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EA201391665A1 - Способ получения фосфорной кислоты дигидратного/полугидратного типа - Google Patents

Способ получения фосфорной кислоты дигидратного/полугидратного типа

Info

Publication number
EA201391665A1
EA201391665A1 EA201391665A EA201391665A EA201391665A1 EA 201391665 A1 EA201391665 A1 EA 201391665A1 EA 201391665 A EA201391665 A EA 201391665A EA 201391665 A EA201391665 A EA 201391665A EA 201391665 A1 EA201391665 A1 EA 201391665A1
Authority
EA
Eurasian Patent Office
Prior art keywords
phosphoric acid
suspension
dihydrate
semi
producing phosphoric
Prior art date
Application number
EA201391665A
Other languages
English (en)
Other versions
EA025514B1 (ru
Inventor
Антуан Окса
Дорина ФАТИ
Original Assignee
Прэйон Текнолоджис
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Прэйон Текнолоджис filed Critical Прэйон Текнолоджис
Publication of EA201391665A1 publication Critical patent/EA201391665A1/ru
Publication of EA025514B1 publication Critical patent/EA025514B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/18—Phosphoric acid
    • C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
    • C01B25/222—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/18—Phosphoric acid
    • C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
    • C01B25/222—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen
    • C01B25/228—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen one form of calcium sulfate being formed and then converted to another form
    • C01B25/231—Dihydrate-hemihydrate process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/18—Phosphoric acid
    • C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
    • C01B25/222—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen
    • C01B25/228—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen one form of calcium sulfate being formed and then converted to another form

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

Описан способ получения фосфорной кислоты, включающий обработку в водной среде фосфатной породы серной кислотой с образованием первой суспензии дигидрата, суспендированной в водной фазе, имеющей содержание свободного РОот 38 до 50% и содержание свободного SOменее чем 0,5%, превращение этой первой суспензии путем нагревания с перекристаллизацией растворенного сульфата кальция, что вызывает образование второй суспензии полугидрата и разделение второй суспензии на продукционную фосфорную кислоту и осадок полугидрата, отличающийся тем, что он включает во время обработки добавление источника фтора в первую суспензию в количестве от 1 до 5 мас.% F относительно РО, содержащегося в фосфатной породе.
EA201391665A 2011-06-01 2011-06-01 Способ получения фосфорной кислоты дигидратного/полугидратного типа EA025514B1 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2011/059128 WO2012163425A1 (fr) 2011-06-01 2011-06-01 Procede de production d'acide phosphorique du type dihydrate/hemihydrate

Publications (2)

Publication Number Publication Date
EA201391665A1 true EA201391665A1 (ru) 2014-04-30
EA025514B1 EA025514B1 (ru) 2016-12-30

Family

ID=44626803

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201391665A EA025514B1 (ru) 2011-06-01 2011-06-01 Способ получения фосфорной кислоты дигидратного/полугидратного типа

Country Status (19)

Country Link
US (1) US9371230B2 (ru)
EP (1) EP2714589B1 (ru)
JP (1) JP5798241B2 (ru)
KR (1) KR101770814B1 (ru)
AR (1) AR086618A1 (ru)
BR (1) BR112013030374B1 (ru)
CA (1) CA2837495C (ru)
EA (1) EA025514B1 (ru)
ES (1) ES2562034T3 (ru)
IL (1) IL229664A (ru)
JO (1) JO3208B1 (ru)
MA (1) MA35179B1 (ru)
MX (1) MX339999B (ru)
PH (1) PH12013502477A1 (ru)
PL (1) PL2714589T3 (ru)
TN (1) TN2013000497A1 (ru)
TW (1) TWI529122B (ru)
WO (1) WO2012163425A1 (ru)
ZA (1) ZA201309397B (ru)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105776303A (zh) * 2016-01-30 2016-07-20 瓮福（集团）有限责任公司 一种α型半水石膏的生产方法
BE1023754B1 (fr) * 2016-06-23 2017-07-12 Prayon Technologies Procede de production de sulfate de calcium
WO2019030403A1 (fr) 2017-08-11 2019-02-14 Prayon Technologies Procede d'attaque acide d'une source phosphatee
CN113443614A (zh) * 2021-07-14 2021-09-28 东华工程科技股份有限公司 一种二水-半水湿法浸提磷酸工艺中二水硫酸钙转化α-半水硫酸钙的方法
IL313842A (en) 2021-12-27 2024-08-01 Prayon A method for purifying at least one aqueous solution of phosphoric acid

