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DE928673C - Use of aluminum alloys with added boron - Google Patents

Use of aluminum alloys with added boron

Info

Publication number
DE928673C
DE928673C DEV5496A DEV0005496A DE928673C DE 928673 C DE928673 C DE 928673C DE V5496 A DEV5496 A DE V5496A DE V0005496 A DEV0005496 A DE V0005496A DE 928673 C DE928673 C DE 928673C
Authority
DE
Germany
Prior art keywords
alloys
aluminum alloys
added boron
aluminum
boron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEV5496A
Other languages
German (de)
Inventor
Paul Dr-Ing Brenner
Werner Dipl-Phys Dr Sautter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vereinigte Leichtmetallwerke GmbH
Original Assignee
Vereinigte Leichtmetallwerke GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vereinigte Leichtmetallwerke GmbH filed Critical Vereinigte Leichtmetallwerke GmbH
Priority to DEV5496A priority Critical patent/DE928673C/en
Application granted granted Critical
Publication of DE928673C publication Critical patent/DE928673C/en
Expired legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/004Details
    • H01G9/04Electrodes or formation of dielectric layers thereon
    • H01G9/042Electrodes or formation of dielectric layers thereon characterised by the material
    • H01G9/045Electrodes or formation of dielectric layers thereon characterised by the material based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Power Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Description

Verwendung von .Aluminium-Legierungen mit Borzusatz Bei der chemischen und elektrolytischen Oberflächenbehandlung von Werkstücken aus Aluminium und seinen Legierungen, insbesondere aus Reinstaluminium und dessen Legierungen, zum Zweck des Beizens, Glänzens oder des Oxydierens wird sehr leicht in unerwünschter Weise das Werkstoffgefüge sichtbar. Dabei läßt sich häufig nachweisen, daß das unterschiedliche Gußgefüge der Barren, auch wenn sie im Stranggußverfahren hergestellt sind" und die ungleichmäßige Verteilung der Legierungsbestandteile zu streifigen und fehlerhaften Oberflächen führt.Use of .aluminum alloys with added boron For chemical and electrolytic surface treatment of workpieces made of aluminum and its Alloys, in particular made of pure aluminum and its alloys, for the purpose pickling, lustering or oxidizing very easily becomes undesirable the structure of the material visible. It can often be demonstrated that the different Cast structure of the bars, even if they are manufactured using the continuous casting process "and the uneven distribution of the alloy components streaky and flawed Surfaces leads.

Diese Erscheinung kann in gewissem Maße dadurch vermieden werden; daß die Gußbarren durch besondere Glühbehandlungen homogenisiert und außerdem mehrmals rekristallisiert werden. Diese Maßnahmen werden jedoch aus wirtschaftlichen Gründen naturgemäß soweit wie möglich beschränkt. Bei diesen Versuchen wurde nun festgestellt, daß bereits durch sehr geringe Zusätze von Bor zu der Metallschmelze das Gefüge derart beeinfluß@t werden kann, daß das fertige Halbzeug keinerlei Strukturabzeichnungen mehr aufweist.This phenomenon can be avoided to a certain extent; that the cast ingots are homogenized by special annealing treatments and also several times be recrystallized. However, these measures are for economic reasons naturally limited as much as possible. In these experiments it has now been found that even very small additions of boron to the molten metal break the structure can be influenced in such a way that the finished semifinished product does not have any structural marks whatsoever has more.

Es ist zwar bekannt, daß gewisse Zusätze zur Metallschmelze, wie z. B. von Titan:, Vanadin, Zirkon, Kohlenstoff, Bor und Cer, ein feinkörniges Gußgefüge bewirken, die Erfahrung zeigt jedoch, daß im allgemeinen die Kornverfeinerung des Gußgefüges keim wirksames Mittel zur Verhinderung von Strukturabzeichnungen im fertigen Halbzeug bildet. Das Wesen vorliegender Erfindung ist nun in der Feststellung begründet, daß allein der Borzusatz die Strukturabzeichnungen im Halbzeug verhindert.It is known that certain additives to the molten metal, such. B. of titanium :, vanadium, zircon, carbon, boron and cerium, a fine-grain cast structure cause, experience shows, however, that in general the grain refinement of the Cast structure germ effective means to prevent structural markings in the finished product Semi-finished product forms. The essence of the present invention is based on the statement, that only the addition of boron prevents the structure from showing in the semi-finished product.

Von den übrigen kornverfeinernden Mitteln müßten überdies viel größere Mengen, angewendet werden, um die angestrebte Wirkung auf die Kornverfeinerung des Guß.blocks zu erreichen. Derartig große Zusätze würden sich jedoch bei der chemischen und elektrolytischen Oberflächenbehandlung als äußerst störend auswirken.Of the other grain-refining agents, much larger ones would also have to be used Quantities, applied to achieve the desired effect on grain refinement of To achieve casting blocks. Such large additives would, however, be found in the chemical and electrolytic surface treatment are extremely disruptive.

