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DK143721B - PROCEDURE AND OVEN FOR DISPOSAL OF WASTE - Google Patents

PROCEDURE AND OVEN FOR DISPOSAL OF WASTE Download PDF

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Publication number
DK143721B
DK143721B DK48777AA DK48777A DK143721B DK 143721 B DK143721 B DK 143721B DK 48777A A DK48777A A DK 48777AA DK 48777 A DK48777 A DK 48777A DK 143721 B DK143721 B DK 143721B
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Denmark
Prior art keywords
waste
gas
shaft
fresh air
combustion
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Application number
DK48777AA
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Danish (da)
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DK143721C (en
DK48777A (en
Inventor
H Mallek
W Jablonski
P Pelzer
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H Mallek
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Publication of DK143721B publication Critical patent/DK143721B/en
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Publication of DK143721C publication Critical patent/DK143721C/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/04Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment drying
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/24Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23BMETHODS OR APPARATUS FOR COMBUSTION USING ONLY SOLID FUEL
    • F23B7/00Combustion techniques; Other solid-fuel combustion apparatus
    • F23B7/002Combustion techniques; Other solid-fuel combustion apparatus characterised by gas flow arrangements
    • F23B7/005Combustion techniques; Other solid-fuel combustion apparatus characterised by gas flow arrangements with downdraught through fuel bed and grate

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Incineration Of Waste (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Air Supply (AREA)

Description

(19) DANMARK VjS/(19) DENMARK VjS /

^ (>2) FREMLÆGGELSESSKRIFT ud 1U3721 B^ (> 2) SUBMISSION WRITING out 1U3721 B

DIREKTORATET FOR PATENT- OG VAREMÆRKEVÆSENETDIRECTORATE OF THE PATENT AND TRADEMARKET SYSTEM

121) Ansøgning nr. 487/77 |B„ |nt.a, F 23 6 5/04 (22) Indleveringsdag 4. feb. 1977 (24) Løbedag 4. feb. 1977 (41) Aim. tilgængelig 6. aug. 1977 (44) Fremlagt 28. eep. 1981 (86) International ansøgning nr.121) Application No. 487/77 | B „| nt.a, F 23 6 5/04 (22) Filing date 4 Feb. 1977 (24) Race day 4 Feb 1977 (41) Aim. available Aug. 6 1977 (44) Presented 28th eep. 1981 (86) International application no.

(86) International indleveringsdag (85) Videreføreisesdag -(62) Stamansøgning nr.(86) International filing day (85) Continuation day - (62) Stock application no.

(30) Prioritet 5. feb. 1976, 26044C9, DE(30) Priority Feb 5 1976, 26044C9, DE

(71) Ansøger HEINZ MALLER, D-51 72 Linnich/Tetz, DE.(71) Applicant HEINZ MALLER, D-51 72 Linnich / Tetz, DE.

(72) Opfinder Heinz Mallek, DE: Werner Jablonski, DE: Peter _Pelzer,(72) Inventor Heinz Mallek, DE: Werner Jablonski, DE: Peter _Pelzer,

DETHE

(74) Fuldmægtig Ingeniørfirmaet Hofman-Bang & Bout ard.(74) Associate Engineer Hofman-Bang & Bout ard.

(54) Fremgangsmåde og ovn til forbræn= ding af affald.(54) Process and furnace for incineration of waste.

Opfindelsen angår en fremgangsmåde af den i krav l’s indledning angivne art. Ved denne i GB-patentskrift 1 565 125 beskrevne forbrændingsmetode og den i samme patentskrift beskrevne forbrændingsovn strømmer affaldet fra en indre kegle, der sammen med ovnens væg danner en snæver passage for affaldet, ind i forbrændingsrummet, i hvilket affaldet forbrændes ved hjælp af brændere, der udefra får tilført særskilt brændstof. Nedefra tilført friskluft CD ledes gennem den indre kegle, der er udformet som en rist, ind i den i skakten oven for det snævre sted værende affaldssøjle.The invention relates to a method of the kind set forth in claim 1. By this method of combustion described in GB patent 1,556,125 and the incinerator described in the same patent, the waste flows from an inner cone, which together with the wall of the furnace forms a narrow passage for the waste, into the combustion chamber in which the waste is burned by means of burners. from which external fuel is supplied. From below, fresh air CD is fed through the inner cone, which is designed as a grate, into the waste column above the narrow place.

