DE928673C - Use of aluminum alloys with added boron - Google Patents
Use of aluminum alloys with added boronInfo
- Publication number
- DE928673C DE928673C DEV5496A DEV0005496A DE928673C DE 928673 C DE928673 C DE 928673C DE V5496 A DEV5496 A DE V5496A DE V0005496 A DEV0005496 A DE V0005496A DE 928673 C DE928673 C DE 928673C
- Authority
- DE
- Germany
- Prior art keywords
- alloys
- aluminum alloys
- added boron
- aluminum
- boron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title description 5
- 229910052796 boron Inorganic materials 0.000 title description 5
- 229910000838 Al alloy Inorganic materials 0.000 title description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 7
- 239000000956 alloy Substances 0.000 claims description 7
- 238000007792 addition Methods 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000011265 semifinished product Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- 238000011282 treatment Methods 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- 239000013589 supplement Substances 0.000 claims 1
- 239000000654 additive Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 238000000137 annealing Methods 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
- H01G9/042—Electrodes or formation of dielectric layers thereon characterised by the material
- H01G9/045—Electrodes or formation of dielectric layers thereon characterised by the material based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Power Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
Verwendung von .Aluminium-Legierungen mit Borzusatz Bei der chemischen und elektrolytischen Oberflächenbehandlung von Werkstücken aus Aluminium und seinen Legierungen, insbesondere aus Reinstaluminium und dessen Legierungen, zum Zweck des Beizens, Glänzens oder des Oxydierens wird sehr leicht in unerwünschter Weise das Werkstoffgefüge sichtbar. Dabei läßt sich häufig nachweisen, daß das unterschiedliche Gußgefüge der Barren, auch wenn sie im Stranggußverfahren hergestellt sind" und die ungleichmäßige Verteilung der Legierungsbestandteile zu streifigen und fehlerhaften Oberflächen führt.Use of .aluminum alloys with added boron For chemical and electrolytic surface treatment of workpieces made of aluminum and its Alloys, in particular made of pure aluminum and its alloys, for the purpose pickling, lustering or oxidizing very easily becomes undesirable the structure of the material visible. It can often be demonstrated that the different Cast structure of the bars, even if they are manufactured using the continuous casting process "and the uneven distribution of the alloy components streaky and flawed Surfaces leads.
Diese Erscheinung kann in gewissem Maße dadurch vermieden werden; daß die Gußbarren durch besondere Glühbehandlungen homogenisiert und außerdem mehrmals rekristallisiert werden. Diese Maßnahmen werden jedoch aus wirtschaftlichen Gründen naturgemäß soweit wie möglich beschränkt. Bei diesen Versuchen wurde nun festgestellt, daß bereits durch sehr geringe Zusätze von Bor zu der Metallschmelze das Gefüge derart beeinfluß@t werden kann, daß das fertige Halbzeug keinerlei Strukturabzeichnungen mehr aufweist.This phenomenon can be avoided to a certain extent; that the cast ingots are homogenized by special annealing treatments and also several times be recrystallized. However, these measures are for economic reasons naturally limited as much as possible. In these experiments it has now been found that even very small additions of boron to the molten metal break the structure can be influenced in such a way that the finished semifinished product does not have any structural marks whatsoever has more.
Es ist zwar bekannt, daß gewisse Zusätze zur Metallschmelze, wie z. B. von Titan:, Vanadin, Zirkon, Kohlenstoff, Bor und Cer, ein feinkörniges Gußgefüge bewirken, die Erfahrung zeigt jedoch, daß im allgemeinen die Kornverfeinerung des Gußgefüges keim wirksames Mittel zur Verhinderung von Strukturabzeichnungen im fertigen Halbzeug bildet. Das Wesen vorliegender Erfindung ist nun in der Feststellung begründet, daß allein der Borzusatz die Strukturabzeichnungen im Halbzeug verhindert.It is known that certain additives to the molten metal, such. B. of titanium :, vanadium, zircon, carbon, boron and cerium, a fine-grain cast structure cause, experience shows, however, that in general the grain refinement of the Cast structure germ effective means to prevent structural markings in the finished product Semi-finished product forms. The essence of the present invention is based on the statement, that only the addition of boron prevents the structure from showing in the semi-finished product.
