DK202300159A1

DK202300159A1 - Gas pressure balance method in an electrolyser system, and electrolyser system with a pressure balance valve system

Info

Publication number: DK202300159A1
Application number: DKPA202300159A
Authority: DK
Inventors: Gøbel Füchtbauer Henrik
Original assignee: Green Hydrogen Systems As
Priority date: 2023-02-22
Filing date: 2023-02-22
Publication date: 2024-09-02
Also published as: DK181935B1; WO2024175690A1

Abstract

In a gas pressure balance method in an electrolyser system a predefined pressure difference between pressures in an oxygen gas separation tank and a hydrogen gas separation tank is maintained by controlled release of gases through an oxygen back pressure valve and a hydrogen back pressure valve. in a first step, for each of the oxygen back pressure valves and the hydrogen back pressure valves, a predefined, calibrated pilot gas pressure is generated and in a second step, the predefined, calibrated pilot gas pressures are forwarded to the respective back pressure valves and in a third step, hydrogen and oxygen gasses are released whenever the gas pressures in the hydrogen and oxygen separation tanks exceeds the predefined, calibrated pilot pressure in the respective pilot gas streams.

Description

DK 2023 00159 A1 1

Gas pressure balance method in an electrolyser system, and electrolyser system with a pressure balance valve system. & introduction

In electrolyser systems, such as in pressurised alkaline water electrolysers having a cell stack and product separation tanks for product depletion of electrolytes drawn from the cell stacks, it is a well-known problem, that maintaining a pressure balance in the hydrogen and oxygen gas separation tanks is a challenging task. According to the invention, an improved or at least alternative method and system is provided to ensure a predefined pressure balance in the two product tanks. In the following description, the gases released by electrolysis of water namely hydrogen and oxygen are referred to as product gases. Initially the gases are more or less embedded in lye streams gleaned off the electrolyser stacks, but the gases are released from the lye in the gas/lye separator tanks. 3, Claims axplanations

According to an aspect of the invention, a gas pressure balance method in an electrolyser system is provided whereby a predefined pressure difference between pressures in an oxygen gas separation tank and a hydrogen gas separation tank, with the tanks being connected to each their output side of a water electrolyser stack or multitude of stacks, is maintained by controlled release of gases through an oxygen back pressure valve and a hydrogen back pressure valve arranged in fluid connection with the respective separation tank.

According to this aspect of the invention, in a first step, for each of the oxygen back pressure valves and the hydrogen back pressure valves, a predefined, calibrated pilot gas pressure is generated by a feed and bleed valve system in a pilot gas stream and in a second step, the predefined, calibrated pilot gas pressures are forwarded to the respective back pressure valves and in a third step, hydrogen is released from the hydrogen gas separation tank through the hydrogen back pressure valve whenever the gas pressure in the hydrogen separation tank exceeds the predefined, calibrated pilot pressure in the first pilot gas stream, and oxygen is released from the oxygen gas separation tank through the oxygen back pressure valve whenever the gas pressure in the oxygen gas separation tank exceeds the predefined, calibrated pilot pressure in the second pilot gas stream.

With this system, a very agile and precise regulation of the pressures in the two separation tanks is provided, and a precise pressure difference between the tanks, possibly a zero-pressure difference, may be maintained. Also, quick adaptations to demands of a change in pressure difference will be possible. This is mainly due to the fact that very little mass needs to be moved or accelerated in order to change the setting of the gas release valves when they are guided by a pilot

DK 2023 00159 A1 2 gas pressure. This works particularly well when a dome loaded valve is employed as the gas release valve as for this setup, the pilot gas and the membrane are all that need to budge in order to change the setting of the valve, and both of these work with very little friction and comprise a minimum of masses.

In a further embodiment, the feed and bleed valve system comprises a bleed valve which bleeds off a pilot gas through a bleed orifice to ambient pressure or similarly low pressure, and where the feed and bleed valve system further feeds pilot gas to the bleed valve through an adjustable feed valve, such that pilot gas at the desired pressure is achieved between the bleed valve and the feed valve by adjusting the feed valve opening degree.

This arrangement ensures a precise pilot gas pressure, and keeps the reaction time very low, so that there is a very small time lag from the occurrence of a new input value, such as a pressure value signal from measurements of pressure or pressure difference in one or both separation tank or tanks, until the correction in pilot gas pressure is provided between the feed and the bleed valve.