CMCM

Den gas, der dannes ved tørring, afgasning og forgasning af affal-00 det, suges foroven ud af skakten og ledes gennem anlæg til i- behandling af gassen, f.eks. et rensningsanlæg, hvorefter den så tt Ω 2 143721 ledes behandlede gas atter tilføres forbrændingsovnen. Denne kendte forbrændingsmetode er uøkonomisk for såvidt som den kræver tilførsel af supplerende brændstof, f.eks. olie til affaldets forbrænding. Desuden kræves der til metodens gennemførelse et forbrændingsanlæg, der er kompliceret og bekosteligt især hvad angår gassens behandling og styring.The gas formed by drying, degassing and gasifying the waste-00 is suctioned from the top of the shaft and passed through plants for in-treatment of the gas, e.g. a purification plant, after which the treated gas is then fed 14 2 143721 again to the incinerator. This known combustion method is uneconomical insofar as it requires the addition of supplementary fuel, e.g. oil for waste incineration. In addition, the method requires a combustion plant which is complicated and expensive, especially in terms of gas treatment and control.

Det er opfindelsens formål at angive en let realiserbar fremgangsmåde af den omhandlede art til forbrænding af affald, ved hvilken affaldets brændværdi udnyttes optimalt til affaldets forbrænding, og hvor der selv ved tilførsel af varierende mængder affald sikres en jævn forbrænding, og den dertil nødvendige temperatur opretholdes med enkle midler. Dette opnås ved det i krav l's kendetegnende del angivne. Ved hjælp af fremgangsmåden ifølge opfindelsen, ved hvilken materialet, der skal forbrændes - det tørrede, opvarmede og afgassede afffald samt den ved afgasningen dannede spildgas - såvel som den til forbrændingens opretholdelse tilførte friskluft tilføres på ét og samme sted, nemlig det snævre sted, kan man på enkel vis, nemlig ved regulering af frisklufttilførselen og/eller ved ændring af den hastighed, hvormed affaldet tilføres det snævre sted, tilvejebringe optimale betingelser for forbrændingsprocessen. Den gas, der dannes ved tørringen og afgasningen af affaldet, såkaldt tørdestillationsgas, føres ved fremgangsmåden ifølge opfindelsen - da denne spildgas ledes nedad til det snævre sted - på den korteste vej til den snævre passage mellem skakten og forbrændingskammeret og forbrændes fuldstændigt.SUMMARY OF THE INVENTION It is an object of the invention to provide a readily achievable process of the present kind for the incineration of waste, in which the calorific value of the waste is optimally utilized for the incineration of the waste and where even with the supply of varying amounts of waste a uniform incineration is ensured and the necessary temperature is maintained. by simple means. This is achieved by the characterizing part of claim 1. By means of the process according to the invention, in which the material to be incinerated - the dried, heated and degassed waste and the waste gas formed in the degassing - as well as the fresh air supplied for the maintenance of the combustion can be supplied in one and the same place, namely the narrow place. simple conditions, namely by regulating the supply of fresh air and / or by changing the rate at which the waste is supplied to the narrow place, provide optimum conditions for the combustion process. The gas produced by the drying and degassing of the waste, so-called dry distillation gas, is conducted by the method according to the invention - as this waste gas is directed downwards to the narrow place - on the shortest path to the narrow passage between the shaft and the combustion chamber and is completely incinerated.

