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DK2511637T3 - Process for drying wet particulate matter, wherein the dried particle material is a white mineral having a brightness Ry of at least 65%, by drying in a direct superheated steam dryer - Google Patents

Process for drying wet particulate matter, wherein the dried particle material is a white mineral having a brightness Ry of at least 65%, by drying in a direct superheated steam dryer Download PDF

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Publication number
DK2511637T3
DK2511637T3 DK11162729.5T DK11162729T DK2511637T3 DK 2511637 T3 DK2511637 T3 DK 2511637T3 DK 11162729 T DK11162729 T DK 11162729T DK 2511637 T3 DK2511637 T3 DK 2511637T3
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Prior art keywords
steam
drying chamber
particulate matter
calcium carbonate
drying
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DK11162729.5T
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Danish (da)
Inventor
Alain Cremaschi
Robert Gutsche
Ludovic Hautcoeur
Olav Bergset
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Omya Int Ag
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B23/00Heating arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B3/00Drying solid materials or objects by processes involving the application of heat
    • F26B3/02Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00Compounds of calcium, strontium, or barium
    • C01F11/18Carbonates
    • C01F11/185After-treatment, e.g. grinding, purification, conversion of crystal morphology
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B11/00Machines or apparatus for drying solid materials or objects with movement which is non-progressive
    • F26B11/12Machines or apparatus for drying solid materials or objects with movement which is non-progressive in stationary drums or other mainly-closed receptacles with moving stirring devices
    • F26B11/16Machines or apparatus for drying solid materials or objects with movement which is non-progressive in stationary drums or other mainly-closed receptacles with moving stirring devices the stirring device moving in a vertical or steeply-inclined plane
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B17/00Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement
    • F26B17/18Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement with movement performed by rotating helical blades or other rotary conveyors which may be heated moving materials in stationary chambers, e.g. troughs
    • F26B17/20Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement with movement performed by rotating helical blades or other rotary conveyors which may be heated moving materials in stationary chambers, e.g. troughs the axis of rotation being horizontal or slightly inclined
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B23/00Heating arrangements
    • F26B23/001Heating arrangements using waste heat
    • F26B23/002Heating arrangements using waste heat recovered from dryer exhaust gases
    • F26B23/004Heating arrangements using waste heat recovered from dryer exhaust gases by compressing and condensing vapour in exhaust gases, i.e. using an open cycle heat pump system
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B2200/00Drying processes and machines for solid materials characterised by the specific requirements of the drying good
    • F26B2200/18Sludges, e.g. sewage, waste, industrial processes, cooling towers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/52Heat recovery pumps, i.e. heat pump based systems or units able to transfer the thermal energy from one area of the premises or part of the facilities to a different one, improving the overall efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Microbiology (AREA)
  • Drying Of Solid Materials (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Freezing, Cooling And Drying Of Foods (AREA)

Description

Description [0001] The present invention relates to the field of drying processes, and more specifically to a method for drying wet particulate matter using superheated steam. [0002] Superheated steam drying is an emerging technology, which utilizes superheated steam as drying medium in direct contact with the wet product to be dried. Compared to direct air or inert gas dryers, direct superheated steam dryers have a number of well known basic advantages such as lower energy consumption due to no air or inert gas heating, the excess steam is more suitable for heat recovery as it is not mixed with air or inert gas, negligible emission of polluted air or inert gas, no explosion risk inside equipment, or low oxidation of products that would normally oxidize by air. [0003] Saturated steam is often used as the energy source in indirect drying processes, which are based on a drying principle giving potentially the same basic advantages as a direct superheated steam dryer. However, the indirect drying principle differs significantly from the direct drying principle as heat is not supplied via direct contact between wet product and drying medium. Rather, heat issuppliedvia hotsurface in contact with the product to be dried. Furthermore, indirect dryers require specially designed heat exchangers for use inside the drying chamber, which are complex and costly compared to standard heat exchangers. [0004] The Netherlands Organization for Applied Scientific Research (TNO) published in June 2004 a report (R 2004/239), entitled "Industrial superheated steam drying", which mentions that so far over hundred drying installations are found which utilize the superheated steam drying technology, mostly large scale continuous dryers for bulk materials. However, the superheated steam dryers known in the art still suffer from the problem that due to their construction a lot of the employed energy cannot be recovered. This is particularly the case when a superheated steam dryer is not connected to other external processes or heat sinks but is used as standalone system. [0005] WO 03/052336 describes a mixing dryer based on the principle of direct superheated steam drying, with a cyclone, i.e. a fines/steam separator, in the drying chamber outlet steam and with a traditional energy system. The need of a cyclone in the recirculation circuit causes an increased pressure drop that needs to be compensated by higher differential pressure of the circulation fan, and hence, results in significantly increased energy consumption of the circulation fan. Furthermore, the use of a traditional energy system means that energy recovery is only possible by connecting this mixing dryer to other external processes or heat sinks. [0006] US patent no. 5,291,668 discloses an atmospheric superheated steam drying process using a flash type dryer, wherein the dry product is separated from the steam through the use of a curvilinear louver separator. The water steam separated from the dry product is re covered and recirculated as steam energy through the use of a mechanical vapour compressor, while the drying medium or carrier gas or superheated steam is either heated in external heat exchangers or in heat exchangers internally of the drying chamber or a combination of these methods. One basic limitation of this process, however, is that the drying medium or carrier gas flow rate influences the overall functionality of the drying process, and thus, makes it infeasible to run the described drying system at an optimal energy recovery system temperature level without either increasing the dryer size significantly compared to conventional sizing or introducing complex heat exchanger surfaces inside the drying chamber. Furthermore, a fines and product separator is mandatory in said flash dryer which leads to an additional pressure drop that needs to be compensated by spending more energy for the circulation fan. [0007] EP 0058651 relates to a cattle feed flash-/pneu-matic dryer, wherein the product particles are simultaneously transported in pipeline and dried in the carrier gas or drying medium or superheated steam, wherein the drying medium is re-heated through the double wall pipeline. This drying system has also the limitation that the drying medium or carrier gas flow rate influences the overall functionality of the drying process, and thus, makes it infeasible to run the described drying system at an optimal energy recovery system temperature level without increasing the dryer size significantly compared to conventional sizing. This system also requires a cyclone or other type of separator, which is unfavourable in terms of energy consumption. [0008] US patent no. 4,242,808 describes a direct superheated steam drying process specifically for paper web in a paper mill. The energy can be recovered at least partly by use of a mechanical vapour compressor. However, this system requires a high inlet temperature and also is not suitable for drying particulate matter. [0009] For completeness, the Applicant would like to mention the following US patents, which refer to indirect drying principles with energy recovery by means of mechanical vapour recompression: US 4,523,388, US 4,223,452, US 2,622,342, and US 4,974,335. [0010] There remains a need in the art for a more energy-efficient drying method for wet particulate matter. [0011] Accordingly, it is an object of the present invention to provide a drying method for wet particulate matter, which requires less energy consumption. It would also be desirable to provide an energy-efficient drying system that is not dependant of being connected to other external thermal processes or heat sinks. It is also desirable that such a system can be utilized under industrial conditions. [0012] It is also an object of the present invention to provide a drying method for wet particulate matter that utilizes a less complex steam recirculation circuit which accepts a certain amount of carried particulate matter. It would also be desirable to provide a drying method that allows integrated recycling of carried particulate matter in the excess steam with low or negligible energy con- sumption. [0013] The foregoing and other objects are solved by the provision of a method for drying wet particulate matter, wherein the dried particulate matter is a white mineral having a brightness Ry of at least 65% measured according to DIN 53163, the method comprising the steps of: a) providing at least one feed stream (1) of wet particulate matter, b) providing a recirculation circuit comprising at least one drying chamber (40), at least one circulation fan (41) , and at least one heat exchanger (42), wherein the at least one drying chamber (40) comprises a mixing system and mixed particulate matter, at least one inlet for the at least one feed stream of wet particulate matter, at least one inlet for superheated steam, and at least one outlet for exhaust steam, c) feeding, either continuously or discontinuously, the at least one feed stream (1) of wet particulate matter into the mixed particulate matter in the at least one drying chamber (40) via the at least one inlet for the feed stream, d) feeding superheated steam (6) into the at least one drying chamber (40) via the at least one inlet for superheated steam, e) directly contacting the mixed particulate matter with superheated steam within the at leastonedrying chamber (40) to dry the mixed particulate matterand exhausting said steam via the at least one outlet for exhaust steam (3) without separating from the exhaust steam (3) any carried particulate matter, f) feeding the exhaust steam carrying particulate matter (3, 4, 5) into the at least one heat exchanger (42) , in which the exhaust steam carrying particulate matter is reheated to provide superheated steam (6), wherein the exhaust steam carrying particulate matter passes the at least one circulation fan (41) before or after the at least one heat exchanger (42), and feeding said superheated steam back into the at least one drying chamber (40) via the at least one inlet for superheated steam, g) splitting an excess steam (7) from at least one position within the recirculation circuit, h) feeding the excess steam (7) into at least one mechanical compressor (43), wherein the excess steam is compressed to raise the saturated temperature of the excess steam, using said compressed excess steam (8) as a source of heat in the at least one heat exchanger (42), and discharging the excess steam as a liquid condensate (9), and i) discharging, either continuously or discontinuously, thedried particulate as at least one productstream via at least one outlet to obtain the dried particulate matter. [0014] According to another aspect of the present invention, the drying method according to the present invention is used for manufacturing calcium carbonate having a solid content of more than 95 wt.