DK153660B - HEAT TRANSFER LABEL - Google Patents
HEAT TRANSFER LABEL Download PDFInfo
- Publication number
- DK153660B DK153660B DK346270AA DK346270A DK153660B DK 153660 B DK153660 B DK 153660B DK 346270A A DK346270A A DK 346270AA DK 346270 A DK346270 A DK 346270A DK 153660 B DK153660 B DK 153660B
- Authority
- DK
- Denmark
- Prior art keywords
- wax
- heating
- oxidized
- label
- transfer
- Prior art date
Links
- 238000010438 heat treatment Methods 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 239000003085 diluting agent Substances 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 238000007127 saponification reaction Methods 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 239000001993 wax Substances 0.000 description 37
- 238000001816 cooling Methods 0.000 description 7
- 239000000976 ink Substances 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 3
- 238000005352 clarification Methods 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WCOXQTXVACYMLM-UHFFFAOYSA-N 2,3-bis(12-hydroxyoctadecanoyloxy)propyl 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC(O)CCCCCC)COC(=O)CCCCCCCCCCC(O)CCCCCC WCOXQTXVACYMLM-UHFFFAOYSA-N 0.000 description 1
- 229920003345 Elvax® Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- MOYKHGMNXAOIAT-JGWLITMVSA-N isosorbide dinitrate Chemical compound [O-][N+](=O)O[C@H]1CO[C@@H]2[C@H](O[N+](=O)[O-])CO[C@@H]21 MOYKHGMNXAOIAT-JGWLITMVSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- VLTOSDJJTWPWLS-UHFFFAOYSA-N pent-2-ynal Chemical compound CCC#CC=O VLTOSDJJTWPWLS-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/172—Decalcomanias provided with a layer being specially adapted to facilitate their release from a temporary carrier
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31801—Of wax or waxy material
- Y10T428/31804—Next to cellulosic
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
- Printing Methods (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
- Labeling Devices (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Decoration By Transfer Pictures (AREA)
Description
Den foreliggende opfindelse angår en etikette til overføring ved opvarmning bestående af en bærer og en derpå anbragt overføringsbelægning, der indbefatter en oxideret voks, fremkommet som reaktionsprodukt ved oxidation af en hydrocarbonvoks, hvilken belægning har et smeltepunkt mellem 50°C og 110°C, et syretal mellem 5 og 40, et forsæbningstal mellem ca.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a label for transfer by heating consisting of a carrier and a transfer coating applied thereto including an oxidized wax produced as a reaction product by the oxidation of a hydrocarbon wax having a melting point between 50 ° C and 110 ° C. acid number between 5 and 40, an saponification number between approx.
25 og 150 og en penetrometerhårdhed under 15, målt med 100 g i 5 sekunder, hvilken voks er en oxideret, delvis for-estret og delvis forsæbet montanvoks, som ved en temperatur på mindst 13°C over dens størkningspunkt har en smelteviskositet på mindst ca. 150 centipoise25 and 150 and a penetrometer hardness below 15, measured at 100 g for 5 seconds, which is an oxidized, partially esterified and partially saponified montane wax which at a temperature of at least 13 ° C above its solidification point has a melt viscosity of at least approx. 150 centipoise
Fra ansøgning nr. 4906/67 kendes en etikette af denne art, hvori den nævnte montanvoks findes i belægningen i en mængde på mindst 50 vægt%.Application No. 4906/67 discloses a label of this kind in which said montane wax is present in the coating in an amount of at least 50% by weight.
Det har nu ifølge opfindelsen vist sig, at når belægningen indeholder et harpiksadditiv (eller fortyndingsmiddel), kan mængden af den oxiderede montanvoks reduceres, og samtidig opnås en forbedret glans og påtrykkelighed af etiketten.It has now been found according to the invention that when the coating contains a resin additive (or diluent), the amount of the oxidized montane wax can be reduced, and at the same time an improved gloss and printability of the label is obtained.
Etiketten ifølge opfindelsen er derfor ejendommelig ved, at belægningen indeholder et harpiksadditiv (eller fortyndingsmiddel), og at den oxiderede montanvoks udgør mindst 30%, beregnet på vægten af overføringsbelægningen.The label of the invention is therefore characterized in that the coating contains a resin additive (or diluent) and that the oxidized montane wax is at least 30%, based on the weight of the transfer coating.
