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DE745919C - Drahtziehseifen - Google Patents

Drahtziehseifen

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Publication number
DE745919C
DE745919C DEH16038D DEH0016038D DE745919C DE 745919 C DE745919 C DE 745919C DE H16038 D DEH16038 D DE H16038D DE H0016038 D DEH0016038 D DE H0016038D DE 745919 C DE745919 C DE 745919C
Authority
DE
Germany
Prior art keywords
soaps
fatty acids
wire drawing
acids
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEH16038D
Other languages
English (en)
Inventor
Dr Wilhelm Pape
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to DEH16038D priority Critical patent/DE745919C/de
Priority to DEB5847D priority patent/DE929689C/de
Application granted granted Critical
Publication of DE745919C publication Critical patent/DE745919C/de
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M5/00Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M7/00Solid or semi-solid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single solid or semi-solid substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • CCHEMISTRY; METALLURGY
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • C10M2201/042Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14Synthetic waxes, e.g. polythene waxes
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16Paraffin waxes; Petrolatum, e.g. slack wax
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17Fisher Tropsch reaction products
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/404Fatty vegetable or animal oils obtained from genetically modified species
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
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    • C10N2010/04Groups 2 or 12
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/241Manufacturing joint-less pipes
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/242Hot working
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/243Cold working
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    • C10N2040/244Metal working of specific metals
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
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    • C10N2040/244Metal working of specific metals
    • C10N2040/245Soft metals, e.g. aluminum
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
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    • C10N2040/244Metal working of specific metals
    • C10N2040/246Iron or steel
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
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    • C10N2040/247Stainless steel
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  • Drahtziehseifen Bei der Herstellung von synthetischen Fettsäuren, z. B. durch Oxydation von Paraffinkohlenwasserstoffen, fallen erhebliche Mengen niederer Fettsäur en, d. h. aliphatische Carbonsäuren mit 4. bis rö Kohlenstoffatomen, an. Diese Fettsäuregemische werden durch Fraktionieren von den übrigen höhermolekularen Fettsäuren .getrennt; .da sie bei der Destillation als Vorlauf übergehen, nennt man sie auch Vorlauffettsäuren. Es. ist bisher nicht gelungen, diese 'i\-ebenprodukte einer nutzbringenden Verwendung zuzuführen.
  • Es wurde nun gefunden, daB man äus den Vorlauffettsäuren ein*-xhdfreie Drahtziehseifen dann erhält, wenn man lediglich die Säuren mit etwa 6 bis zo Kohlenstoffatomen verwendet. Die niederen Anteile von etwa d. bis 5 Kohlenstoffatomen im Molekül werden vorher durch fraktionierte Destillation abgetrennt. Die verbleibenden Fettsäuren von etwa 6 bis ro Kohlenstoffatomen im Molekül eignen sich in Form ihrer Alkali- bzw. Erdalkaliseifen für das Ziehen von Drähten.
  • Es ist mitunter vorteilhaft, den Säuren geringe Anteile höherer Fettsäuren bzw. Wachssäuren zur Erhöhung des Schmelzpunktes der Seifen vor der Verseifung hinzuzusetzen.
  • An Stelle der Fettsäuren aus der Oxydation von Paraffinen kann man auch ähnliche Gemische; wie sie z. B. als Vorlauf bei der Destillation von Kernölfettsäuren oder Kokosölfettsäuren anfallen, sowie Säuregemische, die bei der Reduktion von Kohlenoxyd mit Wasserstoff unter Druck 'erhalten werden, verwenden.
  • Beispiel Aus einer Vorlauffettsäure, die bei der Destillation von durch Oxydation von Paraffinen gewonnenen Carbonsäuren anfällt, werden die niederen Anteile durch Destillation abgetrennt; die etwa go °/p betragenden Restfettsäuren, die etwa ; bis 1o Kohlenstoffatonie itn Molekül enthalten. werden mit Ätznatron verseift. -Nach dem Trocknen der Seife wird gemahlen; die Seife kann auch in bekannten Zerstäubungsapparateti zu Pulver versprüht werden. Die entstandene pulverförmige Seife wird nunmehr in bekannter `reise beim Ziehen der Drähte verwendet.
  • Eine ähnlich gute Dralitzieliseife erhält nian, wenn man 94 Teile der vorgenannten Vorlauffettsättre mit <i 'Feilen Montansäure verschmilzt und das Gemisch verseift. An Stelle des Ätznatrons kann man auch Ätzkalk zum Verseifen benutzen.

Claims (1)

  1. PATENTANSPRUCH: Verwendung von aliphatischen Carbonsäuren, die etwa 6 bis ro Kohlenstoffatome im Molekül enthalten, in Form ihrer Seifen als Hilfsmittel beim Ziehen von Drähten oder ähnlichen Gegenständen.
DEH16038D 1939-08-12 1939-08-12 Drahtziehseifen Expired DE745919C (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DEH16038D DE745919C (de) 1939-08-12 1939-08-12 Drahtziehseifen
DEB5847D DE929689C (de) 1939-08-12 1942-11-05 Feste Schmiermittel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEH16038D DE745919C (de) 1939-08-12 1939-08-12 Drahtziehseifen

Publications (1)

Publication Number Publication Date
DE745919C true DE745919C (de) 1944-05-24

Family

ID=7147865

Family Applications (1)

Application Number Title Priority Date Filing Date
DEH16038D Expired DE745919C (de) 1939-08-12 1939-08-12 Drahtziehseifen

Country Status (1)

Country Link
DE (1) DE745919C (de)

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