-%, wherein the calcium carbonate is preferably manufactured without the presence of a classifier. [0015] Advantageous embodiments of the present invention are defined in the corresponding sub-claims. [0016] According to one embodiment the at least one drying chamber (40) comprises at least one outlet for dried particulate matter and the at least one product stream is discharged via the at least one outlet for dried particulate matter from the at least one drying chamber and/or the remaining recirculation circuit excluding the at least one drying cham ber comprises at least one outlet for dried particulate matter and the at least one product stream is discharged via the at least one outlet for dried particulate matter from the recirculation circuit excluding the at least one drying chamber. [0017] According to one embodiment the mixing system within the drying chamber is selected from a one, two- or more shafts mixer, or a one, two- or more shafts combined mixer and mechanical fluidized bed establish-er, preferably the mixing system is a two shafts combined mixer and mechanical fluidized bed establisher. [0018] According to one embodiment the pressure in the at least one drying chamber is from 0 to 5 bar, preferably from 0.1 to 1.5 bar, and more preferably from 0.1 to 0.95 bar or from 1.05 to 1.2 bar. According to another embodiment the superheated steam is superheated water steam and the pressure drop through the recirculation circuit is from 500 to 3000 Pa, preferably from 1000 to 2000 Pa, at a pressure in the at leastonedrying chamber of 0.8 to 1.2 bar. [0019] According to one embodiment the excess steam (7) is split from at least one position within the recirculation circuit, wherein the amount of carried particulate matter is found to be lowest, preferably the excess steam (7) is split from the exhaust steam (3) after leaving the at least one drying chamber (40) and before leaving the at least one circulation fan (41). [0020] According to one embodiment the at least one heat exchanger (42) is a shell and tube heat exchanger. According to another embodiment the at least one mechanical compressor is a centrifugal compressor, a high pressure centrifugal fan, ora positive displacement roots blower, preferably a high pressure centrifugal fan. [0021] According to one embodiment the temperature of the superheated steam (6) and the temperature of the exhaust steam (3) leaving the at least one drying chamber differs by a temperature difference ΔΤΚ, wherein ATR is from 5 to 100°C, preferably from 10 to 50°C, more preferably from 15 to 30°C, even more preferably from 15 to 25°C, and most preferably about 22°C. According to another embodiment the saturated temperature of the excess steam (7) and the saturated temperature of the compressed excess steam (8) differs by a temperature difference ΔΤΕ, wherein ΔΤΕ is from 6 to 130°C, preferably from 11 to 80°C, more preferably from 15 to 60°C, and most preferably from 20 to 45°C. According to still another embodiment the difference between ΔΤΕ and ATr is from 1 to 30°C, preferably from 4 to 20°C, more preferably from 6 to 15°C, and most preferably from 6 to 10°C. [0022] According to one embodiment the excess steam (7) passes at least one separator (44) to remove any carried particulate matterfrom the excess steam before it is fed as purified or reboiled excess steam (17) into at least one mechanical compressor (43). According to another embodiment the removed carried particulate matter is fed as a recycle stream (13) into the at least one drying chamber (40) or into the at least one feed stream (1,2). According to still another embodiment the at least one feed stream (1) is preheated before it is fed into the at least one drying chamber (40), preferably the feed stream (1) is preheated by at least one heat exchanger (46), wherein the liquid condensate (9, 19) and/or the discharge stream from the at least separator (44) is used as a source of heat. [0023] According to one embodiment the obtained dried particulate matter contains less than 15wt.-% total moisture, preferably less than 5 wt.-%, more preferably less than 2 wt.-%, and most preferably less than 1 wt.-%, based on the total weight of the dried particulate matter. According to another embodiment the average retention time of the dried particulate matter inside the recirculation circuit is at least 10 minutes, at least 30 minutes, or at least 60 minutes. [0024] According to one embodiment the white mineral is selected from a calcium carbonate-based mineral or calcium hydroxide or calcium sulphate, preferably calcium carbonate, more preferably ground calcium carbonate, modified calcium carbonate, or precipitated calcium carbonate, or selected from calcium carbonate-containing minerals wherein calcium carbonate-containing minerals preferably comprise dolomite or tailings from calcium carbonate flotation, or mixtures thereof. According to another embodiment the white mineral is a calcium carbonate-based mineral mixed with clay or talc or calcium hydroxide or calcium sulphate, or is calcium carbonate-kaolin mixtures or mixtures of calcium carbonate and bentonite, or mixtures of natural calcium carbonate with aluminium hydroxide, magnesium hydroxide, mica or with synthetic or natural fibers or is co-structures of minerals, preferably talc-calcium carbonate or talc-titanium dioxide or calcium carbonate-titanium dioxide co-structures. [0025] According to one embodiment the obtained dried particulate matter is calcium carbonate having a solid content of more than 95 wt.-%, based on the total weight of the calcium carbonate. Brief description of the figures [0026] Fig. 1 is a schematic flow diagram illustrating an exemplary embodiment of the present invention. Fig. 2 is a schematic flow diagram illustrating another exemplary embodiment of the present invention. Fig. 3 isaschematicflowdiagram illustrating another exemplary embodiment of the present invention. Fig. 4 is a graph showing the total specific energy consumption versus the temperature difference of the temperature of the superheated steam fed into the drying chamber and the temperature of the exhaust steam leaving the drying chamber for an exemplary embodiment of the present invention. Fig. 5 is a graph showing the total specific energy consumption versus the temperature difference of the temperature of the superheated steam fed into the drying chamber and the temperature of the exhaust steam leaving the drying chamber for another exemplary embodiment of the present invention. [0027] For the purpose of the present invention, the term "wet particulate matter", "feed" or "feed stream" refers to a fresh feed or stream, which is fed into the at least one drying chamber employed in the method according to the present invention, and is a homogeneous or heterogeneous mixture of at least one solid substance with a liquid, e.g., in form of a solution, suspension or dispersion, which forms a particulate product through drying. The wet particulate matter may be present, for example, as liquid, slurry, paste, agglomerates, granulates, crystals, pellets, moist particles, moist pieces or moist cake. The liquid may comprise water, organic solvents, or any other liquid substance, or mixtures thereof. The solids content of the wet particulate matter may be at least 5 wt.-%, preferably at least 25 wt.-%, based on the total weight of the wet particulate matter. [0028] For the purpose of the present invention, "dried particulate matter" or "product" is understood to refer to particulate matter having a total moisture content of less than 15 wt.-%, less than 5 wt.-%, less than 2 wt.-%, preferably less than 1 wt.-%, based on the total weight of the dried particulate matter. [0029] The term "mixed particulate matter" as used in the context of the present invention refers to the particulate matter that is inside the drying chamber, which is simultaneously dried by the drying medium and mixed with or wetted by the wet particulate matter. The total moisture content of the mixed particulate matter is between the moisture content of the wet particulate matter and the dried particulate matter. [0030] The term "carried particulate matter" or "fines" as used in the context of the present invention refers to the particulate matter, either partly dried- or dried particulate matter, that is carried along with the exhaust steam from the drying chamber. The total moisture content of the carried particulate matter could change when it travels through the recirculation circuit or when it is carried along with the excess steam. [0031] The term "retention time" as used in the context of the present invention refers to the average retention time of dried particulate matter inside the drying system, and is calculated by dividing the dried particulate matter inside drying system at steady state conditions by the dried particulate matter flow rate in the at least one product stream. [0032] A "mineral" in the meaning of the present invention encompasses a solid inorganic substance having a characteristic chemical composition. A "white" mineral in the meaning of the present invention is a white mineral having a brightness Ryof at least 65% measured according to DIN 53163 (issue date: July 1988). [0033] "Ground calcium carbonate" (GCC) in the meaning of the present invention is a calcium carbonate obtained from natural sources, such as limestone, cal-cite, marble or chalk or dolomite, and processed through a treatment such as grinding, screening and/or fraction-izing by wet and/or dry, for example by a cyclone or classifier. [0034] "Precipitated calcium carbonate" (PCC) in the meaning of the present invention is a synthesized material, generally obtained by precipitation following the reaction of carbon dioxide and lime in an aqueous environment or by precipitation of a calcium