Insbesondere bei Strangpreß.er,zeugnissen wirkt sich der Bonzusatz günstig aus, indem die bisher meist.aufgetretenen Unterschiede zwischen Anfang und Ende der Profile bei der Oberflächenbehandlung nicht mehr sichtbar werden.The addition to the receipt has an effect, particularly in the case of extruded products favorably by eliminating the differences that have mostly occurred up to now between the beginning and the The end of the profiles are no longer visible during the surface treatment.

Zur Steigerung der Wirkung können natürlich Homogenisierungs- und Weichglühbehandlungen beibehalten werden, doch können diese Wärmebehandlungsverfahren bei niedrigerer Temperatur und/oder mit kürzeren Zeiten durdhgeführt werden.To increase the effect, of course, homogenization and Soft annealing treatments can be retained, but these heat treatment processes can be used be carried out at a lower temperature and / or with shorter times.

Der Bonzusatz soll zwischen o;oooi und 0,3'/0, vorzugsweise zwischen o,oor und 0,030/0 betragen. Die höheren Zusätze können bei solchen Aluminiwm-Legierungen, die an sich einen höheren Gehalt an anderen Metallen aufweisen, insbesondere bei aushärtbaren Legierungen, Anwendung finden, bei denen die sonst gegebenentfalls erforderliche längere Homogenisierung des Gußblocks bei honen Temperaturen leicht zu nicht wieder zu :beseitigenden Schädigungen: führt. Bei Reinstaluminium und vorzugsweise dessen homogenen Legierungen, insbesondere bei solchen mit Magnesium bis zu 2,50[o, hält man den Bonzusatz zweckmäßigerweise unter o,oz%, vorzugsweise unter o,0030/0.The additional receipt should be between o; oooi and 0.3 '/ 0, preferably between o, oor and 0.030 / 0. The higher additives can be used in such aluminum alloys, which in themselves have a higher content of other metals, especially in Hardenable alloys are used where the otherwise possibly required longer homogenization of the ingot at high temperatures easily to not again to: eliminating damage: leads. With pure aluminum and preferably its homogeneous alloys, especially those with magnesium up to 2.50 [o, the additional receipt is expediently kept below 0.0 oz%, preferably below 0.0030/0.

Claims (1)

PATENTANSPRÜCHE: r. Verwendung von Aluminium und dessen Legierungen mit einem Bonzusatz von o,ooot bis 0,3, vorzugsweise zwischen o,oo r und 0,03 %, für die Herstellung von geknetetem Halbzeug, dessen Oberfläche einer chemischen und/oder ele!ktrolytiisdhen Behandlung, insbesondere einer Glänzung und/oder einer anodischen Oxydation, unterzogen werden soll. a. Verwendung von Reiustaluminium und dessen homogenen Legierungen, insbesondere solchen mit bis zu a,5 % Magnesium, mit Bo.rzusätzen von o,ooor bis o,oa, vorzugsweise bis o;oo6%, für den im Anspruch i genannten Zweck.PATENT CLAIMS: r. Use of aluminum and its alloys with a supplement of o, ooot to 0.3, preferably between o, oo r and 0.03%, for the production of kneaded semi-finished products, the surface of which is chemical and / or electrolytic treatment, in particular a gloss and / or a anodic oxidation. a. Use of stainless steel and its homogeneous alloys, especially those with up to a.5% magnesium, with additions of o, ooor to o, oa, preferably up to o; oo6%, for the claim i mentioned purpose.
DEV5496A 1953-02-24 1953-02-24 Use of aluminum alloys with added boron Expired DE928673C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEV5496A DE928673C (en) 1953-02-24 1953-02-24 Use of aluminum alloys with added boron

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEV5496A DE928673C (en) 1953-02-24 1953-02-24 Use of aluminum alloys with added boron

Publications (1)

Publication Number Publication Date
DE928673C true DE928673C (en) 1955-06-06

Family

ID=7571257

Family Applications (1)

Application Number Title Priority Date Filing Date
DEV5496A Expired DE928673C (en) 1953-02-24 1953-02-24 Use of aluminum alloys with added boron

Country Status (1)

Country Link
DE (1) DE928673C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1165282B (en) * 1955-11-18 1964-03-12 Aluminium Walzwerke Singen Aluminum foil intended for electrolytic capacitors

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1165282B (en) * 1955-11-18 1964-03-12 Aluminium Walzwerke Singen Aluminum foil intended for electrolytic capacitors

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