DE69926390T2 - Bleichmittelzusammensetzungen - Google Patents

Bleichmittelzusammensetzungen Download PDF

Info

Publication number: DE69926390T2
Authority: DE; Germany
Prior art keywords: amylase; compositions; composition; enzymes; present
Prior art date: 1998-11-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

DE69926390T

Other languages

German (de)

English (en)

Other versions

DE69926390D1 (de

Inventor

Eugene Michael BURNS

Russell Andrew Gateshead GRAYDON

Regine Labeque

Mark Christopher PERKINS

Steven Eugene SADLOWSKI

Kay Barbara WILLIAMS

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-11-13

Filing date

1999-11-09

Publication date

2006-03-30

1999-11-09 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

2005-09-01 Publication of DE69926390D1 publication Critical patent/DE69926390D1/de

2006-03-30 Application granted granted Critical

2006-03-30 Publication of DE69926390T2 publication Critical patent/DE69926390T2/de

2019-11-10 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title description 115
239000007844 bleaching agent Substances 0.000 title description 43
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102000004139 alpha-Amylases Human genes 0.000 description 42
239000004094 surface-active agent Substances 0.000 description 41
239000003054 catalyst Substances 0.000 description 33
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MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 28
238000004061 bleaching Methods 0.000 description 26
239000003599 detergent Substances 0.000 description 25
102000013142 Amylases Human genes 0.000 description 24
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-1 5,12-diethyl-1,5,8,12-tetraaza-bicyclo [6.6.2] hexadecane manganese Chemical compound 0.000 description 17
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SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 9
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HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
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ZDVCYDPCFIHUCY-UHFFFAOYSA-L 4,11-diethyl-1,4,8,11-tetrazabicyclo[6.6.2]hexadecane;manganese(2+);dichloride Chemical compound Cl[Mn]Cl.C1CN(CC)CCCN2CCN(CC)CCCN1CC2 ZDVCYDPCFIHUCY-UHFFFAOYSA-L 0.000 description 6
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DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
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239000002243 precursor Substances 0.000 description 4
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239000011734 sodium Substances 0.000 description 4
239000002904 solvent Substances 0.000 description 4
239000003381 stabilizer Substances 0.000 description 4
239000000758 substrate Substances 0.000 description 4
108010075550 termamyl Proteins 0.000 description 4
238000005406 washing Methods 0.000 description 4
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BETLSGXAHKBRAR-UHFFFAOYSA-N 10-ethylphenothiazine-4-carboxylic acid Chemical compound C1=CC=C(C(O)=O)C2=C1N(CC)C1=CC=CC=C1S2 BETLSGXAHKBRAR-UHFFFAOYSA-N 0.000 description 2
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NJMWXCOSLAUOGE-UHFFFAOYSA-N 4,11-dimethyl-1,4,8,11-tetrazabicyclo[6.6.2]hexadecane Chemical compound C1CN(C)CCCN2CCN(C)CCCN1CC2 NJMWXCOSLAUOGE-UHFFFAOYSA-N 0.000 description 2
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KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
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FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000011565 manganese chloride Substances 0.000 description 1
235000002867 manganese chloride Nutrition 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000005341 metaphosphate group Chemical group 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
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239000001301 oxygen Substances 0.000 description 1
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230000036961 partial effect Effects 0.000 description 1
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150000002989 phenols Chemical class 0.000 description 1
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239000000467 phytic acid Substances 0.000 description 1
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229920000098 polyolefin Polymers 0.000 description 1
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239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
108090000765 processed proteins & peptides Proteins 0.000 description 1
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102000004169 proteins and genes Human genes 0.000 description 1
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239000002516 radical scavenger Substances 0.000 description 1
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230000002441 reversible effect Effects 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
239000002002 slurry Substances 0.000 description 1
229910000033 sodium borohydride Inorganic materials 0.000 description 1
239000012279 sodium borohydride Substances 0.000 description 1
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239000011343 solid material Substances 0.000 description 1
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Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Detergent Compositions (AREA)

