EA023569B1 - Частицы перекрестно-связанного эпоксидного винилового эфира и способы их изготовления и использования - Google Patents
Частицы перекрестно-связанного эпоксидного винилового эфира и способы их изготовления и использования Download PDFInfo
- Publication number
- EA023569B1 EA023569B1 EA201300070A EA201300070A EA023569B1 EA 023569 B1 EA023569 B1 EA 023569B1 EA 201300070 A EA201300070 A EA 201300070A EA 201300070 A EA201300070 A EA 201300070A EA 023569 B1 EA023569 B1 EA 023569B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- particles
- vinyl ester
- epoxy vinyl
- aromatic epoxy
- ester polymer
- Prior art date
Links
- 239000002245 particle Substances 0.000 title claims abstract description 30
- 239000004593 Epoxy Substances 0.000 title claims abstract description 8
- 229920001567 vinyl ester resin Polymers 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 title claims abstract description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 9
- 125000003118 aryl group Chemical group 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims abstract description 7
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 5
- 239000012530 fluid Substances 0.000 claims abstract 5
- 239000007788 liquid Substances 0.000 claims description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 241000758789 Juglans Species 0.000 claims 2
- 235000009496 Juglans regia Nutrition 0.000 claims 2
- 229920005989 resin Polymers 0.000 claims 2
- 239000011347 resin Substances 0.000 claims 2
- 239000004576 sand Substances 0.000 claims 2
- 235000020234 walnut Nutrition 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
- 229910001570 bauxite Inorganic materials 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910010293 ceramic material Inorganic materials 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 229910001873 dinitrogen Inorganic materials 0.000 claims 1
- 229920006241 epoxy vinyl ester resin Polymers 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 239000011256 inorganic filler Substances 0.000 claims 1
- 229910003475 inorganic filler Inorganic materials 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 230000008520 organization Effects 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 239000012815 thermoplastic material Substances 0.000 claims 1
- -1 vinyl aromatic compounds Chemical class 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/80—Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/026—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight
- C08F299/028—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight photopolymerisable compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/25—Methods for stimulating production
- E21B43/26—Methods for stimulating production by forming crevices or fractures
- E21B43/267—Methods for stimulating production by forming crevices or fractures reinforcing fractures by propping
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
- C08J2363/02—Polyglycidyl ethers of bis-phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Fluid Mechanics (AREA)
- Environmental & Geological Engineering (AREA)
- Physics & Mathematics (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
В изобретении заявляется множество частиц перекрестно-связанного ароматического эпоксидного винилэфирного полимера, где частица из множества частиц набухает не более чем на 20% объема при погружении в толуол на 24 ч при температуре 70°С. Заявляется также множество частиц перекрестно-связанного ароматического эпоксидного винилэфирного полимера, где частица из множества частиц сохраняет как минимум 75% своей высоты под давлением 1,7×10Па при температуре как минимум 135°С. Заявляются также смеси множества частиц с другими частицами, жидкости, содержащие множество частиц, способы изготовления множества частиц и способы разрыва подземной геологической формации.
Description
(57) В изобретении заявляется множество частиц перекрестно-связанного ароматического эпоксидного винилэфирного полимера, где частица из множества частиц набухает не более чем на 20% объема при погружении в толуол на 24 ч при температуре 70°С. Заявляется также множество частиц перекрестно-связанного ароматического эпоксидного винилэфирного полимера, где частица из множества частиц сохраняет как минимум 75% своей высоты под давлением 1,7><107 Па при температуре как минимум 135°С. Заявляются также смеси множества частиц с другими частицами, жидкости, содержащие множество частиц, способы изготовления множества частиц и способы разрыва подземной геологической формации.
Ссылка на связанную заявку
Claims (6)
1. Множество частиц, содержащих перекрестно-связанный ароматический эпоксидный винилэфирный полимер, в основном свободный от неорганического наполнителя, где частица из множества частиц набухает не более чем на 20% объема при погружении в толуол на 24 ч при температуре 70°С.