In an embodiment, the first pilot gas stream and the second pilot gas stream are generated by supplying a pressurised pilot gas to a gas pump, and a pressurised booster gas is supplied such as pressurised atmospheric air to a motor whereby the motor drives the gas pump and thereby increases the pressure of the pressurised pilot gas stream, and where further, the pilot gas stream is branched into a first pilot gas stream and second pilot gas stream both having pressures well above the pressures needed to close off back pressure valves for the hydrogen and the oxygen gas separation tanks.

The pressure needed in the pilot gas stream in order to close off a product gas must, by the nature of the oxygen and hydrogen back pressure valves, be higher than the pressures in the respective separation tanks. This high pressure may be generated in a local booster pump, which picks up a pilot gas at a predefined delivery pressure and pressurises it further to the needed pilot gas operation pressure. This may be beneficial in cases where pressure levels not usually available in industrial gases is needed to control the back pressure valves. It is preferred to have the booster pump driven by pressurised air, which is readily available. If an inert or partially inert gas such as nitrogen gas is used as the pilot gas, only one booster pump is needed, and the thereby sufficiently pressurised pilot gas may be branched off to reach each of the two different feed and bleed valve arrangements.

In a further embodiment of the method, the first pilot gas stream is derived from the oxygen pipe and the second pilot gas stream is derived from the hydrogen pipe and furthermore, the two pilot gas streams are boosted by way of each their product gas pump whereby the pumps are driven by motors powered by a source of pressurised atmospheric air.

DK 2023 00159 A1 3

This embodiment allows for the respective product gases to be used as the respective pilot gases, which is highly desirable, as it ensures, that hydrogen is used as pilot gas in a dome loaded hydrogen back pressure valve and oxygen is used as the pilot gas in a dome loaded oxygen back pressure valve. In this way, an increased security against possible mixtures of the oxygen and the hydrogen gases is provided, and a use of a third gas such as nitrogen is omitted. The two product gas booster pumps are preferably driven by a motor powered by pressurised atmospheric air.

In a further embodiment of the method, the gas stream which is continually leaked from the bleed valves of the feed and bleed valve systems are piped to each their gas quality control measurement device and furthermore, a supplement product gas supply valve is arranged in a supplement gas pipe between each of the product gas pipes and the respective gas quality control measurement device whereby this supplement product gas supply valve is guided by a signal derived from a fluid flow measurement device arranged between the bleed valve and the respective gas recipients.

This embodiment ensures, that the gases which escape the bleed valves are used in a gas quality meter. The gas quality meter is a safety requirement and thus a gas stream necessarily must be provided for this purpose, and in case the product gases are used as pilot gas, the bleed off from the bleed valve may as well be used for this purpose too. In order for the gas quality meters to also work when the gas stream is low or pressures are low, a supplemental product gas is provided circumventing the feed and bleed valve system.

The invention also comprises an electrolyser system which has a pressure balance valve system, whereby an oxygen separation tank and a hydrogen separation tank are provided with each their pipe connection to respective sides of separation diaphragms in one or more electrolyser stacks, and an oxygen back pressure valve and a hydrogen back pressure valve, coupled to the respective separation tanks through piping, are provided and adapted to open for controlled release of oxygen and hydrogen product gases at predefined product gas separation tank pressures.

According to this aspect of the invention, the back pressure valves are adapted to open for release of product gas against a predefined pilot gas pressure, and further the feed and bleed valve system generates the predefined pressure from high pressure gas in a pipe interconnecting a feed valve and a bleed valve where the bleed valve is adapted to deliver a bleed off of pilot gas to low pressure, and the feed valve is adapted to be regulated to deliver pilot gas into the pipe interconnecting the feed valve and bleed valve such that the desired predefined pressure is maintained in the pipe between the feed valve and the bleed valve.

The feed valve may preferably be regulated by a PLC setpoint generator, where the setpoint generator amongst others, receives signals indicative of the pressure in the gas separation tank to be regulated, and/or receives a measure of the pressure difference between the two separation tanks as well as the actual pressure in the pipe between the bleed valve and the feed valve, and

DK 2023 00159 A1 4 regularly calculates a revised setting for the opening degree of the feed valve. Agile and expedient generation of the calibrated pilot gas pressure in the pipe between the feed and the bleed valve is assured in this way.

The electrolyser system further comprises a pilot gas source which is connected to a gas pump, where the pump is adapted to act as a booster to further pressurise the pilot gas stream, whereby the pilot gas pump is adapted to be driven by a motor which is adapted to receive its driving energy from a source of pressurised atmospheric air.