DE69926390T 1998-11-13 1999-11-09 Bleichmittelzusammensetzungen Expired - Fee Related DE69926390T2 (de)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US10829298P	1998-11-13	1998-11-13
US108292P		1998-11-13
PCT/US1999/026543 WO2000029537A1 (en)	1998-11-13	1999-11-09	Bleach compositions

Publications (2)

Publication Number	Publication Date
DE69926390D1 DE69926390D1 (de)	2005-09-01
DE69926390T2 true DE69926390T2 (de)	2006-03-30

Family

ID=22321370

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE69926390T Expired - Fee Related DE69926390T2 (de)	1998-11-13	1999-11-09	Bleichmittelzusammensetzungen

Country Status (11)

Country	Link
EP (1)	EP1129164B1 (zh)
JP (1)	JP2002530481A (zh)
CN (1)	CN1333813A (zh)
AR (1)	AR021250A1 (zh)
AT (1)	ATE300601T1 (zh)
AU (1)	AU1522300A (zh)
BR (1)	BR9915319A (zh)
CA (1)	CA2349011A1 (zh)
DE (1)	DE69926390T2 (zh)
TR (1)	TR200101330T2 (zh)
WO (1)	WO2000029537A1 (zh)

Families Citing this family (56)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1351646A (zh)	1999-04-01	2002-05-29	荷兰联合利华有限公司	用于底物漂白的组合物和方法
WO2001016271A1 (en) *	1999-09-01	2001-03-08	Unilever Plc	Composition and method for bleaching a substrate
GB0004990D0 (en)	2000-03-01	2000-04-19	Unilever Plc	Composition and method for bleaching a substrate
EP1208185A2 (en) *	1999-09-01	2002-05-29	Unilever Plc	Composition and method for bleaching a substrate
GB9930695D0 (en)	1999-12-24	2000-02-16	Unilever Plc	Composition and method for bleaching a substrate
GB0030673D0 (en)	2000-12-15	2001-01-31	Unilever Plc	Ligand and complex for catalytically bleaching a substrate
GB0030877D0 (en)	2000-12-18	2001-01-31	Unilever Plc	Enhancement of air bleaching catalysts
GB0102826D0 (en)	2001-02-05	2001-03-21	Unilever Plc	Composition and method for bleaching a substrate
GB0103871D0 (en)	2001-02-16	2001-04-04	Unilever Plc	Bleaching composition of enhanced stability and a process for making such a composition
GB0106285D0 (en)	2001-03-14	2001-05-02	Unilever Plc	Air bleaching catalysts with moderating agent
CA2439524A1 (en)	2001-03-14	2002-09-19	Unilever Plc	Bleaching catalysts with unsaturated surfactant and antioxidants
US7115549B2 (en)	2001-08-02	2006-10-03	Carnegie Mellon University	Composition comprising macrocyclic tetra-amido metal complex as bleaching catalyst
US7086110B2 (en)	2002-02-13	2006-08-08	The Procter & Gamble Company	Selective dispensing of laundry additives during automatic machine laundering of fabric
US7340790B2 (en)	2002-02-13	2008-03-11	Procter & Gamble Company	Universal dispenser for dispensing of laundry additives during automatic machine laundering of fabrics
US7168273B2 (en)	2002-11-07	2007-01-30	The Procter & Gamble Company	Selective dispensing apparatus
US7716956B2 (en)	2002-12-20	2010-05-18	The Procter & Gamble Company	Attachment means
WO2003069042A1 (en)	2002-02-13	2003-08-21	The Procter & Gamble Company	Dispensing of rinse additives into the rinse cycle during automatic machine laundering of fabrics
WO2003069043A1 (en)	2002-02-13	2003-08-21	The Procter & Gamble Company	Sequential dispensing of laundry additives during automatic machine laundering of fabrics
GB0325432D0 (en)	2003-10-31	2003-12-03	Unilever Plc	Ligand and complex for catalytically bleaching a substrate
GB0325430D0 (en)	2003-10-31	2003-12-03	Unilever Plc	Ligand and complex for catalytically bleaching a substrate
US7445643B2 (en)	2003-12-03	2008-11-04	The Procter & Gamble Company	Automatic machine laundering of fabrics
EP1700907A1 (en)	2005-03-11	2006-09-13	Unilever N.V.	Liquid bleaching composition
