EP0000918A3 - Process and apparatus for the preparation of linear, high molecular polyesters - Google Patents

Process and apparatus for the preparation of linear, high molecular polyesters Download PDF

Info

Publication number: EP0000918A3
Authority: EP; European Patent Office
Prior art keywords: linear; preparation; high molecular; molecular polyesters; polyesters
Prior art date: 1977-08-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP78100670A

Other versions

EP0000918A2 (en

EP0000918B1 (en

Inventor

Hans-Josef Dr. Sterzel

Kasimir Von Dziembowski

Hans Dr. Pirzer

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-08-24

Filing date

1978-08-16

Publication date

1979-04-04

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25772598&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0000918(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1977-08-24 Priority claimed from DE19772738093 external-priority patent/DE2738093B1/en

1978-01-27 Priority claimed from DE19782803530 external-priority patent/DE2803530A1/en

1978-08-16 Application filed by BASF SE filed Critical BASF SE

1979-03-07 Publication of EP0000918A2 publication Critical patent/EP0000918A2/en

1979-04-04 Publication of EP0000918A3 publication Critical patent/EP0000918A3/en

1982-03-17 Application granted granted Critical

1982-03-17 Publication of EP0000918B1 publication Critical patent/EP0000918B1/en

Status Expired legal-status Critical Current

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/785—Preparation processes characterised by the apparatus used
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00081—Tubes
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/0013—Controlling the temperature by direct heating or cooling by condensation of reactants
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00168—Controlling or regulating processes controlling the viscosity

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Polyesters Or Polycarbonates (AREA)

EP78100670A 1977-08-24 1978-08-16 Process for the preparation of linear, high molecular polyesters Expired EP0000918B1 (en)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
DE19772738093 DE2738093B1 (en)	1977-08-24	1977-08-24	Process and device for the production of linear high molecular weight polyesters
DE2738093		1977-08-24
DE19782803530 DE2803530A1 (en)	1978-01-27	1978-01-27	Linear high mol. wt. polyester prepn. - by precondensate after-condensn. under reduced pressure while progressively decreasing process temp. opt. continuously
DE2803530		1978-01-27

Publications (3)

Publication Number	Publication Date
EP0000918A2 EP0000918A2 (en)	1979-03-07
EP0000918A3 true EP0000918A3 (en)	1979-04-04
EP0000918B1 EP0000918B1 (en)	1982-03-17

Family

ID=25772598

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP78100670A Expired EP0000918B1 (en)	1977-08-24	1978-08-16	Process for the preparation of linear, high molecular polyesters

Country Status (5)