and carbonate source in water or by precipitation of calcium and carbonate ions, for example CaCI2 and Na2C03, out of solution. [0035] A"drying medium" in the meaning of the present invention, is a solvent that is used to dry and remove the liquid component from the mixed particulate matter. The drying medium composition may be similar or rather similar to the liquid component of the wet particulate matter. [0036] The term "exhaust steam" as used in the context of the present invention refers to superheated steam enriched with moisture and/or volatile components evaporated from the mixed particulate matter during the direct drying process within the at least one drying chamber. Furthermore, the exhaust steam may comprise carried particulate matter that is carried along with the exhaust steam. [0037] For the purpose of the present invention, the phrase "without separating from the exhaust steam any carried particulate matter" means that no fines/steam separating device generating a significant additional pressure drop in the recirculation circuit, such as a cyclone or filter or similar, is used to separate the carried particulate matter from the steam travelling along the recirculation circuit. [0038] For the purpose of the present invention, the term "saturated temperature" refers to the temperature at which the physical state of a drying medium changes from liquid to vaporous, wherein the saturated temperature of the drying medium depends on its pressure. [0039] For the purpose of the present invention, the term "boiling point elevation" refers to the difference between the boiling point of a certain amount of solid substance mixed and/or dissolved with a solvent at a certain pressure, and the saturated temperature of the pure solvent at the same pressure. [0040] The term "solvent" as used in the context of the present invention refers to both solvents that dissolve solid substances and also any other type of liquids not dissolving, however, carrying solids, e.g., in form of a dispersion or suspension. [0041] A "slurry" in the meaning of the present invention comprises insoluble solids and liquid and optionally further additives and dissolved solids and usually contains large amounts of insoluble solids and, thus, is more viscous and generally of higher density than the liquid from which it is formed. [0042] The term "superheated steam" or "steam" as used in the context of the present invention refers to a steam or vapour of a drying medium. The prefix "superheated" refers to a temperature higher than the saturated temperature of the respective drying medium. The term "steam" or "vapour", without prefix superheated, as used in the context of the present invention refers either to a steam at saturated temperature or at a temperature slightly higher than the saturated temperature of the respective solvent. Any kind of superheated solvent steam or mixture of superheated solvent steams may be used in the method of the present invention, for example, but not limited to water, methanol, ethanol, isopropanol, butanol, other alcohols, propylene glycol, mono ethylene glycol, ethylene glycol, other glycols, hydrocarbons, or mixture of at least two of these solvents. [0043] The term "total moisture content" as used in the context of the present invention refers to the amount of solvent absorbed on the surface of the particulate matter and within the particulate matter, which can be evaporated from the particulate matter. In case the solvent is water, the wt.-% water of the particulate matter is determined according to suitable measuring methods for the specific solid substance, for instance the Coulometric Karl Fischer measurement method, wherein the mineral powder and/or the composite particles or particulate matter are heated to 220°C, or a different temperature suitable for the specific solid substance, and the water content is released as vapour or steam and isolated using a stream of nitrogen gas (at 100 ml/min) is determined in a Coulometric Karl Fischer unit. [0044] The term "total energy consumption" as used in the context of the present invention refers to the total electrical energy consumption plus the total thermal energy consumption and is specified in kWh. [0045] The term "total electrical energy consumption" as used in the context of the present invention refers to the electrical energy consumption of all the equipment within the actual process consuming electrical energy and is specified in kWh. [0046] The term "total thermal energy consumption" as used in the context of the present invention refers to the thermal or heat energy consumption required for the actual process to be performing as specified and is specified in kWh. [0047] The term "mechanical fluidized bed establisher" as used in the context of the present invention refers to a fluidized bed of particles, however, not established by means of a fluid passing through a particle bed but instead by means of mechanical forces via the mixing device, while the result is similar as liquefaction by means of a fluid (liquid or steam or gas) that is passed up through the particulate matter, whereby the particulate matter is converted from a static solid-like state to a dynamic fluidlike state. When fluidized, a bed of solid particles will behave as a fluid, like a liquid or steam or gas. [0048] For the purpose of the present invention, the term "bar" refers to the absolute pressure, i.e. 1.01325 bar equals atmospheric pressure, i.e. one standard atmosphere (1 atm). [0049] In the following, the features of the inventive process will be described with the help of Fig. 1 illustrating one embodiment of the drying method of the present invention. [0050] The inventive process for drying wet particulate matter comprises the step of providing at least one feed stream (1) of wet particulate matter. [0051] The wet particulate matter to be dried in the inventive process can be derived from various sources and is a white mineral having a brightness Ry of at least 65% measured according to DIN 53163 (issue date: July 1988) after it has been dried by the inventive method. [0052] According to one embodiment of the present invention, the white mineral is selected from a calcium carbonate-based mineral or calcium hydroxide or calcium sulphate, preferably calcium carbonate, more preferably ground calcium carbonate (GCC), modified calcium carbonate, or precipitated calcium carbonate (PCC), or selected from calcium carbonate-containing minerals wherein calcium carbonate-containing minerals preferably comprise dolomite or tailings from calcium carbonate flotation, or mixtures thereof. [0053] A natural ground calcium carbonate (GCC) may feature, e.g., one or more of marble, limestone, chalk, calcite and/or dolomite. A precipitated calcium carbonate (PCC) may feature, e.g., one or more of aragonitic, va-teritic and/or calcitic mineralogical crystal forms. Aragonite is commonly in the acicular form, whereas vaterite belongs to the hexagonal crystal system. Calcite can form scalenohedral, prismatic, spheral, and rhombohe-dral forms. A modified calcium carbonate may feature a natural ground or precipitated calcium carbonate with a surface and/or internal structure modification, e.g., the calcium carbonate may be treated or coated with a hy-drophobising surface treatment agent such as, e.g. an aliphatic carboxylic acid or a siloxane, or may be reacted with an acid and carbon dioxide. Calcium carbonate may be treated or coated to become cationic or anionic with, for example, a polyacrylate or polydadmac. [0054] Preferably the mineral pigment is ground calcium carbonate, modified calcium carbonate or a precipitated calcium carbonate, or a mixture thereof. [0055] According to another embodiment of the present invention, the white mineral is a calcium carbonate-based mineral mixed with clay or talc or with calcium hydroxide or calcium sulphate, or is calcium carbonate-kaolin mixtures or mixtures of calcium carbonate and bentonite, or mixtures of natural calcium carbonate with aluminium hydroxide, magnesium hydroxide, mica or with synthetic or natural fibers or is co-structures of minerals, preferably talc-calcium carbonate or talc-titanium dioxide or calcium carbonate-titanium dioxide co-structures. [0056] According to one embodiment of the present invention, the wet particulate matter is in form of a liquid, a slurry, a paste, agglomerates, granulates, crystals, pellets, moist particles, moist pieces or a moist cake. Preferably, the wet particulate matter is in form of a slurry. [0057] The liquid component of the wet particulate matter may be water, an organic solvent or any other liquid, or mixtures thereof. Examples for suitable organic solvents are methanol, ethanol, isopropanol, butanol, other alcohols, propylene glycol, mono ethylene glycol, ethylene glycol, other glycols, hydrocarbons, or mixture of at least two of these solvents. Preferably, the liquid component of the wet particulate matter is mainly water, more preferably water. [0058] The solids content of the wet particulate matter may be in the range from 5 to 95 wt.-%, based on the total weight of the wet particulate matter. According to one embodiment of the present invention, the solids content of the wet particulate matter is at least 5 wt.-%, at least 15 wt.-%, preferably at least 25 wt.-%, more preferably at least 35 wt.-%, and most preferably at least 50 wt.-%, based on the total weight of the wet particulate matter. For example, the solids content of the wet particulate matter is from 5 to 95 wt.-%, from 15 to 95 wt.-%, from 25 to 95 wt.-%, from 35 to 95 wt.-%, or from 50 to 95 wt.