EA200600868A1 - Гидрогенолиз сахарного сырья - Google Patents
Гидрогенолиз сахарного сырьяInfo
- Publication number
- EA200600868A1 EA200600868A1 EA200600868A EA200600868A EA200600868A1 EA 200600868 A1 EA200600868 A1 EA 200600868A1 EA 200600868 A EA200600868 A EA 200600868A EA 200600868 A EA200600868 A EA 200600868A EA 200600868 A1 EA200600868 A1 EA 200600868A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- hydrogenolysis
- raw materials
- sugar raw
- sugar
- osmium
- Prior art date
Links
- 238000007327 hydrogenolysis reaction Methods 0.000 title abstract 3
- 239000002994 raw material Substances 0.000 title abstract 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Removal Of Specific Substances (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
Способ гидрогенолиза сахарного сырья в присутствии катализатора, содержащего: (а) рутений или осмий; и (b) органический фосфин; и где гидрогенолиз проводят в присутствии воды и при температуре выше чем 150°С.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0325386.1A GB0325386D0 (en) | 2003-10-30 | 2003-10-30 | Process |
PCT/GB2004/004391 WO2005051874A1 (en) | 2003-10-30 | 2004-10-15 | Hydrogenolysis of sugar feedstock |
Publications (2)
Publication Number | Publication Date |
---|---|
EA200600868A1 true EA200600868A1 (ru) | 2006-08-25 |
EA009667B1 EA009667B1 (ru) | 2008-02-28 |
Family
ID=29725670
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA200600868A EA009667B1 (ru) | 2003-10-30 | 2004-10-15 | Гидрогенолиз сахарного сырья |
Country Status (14)
Country | Link |
---|---|
US (2) | US20070123739A1 (ru) |
EP (1) | EP1678107A1 (ru) |
CN (1) | CN100445249C (ru) |
AR (1) | AR060683A1 (ru) |
AU (1) | AU2004293237A1 (ru) |
BR (1) | BRPI0415550A (ru) |
CA (1) | CA2543281A1 (ru) |
EA (1) | EA009667B1 (ru) |
GB (1) | GB0325386D0 (ru) |
MX (1) | MXPA06004042A (ru) |
MY (1) | MY156341A (ru) |
NZ (1) | NZ545500A (ru) |
WO (1) | WO2005051874A1 (ru) |
ZA (1) | ZA200601812B (ru) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MY148259A (en) * | 2005-12-21 | 2013-03-29 | Virent Inc | Catalysts and methods for reforming oxygenated compounds |
EP2016037B1 (en) | 2006-05-08 | 2015-10-28 | Virent, Inc. | Methods and systems for generating polyols |
CN100381412C (zh) * | 2006-09-14 | 2008-04-16 | 山东西王糖业有限公司 | 一种生产乙二醇的新工艺 |
AR063358A1 (es) | 2006-10-23 | 2009-01-21 | Archer Daniels Midland Co | Mejora de la selectividad en la hidrogenolisis de glicerol |
US20080103340A1 (en) * | 2006-10-27 | 2008-05-01 | Archer-Daniels-Midland Company | Applications of biobased glycol compositions |
CA2650302C (en) | 2006-10-27 | 2013-04-09 | Archer-Daniels-Midland Company | Processes for isolating or purifying propylene glycol, ethylene glycol and products produced therefrom |
CN101568377A (zh) | 2006-12-20 | 2009-10-28 | 维仁特能源系统公司 | 用于生产气态产物的反应器系统 |
ES2817876T3 (es) | 2007-03-08 | 2021-04-08 | Virent Inc | Síntesis de combustibles líquidos a partir de hidrocarburos oxigenados |
EP2061860B1 (en) * | 2007-03-08 | 2013-12-18 | Virent, Inc. | Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons |
JP5517937B2 (ja) | 2007-08-29 | 2014-06-11 | ビーエーエスエフ ソシエタス・ヨーロピア | 糖アルコールからのアミンの製造方法 |
US7615671B2 (en) | 2007-11-30 | 2009-11-10 | Eastman Chemical Company | Hydrogenation process for the preparation of 1,2-diols |
AR072446A1 (es) * | 2008-03-02 | 2010-09-01 | Dow Global Technologies Inc | Proceso de hidrogenacion mejorado |
US20090246430A1 (en) | 2008-03-28 | 2009-10-01 | The Coca-Cola Company | Bio-based polyethylene terephthalate polymer and method of making same |