Ifølge opfindelsen har det vist sig, at klare billeder kan tilvejebringes på modtageflader af etiketten, når der anvendes den ovenfor beskrevne belægning, som er mere detaljeret beskrevet i det følgende. Efter overføringen bortsmeltes den voksmasse, som sammen med billedet er blevet overført til den mod tagende flade, ved hjælp af en varm luftstrøm eller andre passende midler med høj temperatur, som opvarmer voksmassen til eller over dens smeltepunkt med minimumopvarmning af den underliggende overflade, efterfulgt af afkøling for at størkne voksmassen i klar, glat tilstand. Køling blot ved hjælp af den omgivende atmosfære er normalt tilfredsstillende, selv om tvungen køling kan anvendes til hurtigere og til tider bedre afklaring og specielt er nyttig, hvor produktet straks skal behandles som f.eks. ved indpakning.According to the invention, it has been found that clear images can be provided on receiving surfaces of the label when using the coating described above, which is described in more detail below. After the transfer, the wax mass which has been transferred with the image to the receiving surface is removed by a hot air stream or other suitable high temperature means which heats the wax mass to or above its melting point with minimum heating of the underlying surface, followed by cooling to solidify the wax mass in clear, smooth condition. Cooling simply by using the ambient atmosphere is usually satisfactory, although forced cooling can be used for faster and sometimes better clarification and is especially useful where the product is to be treated immediately, e.g. by wrapping.
Opfindelsen forstås bedre ved henvisning til den tilhørende tegning, hvor fig. 1 er et tværsnit af en etikette ifølge opfindelsen, \ fig. 2 et blokdiagram, der illustrerer fremstillingen af de anvendte modificerede montanvoksarter, og fig. 3 et skematisk, isometrisk billede af et apparat til frembringelse af en stråle af en luftart med høj temperatur og rettet mod det overførte billede til klaring af dette.The invention is better understood by reference to the accompanying drawings, in which: FIG. 1 is a cross-sectional view of a label according to the invention; FIG. 2 is a block diagram illustrating the preparation of the modified montane wax species used; and FIG. 3 is a schematic isometric view of an apparatus for producing a high temperature gaseous jet directed at the transmitted image for clarification thereof.
Den på tegningen viste etikette består af en bærer 10 af papir eller lignende, som er dækket med et overføringslag 11, der indeholder mindst 30%, målt efter vægt, af en oxideret montan-voksart, og et billede 12 er trykt på den frie side af voksbelægningen.The label shown in the drawing consists of a carrier 10 of paper or the like, which is covered with a transfer layer 11 containing at least 30% by weight, of an oxidized montane wax species, and an image 12 is printed on the free side of the wax coating.
De oxiderede montanvoksarter, der anvendes her, er tilberedt i overensstemmelse med de i fig. 2 viste metoder og kan fås i forskellige modifikationer fra American Hoechst Corporation, Mountainside, New Jersey. For eksempel kan anvendes voksarter som Hoechst^ OP, X55 0 eller "Special". Sådanne voksarter, der er udbytterige til dette, har høj smelteviskositet sammenlignet med andre mere almindelige voksarter,, som har ret lav smelteviskositet, nogle få grader over deres størkningspunkt, en egenskab, der anses for vigtig for at erholde glathed og klarhed som beskrevet. De anvendte voksarter skal således have en smelteviskositet ved 14°C over deres størkningspunkt på mindst ca. 150 centipoise. Disse voksarter er også i hovedsagen klare, når de smeltes i et væskelag med en tykkelse på ca. 6 mm eller mindre. Disse voksarter er montanvoksarter, som er blevet oxideret, forestret og delvis forsæbet ved behandlingen, som er illustreret i fig. 2. De foran nævnte voksarter har, selv om de ikke altid er beskrevet i den merkantile litteratur som oxiderede voksarter, været udsat for oxidering og har de ovennævnte specificerede egenskaber.The oxidized montane wax species used herein are prepared in accordance with those of FIG. 2 methods and are available in various modifications from American Hoechst Corporation, Mountainside, New Jersey. For example, waxes such as Hoechst ^ OP, X55 0 or "Special" may be used. Such waxes that are rich in this have high melt viscosity compared to other more common waxes, which have rather low melt viscosity, a few degrees above their solidification point, a property considered important to achieve smoothness and clarity as described. Thus, the waxes used must have a melt viscosity at 14 ° C above their solidification point of at least approx. 150 centipoise. These waxes are also generally clear when melted in a liquid layer having a thickness of approx. 6 mm or less. These waxes are montane waxes which have been oxidized, esterified and partially saponified by the treatment illustrated in FIG. 2. The aforementioned waxes, although not always described in the mercantile literature as oxidized waxes, have been subject to oxidation and have the above specified properties.