IN266777B (zh)	2006-03-24	2015-06-01	Acal Energy Ltd
GB0608079D0 (en)	2006-04-25	2006-05-31	Acal Energy Ltd	Fuel cells
GB0614338D0 (en)	2006-07-19	2006-08-30	Acal Energy Ltd	Fuel cells
GB0614337D0 (en)	2006-07-19	2006-08-30	Acal Energy Ltd	Fuel Cells
ES2394847T3 (es) *	2007-01-16	2013-02-06	Catexel Limited	Blanqueo de sustratos
GB0718349D0 (en)	2007-09-20	2007-10-31	Acal Energy Ltd	Fuel cells
GB0718577D0 (en)	2007-09-24	2007-10-31	Acal Energy Ltd	Fuel cells
GB0801199D0 (en)	2008-01-23	2008-02-27	Acal Energy Ltd	Fuel cells
GB0801198D0 (en)	2008-01-23	2008-02-27	Acal Energy Ltd	Fuel cells
GB0810881D0 (en)	2008-06-16	2008-07-23	Unilever Plc	Improvements relating to fabric cleaning
ES2457495T3 (es)	2010-03-31	2014-04-28	Unilever N.V.	Incorporación de microcápsulas a detergentes líquidos estructurados
HUE025312T2 (en)	2010-04-01	2016-02-29	Unilever Nv	Structure of detergent fluids with hydrogenated castor oil
WO2011150138A1 (en) *	2010-05-26	2011-12-01	The Procter & Gamble Company	Encapsulates
EP2441820A1 (en)	2010-10-14	2012-04-18	Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House	Laundry detergent particles
EP2670788B1 (en)	2011-01-31	2015-03-11	Unilever PLC	Alkaline liquid detergent compositions
EP2495300A1 (en)	2011-03-04	2012-09-05	Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House	Structuring detergent liquids with hydrogenated castor oil
ES2421162T3 (es)	2011-04-04	2013-08-29	Unilever Nv	Procedimiento de lavado de telas
CN103517975B (zh)	2011-05-13	2015-11-25	荷兰联合利华有限公司	水性浓缩衣物洗涤剂组合物
EP2522715A1 (en)	2011-05-13	2012-11-14	Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House	Aqueous concentrated laundry detergent compositions
EP2522714A1 (en)	2011-05-13	2012-11-14	Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House	Aqueous concentrated laundry detergent compositions
CN103174011A (zh) *	2011-11-24	2013-06-26	东华大学	四氮双环十四烷金属配合物在纺织品低温练漂助剂中的应用
CN103194895A (zh) *	2011-11-24	2013-07-10	东华大学	四氮杂环十六烷金属配合物在纺织品低温练漂助剂中的应用
CN103194894A (zh) *	2011-11-24	2013-07-10	东华大学	四吡啶基五氮金属配合物在纺织品低温练漂助剂中的应用
EP2794832B1 (en)	2011-12-20	2016-05-25	Unilever Plc.	Isotropic liquid detergents comprising soil release polymer
BR112014026932B1 (pt)	2012-05-16	2021-08-31	Unilever Ip Holdings B.V	Composição detergente para lavar roupa e processo para lavar roupa
CN104937090B (zh)	2013-01-23	2018-10-09	荷兰联合利华有限公司	促进抗颗粒状污垢再沉积的未着色洗衣添加剂材料
EP2770044A1 (en)	2013-02-20	2014-08-27	Unilever PLC	Lamellar gel with amine oxide
EP3277784A1 (en)	2015-04-02	2018-02-07	Unilever Plc.	Composition
CN109153941A (zh)	2016-05-17	2019-01-04	荷兰联合利华有限公司	液体洗衣洗涤剂组合物
CN109196083A (zh)	2016-05-17	2019-01-11	荷兰联合利华有限公司	液体洗衣洗涤剂组合物
WO2017202923A1 (en)	2016-05-27	2017-11-30	Unilever Plc	Laundry composition
WO2018127390A1 (en)	2017-01-06	2018-07-12	Unilever N.V.	Stain removing composition
WO2019038187A1 (en)	2017-08-24	2019-02-28	Unilever Plc	IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS
WO2019038186A1 (en)	2017-08-24	2019-02-28	Unilever Plc	IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB9127060D0 (en) *	1991-12-20	1992-02-19	Unilever Plc	Bleach activation
EP0553607B1 (en) *	1992-01-31	1998-03-18	The Procter & Gamble Company	Detergent compositions inhibiting dye transfer in washing
CA2283163C (en) *	1997-03-07	2006-10-31	The Procter & Gamble Company	Bleach compositions comprising a transition metal bleach catalyst incorporating a cross-bridged macropolycyclic ligand and an oxygen bleach
CN1263759C (zh) *	1997-03-07	2006-07-12	宝洁公司	制备交联桥大环化合物的改进方法

