capable of forming bubbles with a compound of the solid component, while this solid component comprises, in addition to said compound capable of reacting with said anionic agent, a compound capable of solidifying on contact with water.
- the plastic resin is chosen from the group comprising vinyl acetate-vinyl versatate copolymers, acrylic ester-vinyl versatate-vinyl acetate terpolymers and styrene-acrylic compound copolymers.
- the anionic agent of the liquid component is the condensation product of a sodium lauryl ether sulfate and an alcohol comprising from 12 to 14 carbon atoms, while the associated compound of the solid component is sodium ethylhexyl sulfate .
- the constituent of the solid component capable of solidifying on contact with water and plaster, possibly with a setting retarder. Anti-fire charges can also be provided in the composition.
- this prior composition has the disadvantage, as established by the Applicant while continuing its work, of cracking as it ages, whatever the environment. Due to a shrinkage of the resin, cracks appear in the coatings made of such a composition, with the consequence of forming thermal bridges and a serious deterioration of the thermal insulation properties of the coating.
- the present invention aims to remedy these drawbacks by proposing a composition of the same general type as the previous composition mentioned above, but which does not exhibit any aging phenomenon and which can be used at very high temperatures, up to 1000 ° C, without altering or detaching from any support.
- the invention also aims to propose a composition of this type in which cement and plaster can be present simultaneously, the incompatibility of which is well known, without the risk of these two components dissociating after hardening.
- the invention finally aims to propose a composition of this type which can be used in very thin layers, around 3 to 4 mm thick, as a soundproofing and isothermal covering.
- the subject of the invention is a curable composition with two constituents, one liquid, the other solid in the particulate state, which is mixed at the time of use, the liquid constituent comprising a resin. and a plasticizer in solution or in suspension in water, while the solid component comprises a compound capable of causing the expansion of said resin, and fillers,
- this composition being characterized in that said resin and said plasticizer are respectively a modified acrylic copolymer and an acrylic plasticizer, and in that the solid constituent contains, in% by weight, approximately 30 to 60% of plaster, approximately 52 to 4% of cement and, as agent of compatibility between these two products, 3 to 7% of titanium or aluminum oxide.
- Additives known per se may be incorporated in the liquid component as well as in the solid component, for example, antistatic products, germicidal and algicidal compounds, fire-resistant products, setting retarders, etc.
- the solid component will contain aluminum powder or expanded mica.
- the aluminum or expanded mica particles rise to the free surface, before the composition hardens, to then contribute to thermal insulation by reflection of infrared radiation.
- the solid component may contain lead.
- modified acrylic copolymer it is advantageous to use, in the liquid component, a salt of versatic acid.
- the content of modified acrylic copolymer in the liquid component will be about 10 to 30% by weight, while the content of acrylic plasticizer will be about 1 to 6%. Under these conditions, the liquid constituent, with its possible additives, will be in the form of an emulsion which is perfectly stable over time.
- the proportions of plaster and cement of the solid constituent, as well as the nature of these compounds, will vary according to the physical properties required of the coating.
- the plaster content will generally be 30 to 60% by weight and the cement content from 52 to 4%, while the content of titanium oxide or aluminum oxide will be between 3 and 7%.
- the particle size of the solid particles is approximately 0.3 to 2.5 mm.
- This powder ready for use, is also stable during storage.
- the solid component At the time of use, about 100 parts by weight of the solid component are mixed with 140 parts by weight of the liquid component and mechanical mixing is carried out.
- the application is carried out using a worm type spraying machine, which ensures the mixing of the paste while allowing an expansion of the resin.
- the mixture can also be laid, like a mortar, with a trowel or any other conventional device in the building industry.
- the composition according to the invention hardens very quickly, since it takes only a quarter of an hour to obtain appreciable surface hardening, against two and a half hours with a composition according to the aforementioned patent application FR 79 03347.
- a layer with a much smaller thickness is sufficient than with conventional insulators.
- the external temperature of the coating is 58 ° C.
- a 3.5 mm thick layer provides excellent sound insulation on the order of 20 decibels between the medium and the treble.
- composition according to the invention adheres to any type of support, for example to a metallic surface, even polished, to glass or to dry or wet plaster, and it can optionally be applied in several superposed layers. It can be used with advantage for any type of sound or thermal insulation, both on machines and on building facades.
- insulating plates can also be used to glue insulating plates and to protect these plates, which can be made of cellular or expanded materials, for example cellular glass or expanded polystyrene.
- a composition in accordance with the invention is for example the following (% by weight): Liquid component
- algicidal germicidal compound 1% - Chlorinated paraffin emulsified with an oxyethylenated alkylphenol and an aliphatic polyether (anti-fire product): 1% - Water: q. s. p.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/FR1983/000135 WO1985000360A1 (fr) | 1983-07-05 | 1983-07-05 | Composition durcissable a deux constitutants, et application de cette composition comme revetement isophonique et isothermique |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0151106A1 true EP0151106A1 (de) | 1985-08-14 |
Family
ID=9284723
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19830902104 Withdrawn EP0151106A1 (de) | 1983-07-05 | 1983-07-05 | Zwei komponenten abbindende zusammensetzung und anwendung dieser zusammensetzung für isophone und isotherme überzüge |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP0151106A1 (de) |
WO (1) | WO1985000360A1 (de) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2582297A1 (fr) * | 1985-05-24 | 1986-11-28 | Pris K | Composition durcissable a deux constituants et application de cette composition comme revetement isophonique et isothermique |
US7297743B2 (en) * | 2001-04-19 | 2007-11-20 | Kaneka Corporation | Curable composition |
ES2280142B1 (es) * | 2006-02-28 | 2008-06-16 | Juan Alsina Vilamala | Pintura semi-mineral compuesta por tres aglutinantes o formadores de la pelicula. |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1402192A (fr) * | 1964-06-08 | 1965-06-11 | American Cyanamid Co | Procédé de chevillage des roches |
US3869415A (en) * | 1968-04-04 | 1975-03-04 | Temec Limited | Resinous polymer containing waterproofing plaster compositions |
DE2223188A1 (de) * | 1971-05-13 | 1972-11-23 | Gunac Ltd | Gipsmasse,Verfahren zu deren Herstellung und deren Verwendung |
DE2409116A1 (de) * | 1973-02-27 | 1974-10-10 | Friedrich Ruesch | Putzmasse fuer einen isolierenden, elastischen einschichtenputz, insbesondere einschichtenaussenwandputz |
FR2442808A1 (fr) * | 1979-02-09 | 1980-06-27 | Verre Tech | Nouveau revetement isophonique et isothermique a deux composants |
FR2520350B1 (fr) * | 1982-01-25 | 1986-02-14 | Kleinfelden Jean | Composition durcissable a deux constituants, et application de cette composition comme revetement isophonique et isothermique |
-
1983
- 1983-07-05 WO PCT/FR1983/000135 patent/WO1985000360A1/fr unknown
- 1983-07-05 EP EP19830902104 patent/EP0151106A1/de not_active Withdrawn
Non-Patent Citations (1)
Title |
---|
See references of WO8500360A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO1985000360A1 (fr) | 1985-01-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Designated state(s): AT BE CH DE FR GB LI LU NL SE Kind code of ref document: A1 Designated state(s): AT BE CH DE FR GB LI LU NL SE |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 19850611 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: KLEINFELDEN, JEAN |