If a local pilot gas source is used such as pressurised nitrogen, a boost of the pressure of the nitrogen may be needed. With the nature of the electrolyser plant, with oxygen and hydrogen gases under pressure, it is preferred to use a method of compression, which leaves out the risk of electric sparks, electric heating and similar issues and rely on the less hazardous driver of pressurised atmospheric air. Also, the stream of decompressed atmospheric air, which necessarily must exit such a motor, may be used to ensure air renewal in parts of the plant, where air exchange rates are mandatory. Preferably, the motor is supplied with a driver gas stream having a lower pressure than the pressure in the high-pressure pilot gas stream delivered by the pump.

In an embodiment of the invention, the first pilot gas stream originates from the oxygen pipe and is connected to the feed and bleed valve system through a gas booster pump and the second pilot gas stream originates from the hydrogen pipe and is connected to the feed and bleed valve system through a further gas booster pump such that the feed and bleed valve arrangements are provided with product gas for the first and second pilot gas streams.

Using the product gas streams directly as the pilot gas to control the opening and closing of the hydrogen and oxygen release valves requires that the product gas pressure in the pilot gas stream be increased, and thus the pilot gas streams in this case are pressure boosted. Preferably, a compressed air driven pump is used for the boosting of the two pilot gas streams derived from each their product gas stream. When hydrogen is used to regulate the hydrogen back pressure valve, and oxygen is used to regulate the oxygen back pressure valve, there is no risk that hydrogen and oxygen gases are mixed.

In an embodiment of the invention, the back pressure valve is a dome loaded valve, where the pilot pressure is provided on the one side of a membrane, where the product gas side of the membrane is adapted to abut two sets of orifices: a first set of orifices, which are in fluid communication with the mentioned product separation tank, and a second set of orifices which are in communication with a recipient for the respective product gas.

When the membrane abuts the two sets of orifices, product gas is prevented from moving through the valve, and when the membrane is elevated due to higher pressure on the product gas side

DK 2023 00159 A1 thereof, the valve is open, and gas will pass from the first set of orifices to the second set of orifices.

The valve may well be made with orifices placed in concentric circles with inlet orifices placed in a first half-circle and outlet orifices in an opposed second half of the same circle. This placement allows for a gradual opening and closing action of the valve, and this ensures, that regulation 5 characteristics are the same regardless of the opening degree.

In an embodiment, in a gas exit pipe between the bleed valve and a product gas recipient, a gas quality control measurement device is arranged and furthermore, a supplement product gas supply valve is arranged in a supplement gas pipe between each of the product gas pipes and the respective gas quality control measurement device whereby this supplement product gas supply valve is arranged to be guided by a signal derived from a fluid flow measurement device arranged between the bleed valve and the respective gas recipients at a far end of a gas exit pipe.

The supplement gas pipe ensures that even when the flow through the bleed valve is too low to ensure a reliable gas quality measurement, reliable data are obtained. During steady state production the supplement product gas supply valve is closed, and the gas flowing out of the bleed valve will be sufficient.

Brief description of the figures.

S00 List af Syures

Fig. 1 is a schematic representation of a system according to the invention,

Fig. 2 shows a schematic representation of a further system according to the invention,

Fig. 3 discloses a schematic representation of a system wherein oxygen pressure is lead,

Fig. 4 shows a gas back pressure valve,

Fig. 5 is a schematic view of a pilot gas pressure regulation valve of the dome loaded kind with an accompanying feed and bleed valve system,

Fig. 6 shows a schematic representation of the re-use of the excess gases from the bleed valve in a gas quality surveillance device and

Fig. 7 is a schematic representation of a system including booster pumps 47 adapted to boost the pressure of the product gases to be used as pilot gas.

S Doataled desoriplion

Various exemplifying and non-limiting embodiments both as to constructions and to methods of operation, together with additional objects and advantages thereof, will be best understood from the following description of specific exemplifying and non-limiting embodiments when read in conjunction with the accompanying drawings.

The verbs "to comprise” and "to include” are used in this document as open limitations that neither exclude nor require the existence of unrecited features. The features recited in dependent claims are mutually freely combinable unless otherwise explicitly stated. Furthermore, it is to be

DK 2023 00159 A1 6 understood that the use of “a” or “an”, i.e. a singular form, throughout this document does not exclude a plurality. 8. Bleotrofyser and gas releases valves

The system disclosed in Fig. 1 comprises a source such as a gas separation tank 1,2 for each product gas from an electrolyser stack. Each source 1,2 is indicated by a circle in the figures and comprises a gas/electrolyte separation tank 1,2. The hydrogen gas separation tank 2 receives the catholyte and hydrogen (product) gas mixture from the first side 19 of separation diaphragms 17 of one or more stacks 3, via a catholyte and hydrogen gas line 37. The oxygen separation tank 1 receives the anolyte and oxygen gas (product) mixture from a second side 20 of the separation diaphragm or diaphragms 17 of the same stack 3 or stacks via an anolyte and oxygen gas line 36.