Ovennævnte voksarter i de foreskrevne mængder viser sig at være enestående med hensyn til at give klare overføringsetiketter på gennemførlig måde. Det antages, at deres komplekse sammensætning og relativt høje smelteviskositet væsentligt mindsker deres evne til krystallisering, når de afkøles, således at disse voksarter, som hovedsagelig er klare i smeltet tilstand, kan blive relativt hurtigt afkølet til en klar, fast og i det væsentlige amorf tilstandsform.The aforementioned waxes in the prescribed quantities are found to be unique in providing clear transfer labels in a feasible manner. It is believed that their complex composition and relatively high melt viscosity significantly diminish their ability to crystallize when cooled, so that these waxes, which are mostly clear in the molten state, can be cooled relatively quickly to a clear, solid and substantially amorphous state.
Overføringslagene, som anvendes ifølge opfindelsen, kan påføres bærere ved en passende metode, f.eks. ved anvendelse af emulgeringer, varme, smeltebade, eller som opløsninger. Det belagte papir bliver herpå trykt med tekst eller billeder på konventionel måde med trykkemaskiner, såsom kopipresse, rotationspresse, rotationsdybtryk, og med konventionel tryksværte i et antal af forskellige farver om ønsket, og indbefattet sværte fremstillet af metalpulver. Betegnelsen billede indbefatter, som det er anvendt i det foregående, både tryk- og billedfremstilling eller en kombination af begge dele.The transfer layers used according to the invention can be applied to carriers by a suitable method, e.g. using emulsions, heat, melt baths, or as solutions. The coated paper is then printed with text or images in conventional fashion with printing machines such as copy press, rotary press, rotary printing, and with conventional printing inks in a number of different colors if desired, including ink made from metal powder. The term image, as used above, includes both print and image production or a combination of both.
De oxiderede modificerede montanvoksarter her beskrevet er relativt viskose, sprøde og/eller kostbare, hvis de bruges alene, og de anvendes derfor sammen med et harpiksadditiv (eller fortynding smiddel ) , f.eks. som anført i US-patent nr. 2.990.311, for at forbedre pris, dækegenskaber, forhold ved belægning, glans, trykkelighed og lignende i den færdige belægning. Passende angivelser er givet i tabel 1, hvor alle angivelser refererer til vægt.The oxidized modified montane waxes described herein are relatively viscous, brittle and / or expensive if used alone, and are therefore used in conjunction with a resin additive (or diluent), e.g. as disclosed in U.S. Patent No. 2,990,311, to improve price, tire properties, coating, gloss, printability, and the like in the finished coating. Appropriate entries are given in Table 1, where all entries refer to weight.
TABEL 1.TABLE 1.
^ HoechsC^OP er en hård oxideret montanvoks, modificeret som angivet i fig. 2, og som har et dråbepunkt (ASTM 566-49) på 100 til 105°C, et størkningspunkt på 74 til 80°C (ASTM D938-49. en syreværdi på 10 til 15 og en forsæbningsværdi på 100 til 115.^ HoechsC ^ OP is a hard oxidized montane wax, modified as indicated in FIG. 2, and having a drop point (ASTM 566-49) of 100 to 105 ° C, a solidification point of 74 to 80 ° C (ASTM D938-49. An acid value of 10 to 15 and a saponification value of 100 to 115).
^ 'Hoechs-^XSS er en lignende montanvoks, som har et dråbepunkt på 98 til 103°C, et størkningspunkt på 75 til 80°C, en syreværdi på 10 til 15 og en forsæbningsværdi på 90 til 110.Hoechs-XSS is a similar montane wax having a drop point of 98 to 103 ° C, a solidification point of 75 to 80 ° C, an acid value of 10 to 15 and a saponification value of 90 to 110.