Country	Link
US (2)	US4214072A (en)
EP (1)	EP0000918B1 (en)
JP (1)	JPS5443997A (en)
DE (1)	DE2861668D1 (en)
IT (1)	IT1097584B (en)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3820362A1 (en) *	1988-06-15	1990-03-15	Basf Ag	METHOD FOR THE CONTINUOUS PRODUCTION OF LINEAR THERMOPLASTIC POLYESTERS
US5238740A (en) *	1990-05-11	1993-08-24	Hoechst Celanese Corporation	Drawn polyester yarn having a high tenacity and high modulus and a low shrinkage
US5869011A (en) *	1994-02-01	1999-02-09	Lee; Jing Ming	Fixed-bed catalytic reactor
US5520891A (en) *	1994-02-01	1996-05-28	Lee; Jing M.	Cross-flow, fixed-bed catalytic reactor
JP3001181B2 (en) *	1994-07-11	2000-01-24	株式会社クボタ	Reaction tube for ethylene production
DE19509551A1 (en) *	1995-03-16	1996-09-19	Basf Ag	Process for the continuous production of thermoplastic polyesters
DE19615886C1 (en)	1996-04-22	1997-07-31	Huels Chemische Werke Ag	Increasing yield in crude di:methyl terephthalate prodn.
US6194609B1 (en) *	1997-06-30	2001-02-27	Bp Amoco Corporation	Crystallization in a plate heat exchanger
DE19929791A1 (en) *	1999-06-29	2001-02-01	Basf Ag	Process for the continuous production of polybutylene terephthalate from terephthalic acid and butanediol
FR2811789B1 (en) *	2000-07-13	2003-08-15	France Etat Ponts Chaussees	METHOD AND DEVICE FOR CLASSIFYING VEHICLES INTO SILHOUETTE CATEGORIES AND FOR DETERMINING THEIR SPEED, FROM THEIR ELECTROMAGNETIC SIGNATURE
US6906164B2 (en)	2000-12-07	2005-06-14	Eastman Chemical Company	Polyester process using a pipe reactor
ES2399881T3 (en)	2000-12-07	2013-04-04	Grupo Petrotemex, S.A. De C.V.	Procedure for the production of low cost polyesters using a tubular reactor
US7135541B2 (en)	2003-06-06	2006-11-14	Eastman Chemical Company	Polyester process using a pipe reactor
US7074879B2 (en)	2003-06-06	2006-07-11	Eastman Chemical Company	Polyester process using a pipe reactor
DE102004001914A1 (en)	2004-01-14	2005-08-04	Sms Eumuco Gmbh	Coupling device for a mechanical press, scissors or punching device
US7332548B2 (en)	2004-03-04	2008-02-19	Eastman Chemical Company	Process for production of a polyester product from alkylene oxide and carboxylic acid
DE102004019810A1 (en)	2004-04-23	2005-03-24	Zimmer Ag	Production of thermoplastic polyester for use e.g. in fibres, film or bottles, involves precondensation by passing an esterification product downwards under reduced pressure through a column with structured packing
US20060251547A1 (en) *	2005-05-05	2006-11-09	Windes Larry C	Family of stationary film generators and film support structures for vertical staged polymerization reactors
US7834208B2 (en)	2005-05-19	2010-11-16	Eastman Chemical Company	Process to produce a post catalyst removal composition
US20060264664A1 (en) *	2005-05-19	2006-11-23	Parker Kenny R	Esterification of an exchange solvent enriched composition
US7880031B2 (en) *	2005-05-19	2011-02-01	Eastman Chemical Company	Process to produce an enrichment feed
US7741516B2 (en) *	2005-05-19	2010-06-22	Eastman Chemical Company	Process to enrich a carboxylic acid composition
US7304178B2 (en) *	2005-05-19	2007-12-04	Eastman Chemical Company	Enriched isophthalic acid composition
US7432395B2 (en)	2005-05-19	2008-10-07	Eastman Chemical Company	Enriched carboxylic acid composition
US20060264662A1 (en) *	2005-05-19	2006-11-23	Gibson Philip E	Esterification of an enriched composition
US7919652B2 (en) *	2005-05-19	2011-04-05	Eastman Chemical Company	Process to produce an enriched composition through the use of a catalyst removal zone and an enrichment zone
US20060264656A1 (en) *	2005-05-19	2006-11-23	Fujitsu Limited	Enrichment process using compounds useful in a polyester process
US7557243B2 (en) *	2005-05-19	2009-07-07	Eastman Chemical Company	Enriched terephthalic acid composition
US7884231B2 (en) *	2005-05-19	2011-02-08	Eastman Chemical Company	Process to produce an enriched composition
US7897809B2 (en) *	2005-05-19	2011-03-01	Eastman Chemical Company	Process to produce an enrichment feed
US7888529B2 (en) *	2006-03-01	2011-02-15	Eastman Chemical Company	Process to produce a post catalyst removal composition
US7649109B2 (en)	2006-12-07	2010-01-19	Eastman Chemical Company	Polyester production system employing recirculation of hot alcohol to esterification zone
US7943094B2 (en)	2006-12-07	2011-05-17	Grupo Petrotemex, S.A. De C.V.	Polyester production system employing horizontally elongated esterification vessel
US7863477B2 (en)	2007-03-08	2011-01-04	Eastman Chemical Company	Polyester production system employing hot paste to esterification zone
US7847053B2 (en)	2007-07-12	2010-12-07	Eastman Chemical Company	Multi-level tubular reactor with oppositely extending segments
US7858730B2 (en)	2007-07-12	2010-12-28	Eastman Chemical Company	Multi-level tubular reactor with dual headers
US7872090B2 (en)	2007-07-12	2011-01-18	Eastman Chemical Company	Reactor system with optimized heating and phase separation
US7868130B2 (en)	2007-07-12	2011-01-11	Eastman Chemical Company	Multi-level tubular reactor with vertically spaced segments
US7842777B2 (en)	2007-07-12	2010-11-30	Eastman Chemical Company	Sloped tubular reactor with divided flow
US7868129B2 (en)	2007-07-12	2011-01-11	Eastman Chemical Company	Sloped tubular reactor with spaced sequential trays
US7829653B2 (en)	2007-07-12	2010-11-09	Eastman Chemical Company	Horizontal trayed reactor
US7872089B2 (en)	2007-07-12	2011-01-18	Eastman Chemical Company	Multi-level tubular reactor with internal tray
US10010812B2 (en)	2014-05-08	2018-07-03	Eastman Chemical Company	Furan-2,5-dicarboxylic acid purge process
US9504994B2 (en)	2014-05-08	2016-11-29	Eastman Chemical Company	Furan-2,5-dicarboxylic acid purge process
US9944615B2 (en)	2014-05-08	2018-04-17	Eastman Chemical Company	Purifying crude furan 2,5-dicarboxylic acid by hydrogenation and a purge zone
US20190023837A1 (en)	2017-07-20	2019-01-24	Eastman Chemical Company	Production of polyethylene furanoate in a retrofitted polyester plant
US10344011B1 (en)	2018-05-04	2019-07-09	Eastman Chemical Company	Furan-2,5-dicarboxylic acid purge process
US10526301B1 (en)	2018-10-18	2020-01-07	Eastman Chemical Company	Production of purified dialkyl-furan-2,5-dicarboxylate (DAFD) in a retrofitted DMT plant

