EA199800950A1 - METHODS OF OBTAINING HYDROXYALDEHYDES - Google Patents
METHODS OF OBTAINING HYDROXYALDEHYDESInfo
- Publication number
- EA199800950A1 EA199800950A1 EA199800950A EA199800950A EA199800950A1 EA 199800950 A1 EA199800950 A1 EA 199800950A1 EA 199800950 A EA199800950 A EA 199800950A EA 199800950 A EA199800950 A EA 199800950A EA 199800950 A1 EA199800950 A1 EA 199800950A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- substituted
- reaction
- hydroxyaldehydes
- hydroformylation
- unsubstituted
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 5
- 238000007037 hydroformylation reaction Methods 0.000 abstract 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 230000002829 reductive effect Effects 0.000 abstract 2
- FPFTWHJPEMPAGE-UHFFFAOYSA-N 6-hydroxy caproaldehyde Chemical class OCCCCCC=O FPFTWHJPEMPAGE-UHFFFAOYSA-N 0.000 abstract 1
- 101100345589 Mus musculus Mical1 gene Proteins 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Изобретение относится к способам получения одно- или более замещенных или незамещенных гидроксиальдегидов, например 6-гидроксигексаналей, который включает введение одно- или более замещенных или незамещенных алкадиенов, например бутадиена, в реакцию восстановительного гидроформилирования в присутствии катализатора восстановительного гидроформилирования, например комплекса металла с фосфорорганическим лигандом, и реакцию гидроформилирования в присутствии катализатора гидроформилирования, например комплекса металла с фосфорорганическим лигандом, для получения одно- или более замещенных или незамещенных гидроксиальдегидов. Замещенные и незамещенные гидроксиальдегиды, получаемые заявленным способом, подвергают дополнительной реакции (реакциям) для получения их желаемых производных, например эпсилонкапролактона. Это изобретение также частично относится к реакционным смесям, включающим одно- или более замещенные или незамещенные гидроксиальдегиды в качестве основного продукта (продуктов) реакции.Международная заявка была опубликована вместе с отчетом о международном поиске.The invention relates to methods for producing one or more substituted or unsubstituted hydroxyaldehydes, for example 6-hydroxyhexanals, which involves the introduction of one or more substituted or unsubstituted alkadiens, for example butadiene, in the reaction of reductive hydroformylation in the presence of a catalyst for reductive hydroformylation, for example, a complex of an organophosphate ligand , and the reaction of hydroformylation in the presence of a catalyst of hydroformylation, for example, a complex of a metal with phosphorus nical ligand to produce one or more substituted or unsubstituted hydroxyaldehydes. The substituted and unsubstituted hydroxyaldehydes obtained by the claimed method undergo an additional reaction (reactions) to obtain their desired derivatives, for example, epsilon caprolactone. This invention also relates in part to reaction mixtures comprising one or more substituted or unsubstituted hydroxyaldehydes as the main product (s) of the reaction. The international application was published along with an international search report.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US84334096A | 1996-04-15 | 1996-04-15 | |
| US1626396A | 1996-04-24 | 1996-04-24 | |
| US1637896P | 1996-04-24 | 1996-04-24 | |
| US1617496A | 1996-04-24 | 1996-04-24 | |
| US1625996A | 1996-06-24 | 1996-06-24 | |
| PCT/US1997/006881 WO1997040001A1 (en) | 1996-04-24 | 1997-04-23 | Processes for producing hydroxyaldehydes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EA199800950A1 true EA199800950A1 (en) | 1999-04-29 |
Family
ID=58192432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA199800950A EA199800950A1 (en) | 1996-04-15 | 1997-04-23 | METHODS OF OBTAINING HYDROXYALDEHYDES |
Country Status (1)
| Country | Link |
|---|---|
| EA (1) | EA199800950A1 (en) |
-
1997
- 1997-04-23 EA EA199800950A patent/EA199800950A1/en unknown
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