-%, based on the total weight of the wet particulate matter. [0059] The inventive method for drying wet particulate matter comprises further the step of providing a recirculation circuit comprising at least one drying chamber (40), at least one circulation fan (41), and at least one heat exchanger (42). The at least one drying chamber comprises a mixing system and mixed particulate matter, at least one inlet for the feed stream of wet particulate matter, at least one inlet for superheated steam, and at least one outlet for exhaust steam. [0060] Thenumberand position ofthe at leastone inlet for the at least one feed stream (1,2) and/or the number and position inside the drying chamber, where the at least one feed stream enters and distributes onto the mixed particulate matter may depend on the characteristics of the wet particulate matter, the characteristics of the mixed particulate matter, the design of the at least one drying chamber, and the tendency of the mixed particulate matter to generate fines within the drying chamber. Depending on the characteristics of the wet particulate matter and the mixed particulate matter, the design of the at least one drying chamber, and the tendency of the mixed particulate matter to generate fines within the at least one drying chamber, the at least one drying chamber may also contain more than one inlet for the feed stream, e.g., two, three, four or five inlets for the at least one feed stream. [0061] The number and position of the at least one inlet for the superheated steam (6) and/or the at least one outlet for exhaust steam (3) may depend on the characteristics of the mixed particulate matter, the design of the at least one drying chamber, and the tendency of the mixed particulate matter to generate fines within the at least one drying chamber. [0062] According to one embodiment of the present invention, the at least one drying chamber comprises at least one outlet for dried particulate matter. At least for continuous vacuum operation a valve arrangement may be present for the at least one product stream (10). [0063] According to one embodiment of the present invention, the at least one drying chamber comprises at least one additional inlet for a recycle stream, e.g., such as shown in Fig. 3 (see Fig. 3, reference 13). [0064] According to one embodiment of the present invention, the mixing system is selected from a one, two-or more shafts mixer, or a one-, two- or more shafts combined mixer and mechanical fluidized bed establisher. The mixing design aims to achieve homogenous mixed particulate matter composition and also to control a uniform size distribution of the particles, agglomerates or granulates. According to a preferred embodiment, the mixing system is a two shafts combined mixer and mechanical fluidized bed establisher. [0065] The at least one feed stream (1) of wet particulate matter isfed, eithercontinuouslyordiscontinuously, into the mixed particulate matter in the at least one drying chamber (40) via the at least one inletfor the feed stream, and superheated steam (6) is fed into the drying chamber (40) via the at least one inlet for superheated steam. [0066] The skilled person will be aware that the pressure of the at least one feed stream must be sufficiently higher than pressure inside the drying chamber. The pressure of the at least one feed stream may also depend on distribution means inside the at leastone drying chamber for the at least one feed stream. [0067] According to an exemplary embodiment of the present invention, the at least one feed stream comprises one feed stream comprising wet particulate matter in form of a slurry and one feed stream com prising wet particulate matter in form of a moist cake. [0068] The mixed particulate matter is directly contacted with superheated steam within the at least one drying chamber (40) to dry the mixed particulate matter and said steam is exhausted via the at least one outlet for exhaust steam without separating from the exhaust steam (3) any carried particulate matter. [0069] The at leastone drying chamber with the mixing system operates under the direct drying principle, i.e. the superheated steam is in direct contact with the mixed particulate matter. The superheated steam supplies heat for evaporation of the moisture of the mixed particulate matter and carries away the evaporated moisture. The superheated steam enters through the at least one inlet for superheated steam, contacts the mixed particulate matter, and exits the at least one drying chamber through the at least one outlet for exhaust steam. Without being bound to any theory, it is believed that a drying chamber with a mixing system provides a very efficient mass and heat transfer due to the intimate contact and mixing of the superheated steam and the mixed particulate matter. [0070] The exhaust steam travels along the recirculation circuit comprising the at least one drying chamber (40), the at leastone circulation fan (41), and the at least one heat exchanger (42). According to one embodiment of the present invention, the at leastone drying chamber and/or the remaining recirculation circuit excluding the at least one drying cham ber comprises at least one outlet for dried particulate matter. [0071] The exhaust steam (3, 4, 5) is fed into the at least one heat exchanger (42), wherein the exhaust steam passes the at least one circulation fan (41) before or after the at leastone heat exchanger (42). The at least one circulation fan maintains the flow rate of the steam in the recirculation circuit by overcoming the pressure drop in the recirculation circuit. [0072] In the at least one heat exchanger, the exhaust steam (5) is reheated to provide superheated steam (6). The obtained superheated steam isfed back into the drying chamber (40) via the at leastone inletfor superheated steam. [0073] The at least one heat exchanger (42) may comprise at leastone inlet for exhaust steam and at leastone outlet for superheated steam. [0074] According to one embodiment of the present invention, the at least one heat exchanger (42) is a shell and tube heat exchanger. Without being bound to any theory, it is believed that such a heat exchanger design is advantageous since, for example, it is robust to carried particulate matter and could be designed for sufficient low pressure drop. Other heat exchangers that may be used are plate heat exchanger of various types. [0075] According to one embodiment of the present invention, the exhaust steam (3, 4) passes the at least one circulation fan (41) before the at least one heat exchanger (42), e.g., such as shown in Fig. 1. [0076] According to another embodiment of the present invention, the exhaust steam passes the at least one circulation fan (41) after the at least one heat exchanger (42), e.g., such asshown in Fig. 2. Such a design may lead to a reduced total moisture content of the carried particulate matter fed to the circulation fan (41), as the carried particulate matter would be further dried through the at least one heat exchanger (42). Another advantage, may be that the temperatures of the exhaust steam entering the at least one heat exchanger (42) and the superheated steam leaving the at least one heat exchanger (42) are slightly lower, and hence the compressed steam (8, 18) saturated temperature would decrease and energy consumption for mechanical vapour recompression system would be correspondingly slightly lower, as the electrical energy input to the at least one circulation fan (41), and hence the corresponding temperature increase of the superheated steam, in this case would be done after the at least one heat exchanger (42). In case a separation by gravity is used before the at least one circulation fan (41), as described below as an optional embodiment, another advantage, may be that the amount of carried particulate matter fed into the at least one circulation fan (41) would be reduced. [0077] According to another exemplary embodiment of the present invention, the exhaust steam (3, 4) is split and passes at least two parallel circulation fans before or after the at least one heat exchanger (42). [0078] The inventive method for drying wet particulate matter comprises further the step of splitting an excess steam (7) from at least one position within the recirculation circuit. [0079] The excess steam may be split from any position within the recirculation circuit, e.g., from the exhaust steam (3, 4, 5), the superheated steam (6), the at least one drying chamber (40), the at least one circulation fan (41) and/or the at least one heat exchanger (42). [0080] According to one embodiment of the present invention, the excess steam (7) is split from at least one position within the recirculation circuit, wherein the amountof carried particulate matter is found to be lowest. An exemplary embodiment is shown in Fig. 1, wherein the excess steam (7) is split from the exhaust steam (3) after leaving the drying chamber (40) and before leaving the circulation fan (41), while the remaining exhaust steam travels along the recirculation circuit and is reheated to provide superheated steam. [0081] The excess steam (7) is fed into at least one mechanical compressor (43), wherein the excess steam is compressed to raise the pressure, and hence the saturated temperature of the excess steam. When a mechanical compressor is used directly in process steam orvapour as described above and the compressed steam is used as energy source for the same thermal process, the term "mechanical vapour recompression (MVR)" is commonly used. [0082] According to one embodiment of the present invention, the at least one mechanical compressor is, for instance, a centrifugal compressor, a high pressure centrifugal fan, ora positive displacement roots blower. Preferably, the at least one mechanical compressor is a high pressure centrifugal fan, which has the advantage that it accepts a certain amount of carried particulate matter, and thus, renders the presence of a fines/steam separa tor unnecessary. The choice of the mechanical compressor may also depend upon the evaporated water capacity and/or the total temperature difference ΔΤΕ defined below. The different mechanical compressor types have also different compression efficiencies. [0083] Alternatively, the energy system may be based on thermal recompression of the excess steam by means of a steam ejector, for which high pressure steam is used as driving force for the ejector. However, such an alternative energy system may provide a lesser degree of energy recovery. [0084] A major part of the energy recovery in the inventive method is achieved by mechanical recompression of the excess steam. The energy used for the at least one mechanical compressor can be electric or thermal energy. If thermal energy is used, waste energy from the at least one mechanical compressor may be utilized, at least partially, as energy supply for the inventive process. [0085] After leaving the at least one mechanical compressor, the compressed excess steam (8) is used as a source of heat in the at least one heat exchanger (42), and is discharged as a liquid condensate (9). The condensate (9) may either be directly discharged or fully or partly used for heating, for example, for heating the feed stream in a pre-heater as shown in Fig. 3 (see Fig. 3, reference 46), and/or fully or partly internally reused before being discharged. [0086] The at least one heat exchanger (42) may comprise at least one inlet for compressed excess steam (8) and at least one outlet for liquid condensate (9). [0087] The dried particulate matter is discharged, either continuously ordiscontinuously, as at least one product stream via at least one outlet to obtain the dried particulate matter. [0088] According to one embodiment of the present invention, the at least one drying chamber (40) comprises at least one outlet for dried particulate matter and the at least one product stream (10) is discharged via the at least one outlet fordried particulate matterfrom the drying chamber, e.g., such as shown in Fig. 1. According to another embodiment of the present invention, the remaining recirculation circuit excluding the at least one drying chamber comprises at least one outlet for dried particulate matter and the at least one product stream is discharged via the at least one outlet for dried particulate matterfrom the recirculation circuit excluding the at least one drying chamber. According to still another embodiment of the present invention, the at least one drying chamber (40) comprises at least one outlet for dried particulate matter and the remaining recirculation circuit excluding the at least one drying chamber comprises at least one outlet for dried particulate matter and the at least one product stream is discharged via the at least one outlet for dried particulate matter from the drying chamber and via the at least one outlet for dried particulate matter from the recirculation circuit excluding the at least one drying chamber.