1999
- 1999-11-09 TR TR2001/01330T patent/TR200101330T2/xx unknown
- 1999-11-09 WO PCT/US1999/026543 patent/WO2000029537A1/en active IP Right Grant
- 1999-11-09 AT AT99957539T patent/ATE300601T1/de not_active IP Right Cessation
- 1999-11-09 JP JP2000582521A patent/JP2002530481A/ja not_active Withdrawn
- 1999-11-09 BR BR9915319-0A patent/BR9915319A/pt not_active Application Discontinuation
- 1999-11-09 EP EP99957539A patent/EP1129164B1/en not_active Expired - Lifetime
- 1999-11-09 CA CA002349011A patent/CA2349011A1/en not_active Abandoned
- 1999-11-09 CN CN99815476.8A patent/CN1333813A/zh active Pending
- 1999-11-09 AU AU15223/00A patent/AU1522300A/en not_active Abandoned
- 1999-11-09 DE DE69926390T patent/DE69926390T2/de not_active Expired - Fee Related
- 1999-11-12 AR ARP990105756A patent/AR021250A1/es unknown

Also Published As

Publication number	Publication date
AR021250A1 (es)	2002-07-03
BR9915319A (pt)	2001-08-07
EP1129164A1 (en)	2001-09-05
AU1522300A (en)	2000-06-05
DE69926390D1 (de)	2005-09-01
CN1333813A (zh)	2002-01-30
TR200101330T2 (tr)	2001-10-22
EP1129164B1 (en)	2005-07-27
JP2002530481A (ja)	2002-09-17
WO2000029537A1 (en)	2000-05-25
CA2349011A1 (en)	2000-05-25
ATE300601T1 (de)	2005-08-15

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DE69926390T2 (de)	2006-03-30	Bleichmittelzusammensetzungen
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DE69522579T2 (de)	2002-07-11	Verwendung von spezifische lipolytische enzyme in reinigungsmitteln
DE3322950C2 (zh)	1991-10-10
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DE69719568T2 (de)	2003-12-24	Oxidoreductase enthaltende reinigungszusammensetzungen
DE602004012766T2 (de)	2009-05-07	Flüssiges waschmittel
US6653270B2 (en)	2003-11-25	Stabilized bleach compositions
DE69618465T2 (de)	2002-09-19	Reinigen von schmutzigen geweben mit amylase enthaltenden waschmittelzusammensetzungen
DE69722802T2 (de)	2004-05-19	Waschmittel enthaltend ein gemisch aus kationischen, anionischen und nichtionischen tensiden
EP0822973B1 (de)	1999-06-16	Cellulasehaltiges waschmittel
DE69623049T2 (de)	2003-04-24	Verwendung von polyamin-scavenger in enzyme enthaltenden waschmittelzusammensetzungen
US6667288B2 (en)	2003-12-23	Bleach compositions
DE69632037T2 (de)	2004-11-18	Bleichmittelvorläuferzusammensetzungen
DE69727704T3 (de)	2012-06-06	Reinigungszusammensetzungen enthaltend eine spezifische oxygenase

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Date	Code	Title	Description
2006-08-17	8364	No opposition during term of opposition
2007-09-13	8339	Ceased/non-payment of the annual fee