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DE847001C - Process for the production of gaseous, unsaturated hydrocarbons, in particular of ethylene, and of aromatic hydrocarbons - Google Patents

Process for the production of gaseous, unsaturated hydrocarbons, in particular of ethylene, and of aromatic hydrocarbons

Info

Publication number
DE847001C
DE847001C DEP46299A DEP0046299A DE847001C DE 847001 C DE847001 C DE 847001C DE P46299 A DEP46299 A DE P46299A DE P0046299 A DEP0046299 A DE P0046299A DE 847001 C DE847001 C DE 847001C
Authority
DE
Germany
Prior art keywords
hydrocarbons
production
ethylene
gaseous
aromatic hydrocarbons
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEP46299A
Other languages
German (de)
Inventor
Gerhard Dr Free
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DEP46299A priority Critical patent/DE847001C/en
Application granted granted Critical
Publication of DE847001C publication Critical patent/DE847001C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/26—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with discontinuously preheated non-moving solid material, e.g. blast and run
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/28—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material
    • C10G9/30—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material according to the "moving bed" method

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Verfahren zur Herstellung gasförmiger ungesättigter Kohlenwasserstoffe, insbesondere von Äthylen, sowie von aromatischen Kohlenwasserstoff en 1)as I';tteut S-o 2317 hetrittt ein Verfahren zur Herstellung <"astiirtniger ungesättigter Kohlen- ttassersttitfiltslttsl1ittiere von Äthylen, und von arotnatis(lten Kohieimasserstoffen aus vorNviegend parattinis@hcn Kohlenwasserstoftölen oder deren Fraktionrii, ttoltei inan die Ausgangsstoffe mit por@isell, inerten Stoffest in feinverteilter oder stücki@@er Form hei "hcml@eraturen oberhalb 5oo° his cttt a -00 und edier Durchsatzgeschwindigkeit von o.it bis ett\a 3, zwecl:ni;il.iig his etwa i.; Raum- je l\'.attititeil Reaktionsrahm tind Stunde in lieriilii-ttlig hrillgt. 1--.s hat sich nun gezeigt, daß inan bei dieseln erfahren bei Verwendung der porösen, inerten und nichtmetallischen Stoffe mit der Durchsatzge- schwintligl:eit unter o,6 Raumteile .,#usnangsstoffe jt# l\>,atiniteil Reaktionsraum und Stunde herunter- gehest lcami- sinn erhält noch brauchbare Aus- beuten aii t\ ertvollen ungesättigten Kohlenwasser- stoffen bei eilrein Durchsatz von nur etwa 0,3 Raum- teilen je Raumteil Reaktionsraum und Stunde; weiter mit der Strömungsgeschwindigkeit herunterzugehen empfiehlt sich nicht. Die übrigen Reaktionsbedingungen können in der im Hauptpatent angegebenen Weise gewählt werden.Process for the production of gaseous unsaturated hydrocarbons, in particular ethylene, and aromatic hydrocarbons 1) as I '; tteut So 2317 a proceeding occurs Production of unsaturated carbon ttassersttitfiltslttsl1ittiere of ethylene, and of arotnatis (contain carbon masses from predominantly parattinis @ hcn hydrocarbon oils or their Fraktionrii, ttoltei inan the starting materials with por @ isell, inert mass of material in finely divided or Stücki @@ he form is called hcml @ eraturen above 500 ° his cttt a -00 and edier throughput speed of o.it to ett \ a 3, zwecl: ni; il.iig to about i .; Space- je l \ '. attititeil reaction cream tind hour in lieriilii-ttlig hrillgt. 1 -. It has now been shown that inan diesels experienced when using the porous, inert and non-metallic materials with the throughput schwintligl: eit under o, 6 room parts., # usnangsstoffe jt # l \>, atini part reaction space and hour down- go lcami-sinn still gets usable output prey on full unsaturated hydrocarbons materials with an urgent throughput of only about 0.3 share reaction room and hour per room part; Going further down with the flow velocity is not recommended. The other reaction conditions can be selected in the manner indicated in the main patent.