[0089] According to one embodiment of the present invention, the obtained dried particulate matter contains less than 15 wt.-% total moisture, preferably less than 5 wt.-%, more preferably less than 2 wt.-%, and most preferably less than 1 wt.-%, based on the total weight of the dried particulate matter. [0090] According to an exemplary embodiment of the present invention, the at least one drying chamber (40) comprises a first outlet for dried particulate matter and the remaining recirculation circuit excluding the at least one drying chamber comprises a second outlet for dried particulate matter and afirst product stream is discharged via the first outlet and second product stream is discharged via the second outlet, wherein the moisture content of dried particulate matter in the first product stream is greater than the moisture content of the dried particulate matter in the second product stream. [0091] The method according to the present invention may be used for manufacturing calcium carbonate having a solid content of more than 95 wt.-%, based on the total weight of the calcium carbonate. According to a preferred embodiment, the calcium carbonate is manufactured without the presence of a classifier. [0092] According to one embodiment of the present invention, the obtained dried particulate matter is calcium carbonate having a solid content of more than 95 wt.-%, preferably more than 98 wt.-%, and most preferably more than 99 wt.-%, based on the total weight of the calcium carbonate. [0093] According to another embodiment of the present invention, the white mineral obtainable by the method according to the present invention is calcium carbonate having a total moisture of less than 5 wt.-%, preferably less than 2 wt.-%, and most preferably less than 1 wt.-%, based on the total weight of the calcium carbonate. [0094] According to one embodiment of the present invention, the average retention time of the dried particulate matter inside the recirculation circuit is at least 10 minutes, at least 30 minutes, or at least 60 minutes. [0095] The method of the present invention may be carried out at a drying chamber pressure of 0 to 5 bar. According to a preferred embodiment, the pressure in the drying chamber is from 0.1 to 1.5 bar, and more preferably from 0.1 to 0.95 bar or from 1.05 to 1.2 bar. A vacuum pump may be used in order to carry out the inventive method under vacuum. [0096] The method of the present invention, wherein the superheated steam is superheated water steam and the pressure in the at least one drying chamber is from 0.8 to 1.2 bar, may be carried out with a pressure drop through the recirculation circuit of from 500 to 3000 Pa, preferably from 1000 to 2000 Pa. [0097] According to one exemplary embodiment of the present invention, the flow rate of the superheated water steam (6) having a pressure of 1.05 bar fed into the at least one drying chamber is from 6 to 100 m3/s, preferably 12 to 50 m3/s, and more preferably 18 to 35 m3/s, and most preferably 22 to 35 m3/s, and the excess steam flow rate is 1000 kg/hour. [0098] Surprisingly, it has been found that by utilizing at least one drying chamber with a mixing system, one maintain large and stable mixed particulate matter heat-and mass transfer surface area and rather low concentration of carried particulate matter in the exhaust steam leaving the at least one drying chamber, even with high steam flow rates in the recirculation circuit. Furthermore, it has been found that the inventive method does not require afines/steam separator in the recirculation circuit since the carried particulate matter in the exhaust steam is handled efficiently in the inventive drying method. Rather, the presence of carried particulate matter may even increase the heat transfer efficiency of the at least one heat exchanger in the recirculation circuit. [0099] The absence of a fines/steam separator in the recirculation circuit avoids a significant pressure drop, and thus, the system can be operated with a lower differential pressure within the recirculation circuit, which reduces the energy consumption of the drying process significantly. If necessary, depending on the actual wet particulate matter characteristics, for handling the carried particulate matter that is present within the recirculation circuit excluding the at least one drying chamber one can apply a mainly vertical arrangement of the recirculation circuit, maintain sufficient high velocity, introduce specific means in the recirculation circuit or discharge the carried particulate matter by gravity from the recirculation circuit excluding the at least one drying chamber, or combine two or more of these means. [0100] Furthermore, it has been found that there is a specific temperature difference ATR between the temperature of the superheated steam that is fed into the at least one drying chamber via the at least one inlet for the superheated steam and the temperature of the exhaust steam leaving the at least one drying chamber that is advantageous in combination with the at least one mechanical compressor used in the inventive method. [0101] According to one embodiment of the present invention, the temperature of the superheated steam (6) that is fed into the at least one drying chamber and the temperature of the exhaust steam (3) leaving the at least one drying chamber differs by a temperature difference ΔΤΚ, wherein ΔΤΚ is from 5 to 100°C, preferably 10 to 50°C, more preferably 15 to 30°C, even more preferably 15 to 25°C, and most preferably about 22°C. [0102] According to an exemplary embodiment of the present invention, the superheated steam is superheated water steam and the temperature of the superheated steam (6) is from 105 to 220°C, preferably from 110 to 170°C, more preferably from 115°C to 150°C, and most preferably 115 to 135°C at a pressure of 1.05 bar, and/or the temperature of the exhaust steam (3) is from 101 to 120°C, preferably from 102 to 115°C, even more preferably 102 to 110°C, and most preferably about 102 to 105°C, at a pressure of 1.05 bar. [0103] According to one embodiment of the present invention, the saturated temperature of the compressed excess steam (8) and the saturated temperature of the excess steam (7) difFer by a temperature difference ΔΤε, wherein ΔΤΕ is from 6 to 130°C, preferably from 11 to 80°C, more preferably from 15 to 60°C, and most preferably 20 to 45°C. [0104] According to a preferred embodiment of the present invention, the superheated steam is superheated water steam and ATR is from 5 to 100°C, preferably from 10 to 50°C, more preferably from 15 to 30°C, and/or ΔΤE is from 6 to 130°C, preferably from 11 to 80°C, more preferably from 15 to 60°C, and most preferably from 20 to 45°C. [0105] According to another preferred embodiment of the present invention, the superheated steam is superheated water steam and ΔΤΚ is from 15 to 30°C and ΔΤΕ is from 20 to 45°C. [0106] According to one embodiment of the present invention, the difference between ΔΤΕ and ΔΤΚ is from 1 to 30°C, preferably from 4 to 20°C, more preferably from 6 to 15°C, and most preferably 6 to 10°C. [0107] In addition to the features described above, the method of the present invention may comprise further, optional features, which will be described with the help of Fig. 3, illustrating another embodiment of the drying method of the present invention. [0108] According to an optional embodiment of the present invention, the excess steam (7) passes at least one separator (44) to remove any carried particulate matter from the excess steam before it is fed as purified or reboiled excess steam (17) into the at least one mechanical compressor (43). [0109] The at least one separator (44) may be a dry separator or a wet separator. Examples for suitable dry separators are cyclones or filters. Examples for suitable wet separators are scrubbers or reboilers. [0110] The at least one separator (44) may be connected to a vent line or a vacuum pump (47) in order to purge air or inert gases. The condensate stream (9, 19) may also be connected to a vent line or a vacuum line (not illustrated in Fig. 3). [0111] According to an optional embodiment of the present invention, the removed carried particulate matter in the at least one separator (44) is fed as a recycle stream (13) into the at least one drying chamber (40). The recycle stream (13) may be fed via at least one inlet for the recycle stream into the at least one drying chamber. The recycle stream can also be directed to the at least one feed stream (1,2), however, not shown in Fig. 3. [0112] If the height difference between the at least one separator and the at least one drying chamber or the at least one feed stream is sufficient, this recycle stream flow can be maintained with no further pressurizing device. If a wet separator is used, the recycle stream (13) is in liquid state containing the diluted carried particulate matter, and said stream (13) may be concentrated before being fed into the at least one drying chamber (40) via the at least one inlet for the recycle stream or into the at least one feed stream (1,2). Wet separators with an integrated potential functionality of concentrating the diluted carried particulate matter are, for example, scrubbers or reboilers. [0113] This optional embodiment may have the advantage that the carried particulate matter in the excess steam can be recycled by means of a fully integrated system with low or negligible additional energy consumption, the absolute value depending on the ratio of carried particulate matter of the recycle stream (13) and the excess steam (7), and, if a wet separator is applied, also the boiling point elevation of the recycle stream (13). In other words, this optional embodiment may permit a twofold reduction of costs involved in the drying of wet particulate matter; there is no loss of carried particulate matter since it is recycled and there may only be low or negligible extra energy required for the recycling. [0114] According to an optional embodiment of the present invention, at least a part of the condensate (9, 19) is fed into the at least one separator (44) for maintaining the solvent mass balance within the at least one separator and the overall drying system. [0115] According to another optional embodiment of the present invention, the removed carried particulate matter in the at least one separator (44) is discharged as discharge stream from said separator. In case a dry separator is used and the carried particulate matter is sufficiently dry, the removed carried particulate matter may be discharged as a dried particulate matter contributing to the total system dried particulate matter mass balance. Alternatively, in case of wet separator, the diluted carried particulate matter may be discharged as discharge stream in form of a liquid or a slurry, wherein, depending on the ratio of carried particulate matter of the discharge stream and the excess steam (7), at least a part of the condensate (9,19) is fed into the at least one separator (44) for maintaining the mass balance within the at least one separator and the overall drying system. [0116] According to one optional embodiment of the present invention, the at least one feed stream (1) is preheated before itisfed intotheatleastonedrying chamber (40). Preferably, the at least one feed steam (1) is preheated by at least one heat exchanger (46) designed to handle the wet particulate matter, wherein the liquid condensate (9, 19) and/or the discharge stream from the at least one separator (44) is used as a source of heat. The at least one heat exchanger (46) may comprise at least one inlet for feed stream (1), at least one outlet for preheated feed stream (2), at least one inlet for hot condensate (9, 19) or hot discharge stream from the separator (44), and at least one outlet for sub-cooled condensate (20) or sub-cooled discharge stream from the at least one separator (44). [0117] According to one optional embodiment of the present invention, the carried particulate matter in the recirculation circuit excluding the at least one drying chamber could be partly separated by simply gravity means at any position in the recirculation circuit excluding the at least one drying chamber, preferably at a position after the at least one heat exchanger (42) and before the at least one drying chamber (40). In case the carried particulate matter is sufficiently dry, this carried particulate matter discharge would contribute to the total system dried particulate matter mass balance. Optionally said carried particulate matter discharge may be recycled back into the at least one drying chamber via at least one inlet