Each of the oxygen and hydrogen separation tanks 1,2 may receive gas/electrolyte mixtures from one or more electrolyser stacks 3. Usually, a stack 3 comprises a multitude of pairs of electrolytic chambers, each such pair being separated by a diaphragm 17, however for the sake of simplifying the drawing only one such pair of chambers is illustrated in Fig. 1. In the example given in Fig. 1, product depleted anolyte in an anolyte pump back line 34 and product depleted catholyte in a catholyte pump back line 35 reach each their respective side of the diaphragm or diaphragms 17 to completely separate anolyte and catholyte flow circuits. In other electrolyser systems for the generation of hydrogen from water, the anolyte and catholyte flows are mixed prior to the introduction of the electrolyte in the cathodic and anodic chambers of the stack. Pumps and heat exchangers in the return pipes to the stacks are not disclosed in Fig. 1 but may well be provided to enhance fluid flow and ensure temperature adjustment of the fluids to be introduced into the stack.

The pressure in the two tanks 1,2 should be maintained in balance to ensure that the pressures at each side of the diaphragm 17 in the stack 3 are alike and do not deviate from each other beyond predefined limits. This is obtained by a controlled release of product gases namely oxygen and hydrogen through controlled back pressure valves 4,5 arranged in gas pipes adapted to pipe the produced gases to recipients 45, 46 thereof. A hydrogen pipe 38 ensures passage from the hydrogen gas separation tank 2 and the hydrogen back pressure valve 4, and an oxygen pipe 39 ensures passage from the oxygen gas separation tank 1 and the oxygen back pressure valve 5.

Each of the back pressure valves 4,5 is controlled by a dedicated pilot gas having each its pilot gas pressure. 7 Dome nade valve

In one form, the back pressure valve 4,5 is a dome loaded valve 22, where the pilot pressure is provided on the closing pressure side 16 of a membrane 23, where the product gas side 18 of the membrane 23 is adapted to abut two sets of orifices: a first set of orifices 24, which are in fluid communication with the mentioned product separation tank, and a second set of orifices 25 which are in communication with a recipient (not shown) for the respective product gas. When the pressure on the closing pressure side 16 of the membrane is higher than the pressure on the

DK 2023 00159 A1 7 product gas side 18, the two sets of orifices are closed as the membrane 23 is pressured towards the orifices 24,25 and vice versa: when the pilot pressure is lower than the product pressure, the membrane 23 is lifted off the two sets of orifices 24,25 as seen in Fig. 5, and gas shall pass through the valve 22 from the respective connected gas separation tanks 1,2 to the recipient (not shown).

The dome loaded valve 22 is very agile as both internal friction and moved masses during opening or closing are minimal. Also, this type of valve tends to maintain unchanged dynamic characteristics throughout its opening range.

J. Piafon vyalva with args exs hange

In a further form, the back pressure valve 4,5 as schematically shown in Fig. 4 is a piston valve member 21. The valve member 21 has a piston 26 which at a first end 27 has a gas pressure impact area A+ for moving the piston 26 in a first direction and at a second end 28 has another gas pressure impact area Az for moving the piston in a second, opposed direction. In the design of the valve disclosed in Fig. 4, the first gas pressure impact area A: is adapted to be in fluid communication with the pilot gas, and the second gas impact area A: is adapted to be charged with the product gas at its product gas pressure. When the product gas pressure increases to a level where this pressure is able to move the piston in the second direction (upwards in Fig. 4), an opening 29 will be provided for the product gas to escape therethrough to reach an outlet. The outlet shall be connected to a recipient (not shown) for the product gas. The pressure in the pilot gas maintains the valve in a closed position whenever the quotient product gas pressure/pilot gas pressure is bigger than the A+/Az quotient. A difference in the Ar and A: areas allows for the valve to close even if the pilot gas pressure is below the product gas pressure. In an embodiment shown in Fig. 4, the piston 26 is adapted to move in a cylinder 30 and comprises piston rings or O-rings 31 or the like gasketing between piston 26 and cylinder 30 at both the A: and Az ends of the piston 26.