13)13)
Cardis One er en polyethylen-modificeret mikrokrystallinsk voks fra (fremstillet af) Warwick Wax Division of Western Petrochemical Corporation.Cardis One is a polyethylene modified microcrystalline wax from (manufactured by) the Warwick Wax Division of Western Petrochemical Corporation.
(4)(4)
Pentalyn H er pentaerythritolesteren af hydrogeneret harpiks, som kan fås fra Hercules Chemical Company.Pentalyn H is the pentaerythritol ester of hydrogenated resin available from Hercules Chemical Company.
(5)(5)
Elvax 410 er et blandingspolymerisat af ethylen og vinylacetat og kan fås fra E.I. duPont Company.Elvax 410 is a blend polymerized ethylene and vinyl acetate and is available from E.I. duPont Company.
Den mikrokrystallinske voks, der blev brugt i ovennævnte eksempler, var "Warco" 65°C (eksempel 2) fra Warwick Wax Division of Western Petrochemical Corporation eller'bltraflex White"(eksempel 8) fra Petrolite Corporation, ricinusvoksen var hydrogeneret ricinusolie fra Baker Chemical Company, og paraffinvoks-arten var "Sunoco 5512", som er voks fra Sun Oil Company, og som har et smeltepunkt på omkring 70°C.The microcrystalline wax used in the above examples was "Warco" 65 ° C (Example 2) from the Warwick Wax Division of Western Petrochemical Corporation or Bltraflex White "(Example 8) from the Petrolite Corporation, the castor wax was hydrogenated castor oil from Baker Chemical Company and the paraffin wax species was "Sunoco 5512" which is a Sun Oil Company wax and has a melting point of about 70 ° C.
Papiret bliver derpå - på den side, som er belagt med voks -trykt med en blank, organisk-opløsende type tryksværte. Efter at sværten er blevet tør, bliver billedet overført til den modtagende overflade ved anvendelse af rulning og trykpåvirkning fra en opvarmet overflade ved en temperatur mellem ca. 121°C og 315°C, f.eks. 177°C. Etiketten kan også være forvarmet, hvis det ønskes. Efter overføringen bliver bæreren øjeblikkeligt fjernet, medens den endnu er varm, idet den efterlader billedet fast anbragt på den modtagende flade.The paper is then - on the side coated with wax - printed with a glossy, organic-dissolving type of ink. After the ink has dried, the image is transferred to the receiving surface using scrolling and pressure exertion from a heated surface at a temperature between ca. 121 ° C and 315 ° C, e.g. 177 ° C. The label can also be preheated if desired. After the transfer, the carrier is immediately removed while still warm, leaving the image firmly affixed to the receiving surface.
Under overføringen har den smeltede voks, der overføres sammen med tryksværten, tilbøjelighed til at blive ujævn og mørk, hvilket nedsætter kvaliteten af det overførte billede.During the transfer, the molten wax transmitted together with the ink tends to become uneven and dark, which reduces the quality of the transferred image.
Man har opdaget, at for at forbedre udseendet af det overførte billede og for at få klar voks, kan det overførte billede inklusive den overførte størknede voks udsættes for stråler af varm luft, enten for en direkte gasflamme eller for en hed luft- stråle på 150°C til 200°C eller højere/ i en tid, der netop er tilstrækkelig til at smelte voksmassen. Ved disse fremgangsmåder bliver kun overfladen af billedet indbefattet voksen opvarmet, og afkøling foregår relativt hurtigt blot ved udsættelse for den omgivende atmosfære, og en klar film er resultatet. Hvis man ønsker det, kan hurtig køling imidlertid anvendes.It has been discovered that to improve the appearance of the transmitted image and to obtain clear wax, the transmitted image including the transmitted solidified wax can be exposed to hot air jets, either to a direct gas flame or to a hot air jet of 150 ° C to 200 ° C or higher / for a time sufficient to melt the wax. In these methods, only the surface of the image including the wax is heated, and cooling occurs relatively quickly simply by exposure to the ambient atmosphere, and a clear film results. However, if desired, rapid cooling can be used.
Sådan fremskyndet køling har en fordel, hvor man ønsker, at de etiketterede produkter straks behandles, med hensyn til indpakning eller lignende.Such accelerated cooling has an advantage where one wishes the labeled products to be processed immediately, for packaging or the like.