WO2010025241A2 (en) * | 2008-08-27 | 2010-03-04 | Virent Energy Systems, Inc. | Synthesis of liquid fuels from biomass |
JP5784510B2 (ja) | 2009-03-03 | 2015-09-24 | ザ コカ・コーラ カンパニーThe Coca‐Cola Company | バイオベースポリエチレンテレフタレートパッケージング及びその製造方法 |
WO2010119351A1 (en) | 2009-04-16 | 2010-10-21 | Chemtex Italia S.R.L. | Method for hydrogenolysis of sugar alcohols |
MX2011013988A (es) * | 2009-06-30 | 2012-09-07 | Virent Inc | Proceso y sistemas de reactores para convertir azucares y alcoholes sacarosos. |
US8829248B2 (en) | 2010-08-18 | 2014-09-09 | Eastman Chemical Company | Method for recovery and recycle of ruthenium homogeneous catalysts |
US8466328B2 (en) | 2010-08-18 | 2013-06-18 | Eastman Chemical Company | Method for recovery and recycle of ruthenium homogeneous catalysts |
US9227896B2 (en) | 2010-08-18 | 2016-01-05 | Eastman Chemical Company | Process for the separation and purification of a mixed diol stream |
US8709376B2 (en) | 2010-09-23 | 2014-04-29 | Eastman Chemical Company | Process for recovering and recycling an acid catalyst |
US8785686B2 (en) | 2010-09-23 | 2014-07-22 | Eastman Chemical Company | Process for recovering and recycling an acid catalyst |
WO2013148493A1 (en) | 2012-03-27 | 2013-10-03 | Eastman Chemical Company | Process for the separation and purification of a mixed diol stream |
US8765999B2 (en) | 2012-03-27 | 2014-07-01 | Eastman Chemical Company | Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst |
US8829234B2 (en) | 2012-03-27 | 2014-09-09 | Eastman Chemical Company | Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and heterogeneous catalyst |
US8927766B2 (en) | 2012-03-27 | 2015-01-06 | Eastman Chemical Company | Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst |
US8703999B2 (en) | 2012-03-27 | 2014-04-22 | Eastman Chemical Company | Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst |
US9040748B2 (en) | 2012-06-08 | 2015-05-26 | Eastman Chemical Company | Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration |
CN104370692B (zh) * | 2013-08-13 | 2017-02-15 | 北京化工大学 | 一种葡萄糖氢解制备多元醇的方法 |
EP3039001B1 (en) * | 2013-08-26 | 2018-07-25 | Shell International Research Maatschappij B.V. | Process for the preparation of glycols |
CA2939184A1 (en) * | 2014-02-24 | 2015-08-27 | Biochemtex S.P.A. | Integrated process for producing cellulosic pulp and polyols stream |
CN106061930A (zh) * | 2014-02-25 | 2016-10-26 | 拜奥开姆泰克股份公司 | 用于制备乙二醇流的连续方法 |
KR102107274B1 (ko) * | 2014-04-10 | 2020-05-06 | 아처 다니엘 미드랜드 캄파니 | 산 촉매의 혼합 조합을 이용한 당 알코올의 탈수 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3011002A (en) * | 1958-03-06 | 1961-11-28 | Inventa Ag | Process for the manufacture of glycols, glycerol and hexitol from dilute sugar solution |
US3454644A (en) * | 1966-05-09 | 1969-07-08 | Shell Oil Co | Homogeneous hydrogenation process employing a complex of ruthenium or osmium as catalyst |
US3935284A (en) * | 1973-10-19 | 1976-01-27 | Ici United States Inc. | Homogeneous hydrogenation of saccharides using ruthenium triphenyl phosphine complex |
US4366332A (en) * | 1981-01-21 | 1982-12-28 | Hydrocarbon Research, Inc. | Catalytic hydrogenolysis of alditols to product glycerol and polyols |
US4380678A (en) * | 1981-01-21 | 1983-04-19 | Hydrocarbon Research, Inc. | Multi-stage aldoses to polyols process |
US4401823A (en) * | 1981-05-18 | 1983-08-30 | Uop Inc. | Hydrogenolysis of polyhydroxylated compounds |
US4404411A (en) * | 1982-02-01 | 1983-09-13 | E. I. Du Pont De Nemours And Company | Hydrogenolysis of polyols to ethylene glycol in nonaqueous solvents |
US4476331A (en) * | 1982-02-11 | 1984-10-09 | Ethyl Corporation | Two stage hydrogenolysis of carbohydrate to glycols using sulfide modified ruthenium catalyst in second stage |
