DE865510C - Process for the production of mixtures of substances which are insoluble or only slightly soluble in water, which can be diluted with water without excretions - Google Patents
Process for the production of mixtures of substances which are insoluble or only slightly soluble in water, which can be diluted with water without excretionsInfo
- Publication number
- DE865510C DE865510C DEP11855A DEP0011855A DE865510C DE 865510 C DE865510 C DE 865510C DE P11855 A DEP11855 A DE P11855A DE P0011855 A DEP0011855 A DE P0011855A DE 865510 C DE865510 C DE 865510C
- Authority
- DE
- Germany
- Prior art keywords
- water
- mixtures
- substances
- diluted
- insoluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 13
- 239000000203 mixture Substances 0.000 title claims description 9
- 239000000126 substance Substances 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 4
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 230000029142 excretion Effects 0.000 title description 3
- 239000003205 fragrance Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 4
- 235000019568 aromas Nutrition 0.000 claims description 2
- 239000000796 flavoring agent Substances 0.000 claims description 2
- 235000019634 flavors Nutrition 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- YXWWHNCQZBVZPV-UHFFFAOYSA-N 2'-methylacetophenone Chemical compound CC(=O)C1=CC=CC=C1C YXWWHNCQZBVZPV-UHFFFAOYSA-N 0.000 description 2
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 2
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 2
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- -1 triethanolamine monolauric acid ester Chemical class 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- XKCLIPLFEJSOAT-UHFFFAOYSA-N 1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalen-2-yl acetate Chemical compound C1CCCC2CC(OC(=O)C)CCC21 XKCLIPLFEJSOAT-UHFFFAOYSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- LGLVRUSFVKBFBU-UHFFFAOYSA-N 2-(6-methylheptyl)naphthalen-1-ol Chemical compound C1=CC=CC2=C(O)C(CCCCCC(C)C)=CC=C21 LGLVRUSFVKBFBU-UHFFFAOYSA-N 0.000 description 1
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- FHRPPAKHJATMEV-UHFFFAOYSA-N 2-octadecylnaphthalen-1-ol Chemical compound C1=CC=CC2=C(O)C(CCCCCCCCCCCCCCCCCC)=CC=C21 FHRPPAKHJATMEV-UHFFFAOYSA-N 0.000 description 1
- ZLRANBHTTCVNCE-UHFFFAOYSA-N 2-phenyl-3-(trifluoromethyl)pyridine Chemical compound FC(F)(F)C1=CC=CN=C1C1=CC=CC=C1 ZLRANBHTTCVNCE-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 229940044949 eucalyptus oil Drugs 0.000 description 1
- 239000010642 eucalyptus oil Substances 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- IIRDTKBZINWQAW-UHFFFAOYSA-N hexaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCO IIRDTKBZINWQAW-UHFFFAOYSA-N 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 235000015961 tonic Nutrition 0.000 description 1
- 230000001256 tonic effect Effects 0.000 description 1
- 229960000716 tonics Drugs 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
- A61K47/08—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing oxygen, e.g. ethers, acetals, ketones, quinones, aldehydes, peroxides
- A61K47/10—Alcohols; Phenols; Salts thereof, e.g. glycerol; Polyethylene glycols [PEG]; Poloxamers; PEG/POE alkyl ethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Chemical & Material Sciences (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Nutrition Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
Description
Verfahren zur Herstellung von mit Wasser ohne Ausscheidungen verdünnbaren Mischungen von in Wasser nicht oder schwerer löslichen Stoffen Es wurde gefunden, daß man aus Riechstoffen, Riechstoffixateuren oder -lösern oder Geschmacksaromen, die in Wasser nicht oder schwer löslich sind, in einfacher Weise Mischungen erhalten kann, die mit Wasser weitgehend verdünnt werden können, ohne daß Ausscheidungen entstehen, wenn man sie mit Polyäthern, die im Molekül mindestens drei, zweckmäßig mehr als fünf -C2H 0-Gruppen aufweisen, gegebenenfalls unter Erwärmen, mischt.Process for the preparation of dilutable with water without excretions Mixtures of substances that are insoluble or sparingly soluble in water It was found, that from odorants, odorant fixers or dissolvers or flavor aromas, which are insoluble or sparingly soluble in water can be obtained in a simple manner in mixtures can, which can be largely diluted with water without causing excretions arise if you combine them with polyethers, which have at least three in the molecule, expediently have more than five -C2H 0 groups, if appropriate with heating, mixes.