2. Множество частиц перекрестно-связанного ароматического эпоксидного винилэфирного полимера, где частица из множества частиц сохраняет как минимум 75% своей высоты под давлением 1,7х107 Па при температуре как минимум 135°С.
3. Множество частиц по любому из пп.1 или 2, отличающееся тем, что перекрестно-связанный ароматический эпоксидный винилэфирный полимер представляет собой сополимер ароматической эпоксидной винилэфирной смолы и как минимум одного из виниловых ароматических компаундов или монофункционального акрилата или метакрилата.
4. Жидкость для переноса крепежного материала, содержащая множество диспергированных в ней частиц в соответствии с одним из пп.1 или 2, где жидкость включает в себя как минимум один из следующих элементов: вода, насыщенный минеральный раствор, спирт, двуокись углерода, газообразный азот или углеводород.
- 20 023569
5. Жидкость по п.4, отличающаяся тем, что содержит другие частицы, содержащие по крайней мере один из следующих элементов: песок, песок с покрытием из смолы, калиброванная ореховая скорлупа, ореховая скорлупа с покрытием из смолы, спеченный боксит, дробленые керамические материалы, стеклянные гранулы и дробленые термопластичные материалы.
6. Способ разрыва подземной геологической формации, сквозь которую пробурена скважина, способ заключается в следующем:
закачивание в скважину, проходящую сквозь подземную геологическую формацию, разрывной жидкости под давлением, достаточным для разрыва этой формации; и ввод в разрыв жидкости в соответствии с п.4.
4^^ Евразийская патентная организация, ЕАПВ Россия, 109012, Москва, Малый Черкасский пер., 2
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36879210P | 2010-07-29 | 2010-07-29 | |
| PCT/US2011/045444 WO2012015857A2 (en) | 2010-07-29 | 2011-07-27 | Crosslinked epoxy vinyl ester particles and methods for making and using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201300070A1 EA201300070A1 (ru) | 2013-06-28 |
| EA023569B1 true EA023569B1 (ru) | 2016-06-30 |
Family
ID=45530679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201300070A EA023569B1 (ru) | 2010-07-29 | 2011-07-27 | Частицы перекрестно-связанного эпоксидного винилового эфира и способы их изготовления и использования |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20130126160A1 (ru) |
| EP (1) | EP2598558A4 (ru) |
| CN (1) | CN103025801B (ru) |
| BR (1) | BR112013002223A2 (ru) |
| CA (1) | CA2806692A1 (ru) |
| EA (1) | EA023569B1 (ru) |
| WO (1) | WO2012015857A2 (ru) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2598600A1 (en) | 2010-07-29 | 2013-06-05 | 3M Innovative Properties Company | Elastomer-modified crosslinked epoxy vinyl ester particles and methods for making and using the same |
| WO2014051918A1 (en) | 2012-09-25 | 2014-04-03 | 3M Innovative Properties Company | Rigid and contorted divinyl crosslinkers |
| CN111655651A (zh) * | 2017-12-29 | 2020-09-11 | 埃尼股份公司 | 用于控制石油井的渗透性的方法 |
| CN112574470B (zh) * | 2020-12-08 | 2021-11-19 | 中国科学院山西煤炭化学研究所 | 一种催化降解环氧乙烯基酯树脂的方法 |
| CN113355916B (zh) * | 2021-06-22 | 2022-09-06 | 江苏恒神股份有限公司 | 碳纤维集束剂、缠绕成型用碳纤维束及其制备方法和应用 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03134028A (ja) * | 1989-10-19 | 1991-06-07 | Daiso Co Ltd | 繊維強化樹脂積層体 |
| US6034155A (en) * | 1998-03-16 | 2000-03-07 | Ect Incorporated | Polymer concrete compositions, structures made therefrom and methods of manufacture |
| US20060078682A1 (en) * | 2004-09-20 | 2006-04-13 | Mcdaniel Robert R | Particles for use as proppants or in gravel packs, methods for making and using the same |