Et apparat, der er passende til omsmeltning af voksbelægningen, ses på fig. 3. En klar flaske 20 eller lignende af plast, hvorpå der er anbragt en overføringsetikette 22, er anbragt på transportøren 24 og føres forbi et par første opvarmningsstationer 26 og 28. Opvarmningsstationerne 26 og 28 får tilført gas til frembringelse af en flamme 30, der direkte rammer emnet 20 og etiketten 22, medens de bevæger sig forbi opvarmningsstationerne på transportøren 24. Transportøren 24 bevæger sig med en hastighed, så emnet føres forbi opvarmningsstationerne 26 og 28 med netop den hastighed, der er tilstrækkelig for at smelte vokslaget, som rundt om etiketten 22 klæber sig til denne, medens selve emnet 20 tilføres et minimum af varme.An apparatus suitable for remelting the wax coating is shown in FIG. 3. A clear plastic bottle 20 or the like on which a transfer label 22 is placed is placed on the conveyor 24 and passed a pair of first heating stations 26 and 28. The heating stations 26 and 28 are fed with gas to produce a flame 30 which directly striking the blank 20 and the label 22 as they move past the heating stations of the conveyor 24. The conveyor 24 moves at a speed so that the blank is passed by the heating stations 26 and 28 at precisely the speed sufficient to melt the wax layer, as around the label 22 adheres thereto while the item itself 20 is supplied with a minimum of heat.
Efter at emnet 20 har passeret opvarmningsstationerne 26 og 28, føres det forbi drejebordet 32 og imod ledeskinnen 34, hvilket tilsammen får emnet til at dreje sig, normalt omkring 90 grader, tilstrækkeligt til at dreje emnet 20, så områderne, der på grund af emnets 20 krumning ikke er opvarmede, bliver drejet udad. Derefter passerer beholderen 20 et andet par opvarmningsstationer 36 og 38, som på lignende måde opvarmer begge sider på etiketten i et tidsrum, der netop er tilstrækkeligt til at smelte voksen uden at opvarme beholderen 20 væsentligt.After the workpiece 20 has passed the heating stations 26 and 28, it is passed past the turntable 32 and towards the guide rail 34, which together causes the workpiece to rotate, usually about 90 degrees, sufficiently to rotate the workpiece 20 so that the 20 curves are not heated, are turned outwards. Thereafter, the container 20 passes another pair of heating stations 36 and 38 which similarly heat both sides of the label for a period just sufficient to melt the wax without significantly heating the container 20.
Som vist i fig. 3, er flere opvarmningsstationer 26, 28, 36 og 38 nyttige til fuldstændig opvarmning og afkøling af etiketter,As shown in FIG. 3, several heating stations 26, 28, 36 and 38 are useful for complete heating and cooling of labels,
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US85726869A | 1969-08-11 | 1969-08-11 | |
| US85726869 | 1969-08-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DK153660B true DK153660B (en) | 1988-08-08 |
| DK153660C DK153660C (en) | 1988-12-19 |
Family
ID=25325597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK346270A DK153660C (en) | 1969-08-11 | 1970-07-02 | HEAT TRANSFER LABEL |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3616015A (en) |
| DK (1) | DK153660C (en) |
| FR (1) | FR2057626A6 (en) |
| GB (1) | GB1325930A (en) |
| NL (1) | NL6919682A (en) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3894167A (en) * | 1972-04-24 | 1975-07-08 | Xavier Leipold F | Decalcomania for decorating ceramic ware |
| US3859094A (en) * | 1973-01-05 | 1975-01-07 | Minnesota Mining & Mfg | Sheet material useful in image transfer techniques |
| US3974014A (en) * | 1974-07-10 | 1976-08-10 | Hallmark Cards, Incorporated | Method for transferring design image to wax articles |
| US4307761A (en) * | 1978-10-27 | 1981-12-29 | Diamond International Corporation | Article inflating system including an endless belt assembly |