Als Als Polyäther der genannten Art seien beispielsweise genannt die Einwirkungsprodukte von 3, 6, I2, 20, 60 oder mehr Mol Äthylenoxyd auf 1 Mol einer umsetzungsfähigen organischen Verbindung, wieÄthylalkohol, Äthylenglykol, Glykolmonoäthyläther, Glycerin, I,3- oder I, 4-Butandiol, Sorbit, Dodecylalkohol, Benzylalkohol, Isooctylphenol, Stearylnaphthol, Ölsäure, Abietinsäure, ilticinolsäuremonoglycerid, Ölsäureamid, Rizinusöl, Eukalyptusöl, Triäfhanolamin, Triäthanolaminmonolaurinsäureester, Diäthylentriamin, Hexamethylentetramin, Octodecylamin, Melamin, Harnstoff, Tetraäthanolammoniumhydroxyd, Dodecylmercaptan, Benzoesäure, Salizylsäure u. dgl. Geeignet sind ferner Rondensationsprodukte von Benzoesäure, Abietinsäure und anderen organischen Säuren mit den vorerwähnten Polyäthern. As polyethers of the type mentioned, for example the products of action of 3, 6, 12, 20, 60 or more moles of ethylene oxide to 1 mole a reactive organic compound such as ethyl alcohol, ethylene glycol, Glycol monoethyl ether, glycerine, I, 3- or I, 4-butanediol, sorbitol, dodecyl alcohol, Benzyl alcohol, isooctylphenol, stearylnaphthol, oleic acid, abietic acid, ilticinoleic acid monoglyceride, Oleic acid amide, castor oil, eucalyptus oil, triethanolamine, triethanolamine monolauric acid ester, Diethylenetriamine, hexamethylenetetramine, octodecylamine, melamine, urea, tetraethanolammonium hydroxide, Dodecyl mercaptan, benzoic acid, salicylic acid and the like are also suitable rondensation products of benzoic acid, abietic acid and other organic acids with the aforementioned Polyethers.
Söfern' sich die Stoffe nicht ohne weiteres nWiteinander homogen mischen lassen, empfiehlt es sich, sie miteinander zu erwärmen. Im allgemeinen genügt ein gelindes Erwärmen auf etwa 30 bis &o0,--indessen kann auch auf höhere Temperaturen erwärmt werden. If the substances do not simply become homogeneous with one another let mix, it is advisable to heat them together. In general it is sufficient a gentle warming to about 30 to & o0, - however, can also to higher temperatures be heated.
Oftmals- ist- es e& vvorteilhaft, den Mischungen noch -Lösungsmiffel, z. B. Äthylalkohol, Isopropylalkohbl, Aceton, Glycerin u. dgl., einzuverleiben. Den wäßrigen Verdünnungen solcher Mischungen können auch Tonerdesalze, Zinksalze, wasserlösliche Kolloide od. dgl. oder organische Säuren zugesetzt werden.Often it is advantageous to add solvents to the mixtures, z. B. ethyl alcohol, isopropyl alcohol, acetone, glycerin and the like. The aqueous dilutions of such mixtures can also include alumina salts, zinc salts, water-soluble colloids or the like or organic acids are added.
Die nach dem beschriebenen Verfahren erhältlichen Mischungen eignen sich vorzüglich zur Herstellung von Haarpflegemitteln, Gesichtswässern und anderen kosmetischen Mitteln, von Parfüms, Geschmacksaromen und Konservierungsmitteln: Die in den nachstehend - aufgeführten Beispielen angegebenen Teile sind Gewichtsteile. The mixtures obtainable by the process described are suitable excellent for the production of hair care products, facial tonics and others cosmetic products, of perfumes, flavorings and preservatives: The In the examples given below, parts are parts by weight.
Beispiel I Man erwärmt das Einwirkungsprodukt von 12 Mo1 Äthylenoxyd auf x Mol DodecylalkQhol zusammen. mit gleichen Teilen Isooctylalkohol auf etwa 400 - Die -viskose, hellgelbe Lösung läßt sich mit Wasser beliebig verdünnen, wobei man durchscheinende Lösungen erhält. Stellt man eine Mischung ein aus 2 Teilen Isopropylalkohol, I Teil Isooctanol und I Teil des genannten Kondensationsproduktes und verdünnt diese mit Wasser, so erhält man völlig klare Lösungen. Example I The product of action of 12 mol of ethylene oxide is heated to x moles of dodecyl alcohol. with equal parts isooctyl alcohol to about 400 - The viscous, light yellow solution can be diluted with water as desired, whereby translucent solutions are obtained. If you make a mixture of 2 parts isopropyl alcohol, I part of isooctanol and I part of the condensation product mentioned and dilutes them with water, completely clear solutions are obtained.