| US20060258546A1 (en) * | 2005-05-12 | 2006-11-16 | Bj Services Company | Structured composite compositions for treatment of subterranean wells |
| US20070021309A1 (en) * | 2005-06-13 | 2007-01-25 | Sun Drilling Products Corporation | Thermoset particles with enhanced crosslinking, processing for their production, and their use in oil and natural gas driliing applications |
| US7556853B2 (en) * | 2003-05-02 | 2009-07-07 | Astrium Sas | High toughness vinylester and/or epoxy resin-based material, its process of manufacture, composite material comprising it and uses thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4063603A (en) * | 1976-09-02 | 1977-12-20 | Rayborn Jerry J | Drilling fluid lubricant |
| CA2521007C (en) * | 2003-04-15 | 2009-08-11 | Hexion Specialty Chemicals, Inc. | Particulate material containing thermoplastic elastomer and methods for making and using same |
| JP5582524B2 (ja) * | 2006-07-14 | 2014-09-03 | ディーエスエム アイピー アセッツ ビー．ブイ． | 有機ナノ粒子の調製方法 |
| US9096790B2 (en) * | 2007-03-22 | 2015-08-04 | Hexion Inc. | Low temperature coated particles comprising a curable liquid and a reactive powder for use as proppants or in gravel packs, methods for making and using the same |
| US20090110529A1 (en) * | 2007-10-31 | 2009-04-30 | M-I Llc | Pneumatic transfer of finely ground clay material |
-
2011
- 2011-07-27 EA EA201300070A patent/EA023569B1/ru not_active IP Right Cessation
- 2011-07-27 WO PCT/US2011/045444 patent/WO2012015857A2/en active Application Filing
- 2011-07-27 US US13/812,984 patent/US20130126160A1/en not_active Abandoned
- 2011-07-27 CA CA2806692A patent/CA2806692A1/en not_active Abandoned
- 2011-07-27 BR BR112013002223A patent/BR112013002223A2/pt not_active IP Right Cessation
- 2011-07-27 EP EP11813070.7A patent/EP2598558A4/en not_active Withdrawn
- 2011-07-27 CN CN201180036584.2A patent/CN103025801B/zh not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03134028A (ja) * | 1989-10-19 | 1991-06-07 | Daiso Co Ltd | 繊維強化樹脂積層体 |
| US6034155A (en) * | 1998-03-16 | 2000-03-07 | Ect Incorporated | Polymer concrete compositions, structures made therefrom and methods of manufacture |
| US7556853B2 (en) * | 2003-05-02 | 2009-07-07 | Astrium Sas | High toughness vinylester and/or epoxy resin-based material, its process of manufacture, composite material comprising it and uses thereof |
| US20060078682A1 (en) * | 2004-09-20 | 2006-04-13 | Mcdaniel Robert R | Particles for use as proppants or in gravel packs, methods for making and using the same |
| US20060258546A1 (en) * | 2005-05-12 | 2006-11-16 | Bj Services Company | Structured composite compositions for treatment of subterranean wells |
| US20070021309A1 (en) * | 2005-06-13 | 2007-01-25 | Sun Drilling Products Corporation | Thermoset particles with enhanced crosslinking, processing for their production, and their use in oil and natural gas driliing applications |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012015857A2 (en) | 2012-02-02 |
| CN103025801A (zh) | 2013-04-03 |
| WO2012015857A3 (en) | 2012-05-24 |
| CA2806692A1 (en) | 2012-02-02 |
| EA201300070A1 (ru) | 2013-06-28 |
| EP2598558A4 (en) | 2014-03-19 |
| US20130126160A1 (en) | 2013-05-23 |
| EP2598558A2 (en) | 2013-06-05 |
| CN103025801B (zh) | 2015-04-29 |
| BR112013002223A2 (pt) | 2016-05-24 |
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| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
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| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AZ KZ RU |