Ved før det snævre sted at tilføre det opvarmede affald og spildgassen friskluft med en temperatur på mindst 800°C og i et understøkiometrisk mængdeforhold opnår man, at affaldet forbrændes delvis før det snævre sted, og at affaldets afgasning derved intensiveres. Den mængde friskluft, der tilføres oven for det snævre sted, er således afpasset efter mængden af den direkte på det snævre sted tilførte friskluft, at der opnås en optimal forbrænding i selve forbrændingskammert. Ved at ændre dette mængdeforhold kan man let styre forbrændingen. Derved er det på grund af den store gasandel på det snævre sted muligt at nå op på en temperatur på tilnærmelsesvis 1500° C i forbrændingskammeret, såfremt man ønsker en slaggesmelte.By supplying the heated waste and waste gas with fresh air at a temperature of at least 800 ° C before the narrow place, in a lower stoichiometric ratio, the waste is partially incinerated before the narrow place and the gasification of the waste is thereby intensified. The amount of fresh air supplied above the narrow place is so adapted to the amount of fresh air supplied directly in the narrow place that optimum combustion is achieved in the combustion chamber itself. Changing this ratio can easily control combustion. This makes it possible to reach a temperature of approximately 1500 ° C in the combustion chamber due to the large proportion of gas in the narrow place if a slag melt is desired.

3 1437213 143721

Også det i krav 2 angivne bidrager til at sikre en effektiv styring af forbrændingsprocessen, idet overskudsgas, der ikke er nødvendig til affaldets forbrænding, fjernes fra forbrændingen.Also, the claim of claim 2 also contributes to ensuring efficient control of the combustion process, removing excess gas not necessary for the incineration of the waste from the incineration.

Sådanne eventuelle overskydende gasmængder kan anvendes andetsteds som brændgas. Til forbrænding af vanskeligt forbrændbart affald, f.eks. affaldsslam, kan der før det snævre sted tilføres det opvarmede affald og spildgassen en forbrændingen fremmende gas, f.eks. methanholdig naturgas.Such excess gas quantities may be used elsewhere as fuel gas. For incineration of difficult combustible waste, e.g. waste sludge, prior to the narrow site, the heated waste and the waste gas can be fed a combustion-promoting gas, e.g. methane-containing natural gas.

Opfindelsen angår tillige en ovn af den i krav 3»s indledning angivne art til udøvelse af fremgangsmåden. Ovnen er ejendommelig ved det i krav 3*s kendetegnende del angivne. Gennem de oven for det snævre sted i skakten mundende frisklufttilførselsledninger indføres der i det opvarmede affald og i spildgassen friskluft i understøkiometrisk mængdeforhold til delsvis forbrænding og afgasning af affaldet. Da forbrændingskammerets aftræksrum omslutter den centrale skakt, opvarmes affaldet i skakten af røggassen i aftræksrummet, så at der ikke kræves nogen supplerende opvarmning ved hjælp af særskilt tilført brændstof såsom olie. Da affaldsmaterialet i skakten holdes i bevægelse ved hjælp af bevægeorganeme, omvæltes og blandes affaldet i skakten, hvorved affaldets opvarmning fremmes samtidigt med, at materialet under bevægelse på grund af tyngdekraften tilføres det snævre sted.The invention also relates to an oven of the kind specified in the preamble of claim 3 for carrying out the method. The furnace is peculiar to the characteristic part of claim 3 *. Through the fresh air supply conduits opening above the narrow spot in the shaft, fresh air is introduced into the heated waste and into the waste gas in sub-stoichiometric proportions for partial combustion and degassing of the waste. As the combustion chamber's exhaust chamber encloses the central shaft, the waste in the shaft of the flue gas is heated in the extraction chamber so that no additional heating is required by means of separately supplied fuel such as oil. As the waste material in the shaft is kept in motion by means of the moving means, the waste is overturned and mixed in the shaft, thereby promoting the heating of the waste while the material in motion due to gravity is applied to the narrow place.

Endelig tjener det i krav 4 angivne til efter ønske enten at trække en del af den ved affaldets afgasning dannede spildgas bort, så at denne gasdel undrages forbrændingen, eller til tilføre forbrændingen fremmende gas i de tilfælde, hvor vanskeligt brændbart affald skal forbrændes.Finally, the claim as claimed in claim 4 serves to either withdraw part of the waste gas formed during the degassing of the waste so that this gas part is avoided by the combustion or to supply the combustion gas in cases where difficult combustible waste is to be incinerated.