Beispiel 2 Man löst in 60 Teilen des Einwirkungsproduktes von Io Mol Äthylenoxyd auf I Mol Isooctylnaphthol 40 Teile Dekahydronaphtholacétat. Bei der Verdünnung mit Wasser erhält man Lösungen, die keine Abscheidungen zeigen. Example 2 The product of the action of Io is dissolved in 60 parts Mole of ethylene oxide to 1 mole of isooctylnaphthol 40 parts of decahydronaphthol acetate. at dilution with water gives solutions which do not show any deposits.
Beispiel 3 Man mischt Hexaäthylenglykol mit 4 0/o Methylacetophenon. Es entsteht ein hellgelbes dünnfiüssiges Öl welches sich mit Wasser ohne Niederschlagsbildung beliebig verdünnen läßt. EXAMPLE 3 Hexaethylene glycol is mixed with 4 0 / o methylacetophenone. The result is a light yellow, thin oil which dissolves with water without the formation of a precipitate can be diluted as required.
Beispiel 4 Man löst in 95 Teilen des Einwfrkungsproduktes von 58 Mol Äthylenoxyd auf I Mol Diäthylenglykol 5 Teile Benzaldehyd bei 80". Man erhält eine gelb--braune halbfeste Masse, die sich mit Wasser ohne Trübung beliebig verdünnen läßt. Example 4 Dissolve in 95 parts of the ingredient of 58 Mole of ethylene oxide to 1 mole of diethylene glycol 5 parts of benzaldehyde at 80 ". One obtains a yellow-brown semi-solid mass that can be diluted with water without clouding leaves.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR865510X | 1948-06-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE865510C true DE865510C (en) | 1953-02-02 |
Family
ID=9344398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEP11855A Expired DE865510C (en) | 1948-06-30 | 1948-10-02 | Process for the production of mixtures of substances which are insoluble or only slightly soluble in water, which can be diluted with water without excretions |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE865510C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2397188A1 (en) * | 1977-07-11 | 1979-02-09 | Henkel Kgaa | AQUEOUS OR HYDROALCOOLIC STABLE SOLUTION OF PERFUMES SOLUBLE IN OILS |
| EP0017207A1 (en) * | 1979-04-04 | 1980-10-15 | Henkel Kommanditgesellschaft auf Aktien | Stable aqueous or hydro-alcoholic solutions of fat-soluble perfume oils |
| EP0032658A2 (en) * | 1980-01-16 | 1981-07-29 | BASF Aktiengesellschaft | Use of di-tert.-alkylphenolethoxylates as solubilizing agents for cosmetic and pharmaceutical preparations |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE534326C (en) * | 1929-12-12 | 1931-09-25 | I G Farbenindustrie Akt Ges | Dispersions |
| DE605973C (en) * | 1930-11-30 | 1934-11-22 | I G Farbenindustrie Akt Ges | Process for the production of ethers from hydroxyl-containing organic compounds and ethylene oxide |
| DE675966C (en) * | 1935-08-25 | 1939-05-23 | I G Farbenindustrie Akt Ges | Process for the production of clear aqueous solutions of ethereal oils, camphor, terpenes |
-
1948
- 1948-10-02 DE DEP11855A patent/DE865510C/en not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE534326C (en) * | 1929-12-12 | 1931-09-25 | I G Farbenindustrie Akt Ges | Dispersions |
| DE605973C (en) * | 1930-11-30 | 1934-11-22 | I G Farbenindustrie Akt Ges | Process for the production of ethers from hydroxyl-containing organic compounds and ethylene oxide |
| DE675966C (en) * | 1935-08-25 | 1939-05-23 | I G Farbenindustrie Akt Ges | Process for the production of clear aqueous solutions of ethereal oils, camphor, terpenes |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2397188A1 (en) * | 1977-07-11 | 1979-02-09 | Henkel Kgaa | AQUEOUS OR HYDROALCOOLIC STABLE SOLUTION OF PERFUMES SOLUBLE IN OILS |
| EP0017207A1 (en) * | 1979-04-04 | 1980-10-15 | Henkel Kommanditgesellschaft auf Aktien | Stable aqueous or hydro-alcoholic solutions of fat-soluble perfume oils |
| EP0032658A2 (en) * | 1980-01-16 | 1981-07-29 | BASF Aktiengesellschaft | Use of di-tert.-alkylphenolethoxylates as solubilizing agents for cosmetic and pharmaceutical preparations |
| EP0032658A3 (en) * | 1980-01-16 | 1982-08-04 | Basf Aktiengesellschaft | Use of di-tert.-alkylphenolethoxylates as solubilizing agents for cosmetic and pharmaceutical preparations |
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