or into the at least one feed stream. [0118] The inventive drying method may be carried out in a well insulated drying system or in a drying system that is externally heated via double wall shell to eliminate or minimize internal condensation inside the drying system, e.g., in the areas comprising particulate matter. [0119] According to another optional embodiment, the at least one drying chamber and/or steam pipelines used to carry out the inventive method comprise a double wall shell and a part of the compressed steam (8, 18) is used as a source of heat for internal reheating of the drying medium or superheated steam in the at least one drying chamber (40) and/or connected pipelines used to carry out the inventive method. This may further reduce the overall energy consumption due to reduced superheated steam (6) flow rate and at the same time may result in a lower risk of condensation inside the at least one drying chamber and the steam pipelines. [0120] According to still another optional embodiment, the liquid condensate (9, 19) is used to cool the compressed steam (8, 18) before it enters the at least one heat exchanger (42). The injection of liquid condensate for this purpose could be either before or after the at least one mechanical compressor (43). [0121] According to still another optional embodiment of the present invention, an external energy input (11) may be employed to startthe inventive method. Asuitable external energy input may be steam from a boiler or hot water. However, an external energy input is not mandatory for start up purpose. For example, if a hot feed stream, a running at least one circulation fan, and the at least one mechanical compressor are driven, the drying system can be heated up by its own. At steady state operation an external energy input may be not required in case of an excess of energy in the total system, and is hence shut off via an on/off valve. When external energy is required during operation due to total energy balance and/or the feed characteristics, it could either be supplied directly into the compressed steam or indirectly via the at least one separate heat exchanger in the recirculation circuit. If excess of energy in the total system is present, this may be removed from a steam line between the at least one drying chamber (40) and the at least one heat exchanger (42) by an externally cooled condenser to maintain total energy balance. [0122] According to still, another, optional embodiment, the method according to the present invention may comprise at least two drying chambers in series, parallel or combination of series and parallel. In case serially connected chambers are used, the method of the present invention may be carried out without reheating between drying chambers or with reheating between at least two of the chambers, without superheated steam bypass of the drying chambers or with superheated steam bypass of at least one drying chamber, with similar moisture content of the mixed particulate matter or with different moisture content of the mixed particulate matter in at least two drying chambers, with similar drying chamber temperatures or with different drying chamber superheated steam inlet/outlet temperatures in at least two dying chambers, and with at least one MVR system. Some potential advantages of this optional embodiment may be an overall further optimized drying method, a drying method optimized for each type of wet particulate matter to be dried, improved energy efficiency, improved heat-and mass transfer in drying chambers and/or lower amount of carried particulate matter in the main recirculation circuit excluding the at least one drying chamber. [0123] The white mineral obtainable by a method according to the present invention may be used in paper applications, paints, sealants, adhesives, concrete, agriculture, cosmetics, food, feed, pharmaceuticals, water treatment and/or plastics.ExamplesExample 1 [0124] Example 1 is a comparison between the energy consumption of the inventive drying process and a drying process using a conventional direct superheated steam mixing dryer without energy recovery of the excess steam latent heat. [0125] The conventional dryer included a fines/steam cyclone type separator in the recirculation circuit which leads to a higher estimated pressure drop in the steam recirculation circuit. The total energy consumption was calculated in accordance to the overall system energy balance. The electrical energy consumption was based on standard calculation models of energy consumption for the circulation fan based on differential pressure, volume flow rate and total fan efficiency and using the commonly assumed values of electrical energy consumption of mixing device and pumps. The inventive drying process setup was based on the process design shown in Fig. 1. [0126] In the results, the consequence of a fines/steam separator in the recirculation circuit of the inventive drying process is discussed. The numbers in brackets refer to the actual equipment, steam or stream position in Fig. 1. The effect consumption (kW) must be seen in relation to the evaporated water capacity specified in the common design data. Common design data[0127]
Wet particulate matter: CaC03 in water Feed concentration (1): 50 wt.-% solids content Product concentration (10): 99 wt.-% solids content Feed capacity: 2000 kg/h Evaporated water capacity (7, 8, 9): 1000 kg/h Drying chamber pressure: 1.05 bar Retention time: more than 30 minutes Effect consumption mixer and pumps: 30 kW Circulation fan efficiency (41): 0.65 Mechanical compressor efficiency (43): 0.60 Conventional direct superheated steam drying process[0128] Temperature inlet to drying chamber: 164°C Temperature outlet of drying chamber: 102°C Pressure drop in recirculation circuit: 6000 Pa Total thermal effect consumption: 550 kW Total electric effect consumption circulation fan: 70 kW Total effect consumption: 650 kW Inventive process[0129] Temperature inlet to drying chamber (6): 124°C Temperature outlet of drying chamber (3): 102°C ΔΤ R or temperature difference of superheated steam entering (6) and the exhaust steam (3) leaving the drying chamber: 22°C ΔΤΕ or temperature increase MVR system (43): ATR + 6°C =28°C Pressure drop in recirculation circuit (3-4-41-5-42-6-40): 1500 Pa Superheated steam volume flow rate (6): 24 m3/s Total thermal effect consumption: 0 kW Electrical effect consumption circulation fan: 50 kW Electrical effect consumption MVR system: 75 kW Total effect consumption: 155 kW Result [0130] The inventive process according to this example showed an approximately 76% lower total energy consumption than the conventional drying process. The presence of a fines/steam separating device in the recirculation circuit (e.g. a cyclone), with assumed additional pressure drop of 4500 Pa and otherwise the same design data, led to an approximately 150 kW increased electrical effect consumption forthe circulation fan, and hence, the total energy consumption was 305 kW, i.e. two times higher than for the inventive process.Example 2 [0131] Fig. 4 shows a calculation of the total specific energy consumption (i.e. kWh per ton evaporated water) versus temperature difference of the superheated steam fed into drying chamber and the exhaust steam leaving the drying chamber based on the design data specified below for the inventive process illustrated in Fig. 3. In this example also the sensitivity of the recirculation circuit pressure drop versus the optimum temperature levels for the process is shown. The numbers in brackets refer to the actual equipment, steam or stream position in Fig. 3. Design data[0132] Wet particulate matter: CaC03 in water Feed concentration (1): 50 wt.-% solids content Product concentration (10): 99 wt.-% solids content Drying chamber pressure (40): 1.05 bar Retention time: more than 30 minutes Carried particulate matter in excess steam (7): 1 wt.-% ΔΤε or temperature increase MVR system: ΔΤΚ + 10°C Pressure drop in recirculation circuit (3-4-41-5-42-6-40): 1100 or 1500 or 1900 Pa Circulation fan efficiency (41): 0.75 Mechanical compressor efficiency (43): 0.78 Specific energy consumption mixer and pumps: 30 kWh/ton evaporated water [0133] Fig. 4 illustrates that the optimum energy consumption versus ATr occurred at approximately ATr= 15-30°C. The energy consumption of the circulation fan was reduced when ATR was increased due to the reduced flow rate of the superheated steam. The opposite occurred for the mechanical compressor energy consumption due to the need of a higher ΔΤΕ, to compensate for the higher ΔΤΚ, or more specifically the highersuperheat-ed steam temperature outlet from the heat exchanger (42). Fig. 4 also illustrates the effect of a reduced (1100 Pa) or increased (1900 Pa) pressure drop (dP) in the recirculation circuit, and shows that the optimum temperature level is still rather low and rather within the same range.Example 3 [0134] Fig. 5 shows the sensitivity of increased temperature difference between ΔΤΕ and ATr, which is relevant, for instance, when the boiling point elevation is increasing. In this example, the wet particulate matter composition was only defined indirectly by the mixed particulate matter boiling point elevation characteristics specified below. For three different cases, calculations of the total specific energy consumption (i.e. kWh per ton evaporated water) versus temperature difference of the superheated steam fed into drying chamber and the exhaust steam leaving the drying chamber are shown based on the design data specified below forthe inventive process illustrated in Fig. 1. The numbers in brackets refer to the actual equipment, steam or stream position in Fig. 1. Design data used[0135] Wet particulate matter: in relation to the mixed particulate matter definition Mixed particulate matter boiling point elevation: 0 or 6 or 12°C Feed concentration (1): 50 wt.-% solids content Product concentration (10): 99 wt.-% solids content Drying chamber pressure (40): 1.05 bar Retention time: more than 30 minutes ΔΤε or temperature increase MVR system (43): ATr + 8 orATR+14 orATR +20°C Pressure drop in recirculation circuit (3-4-41-5-42-6-40): 1100 Pa Circulation fan efficiency (41): 0.75 Mechanical compressor efficiency (43): 0.78 Specific energy consumption mixer and pumps: 30 kWh/ton evaporated water [0136] The results of the calculations are illustrated in Fig. 5, which shows that the optimum Δ TR temperature level is rather low and within the same range for the three different cases, wherein the optimum ΔΤΚ range is from 15 to 25°C. Consequently, when drying a wet or mixed particulate matter with higher boiling point elevation one may keep the same ΔΤρ>, while the ΔΤΕ and hence the mechanical compressor energy consumption may be increased to compensate for the higher boiling point elevation.Example 4 [0137] This example is based on the inventive process illustrated in Fig. 3 and shows the additional energy consumption for carried particulate matter in excess steam recycling by use of a wet type separator. The inventive process without recycling of the carried particulate matter in the excess steam was compared with the inventive process with recycling. Two examples for recycling are used, with 0.5 wt.-% and 2.0 wt.-% carried particulate matter in the excess steam, respectively. The numbers in brackets refertothe actual equipment, steam orstream position in Fig. 3. Design data used:[0138] Wet particulate matter: CaC03 in water Feed concentration (1): 50 wt.-% solids content Product concentration (10): 99 wt.-% solids content Drying chamber pressure (40): 0.91 bar Retention time: more than 30 minutes Carried particulate matter in excess steam (7): 0.5 wt.-% and 2.0 wt.-% Concentration of carried particulate matter in recycle stream (13): 50 wt.-% ATr or tern perature d ifference of su perheated stea m entering (6) and the exhaust steam (3) leaving the drying chamber: 22°C ΔΤε or temperature increase MVR system, without recycling: ΔΤΚ + 12°C ΔΤε or temperature increase MVR system, with recycling: ΔΤΚ + 13°C Pressure drop in recirculation circuit (3-4-41-5-42-6-40): 1400 Pa Circulation fan efficiency (41): 0.70 Mechanical compressor efficiency (43): 0.75 Specific energy consumption mixer and pumps: 30 kWh/ton evaporated water Results:[0139] Specific energy consumption without recycling = 154 kWh/ton Specific energy consumption with recycling, 0.5 wt.-% carried particulate matter in excess steam = 158 kWh/ton Specific energy consumption with recycling, 2.0 wt.-% carried particulate matter in excess steam = 160 kWh/ton [0140] The additional energy consumption with recycling was hence 2-4%.