Other kinds of pistons, such as bellows sealed pistons and cylinder pairs may be used for reduced friction and inertia and increase agility of the valve 21. The piston 26 may be made from a lightweight material such as a polymer, and/or may be hollow to ensure that the moved mass remains as small as possible to ensure good closing and opening characteristics of the valve. $. Das pressure halanos method

As seen in Figs. 1, 2 and 3 a feed and bleed valve system 12 is arranged to deliver a predefined pilot gas pressure to control the opening pressure of either a dome loaded valve 22 or a piston valve member 21. If a dome loaded valve 22 is used, the pilot gas pressure needs to be higher than the pressure in the product gas in order to move the membrane 23 towards the two sets of orifices 24, 25. To produce the necessary pressure in the first and second pilot gas streams, the pilot gas streams are produced by boosting the pressure of a pre-pressurised nitrogen gas stream 9. As shown in Fig. 1, this is done by feeding the pre-pressurised nitrogen gas stream 9 through a gas pump 8 which is driven by a motor 11, such that the nitrogen gas stream 9 leaves the pump at a higher pressure than its entering pressure. In the embodiment in Fig. 1, the motor 11 is driven by a stream of compressed air 10. A gearing or other mechanical exchange between the compressed

DK 2023 00159 A1 8 air driven motor 11 and the gas pump allows for the pump 8 to deliver the pilot nitrogen gas at a pressure well above the highest pressure of any of the product gases. Any inert gas or gas composition other than nitrogen may be used as pilot gas. As seen in Fig. 1, the boosted pressurised nitrogen gas is split into a first pilot gas stream 6 and a second pilot gas stream 7.

TE, DC safpoint generation

Feed and bleed valve systems 12 are arranged to downsize the pilot gas stream 6,7 pressures according to a PLC generated setpoint for controlled release of product gases 38, 39. The setpoints for the hydrogen and oxygen back pressure valves 4,5 are derived from a pressure or pressure difference signals 40, 41 originating from pressure measurement in the product gas streams 38, 39 as seen in Fig. 1 and Fig. 2. The setpoint is determined under the guidance of a PLC release pressure setpoint generator 32, 33. PLC setpoint generators 32, 33 are programmable devices, which will be able to take into account a range of parameters, such as time constants of the system, electric power provided to the electrolysers, signals derived from time dependent pressure changes of the measured input pressure signals and the like, especially differential and integration signals. In Fig. 5, the setpoint generator 32,33 controls the opening degree of the pilot gas feed valve 14 based on the calculated setpoint and the pressure P between the feed valve 14 and the bleed valve 13. The setpoint may be calculated from the pressure in the gas separation tank from which product gas is to be released, in which case, the pressure in the other gas separation tank shall be guided by the differential pressure between the two tanks. This is illustrated in Fig. 1 and Fig 2. In Fig. 2 as well as in Fig. 1, the gas pressure signal 40 from the pressure in the hydrogen pipe 38, which is also a measure of the pressure in the hydrogen release tank 2, is served at the PLC hydrogen release pressure setpoint generator, which then calculates the setpoint for the feed valve 14. Furthermore, the pressure difference signal 41 is served at the

PLC oxygen release pressure setpoint generator 33, in order for the setpoint generator 33 to calculate a setpoint for the feed valve 14 to control the release of oxygen through the oxygen back pressure valve 5. In this way, the pressure in the oxygen pipe 39 which again is a measure of the pressure in the oxygen gas separation tank 1 may be guided to follow or deviate in a predetermined manner from the pressure in the hydrogen gas separation tank. In Fig. 3, a similar system is shown, however here the pressure in the oxygen tank 1 via pressure signal 40.1 from the pipe 39 is used to direct the release of oxygen, while the differential pressure signal 41 between the pressure in the hydrogen and the oxygen separation tanks guides the release of the hydrogen.

The setpoints from the PLC devices are used in the feed and bleed valve systems 12 to regulate the setting of the feed valves 14 seen in Figs. 1, 2, 3, and 6. Increased pilot gas feed through the feed valve 14 into pipe 48 will thereby cause an increase in the calibrated pressure 6.1,7.1 delivered out of the feed and bleed valve system 12 to back pressure valves 4,5. By monitoring the pressure in the pipe 48 between the feed valve 14 and the bleed valve as indicated in Fig. 5 by pressure monitor P, the difference between a setpoint which has been calculated in PLC 32 or 33

DK 2023 00159 A1 9 and the present measured calibrated pressure may be determined, and a corresponding regulation action signal forwarded to the regulated feed valve 14. The shown bleed valve 13 may be a regulatable or an un-regulatable valve. If valve 13 is a regulatable valve, the bleed flow may be increased or decreased according to need. In case the need for regulation of the setting of back pressure valves 4,5 is very limited, such as in a hot stand by situation, very little bleed of gases is required to maintain a setting of the back pressure valves 4,5 and followingly the bleed rate can be maintained very small. In other kinds of settings, where fast opening or closing action of the back pressure valves is required, a higher bleed rate is beneficial, as it allows for faster pressure drops in the pipe segments 7.1, 6.1 between the feed and bleed valves.