I det følgende forklares opfindelsen nærmere ved hjælp af tegningen, der dels set fra siden og dels i lodret snit viser en udførelsesform for ovnen til udøvelse af fremgangsmåden ifølge opfindelsen. Den på tegningen viste ovn har en central skakt 1 og et neden for denne placeret forbrændingskammer 3, der forneden kan lukkes ved hjælp af en klap 2, og som har et skakten 1 omsluttende aftræksrum 3a. En konisk ovnmuffel 4 slutter fra neden op til skakten 1, medens en rørformet del med et kegleformet nedre endeparti 5 fra oven rager ned i skakten. Det koniske endeparti 5 danner sammen med ovnmuffelen 4 ved skakten 1 * s nedre 4 143721 ende og ved overgangen til kammeret 3 en snæver passage i form af en ringspalte, hvis vidde kan varieres ved hjælp af det i højden indstillelige nedre endeparti 5 på den rørformede del.In the following, the invention is explained in more detail with the aid of the drawing, which shows, partly from the side and partly in vertical section, an embodiment of the furnace for carrying out the method according to the invention. The furnace shown in the drawing has a central shaft 1 and a combustion chamber 3 located below it, which can be closed below by means of a flap 2, and which has a shaft 1 enclosing extractor space 3a. A tapered furnace muffle 4 terminates from below up to the shaft 1, while a tubular portion with a cone-shaped lower end portion 5 from above protrudes into the shaft. The tapered end portion 5 together with the furnace muffle 4 at the lower end of the shaft 1 * and at the transition to the chamber 3 form a narrow passage in the form of a ring slot, the width of which can be varied by the height-adjustable lower end portion 5 of the tubular share.

I hulrummet i endepartiet 5 er anbragt en kegle 6, der er således udformet, dimensioneret og placeret, at den sammen med den rørformede del ved sidstnævntes nedre ende danner slidser, der er rettet mod det snævre sted, dvs. ringspalten.In the cavity of the end portion 5 is arranged a cone 6 which is so designed, dimensioned and positioned that it forms, together with the tubular part at the lower end of the latter, slots which are directed towards the narrow place, ie. the annular gap.

Den rørformede dels endeparti 5 er som vist på tegningen således koaksialt omgivet af et rør, at der dannes en udefra ind i skakten 1 ragende og i dennes nedre del mundende ledning eller passage 7. På det nævnte rør findes stænger 8, der i sideretningen rager ud i det af skakten 1 og ovnmuffelen 4 dannede skaktformede rum. Desuden findes der på skakten l's indre væg rør 9» som med deres øvre ender rager op over aftræksrummet 3a, og hvis nedre ender er beliggende ved ovnmuffelen 4’s øvre del.As shown in the drawing, the end portion 5 of the tubular member is coaxially surrounded by a tube so as to form a conduit or passage leading from the outside into the shaft 1 and in the lower part thereof 7 or on the said pipe there are bars 8 which project in the lateral direction. into the shaft-shaped compartments formed by the shaft 1 and the furnace muffle 4. In addition, on the inner wall of the shaft 1, there are pipes 9 »which with their upper ends protrude above the extractor compartment 3a and whose lower ends are located at the upper part of the furnace muffle 4.

Ved udøvelse af fremgangsmåden ifølge opfindelsen er skakten 1 ved hjælp af et tilførselsorgan 10 fyldt med affald tilnærmelsesvis op til aftræksrummet 3a’s højde. Friskluften tilføres dels direkte det snævre sted og ledes dels ind i skaktens øvre del.In carrying out the method according to the invention, the shaft 1 is filled by means of a supply means 10 with waste approximately up to the height of the extraction chamber 3a. The fresh air is supplied directly to the narrow place and partly to the upper part of the shaft.