Citations (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1545487A (en) *	1966-11-30	1968-11-08	Bemberg Spa	Continuous process for the production of polymethylene terephthalate with a high degree of polymerization, the product thus obtained and fibers made therefrom
DE1920954A1 (en) *	1968-04-24	1969-11-06	Asahi Chemical Ind	Process and apparatus for the production of polymers
DE1959455A1 (en) *	1968-11-26	1970-06-11	Rhodiaceta	Method and device for the production of polyesters
US3640962A (en) *	1968-05-08	1972-02-08	Hoechst Ag	Polyester polycondensation process under decreasing temperatures

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US401685A (en) *		1889-04-16		Ments
US1200996A (en) *	1912-10-14	1916-10-10	Techno Chemical Lab Ltd	Method of evaporation, &c.
US1327599A (en) *	1914-05-25	1920-01-06	Andrew M Hunt	Apparatus for cooling and scrubbing gases
DE517176C (en) *	1927-01-10	1931-01-31	Karl Fried Dr	Device for evaporating and thickening liquids
FR702279A (en) *	1929-12-10	1931-04-03		gas and smoke purifier
US2689839A (en) *	1951-08-22	1954-09-21	Du Pont	Dispersion of delusterants in polyamides
US2994724A (en) *	1958-08-14	1961-08-01	Exxon Research Engineering Co	Cyclodiene dimer vapor phase cracking method and furnace
NL130338C (en) *	1963-06-11	1900-01-01
GB1101348A (en) *	1964-06-16	1968-01-31	Ici Ltd	Improvements in sodium bicarbonate manufacture by the ammonia-soda process
US3499873A (en) *	1967-06-22	1970-03-10	Vickers Zimmer Ag	Preparation of polyethylene terephthalate by means of free falling films
NL6809754A (en) *	1968-04-11	1969-10-14
DE1920945C3 (en) *	1969-04-24	1973-11-08	Polysius Ag, 4723 Neubeckum	Device for cooling pourable material
DE2514116C3 (en) *	1975-03-29	1983-03-17	Basf Ag, 6700 Ludwigshafen	Process for the continuous production of linear, high molecular weight polybutylene terephthalates
DE2557580A1 (en) *	1975-12-20	1977-06-30	Dynamit Nobel Ag	PROCESS AND DEVICE FOR PRODUCING POLYCONDENSATE

1978
- 1978-07-31 IT IT26342/78A patent/IT1097584B/en active
- 1978-08-10 US US05/932,632 patent/US4214072A/en not_active Expired - Lifetime
- 1978-08-16 EP EP78100670A patent/EP0000918B1/en not_active Expired
- 1978-08-16 DE DE7878100670T patent/DE2861668D1/en not_active Expired
- 1978-08-22 JP JP10151178A patent/JPS5443997A/en active Pending
1979
- 1979-03-27 US US06/024,298 patent/US4235844A/en not_active Expired - Lifetime

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1545487A (en) *	1966-11-30	1968-11-08	Bemberg Spa	Continuous process for the production of polymethylene terephthalate with a high degree of polymerization, the product thus obtained and fibers made therefrom
DE1920954A1 (en) *	1968-04-24	1969-11-06	Asahi Chemical Ind	Process and apparatus for the production of polymers
US3640962A (en) *	1968-05-08	1972-02-08	Hoechst Ag	Polyester polycondensation process under decreasing temperatures
DE1959455A1 (en) *	1968-11-26	1970-06-11	Rhodiaceta	Method and device for the production of polyesters

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 73, no. 12, 21 sept 1970, Columbus, Ohio, (USA) FISYUK, L.T. GRAIZEL, L.A.: "Intensification of the poly condensation stage during the production of poly (ethylene terephtphalate), Seite 39, 1e Spalte, Zusammenfassung 57003q, KHIM. VOLOKNA 1970, (3) 70-1 *