In the Fig. 2, Fig. 3, Fig. 6, and Fig. 7 embodiments, the pilot gas for the hydrogen release valve 4 is hydrogen derived from the hydrogen separation tank, and the pilot gas for the oxygen release valve 5 is the oxygen derived from the oxygen separation tank. In these cases, it will be necessary to either boost the pilot gas pressures to be able to feed pilot gas through the feed and bleed valve system 12 and provoke a calibrated output pilot gas pressure, which is sufficient for the closing of a dome loaded valve 22, or alternatively use a back pressure valve 4,5 which will close at a lower pilot gas pressure than the back pressure in the pipes 38, 39 respectively. In case boost of the pilot gas, which is now also production gas, is used, pressurised atmospheric air may be used in a set of motors, which drives each their gas pump 47 operating on gas supplied from the gas separation tanks to control each of the dome loaded valves. This is indicated in Fig. 7. In this way the valve controlling the outflow of hydrogen is loaded with hydrogen for the control of the membrane 23, and followingly the valve controlling the outflow of oxygen is loaded with oxygen for the control of the membrane 23. Improved security is achieved in that the risk of oxygen and hydrogen mixing is minimised.

It is also possible to introduce a pressure drop in the oxygen and hydrogen pipes 38,39 between the pilot gas branches 6,7 and the back pressure regulators 4,5 to thereby ensure that there is always a higher pressure in the branches 6,7 than at the back pressure regulators 4,5. This may however lead to lower output pressure at the recipients 45, which is un-desirable.

Alternatively, a back pressure regulated piston valve 21 as shown in Fig. 4 may be used, wherein a closing action area A; at a first end 27 of a back pressure valve piston 26, is charged with the pilot gas pressure, and is somewhat larger than the opening action area A: of a second end 28 of the back pressure valve piston 26, which is charged with the pressure within the respective separation tank. The release valve piston 26 is adapted to regulate an opening 29 which closes off a product gas stream therethrough, whenever the in-equation:

Az x product gas pressure < Aj x pilot gas pressure

DK 2023 00159 A1 10 is true. As seen, A1 is somewhat larger than Az, and thus even when a calculated pressure loss through the feed and bleed valve system 12 for the generation of the right pilot gas pressure is accommodated, it will always be able to provide the needed pressure to close the valve 21 with the use of the product gas and un-boosted product gas pressure as the pilot gas and pilot pressure.

This is indicated in Fig. 6, where there is no boost of the pilot gas streams 6,7. It is preferred that 11xXA<A <2xA

By ensuring the relation that A: is between 1.1 times bigger and no more than 2 times bigger than

Az, it will always be possible to close the valve, and a good precision is obtainable. If a better precision and dynamic performance is desired, it is preferred that 1.06 x A <A1<1.2X Az

By keeping A1 even closer to the area of Az such as 1.05 times bigger than A2 and no more than 1.2 times bigger than Az, even better dynamic performance may be ensured.

In Figs. 2 and 3, either boost of the pilot gas or a valve with the special back pressure valve piston 26 is used.

NS, Roun af leaked gases fhHrough the Masa valve

A gas stream will continually be leaked from the bleed valves 13 of the feed and bleed valve systems 12 described above when regulating the back pressure valves, however in the case where the product gas is used as the pilot gas, this leaked gas stream may be used in a gas quality control measurement device 15 for each of the two leaked gas streams. This is disclosed in Fig. 6. Hereby it is ensured, that the leaked gas is used to generate necessary information on the quality of the produced gases or used for the generation of safety data, such as the proportion of Hz in the Oz gas and the proportion of Oz in the produced H: gas.