Den ind i skakten l’s øvre del førte friskluft passerer ikke gennem den tætpakkede affaldssøjle, men via rørene 9, i hvilken den opvarmes ligesom den gennem partiet 5 førte friskluft, ind i søjlens nedre del, hvor denne luft medfører en delvis forbrænding og afgasning af affaldsmaterialet. I den del af affaldssøjlen, der er beliggende i højde med rørene 9» er affaldsmaterialet således praktisk taget lufttæt indesluttet men underkastet en intensiv tørring og afgasning, fordi den centrale skakt 1 opvarmes af den varme røggas, der strømmer gennem aftræksrummet 3a omkring skakten.The fresh air introduced into the upper part of the shaft 1 does not pass through the tightly packed waste column, but via the pipes 9, in which it is heated, like the fresh air passing through the portion 5, into the lower part of the column, where this air causes a partial combustion and degassing of the waste material. . Thus, in the portion of the waste column located at the height of the pipes 9, the waste material is substantially airtightly enclosed but subjected to intensive drying and degassing because the central shaft 1 is heated by the hot flue gas flowing through the exhaust chamber 3a around the shaft.

Når forbrændingsovnen er i termisk ligevægt, sættes partiet 5 ved hjælp af en på tegningen ikke vist drivmekanisme i en meget langsom,roterende bevægelse. Herved medbringer de ind i affaldssøjlen ragende stænger 8 affaldsmaterialet til forhindring af brodannelser og ulmezoner i materialesøjlen. Herved fremmes afgasningsprocessen. Ved ændring af partiet 5’s rotationshastighed kan man desuden regulere tilførslen af affald til det snævre sted.When the combustion furnace is in thermal equilibrium, the portion 5 is set in a very slow rotating motion by means of a drive mechanism not shown in the drawing. Hereby, they carry rods 8 into the waste column carrying the waste material to prevent bridging and smearing zones in the material column. This facilitates the degassing process. By changing the rotational speed of the lot 5, you can also regulate the supply of waste to the narrow place.

Claims (2)

143721 5 Overskudsrøggas kan bortsuges gennem·passagen 7 som antydet ved pilene. Gennem ledningen 7 kan der dog også tilføres affaldet brændgas. Ikke forbrændte bestanddele, der falder .ned på askelejet, kommer her i berøring med den endnu oxygenholdige varme gasstrøm, hvorved disse andele forbrændes fuldt ud. Ved kontinuerlig drift af ovnen fjernes asken fra denne i intervaller på 1 til 2 døgn. I røggassen i aftræksrummet 3a svævende og af røggasstrømmen medrevne faststofpartikler aflejres på filtermåtter 11, der er anbragt ved aftræksrummets udløb. Disse faststofandele forbrændes her ligeledes fuldt ud af den oxygen, der endnu er tilstede i den varme gas. Filtermåtterne 11 er presset af fibre med en tykkelse på tilnærmelsesvis 0,003 mm, og måtterne har en tykkelse på tilnærmelsesvis 10 til 15 mm. I en forbrændingsovn svarende til den på teningen viste har man forbrændt et affaldsmateriale bestående af dyrekadavere, papir og fugtigt løv med et kalorieindhold på tilnærmelsesvis 1500 kcal/kg, hvorved ovnen holdtes i termisk ligevægt ved en temperatur på over 1000°C i forbrændingskammeret.143721 5 Excess flue gas can be aspirated through the passage 7 as indicated by the arrows. However, through the conduit 7, the waste fuel gas can also be supplied. Unburning constituents falling on the ash bed here come into contact with the still oxygen-containing hot gas stream, thus burning these proportions fully. Continuous operation of the oven removes the ash from it in intervals of 1 to 2 days. Floating solids in the flue gas in the exhaust chamber 3a and solid particles entrained by the flue gas stream are deposited on filter mats 11 which are arranged at the outlet of the extractor compartment. These solids are also fully combusted here by the oxygen still present in the hot gas. The filter mats 11 are pressed from fibers of approximately 0.003 mm thickness and the mats have a thickness of approximately 10 to 15 mm. In a combustion furnace similar to the one shown in the ignition, a waste material consisting of animal carcasses, paper and moist leaves with a caloric content of approximately 1500 kcal / kg has been incinerated, whereby the furnace is kept in thermal equilibrium at a temperature above 1000 ° C in the combustion chamber. 1. Fremgangsmåde til forbrænding af affald, der opstemmes oven for et snævert sted mellem en affaldet optagende skakt (1) og et umiddelbart efter skakten placeret forbrændingskammer (3) og tørres samt afgasses i skakten ved opvarmning, hvor den herved dannede spildgas forbrændes i forbrændingskammeret under tilførsel af friskluft, og hvor der før det snævre sted tilføres det opvarmede affald opvarmet friskluft, og der på det snævre sted tilføres det afgassede affald yderligere friskluft til forbrænding af affaldet, kendetegnet ved, at affaldet opvarmes i skakten under udelukkelse af luft, at den nævnte opvarmede friskluft før det snævre sted tilføres spildgassen og det afgassede affald i et understøkiometrisk mængdeforhold, og at spildgassen trækkes bort ned gennem det snævre sted.A process for combustion of waste, which is stored above a narrow space between a waste receiving shaft (1) and a combustion chamber (3) located immediately after the shaft and dried and degassed in the shaft by heating, whereby the resulting waste gas is incinerated in the combustion chamber. during supply of fresh air, and where, before the narrow place, the heated waste is supplied with fresh air, and in the narrow place the degassed waste is supplied with additional fresh air for incineration of the waste, characterized in that the waste is heated in the shaft under exclusion of air. said heated fresh air before the narrow site is fed to the waste gas and the degassed waste in a lower stoichiometric ratio and that the waste gas is drawn down through the narrow place.
DK48777A 1976-02-05 1977-02-04 PROCEDURE AND OVEN FOR DISPOSAL OF WASTE DK143721C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2604409A DE2604409C3 (en) 1976-02-05 1976-02-05 Process and incinerator for incinerating waste
DE2604409 1976-02-05