Also Published As

Publication number	Publication date
EP0000918A2 (en)	1979-03-07
US4214072A (en)	1980-07-22
DE2861668D1 (en)	1982-04-15
US4235844A (en)	1980-11-25
IT7826342A0 (en)	1978-07-31
IT1097584B (en)	1985-08-31
JPS5443997A (en)	1979-04-06
EP0000918B1 (en)	1982-03-17

Publication	Publication Date	Title
EP0000918A3 (en)	1979-04-04	Process and apparatus for the preparation of linear, high molecular polyesters
JPS51130091A (en)	1976-11-12	Surgical method
JPS51144736A (en)	1976-12-13	Pharmacy and process for preparing same
DE2862403D1 (en)	1984-06-20	Process for the preparation of poly(phenylene-oxy-phenylene-sulfone)
JPS5250396A (en)	1977-04-22	High molecular weight polyamine and process for producing same
JPS53116284A (en)	1978-10-11	Osmosis apparatus and manufacture thereof
AU507508B2 (en)	1980-02-14	Sterilization process
DE3071484D1 (en)	1986-04-17	Linear polychlorophosphazenes, process for their preparation and their use
GB2022008B (en)	1982-06-09	Process and apparatus for the manufacture of projecting surfacung with high barrier properties
IL54497A0 (en)	1978-07-31	L-sucrose and process for producing the same
ZA783511B (en)	1979-06-27	Sulfamoyl-aryl-ketones and process for the preparation thereof
GB2014343A (en)	1979-08-22	Procedure and apparatus for repetitive or series production
JPS5238000A (en)	1977-03-24	Aromatic polymer and process for producing same
IL55174A0 (en)	1978-09-29	Novel 7a-methoxycephalosporins and process for producing the same
ZA761538B (en)	1977-03-30	13,14-dehydro-11deoxy-prostaglandins and process for their preparation
GR61407B (en)	1978-11-11	Antibiotics and process for the preparation thereof
JPS52133347A (en)	1977-11-08	High molecular products
CA1028974A (en)	1978-04-04	Formcoke process and apparatus
JPS5243895A (en)	1977-04-06	Pasteeextrudable tetrafluoroethylene polymer and process for producing same
ZA782629B (en)	1979-04-25	Benzenesulfonylureas and process for their manufacture
EG12421A (en)	1981-03-31	Method for the cyclization of gamma-delta-delta,or delta-epsilon-usaturated alcohols and products obtained thereby
GB2011395B (en)	1982-03-03	1,8 naphthyridine compounds and process for preparing the same
ZA786075B (en)	1979-10-31	13,14-didehydro-protaglandins and process for their preparation
IL49761A0 (en)	1976-08-31	16,16-dimethyl-prostaglandins and process for their preparation
ZA784154B (en)	1979-07-25	Novel 7a-methoxycephalosporins and process for producing the same

Legal Events

Date	Code	Title	Description
1979-01-11	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
1979-01-25	PUAL	Search report despatched	Free format text: ORIGINAL CODE: 0009013
1979-03-07	AK	Designated contracting states	Designated state(s): BE CH DE FR GB NL
1979-04-04	AK	Designated contracting states	Designated state(s): BE CH DE FR GB NL
1979-07-11	17P	Request for examination filed
1982-01-15	GRAA	(expected) grant	Free format text: ORIGINAL CODE: 0009210
1982-03-17	AK	Designated contracting states	Designated state(s): BE CH DE FR GB NL
1982-04-15	REF	Corresponds to:	Ref document number: 2861668 Country of ref document: DE Date of ref document: 19820415
1982-11-12	PLBI	Opposition filed	Free format text: ORIGINAL CODE: 0009260
1982-11-15	KL	Correction list	Free format text: 82/06
1982-12-16	NLR4	Nl: receipt of corrected translation in the netherlands language at the initiative of the proprietor of the patent
1983-01-12	26	Opposition filed	Opponent name: ENKA AG Effective date: 19821106
1984-07-19	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: DE Payment date: 19840719 Year of fee payment: 7
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1987-10-29	RDAG	Patent revoked	Free format text: ORIGINAL CODE: 0009271
1987-10-29	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: PATENT REVOKED
1987-12-02	GBPR	Gb: patent revoked under art. 102 of the ep convention designating the uk as contracting state
1987-12-16	27W	Patent revoked	Effective date: 19871016
1988-01-15	REG	Reference to a national code	Ref country code: CH Ref legal event code: PL
1988-01-18	NLR2	Nl: decision of opposition
1989-02-28	BERE	Be: lapsed	Owner name: BASF A.G. Effective date: 19880831
1996-12-05	APAC	Appeal dossier modified	Free format text: ORIGINAL CODE: EPIDOS NOAPO
1996-12-09	APAC	Appeal dossier modified	Free format text: ORIGINAL CODE: EPIDOS NOAPO