A minimum flow through the gas quality control measurement device 15 is required in order to gain reliable gas quality surveillance data, and thus a supplement product gas supply valve 42 is arranged in a supplement gas pipe 44 between the product gas pipes 38, 39 and the gas quality control measurement device 15. This valve is guided by a signal derived from the fluid flow measurement device 43, such that the product gas supply valve 42 will open whenever the flow measurement device 43 registers too low flow through the gas quality control measurement device 15. 38. Hydrogen contra signal Jerived from hpdroagan pipe pressure

In Fig. 1, the pressure in the hydrogen pipe 38 will be the same as the pressure inside the hydrogen as the pressure in the separation tank 2 is used via a pressure signal 40 to regulate the hydrogen back pressure valve 4. In this embodiment, the difference pressure signal 41, which is the pressure difference between pressures in the two separation tanks 2, 1, is used to guide the release of oxygen through the oxygen back pressure valve. In the embodiment the feed and bleed

DK 2023 00159 A1 11 valve systems 12 receive pilot gas streams 6,7 in the shape of nitrogen gas, which has been pressurised to a pressure well above the maximum pressures allowable for the product gas streams. This nitrogen gas stream may well be supplanted by product gas streams which has been boosted or may be supplanted by product gas streams at the pressure in respective separation tanks 1,2 in combination with a back pressure valve member 21 with two different gas acting areas

A1, Az as disclosed in Fig. 4 and described above. 1. Oxygen gas separation tank 2. Hydrogen gas separation tank 3. Water electrolyser stack 4. Hydrogen back pressure valve 5. Oxygen back pressure valve 6. First pilot gas stream (02) 6.1. First calibrated pilot pressure 7. Second pilot gas stream (H») 7.1. Second calibrated pilot pressure 8. Gas booster pump 9. Pressurised nitrogen 10. Pressurised atmospheric air 11. Motor 12. Feed and bleed valve system 13. Bleed valve 14. Feed valve 15. Gas quality control measurement device 16. Closing pressure side of membrane 17. Diaphragm 18. Product gas side of membrane 19. First side of diaphragm or diaphragms 20. Second side of diaphragm or diaphragms 21. Piston valve member 22. Dome loaded valve 23. Membrane 24. First set of orifices 25. Second set of orifices 26. Back pressure valve piston 27. First end 28. Second end 29. Opening 30. Cylinder 31. Piston rings 32. PLC hydrogen release pressure setpoint generator 33. PLC oxygen release pressure setpoint generator 34. Anolyte pump back line 35. Catholyte pump back line 36. Anolyte and oxygen gas line 37. Catholyte and hydrogen gas line 38. Hydrogen pipe 39. Oxygen pipe 40. Pressure signal, hydrogen 40.1. Pressure signal, Oxygen 41. Pressure difference signal 42. Product gas supply valve 43. Fluid flow measurement device

DK 2023 00159 A1 12 44. Supplement product gas supply 45. Product gas recipient 46. Atmosphere recipient 47. Product gas booster pump 48. Tube interconnecting feed valve and bleed valve

Claims

DK 2023 00159 A1 13

1. Gas pressure balance method in an electrolyser system whereby a predefined pressure difference between pressures in an oxygen gas separation tank (1) and a hydrogen gas separation tank (2), with the tanks (1,2) being connected to each their output side of a water electrolyser stack (3) or multitude of stacks, is maintained by controlled release of gasses through an oxygen back pressure valve (5) and a hydrogen back pressure valve (4) arranged in fluid connection with the respective separation tank (2,3), characterised in that,

a. for each of the oxygen back pressure valve (5) and the hydrogen back pressure valve (4), a predefined, calibrated pilot gas pressure (6.1; 7.1) is generated by a feed and bleed valve system (12) in a pilot gas stream (6,7) and,

b. pilot gases at the predefined, calibrated pilot gas pressures (6.1; 7.1) are forwarded to the respective back pressure valves (4,5) and,

c. hydrogen is released from the hydrogen gas separation tank (2) through the hydrogen back pressure valve (4) whenever the gas pressure in the hydrogen separation tank (2) exceeds the predefined, calibrated pilot gas pressure (7.1), and oxygen is released from the oxygen gas separation tank (1) through the oxygen back pressure valve (5) whenever the gas pressure in the oxygen gas separation tank (1) exceeds the predefined, calibrated pilot gas pressure (6.1).

2. Gas pressure balance method as claimed in claim 1, characterised in that the feed and bleed valve system (12) comprises a bleed valve (13) which bleeds off a pilot gas through a bleed orifice to ambient pressure or similarly low pressure, and whereby the feed and bleed valve system (12) further feeds pilot gas to the bleed valve (13) through an adjustable feed valve (14), whereby pilot gas at the desired calibrated pressure (7.1; 6.1) is achieved in a tube (48) between the bleed valve (13) and the feed valve (14) by adjusting the feed valve (14) opening degree.