.Als poröse, nichtmetallische Stoffe kommen z. B. Bimsstein, Bauxit, Kieselgur, Tonscherben, Porzellanscherben oder Koks in Betracht. Besondere Zusätze sind nicht erforderlich. Die günstigsten Temperaturen sind 55o bis 65o°. Beispiel Schwerbenzin aus paraffinbasischem Erdöl wird hei 6oo° über stückiges unglasiertes Porzellan geleitet, wobei man einen Durchsatz von 0,4 Raumteilen Benzin je Raumteil mit Porzellan gefüllten Reaktionsraum und Stunde wählt. Das Porzellan wird von Zeit zu Zeit durch Abbrennen mit Luft von (lern abgeschiedenen Kohlenstoff befreit. Man kann auch das stückige Porzellan von oben nach unten durch einen vertikalen Ofen leiten und kontinuierlicli oder periodisch aus dem Ofen am unteren Ende ausschleusen. Die Regeneration des Porzellans erfolgt außerhalb des Reaktionsraums; danach wird es iit noch heißem Zustand wieder in den Reaktionsraum von oben eingeführt. Man erhält 4o % flüssige Anteile vom Siedebereich des Ausgangsstoffs, die vorwiegend aus aromatischen Kohlenwasserstoffen bestehen, und 51 °/o gasförmige Kohlenwasserstoffe, die 581/o Olefine, hauptsächlich Äthylen, und 25 % Äthan und höhere Kohlenwasserstoffe enthalten. Der restliche Teil der Gase besteht vorwiegend aus Methan..As porous, non-metallic materials come z. B. pumice stone, bauxite, Kieselguhr, pottery shards, porcelain shards or coke into consideration. Special additives are not required. The best temperatures are 55o to 65o °. example Heavy gasoline from paraffin-based petroleum is heated to 600 ° over lumpy unglazed Porcelain passed, with a throughput of 0.4 parts of gasoline per part of space reaction chamber filled with porcelain and select the hour. The porcelain will last from time at times freed from carbon deposited by burning with air. Man the lumpy porcelain can also be put through a vertical oven from top to bottom guide and discharge continuously or periodically from the furnace at the lower end. The regeneration of the porcelain takes place outside the reaction space; after that will it is reinserted into the reaction chamber from above while it is still hot. Man receives 4o% liquid fractions from the boiling range of the starting material, which are predominantly consist of aromatic hydrocarbons, and 51 ° / o gaseous hydrocarbons, the 581 / o olefins, chiefly ethylene, and 25% ethane and higher hydrocarbons contain. The remaining part of the gases consists mainly of methane.

Claims (1)

PATENTANSPRUCH: Weitere Ausbildung des Verfahrens des Patents 840 237 zur Herstellung gasförmiger ungesättigter Kohlenwasserstoffe, insbesondere von Äthylen, und von aromatischen Kohlenwasserstoffen aus Kohlenwasserstoffölen oder deren Fraktionen, wobei man die Ausgangsstoffe mit porösen, inerten und nichtmetallischen Stoffen hei Temperaturen oberhalb 5oo°, insbesondere bei 6oo bis 7oo°, in Berührung bringt, dadurch gekennzeichnet, daß man eine Durchsatzgeschivindigkeit der Ausgangsstoffe wählt, die weniger beträgt als o,6 Raumteile Ausgangsstoffe je Raumteil Reaktionsraum und Stunde, vorteilhaft nicht weniger als 0.3 Raumteile.PATENT CLAIM: Further development of the process of patent 840 237 for the production of gaseous unsaturated hydrocarbons, in particular ethylene, and aromatic hydrocarbons from hydrocarbon oils or their fractions, where the starting materials are mixed with porous, inert and non-metallic substances at temperatures above 500 °, in particular at 600 up to 700 °, in contact, characterized in that a Durchsatzgeschivindigkeit of the starting materials is chosen which is less than 0.6 parts by volume of starting materials per part of space reaction space and hour, advantageously not less than 0.3 parts by volume.
DEP46299A 1949-06-19 1949-06-19 Process for the production of gaseous, unsaturated hydrocarbons, in particular of ethylene, and of aromatic hydrocarbons Expired DE847001C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEP46299A DE847001C (en) 1949-06-19 1949-06-19 Process for the production of gaseous, unsaturated hydrocarbons, in particular of ethylene, and of aromatic hydrocarbons

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEP46299A DE847001C (en) 1949-06-19 1949-06-19 Process for the production of gaseous, unsaturated hydrocarbons, in particular of ethylene, and of aromatic hydrocarbons

Publications (1)

Publication Number Publication Date
DE847001C true DE847001C (en) 1952-08-18

Family

ID=7381605

Family Applications (1)

Application Number Title Priority Date Filing Date
DEP46299A Expired DE847001C (en) 1949-06-19 1949-06-19 Process for the production of gaseous, unsaturated hydrocarbons, in particular of ethylene, and of aromatic hydrocarbons

Country Status (1)

Country Link
DE (1) DE847001C (en)

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