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA915883A (en) * 1972-12-05 Pavonet Engelhard Method for manufacturing phosphoric acid and hemihydrate calcium sulphate by the wet process
LU49007A1 (ru) 1965-07-07 1967-01-09
US3523754A (en) * 1966-04-02 1970-08-11 Central Glass Co Ltd Process for preparing phosphoric acil
DE1592287A1 (de) * 1966-08-19 1971-04-15 Piesteritz Stickstoff Verfahren zur Herstellung von Phosphorsaeure
US3984525A (en) 1967-02-01 1976-10-05 Albright & Wilson Limited Manufacture of phosphoric acid
JPS5230959B2 (ru) * 1972-11-25 1977-08-11
GB1520273A (en) * 1974-07-06 1978-08-02 Fisons Ltd Phosphoric acid and gypsum from phosphatic material
JPS5891021A (ja) * 1981-11-27 1983-05-30 Toyo Soda Mfg Co Ltd 湿式リン酸の製造方法
LU84713A1 (fr) 1983-03-25 1984-11-14 Prayon Soc Procede et preparation d'acide phosphorique et de sulfate de calcium hemihydrate alpha
DE3583209D1 (de) * 1984-11-05 1991-07-18 Prayon Dev Sa Kontinuierliches verfahren zur herstellung von phosphorsaeure und von calciumsulfat.
US5093088A (en) * 1987-07-28 1992-03-03 Potash Corporation Of Saskatchewan Apparatus for producing phosphoric acid from phosphate ore
JP2000264612A (ja) * 1999-03-16 2000-09-26 Asahi Chem Ind Co Ltd 湿式燐酸の製造方法
CN1340457A (zh) 2000-09-01 2002-03-20 山东鲁北企业集团总公司 一种磷酸生产工艺
JP4036426B2 (ja) * 2001-08-23 2008-01-23 下関三井化学株式会社 ろ過性の優れた石膏の製造方法
BE1016065A3 (fr) 2004-06-01 2006-02-07 Prayon Technologies Procede de production d'acide phosphorique.
BE1019055A3 (fr) * 2009-12-02 2012-02-07 Prayon Technologies Procede de production d'acide phosphorique.

Also Published As

Publication number Publication date
AR086618A1 (es) 2014-01-08
EA025514B1 (ru) 2016-12-30
JP2014516908A (ja) 2014-07-17
JP5798241B2 (ja) 2015-10-21
ZA201309397B (en) 2015-04-29
KR101770814B1 (ko) 2017-08-23
IL229664A (en) 2016-06-30
BR112013030374B1 (pt) 2019-12-31
BR112013030374A2 (pt) 2016-12-13
JO3208B1 (ar) 2018-03-08
WO2012163425A1 (fr) 2012-12-06
CA2837495A1 (en) 2012-12-06
TW201305045A (zh) 2013-02-01
EP2714589B1 (fr) 2015-12-16
MX339999B (es) 2016-06-20
PH12013502477A1 (en) 2022-10-26
TN2013000497A1 (fr) 2015-03-30
IL229664A0 (en) 2014-01-30
US20140120020A1 (en) 2014-05-01
MX2013013956A (es) 2014-01-23
US9371230B2 (en) 2016-06-21
PL2714589T3 (pl) 2016-05-31
EP2714589A1 (fr) 2014-04-09
TWI529122B (zh) 2016-04-11
MA35179B1 (fr) 2014-06-02
ES2562034T3 (es) 2016-03-02
CA2837495C (en) 2018-01-09
KR20140035400A (ko) 2014-03-21

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Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ KG MD TJ

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): BY KZ TM RU