3. Gas pressure balance method as claimed in claim 1 or claim 2, characterised in that the two pilot gas streams (6,7) are generated by supplying a pressurised pilot gas to a gas pump (8), and supplying a pressurised booster gas such as pressurised atmospheric air (10) to a motor (11) and driving the gas pump (8) by the motor (11) and thereby increasing the pressure of the pressurised pilot gas stream, and branch the thereby further pressurised pilot gas into a first pilot gas stream (6) and second pilot gas stream (7) both having pressures well above the pressures needed to close off the back pressure valves (4,5) of the hydrogen and the oxygen gas separation tanks (1,2).

4. Gas pressure balance method as claimed in claim 1 or claim 2, characterised in that the first pilot gas stream (6) is derived from and oxygen pipe (39) and the second pilot gas

DK 2023 00159 A1 14 stream (7) is derived from a hydrogen pipe (38) and that the two pilot gas streams are boosted by way of each their product gas pump (47) whereby the pumps (8) are driven by motors (11) powered by a source of pressurised atmospheric air (10).

5. Gas pressure balance method as claimed in claim 4, characterised in that a gas stream leaked from the bleed valves (13) of the feed and bleed valve systems (12) are piped to each their gas quality control measurement device (15 ) and that further a regulatable supplement product gas supply valve (42) is arranged in a supplement gas pipe (44) between each of the product gas pipes (38, 39) and the respective gas quality control measurement device (15) whereby this regulatable supplement product gas supply valve (42) is guided by a signal derived from a fluid flow measurement device (43) arranged between the bleed valve (13) and the respective gas recipients (46).

6. Electrolyser system with a pressure balance valve system, whereby an oxygen separation tank (1) and a hydrogen separation tank (2) are provided with each their pipe connection to respective sides of separation diaphragms (17) in one or more electrolyser stacks (3), and an oxygen back pressure valve (4) and a hydrogen back pressure valve (5) coupled to the respective separation tanks (1,2) are provided and adapted to open for controlled release of oxygen and hydrogen product gasses at predefined product gas separation tank pressures characterised in that, the back pressure valves (4,5) are adapted to open for release of product gas against a predefined calibrated pilot gas pressure (6.1; 7.1), and whereby a feed and bleed valve system (12) generates the predefined calibrated pilot gas pressure in a pilot gas in a tube (48) interconnecting a feed valve (14) and a bleed valve (13) where the bleed valve (13) is adapted to deliver a bleed off of pilot gas from the tube to low pressure, and the feed valve (14) is adapted to be regulated to deliver the desired predefined calibrated pressure (6.1;7.1) of pilot gas in the tube (48).

7. Electrolyser system as claimed in claim 6, characterised in that the first pilot gas stream (6) originates from an oxygen product gas pipe (39) and is connected to the feed and bleed valve system (12) through a gas booster pump (8) and the second pilot gas stream (7) originates from a hydrogen product gas pipe (38) and is connected to the feed and bleed valve system (12) through a further gas booster pump (8) such that the feed and bleed valve arrangements (12) are provided with product gas for the first and second pilot gas streams (6,7).

8. Electrolyser system as claimed in claim 6, characterised in that, a pilot gas source is connected to a gas pump (8), which is adapted to act as a booster and to further pressurise the pilot gas stream, and that the pilot gas pump (8) is adapted to be driven by a motor (11) which is adapted to receive its driving energy from a source of pressurised air (10).

DK 2023 00159 A1 15

9. Electrolyser system as claimed in claim 7 or in claim 8, characterised in that, the back pressure valve (4,5) is a dome loaded valve (22), where the pilot pressure is provided on a far side (16) of a dome membrane (23), where the near side (18) of the dome membrane (23) is adapted to abut two sets of orifices: a first set of orifices (24), which are in fluid communication with the mentioned product separation tank, and a second set of orifices (25) which are in communication with a recipient for the respective product gas.

10. Electrolyser system as claimed in claim 7 or in claim 9, characterised in that, in a gas exit pipe (45) between the bleed valve (13) and a recipient, a gas quality control measurement device (15) is arranged and that further a supplement product gas supply valve (42) is arranged in a supplement gas pipe (44) between each of the product gas pipes (38, 39) and the respective gas quality control measurement device (15) whereby this supplement product gas supply valve (42) is arranged to be guided by a signal derived from a fluid flow measurement device (43) arranged between the bleed valve (13) and respective gas recipients (45).