Von den übrigen kornverfeinernden Mitteln müßten überdies viel größere Mengen, angewendet werden, um die angestrebte Wirkung auf die Kornverfeinerung des Guß.blocks zu erreichen. Derartig große Zusätze würden sich jedoch bei der chemischen und elektrolytischen Oberflächenbehandlung als äußerst störend auswirken.Of the other grain-refining agents, much larger ones would also have to be used Quantities, applied to achieve the desired effect on grain refinement of To achieve casting blocks. Such large additives would, however, be found in the chemical and electrolytic surface treatment are extremely disruptive.
Insbesondere bei Strangpreß.er,zeugnissen wirkt sich der Bonzusatz günstig aus, indem die bisher meist.aufgetretenen Unterschiede zwischen Anfang und Ende der Profile bei der Oberflächenbehandlung nicht mehr sichtbar werden.The addition to the receipt has an effect, particularly in the case of extruded products favorably by eliminating the differences that have mostly occurred up to now between the beginning and the The end of the profiles are no longer visible during the surface treatment.
Zur Steigerung der Wirkung können natürlich Homogenisierungs- und Weichglühbehandlungen beibehalten werden, doch können diese Wärmebehandlungsverfahren bei niedrigerer Temperatur und/oder mit kürzeren Zeiten durdhgeführt werden.To increase the effect, of course, homogenization and Soft annealing treatments can be retained, but these heat treatment processes can be used be carried out at a lower temperature and / or with shorter times.
Der Bonzusatz soll zwischen o;oooi und 0,3'/0, vorzugsweise zwischen o,oor und 0,030/0 betragen. Die höheren Zusätze können bei solchen Aluminiwm-Legierungen, die an sich einen höheren Gehalt an anderen Metallen aufweisen, insbesondere bei aushärtbaren Legierungen, Anwendung finden, bei denen die sonst gegebenentfalls erforderliche längere Homogenisierung des Gußblocks bei honen Temperaturen leicht zu nicht wieder zu :beseitigenden Schädigungen: führt. Bei Reinstaluminium und vorzugsweise dessen homogenen Legierungen, insbesondere bei solchen mit Magnesium bis zu 2,50[o, hält man den Bonzusatz zweckmäßigerweise unter o,oz%, vorzugsweise unter o,0030/0.The additional receipt should be between o; oooi and 0.3 '/ 0, preferably between o, oor and 0.030 / 0. The higher additives can be used in such aluminum alloys, which in themselves have a higher content of other metals, especially in Hardenable alloys are used where the otherwise possibly required longer homogenization of the ingot at high temperatures easily to not again to: eliminating damage: leads. With pure aluminum and preferably its homogeneous alloys, especially those with magnesium up to 2.50 [o, the additional receipt is expediently kept below 0.0 oz%, preferably below 0.0030/0.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEV5496A DE928673C (en) | 1953-02-24 | 1953-02-24 | Use of aluminum alloys with added boron |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEV5496A DE928673C (en) | 1953-02-24 | 1953-02-24 | Use of aluminum alloys with added boron |
Publications (1)
Publication Number | Publication Date |
---|---|
DE928673C true DE928673C (en) | 1955-06-06 |
Family
ID=7571257
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEV5496A Expired DE928673C (en) | 1953-02-24 | 1953-02-24 | Use of aluminum alloys with added boron |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE928673C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1165282B (en) * | 1955-11-18 | 1964-03-12 | Aluminium Walzwerke Singen | Aluminum foil intended for electrolytic capacitors |
-
1953
- 1953-02-24 DE DEV5496A patent/DE928673C/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1165282B (en) * | 1955-11-18 | 1964-03-12 | Aluminium Walzwerke Singen | Aluminum foil intended for electrolytic capacitors |
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