Publications (3)

Publication Number Publication Date
DK48777A DK48777A (en) 1977-08-06
DK143721B true DK143721B (en) 1981-09-28
DK143721C DK143721C (en) 1982-03-15

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DK48777A DK143721C (en) 1976-02-05 1977-02-04 PROCEDURE AND OVEN FOR DISPOSAL OF WASTE

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US (1) US4116136A (en)
JP (1) JPS5295890A (en)
KR (1) KR820001289B1 (en)
AT (1) AT373679B (en)
AU (1) AU507943B2 (en)
BE (1) BE850961A (en)
BR (1) BR7700688A (en)
CA (1) CA1073749A (en)
CH (1) CH598539A5 (en)
DE (1) DE2604409C3 (en)
DK (1) DK143721C (en)
FR (1) FR2340508A1 (en)
GB (1) GB1538013A (en)
IT (1) IT1079163B (en)
LU (1) LU76694A1 (en)
NL (1) NL181523C (en)
SE (1) SE439058B (en)

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NL181523B (en) 1987-04-01
DK143721C (en) 1982-03-15
JPS6243092B2 (en) 1987-09-11
DE2604409C3 (en) 1979-12-06
FR2340508B1 (en) 1984-06-01
BR7700688A (en) 1977-10-11
AU2188777A (en) 1978-08-10
LU76694A1 (en) 1977-06-28
DE2604409A1 (en) 1977-08-11
GB1538013A (en) 1979-01-10
NL181523C (en) 1987-09-01
ATA953976A (en) 1983-06-15
CA1073749A (en) 1980-03-18
IT1079163B (en) 1985-05-08
AU507943B2 (en) 1980-03-06
BE850961A (en) 1977-08-01
US4116136A (en) 1978-09-26
NL7700307A (en) 1977-08-09
JPS5295890A (en) 1977-08-11
AT373679B (en) 1984-02-10
KR820001289B1 (en) 1982-07-19
SE439058B (en) 1985-05-28
FR2340508A1 (en) 1977-09-02
CH598539A5 (en) 1978-04-28
DK48777A (en) 1977-08-06
SE7701203L (en) 1977-08-06
DE2604409B2 (en) 1979-04-12

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