Claims (20)

1. Fremgangsmåde til tørring af vådt partikelmateriale, hvor det tørrede partikelmateriale er et hvidt mineral som har en lysstyrke Ry på mindst 65% målt ifølge DIN 53163, fremgangsmåden omfattende trinnene at a) tilvejebringe mindst en tilførselsstrøm (1) af vådt partikelmateriale, b) tilvejebringe et recirkulationskredsløb omfattende mindst et tørringskammer (40), mindst en cirkulationsblæser (41), og mindst en varmeveksler (42), hvor det mindst ene tørringskammer (40) omfatter et blandingssystem og blandet partikelmateriale, mindst et indløb til tilførselsstrømmen af vådt partikelmateriale, mindst et indløb til overhedet damp, og mindst et udløb til udblæsningsdamp, c) føre, enten kontinuerligt eller diskontinuerligt, den mindst ene tilførselsstrøm (1) af vådt partikelmateriale til det blandede partikelmateriale i det mindst ene tørringskammer (40) via det mindst ene indløb til tilførselsstrømmen, d) føre overhedet damp (6) til det mindst ene tørringskammer (40) via det mindst ene indløb til overhedet damp, e) direkte at bringe det blandede partikelmateriale i kontakt med overhedet damp inden i det mindst ene tørringskammer (40) for at tørre det blandede partikelmateriale og at tømme dampen via det mindst ene udløb til udblæsningsdamp (3) uden at adskille fra udblæsningsdampen (3) noget båret partikelmateriale, f) føre udblæsningsdampen som bærer partikelmateriale (3, 4, 5) til den mindst ene varmeveksler (42), i hvilken udblæsningsdampen som bærer partikelmateriale genopvarmes for at tilvejebringe overhedet damp (6), hvor udblæsningsdampen som bærer partikelmateriale passerer den mindst ene cirkulationsblæser (41) før eller efter den mindst ene varmeveksler (42) , og at føre den overhedede damp tilbage til det mindst ene tørringskammer (40) via det mindst ene indløb til overhedet damp, g) adskille en overskydende damp (7) fra mindst en position inden i recirkulationskredsløbet, h) føre den overskydende damp (7) til mindst en mekanisk kompressor (43) , hvor den overskydende damp komprimeres til at hæve den mættede temperatur af den overskydende damp, ved anvendelse af den komprimerede overskydende damp (8) som en kilde af varme i den mindst ene varmeveksler (42), og at tømme den overskydende damp som et flydende kondensat (9), og i) tømme, enten kontinuerligt eller diskontinuerligt, det tørrede partikelmateriale som mindst en produktstrøm via mindst et udløb for at opnå det tørrede partikelmateriale.A wet particle drying method, wherein the dried particle material is a white mineral having a brightness Ry of at least 65% measured according to DIN 53163, the method comprising the steps of a) providing at least one wet stream feed stream (1), b) providing a recycling circuit comprising at least one drying chamber (40), at least one circulation fan (41), and at least one heat exchanger (42), wherein the at least one drying chamber (40) comprises a mixing system and mixed particulate material, at least one inlet for the wet particle feed stream; at least one superheated steam inlet and at least one exhaust steam outlet; (c) pass, either continuously or continuously, the at least one wet particle feed stream (1) into the mixed particulate material in the at least one drying chamber (40) via the at least one inlet d) supply superheated steam (6) to the at least one drying chamber (40) via the at least one superheated steam inlet; e) directly contacting the mixed particulate material with superheated steam within the at least one drying chamber (40) to dry the mixed particulate material and discharging the steam through the at least one outlet for exhaust vapor (3) without separating from any particulate material from the exhaust vapor (3); superheated steam (6) wherein the particulate exhaust vapor passes through the at least one circulation fan (41) before or after the at least one heat exchanger (42) and returns the superheated steam to the at least one drying chamber (40) via the at least one inlet (g) separating excess steam (7) from at least one position within the recirculation circuit; h) conducting the excess steam ( 7) for at least one mechanical compressor (43), wherein the excess steam is compressed to raise the saturated temperature of the excess steam, using the compressed excess steam (8) as a source of heat in the at least one heat exchanger (42) and discharging the excess steam as a liquid condensate (9), and (i) discharging, either continuously or discontinuously, the dried particulate material as at least one product stream via at least one outlet to obtain the dried particulate material. 2. Fremgangsmåde ifølge krav 1, hvor det mindst ene tørringskammer (40) omfatter mindst et udløb til tørret partikelmateriale og den mindst ene produktstrøm tømmes via det mindst ene udløb til tørret partikelmateriale fra det mindst ene tørringskammer og/eller det resterende recirkulationskredsløb med undtagelse af det mindst ene tørringskammer omfatter mindst et udløb til tørret partikelmateriale og den mindst ene produktstrøm tømmes via det mindst ene udløb til tørret partikelmateriale fra recirkulationskredsløbet med undtagelse af det mindst ene tørringskammer.The method of claim 1, wherein the at least one drying chamber (40) comprises at least one outlet for dried particulate material and the at least one product stream is discharged via the at least one outlet for dried particulate material from the at least one drying chamber and / or the remaining recirculation circuit except the at least one drying chamber comprises at least one outlet for dried particulate material and the at least one product stream is emptied via the at least one outlet for dried particulate material from the recirculation circuit with the exception of the at least one drying chamber. 3. Fremgangsmåde ifølge krav 1 eller 2, hvor blandingssystemet inden i tørringskammeret vælges fra en et-, to- eller flerskaftsblander, eller en et-, toeller flerskaftskombinationsblander og mekanisk fluidiseret-leje-opretter, fortrinsvis er blandingssystemet en toskaftskombinationsblander og mekanisk fluidiseret-leje-opretter.A method according to claim 1 or 2, wherein the mixing system within the drying chamber is selected from a one, two or multiple mixer, or one, two or multiple combination mixer and mechanical fluidised bed mixer, preferably the mixing system is a two combination combination mixer and mechanical fluidized bed. -Creates. 4. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor trykket i det mindst ene tørringskammer er fra 0 til 5 bar, fortrinsvis fra 0,1 til 1,5 bar, og mere fortrinsvis fra 0,1 til 0,95 bar eller fra 1,05 til 1,2 bar.A method according to any one of the preceding claims, wherein the pressure in the at least one drying chamber is from 0 to 5 bar, preferably from 0.1 to 1.5 bar, and more preferably from 0.1 to 0.95 bar. or from 1.05 to 1.2 bar. 5. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den overhedede damp er overhedet vanddamp og trykfaldet igennem recirkulationskredsløbet er fra 500 til 3000 Pa, fortrinsvis fra 1000 til 2000 Pa, ved et tryk i det mindst ene tørringskammer på 0,8 til 1,2 bar.A process according to any one of the preceding claims, wherein the superheated steam is superheated water vapor and the pressure drop through the recirculation circuit is from 500 to 3000 Pa, preferably from 1000 to 2000 Pa, at a pressure in the at least one drying chamber of 0.8 to 1.2 bar. 6. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den overskydende damp (7) er delt fra mindst en position inden i recirkulationskredsløbet, hvor mængden af båret partikelmateriale findes at være lavest, fortrinsvis er den overskydende damp (7) delt fra udblæsningsdampen (3) efter at have forladt det mindst ene tørringskammer (40) og før at have forladt den mindst ene cirkulationsblæser (41).A method according to any one of the preceding claims, wherein the excess steam (7) is divided from at least one position within the recirculation circuit, wherein the amount of particulate material carried is found to be lowest, preferably the excess steam (7) is divided from the exhaust vapor (3) after leaving at least one drying chamber (40) and before leaving at least one circulating fan (41). 7. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den mindst ene varmeveksler (42) er en skal- og rørvarmeveksler.A method according to any one of the preceding claims, wherein the at least one heat exchanger (42) is a shell and tube heat exchanger. 8. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den mindst ene mekanisk kompressor er en centrifugalkompressor, en højtrykscentrifugalblæser, eller en positiv forskydningsrodblæser, fortrinsvis en højtrykscentrifugalblæser.A method according to any one of the preceding claims, wherein the at least one mechanical compressor is a centrifugal compressor, a high-pressure centrifugal blower, or a positive displacement root blower, preferably a high-pressure centrifugal blower. 9. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor temperaturen af den overhedede damp (6) og temperaturen af udblæsningsdampen (3) som forlader det mindst ene tørringskammer er forskellige ved en temperaturforskel ATr, hvor ATr er fra 5 til 100 °C, fortrinsvis fra 10 til 50 °C, mere fortrinsvis fra 15 til 30 °C, endnu mere fortrinsvis fra 15 til 25 °C, og mest fortrinsvis omkring 22 °C.A method according to any one of the preceding claims, wherein the temperature of the superheated steam (6) and the temperature of the exhaust steam (3) leaving the at least one drying chamber are different at a temperature difference ATr, where ATr is from 5 to 100 °. C, preferably from 10 to 50 ° C, more preferably from 15 to 30 ° C, even more preferably from 15 to 25 ° C, and most preferably about 22 ° C. 10. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den mættede temperatur af den overskydende damp (7) og den mættede temperatur af den komprimerede overskydende damp (8) er forskellig ved en temperaturforskel ATe, hvor ATe er fra 6 til 130 °C, fortrinsvis fra 11 til 80 °C, mere fortrinsvis fra 15 til 60 °C, og mest fortrinsvis fra 20 til 45 °C.A method according to any one of the preceding claims, wherein the saturated temperature of the excess vapor (7) and the saturated temperature of the compressed excess vapor (8) are different at a temperature difference ATe, where ATe is from 6 to 130. ° C, preferably from 11 to 80 ° C, more preferably from 15 to 60 ° C, and most preferably from 20 to 45 ° C. 11. Fremgangsmåde ifølge krav 9 eller 10, hvor forskellen mellem ATe og ATr er fra 1 til 30 °C, fortrinsvis fra 4 til 20 °C, mere fortrinsvis fra 6 til 15 °C, og mest fortrinsvis fra 6 til 10 °C.The method of claim 9 or 10, wherein the difference between ATe and ATr is from 1 to 30 ° C, preferably from 4 to 20 ° C, more preferably from 6 to 15 ° C, and most preferably from 6 to 10 ° C. 12. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den overskydende damp (7) passerer mindst en separator (44) til at fjerne eventuelt båret partikelmateriale fra den overskydende damp før den føres som renset eller genkogt overskydende damp (17) til mindst en mekanisk kompressor (43).A method according to any one of the preceding claims, wherein the excess steam (7) passes at least one separator (44) to remove any borne particulate material from the excess steam before passing it as purified or boiled excess steam (17) to at least one mechanical compressor (43). 13. Fremgangsmåde ifølge krav 12, hvor det fjernede bårne partikelmateriale føres som en recirkulationsdamp (13) til det mindst ene tørringskammer (40) eller til den mindst ene tilførselsstrøm (1, 2).The method of claim 12, wherein the removed borne particulate material is fed as a recirculation vapor (13) to the at least one drying chamber (40) or to the at least one feed stream (1, 2). 14. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den mindst ene tilførselsstrøm (1) forvarmes før den føres til det mindst ene tørringskammer (40), fortrinsvis forvarmes tilførselsstrømmen (1) af mindst en varmeveksler (46), hvor det flydende kondensat (9, 19) og/eller udtømningsdampen fra den mindst ene separator (44) anvendes som en varmekilde.A method according to any one of the preceding claims, wherein the at least one supply stream (1) is preheated before being fed to the at least one drying chamber (40), preferably the feed stream (1) is preheated by at least one heat exchanger (46), liquid condensate (9, 19) and / or the discharge steam from the at least one separator (44) is used as a heat source. 15. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor det opnået tørret partikelmateriale indeholder mindre end 15 vægtprocent samlet fugt, fortrinsvis mindre end 5 vægtprocent, mere fortrinsvis mindre end 2 vægtprocent, og mest fortrinsvis mindre end 1 vægtprocent, baseret på den samlede vægt af det tørrede partikelmateriale.A process according to any one of the preceding claims, wherein the dried particle material obtained contains less than 15% by weight total moisture, preferably less than 5% by weight, more preferably less than 2% by weight, and most preferably less than 1% by weight, based on the total weight of the dried particulate matter. 16. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den gennemsnitlige tilbageholdelsestid af det tørrede partikelmateriale inden i recirkulationskredsløbet er mindst 10 minutter, mindst 30 minutter, eller mindst 60 minutter.A method according to any one of the preceding claims, wherein the average retention time of the dried particulate material within the recirculation circuit is at least 10 minutes, at least 30 minutes, or at least 60 minutes. 17. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor det hvide mineral vælges fra et calciumkarbonat-baseret mineral eller calciumhydroxid eller calciumsulfat, fortrinsvis calciumkarbonat, mere fortrinsvis formalet calciumkarbonat, modificeret calcium karbonat, eller præcipiteret calciumkarbonat, eller vælges fra calciumkarbonat-indeholdende mineraler hvor calciumkarbonat-indeholdende mineraler fortrinsvis omfatter dolomit eller affaldsprodukter fra calciumkarbonatflotation, eller blandinger deraf.A process according to any one of the preceding claims, wherein the white mineral is selected from a calcium carbonate-based mineral or calcium hydroxide or calcium sulfate, preferably calcium carbonate, more preferably ground calcium carbonate, modified calcium carbonate, or precipitated calcium carbonate, or selected from calcium carbonate. containing minerals wherein calcium carbonate-containing minerals preferably comprise dolomite or waste products from calcium carbonate flotation, or mixtures thereof. 18. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor det hvide mineral er et calciumkarbonat-baseret mineral blandet med ler eller talkum eller calciumhydroxid eller calciumsulfat, eller er calciumkarbonat-kaolin blandinger eller blandinger af calciumkarbonat og bentonit, eller blandinger af naturligt calciumkarbonat med aluminiumhydroxid, magnesiumhydroxid, mica eller med syntetiske eller naturlige fibre eller er co-strukturer af mineraler, fortrinsvis talkum-calciumkarbonat eller talkum-titandioxid eller calciumkarbonat-titandioxid co-strukturer.A process according to any one of the preceding claims, wherein the white mineral is a calcium carbonate-based mineral mixed with clay or talc or calcium hydroxide or calcium sulfate, or is calcium carbonate-kaolin mixtures or mixtures of calcium carbonate and bentonite, or mixtures of natural calcium carbonate with aluminum hydroxide, magnesium hydroxide, mica or with synthetic or natural fibers or are co-structures of minerals, preferably talc calcium carbonate or talc titanium dioxide or calcium carbonate titanium dioxide co-structures. 19. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor det opnået tørrede partikelmateriale er calciumkarbonat med et faststofindhold på mere end 95 vægtprocent, baseret på den samlede vægt af calciumkarbonatet.A process according to any one of the preceding claims, wherein the dried particle material obtained is calcium carbonate having a solids content greater than 95% by weight, based on the total weight of the calcium carbonate. 20. Anvendelse af fremgangsmåden ifølge et hvilket som helst af kravene 1 til 19 for fremstilling af calciumkarbonat med et faststofindhold på mere end 95 vægtprocent, baseret på den samlede vægt af det våde calciumkarbonat, hvor calciumkarbonatet er fortrinsvis fremstillet uden tilstedeværelsen af en separator.Use of the process according to any one of claims 1 to 19 for the preparation of calcium carbonate having a solids content greater than 95% by weight, based on the total weight of the wet calcium carbonate, wherein the calcium carbonate is preferably made without the presence of a separator.
DK11162729.5T 2011-04-15 2011-04-15 Process for drying wet particulate matter, wherein the dried particle material is a white mineral having a brightness Ry of at least 65%, by drying in a direct superheated steam dryer DK2511637T3 (en)

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CA2831859A1 (en) 2012-10-18
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