| WO1983001019A1 (en) * | 1981-09-25 | 1983-03-31 | Dennison Mfg Co | Screen printing of heat transferable labels |
| US4466994A (en) * | 1981-09-25 | 1984-08-21 | Dennison Manufacturing Company | Heat transferable labels |
| US4557964A (en) * | 1983-06-06 | 1985-12-10 | Dennison Manufacturing Company | Heat transferable laminate |
| US4592946A (en) * | 1983-08-22 | 1986-06-03 | Dennison Manufacturing Company | Thermal ink transfer recording |
| US4548857A (en) * | 1983-09-26 | 1985-10-22 | Dennison Manufacturing Co. | Heat transferable laminate |
| US4536434A (en) * | 1983-10-20 | 1985-08-20 | Dennison Manufacturing Co. | Heat transfer laminate |
| US4684554A (en) * | 1985-04-12 | 1987-08-04 | Minnesota Mining And Manufacturing Company | Polymeric coating for container induction innerseal |
| US4555436A (en) * | 1985-09-19 | 1985-11-26 | Dennison Manufacturing Co. | Heat transferable laminate |
| US6159568A (en) * | 1992-02-21 | 2000-12-12 | Avery Dennison Corporation | Peelable label |
| US6344269B1 (en) * | 1996-12-11 | 2002-02-05 | Avery Dennison Corporation | Heat-transfer label |
| US5840142A (en) * | 1996-11-22 | 1998-11-24 | Stevenson; Michael J. | Decoration and printing on polyolefin surfaces |
| GB9820352D0 (en) * | 1998-09-19 | 1998-11-11 | Polycarta Limited | Tranfers |
| US6254970B1 (en) | 1998-10-08 | 2001-07-03 | International Playing Card & Label Co. | Substrates for heat transfer labels |
| DE19952563A1 (en) * | 1999-11-01 | 2001-05-03 | Romonta Gmbh | Wax compound |
| US6758000B2 (en) | 2001-01-10 | 2004-07-06 | Avery Dennison Corporation | Livestock security tag assembly |
| US6756095B2 (en) | 2001-01-10 | 2004-06-29 | Avery Dennison Corporation | Heat-sealable laminate |
| US6773653B2 (en) | 2001-10-05 | 2004-08-10 | Avery Dennison Corporation | In-mold labeling method |
| US9206338B2 (en) | 2002-01-16 | 2015-12-08 | Multi-Color Corporation | Heat-transfer label assembly and method of using the same |
| US20030134110A1 (en) * | 2002-01-16 | 2003-07-17 | Laprade Jean Paul | Heat-transfer label assembly and method of using the same |
| US6716501B2 (en) | 2002-07-18 | 2004-04-06 | Avery Dennison Corporation | Multilayered film |
| US7364777B1 (en) | 2004-08-18 | 2008-04-29 | Multi-Color Corporation | Heat-transfer label assembly and method of using the same |
| US8518001B2 (en) * | 2007-06-13 | 2013-08-27 | The Procter & Gamble Company | Skin treatment device |
| US9511621B2 (en) | 2011-02-04 | 2016-12-06 | Multi-Color Corporation | Release formulation for label including synthetic wax |
| EP2739481B1 (en) | 2011-08-01 | 2017-09-20 | Sun Chemical Corporation | High-stretch energy curable inks and method of use in heat transfer label applications |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK135158B (en) * | 1966-12-19 | 1977-03-14 | Dennison Mfg Co | Transfer label with a coating of an oxidized hydrocarbon wax. |
-
1969
- 1969-08-11 US US3616015D patent/US3616015A/en not_active Expired - Lifetime
- 1969-12-31 NL NL6919682A patent/NL6919682A/xx unknown
-
1970
- 1970-01-28 FR FR7002971A patent/FR2057626A6/fr not_active Expired
- 1970-07-02 DK DK346270A patent/DK153660C/en not_active IP Right Cessation
- 1970-08-11 GB GB3868570A patent/GB1325930A/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK135158B (en) * | 1966-12-19 | 1977-03-14 | Dennison Mfg Co | Transfer label with a coating of an oxidized hydrocarbon wax. |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6919682A (en) | 1971-02-15 |
| DE2016438B2 (en) | 1972-09-28 |
| FR2057626A6 (en) | 1971-05-21 |
| DK153660C (en) | 1988-12-19 |
| US3616015A (en) | 1971-10-26 |
| DE2016438A1 (en) | 1971-04-08 |
| GB1325930A (en) | 1973-08-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUP | Patent expired |