US4496780A (en) * | 1983-06-22 | 1985-01-29 | Uop Inc. | Hydrocracking of polyols |
US4642394A (en) * | 1985-07-16 | 1987-02-10 | Celanese Corporation | Production of propanediols |
GB8720491D0 (en) * | 1987-08-29 | 1987-10-07 | Bp Chem Int Ltd | Synthesis of glycerol |
DE3818198A1 (de) * | 1988-05-28 | 1989-12-21 | Basf Ag | Verfahren zur herstellung niederer mehrwertiger alkohole |
DE3928285A1 (de) * | 1989-08-26 | 1991-02-28 | Basf Ag | Verfahren zur herstellung niederer, mehrwertiger alkohole |
US5026927A (en) * | 1989-11-16 | 1991-06-25 | The United States Of America As Represented By The United States Department Of Energy | Hydrocracking of carbohydrates making glycerol, glycols and other polyols |
DE4023255A1 (de) * | 1990-07-21 | 1992-01-23 | Basf Ag | Verfahren zur herstellung von glykolen, insbesondere propylenglykol aus formaldehyd |
IT1256802B (it) * | 1992-01-31 | 1995-12-15 | Novamont Spa | Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'drogenazione e/o idrogenolisi di carboidrati e polioli. |
IT1256801B (it) * | 1992-01-31 | 1995-12-15 | Novamont Spa | Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'idrogenazione e/o idrogenolisi di carboidrati e polioli. |
IT1256800B (it) * | 1992-01-31 | 1995-12-15 | Novamont Spa | Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento. |
TW476746B (en) * | 1997-07-23 | 2002-02-21 | Shell Int Research | Hydrogenolysis of glycerol |
US6291725B1 (en) * | 2000-03-03 | 2001-09-18 | Board Of Trustees Operating Michigan State University | Catalysts and process for hydrogenolysis of sugar alcohols to polyols |
US6479713B1 (en) * | 2001-10-23 | 2002-11-12 | Battelle Memorial Institute | Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen |
-
2003
- 2003-10-30 GB GBGB0325386.1A patent/GB0325386D0/en not_active Ceased
-
2004
- 2004-10-15 CA CA002543281A patent/CA2543281A1/en not_active Abandoned
- 2004-10-15 CN CNB2004800262282A patent/CN100445249C/zh not_active Expired - Fee Related
- 2004-10-15 EP EP04768921A patent/EP1678107A1/en not_active Withdrawn
- 2004-10-15 MX MXPA06004042A patent/MXPA06004042A/es unknown
- 2004-10-15 NZ NZ545500A patent/NZ545500A/en unknown
- 2004-10-15 WO PCT/GB2004/004391 patent/WO2005051874A1/en active Application Filing
- 2004-10-15 EA EA200600868A patent/EA009667B1/ru not_active IP Right Cessation
- 2004-10-15 AU AU2004293237A patent/AU2004293237A1/en not_active Abandoned
- 2004-10-15 US US10/576,487 patent/US20070123739A1/en not_active Abandoned
- 2004-10-15 BR BRPI0415550-5A patent/BRPI0415550A/pt not_active IP Right Cessation
- 2004-10-15 ZA ZA200601812A patent/ZA200601812B/en unknown
- 2004-10-25 MY MYPI20044395A patent/MY156341A/en unknown
- 2004-10-29 AR ARP040103966A patent/AR060683A1/es not_active Application Discontinuation
-
2009
- 2009-08-18 US US12/543,034 patent/US20090306365A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
MY156341A (en) | 2016-02-15 |
AU2004293237A1 (en) | 2005-06-09 |
EP1678107A1 (en) | 2006-07-12 |
GB0325386D0 (en) | 2003-12-03 |
US20090306365A1 (en) | 2009-12-10 |
EA009667B1 (ru) | 2008-02-28 |
CN1849284A (zh) | 2006-10-18 |
WO2005051874A1 (en) | 2005-06-09 |
MXPA06004042A (es) | 2006-06-28 |
CN100445249C (zh) | 2008-12-24 |
AR060683A1 (es) | 2008-07-10 |
CA2543281A1 (en) | 2005-06-09 |
NZ545500A (en) | 2009-11-27 |
US20070123739A1 (en) | 2007-05-31 |
BRPI0415550A (pt) | 2006-12-26 |
ZA200601812B (en) | 2007-07-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG MD TJ TM |
|
MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): RU |