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DE69909502D1 - Mehrstufiges ethylenpolymerisationsverfahren - Google Patents

Mehrstufiges ethylenpolymerisationsverfahren

Info

Publication number
DE69909502D1
DE69909502D1 DE69909502T DE69909502T DE69909502D1 DE 69909502 D1 DE69909502 D1 DE 69909502D1 DE 69909502 T DE69909502 T DE 69909502T DE 69909502 T DE69909502 T DE 69909502T DE 69909502 D1 DE69909502 D1 DE 69909502D1
Authority
DE
Germany
Prior art keywords
reactor
polymerization process
ethylene polymerization
stage ethylene
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69909502T
Other languages
English (en)
Other versions
DE69909502T2 (de
Inventor
Isam Jaber
John Brown
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nova Chemicals International SA
Original Assignee
Nova Chemicals International SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chemicals International SA filed Critical Nova Chemicals International SA
Publication of DE69909502D1 publication Critical patent/DE69909502D1/de
Application granted granted Critical
Publication of DE69909502T2 publication Critical patent/DE69909502T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/06Organic solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
DE69909502T 1998-09-22 1999-08-27 Mehrstufiges ethylenpolymerisationsverfahren Expired - Lifetime DE69909502T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CA2247703 1998-09-22
CA002247703A CA2247703C (en) 1998-09-22 1998-09-22 Dual reactor ethylene polymerization process
PCT/CA1999/000790 WO2000017244A1 (en) 1998-09-22 1999-08-27 Dual reactor ethylene polymerization process

Publications (2)

Publication Number Publication Date
DE69909502D1 true DE69909502D1 (de) 2003-08-14
DE69909502T2 DE69909502T2 (de) 2004-06-09

Family

ID=4162832

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69909502T Expired - Lifetime DE69909502T2 (de) 1998-09-22 1999-08-27 Mehrstufiges ethylenpolymerisationsverfahren

Country Status (12)

Country Link
US (1) US6277931B1 (de)
EP (1) EP1124864B1 (de)
JP (1) JP4576049B2 (de)
KR (1) KR100615758B1 (de)
CN (1) CN1138792C (de)
AT (1) ATE244733T1 (de)
AU (1) AU5403699A (de)
BR (1) BR9913881A (de)
CA (1) CA2247703C (de)
DE (1) DE69909502T2 (de)
ES (1) ES2203165T3 (de)
WO (1) WO2000017244A1 (de)

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KR101141494B1 (ko) * 2007-09-05 2012-05-03 에스케이이노베이션 주식회사 다봉 분자량 분포를 갖는 에틸렌 공중합체 및 이의제조방법
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EP2256159A1 (de) 2009-05-26 2010-12-01 Borealis AG Polymerzusammensetzung für vernetzte Rohre
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US8796408B2 (en) 2012-08-31 2014-08-05 Exxonmobil Chemical Patents Inc. Plants and processes for forming polymers
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US9475927B2 (en) 2012-12-14 2016-10-25 Nova Chemicals (International) S.A. Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
EP3209721B1 (de) 2014-10-21 2021-09-22 Nova Chemicals (International) S.A. Kontinuierliches lösungspolymerisationsverfahren
EP3209722A2 (de) * 2014-10-21 2017-08-30 Nova Chemicals (International) S.A. Ethyleninterpolymerprodukt mit verdünnungsindex
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CA2874344C (en) 2014-12-15 2021-08-31 Nova Chemicals Corporation Spheroidal catalyst for olefin polymerization
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CA2891693C (en) 2015-05-21 2022-01-11 Nova Chemicals Corporation Controlling the placement of comonomer in an ethylene copolymer
CA2892552C (en) 2015-05-26 2022-02-15 Victoria Ker Process for polymerization in a fluidized bed reactor
CA2892882C (en) 2015-05-27 2022-03-22 Nova Chemicals Corporation Ethylene/1-butene copolymers with enhanced resin processability
US9758653B2 (en) 2015-08-19 2017-09-12 Nova Chemicals (International) S.A. Polyethylene compositions, process and closures
CA2914354C (en) 2015-12-10 2022-11-08 Nova Chemicals Corp. Hot fill process with closures made frm bimodal polyethylene compositions
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US9783664B1 (en) 2016-06-01 2017-10-10 Nova Chemicals (International) S.A. Hinged component comprising polyethylene composition
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JP7326283B2 (ja) * 2017-12-26 2023-08-15 ダウ グローバル テクノロジーズ エルエルシー マルチモーダルエチレン系ポリマーの製造のための二重反応器溶液プロセス
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BR112021011902B1 (pt) 2018-12-18 2024-01-23 Nova Chemicals (International) S.A Filmes de múltiplas camadas
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Also Published As

Publication number Publication date
JP2002526573A (ja) 2002-08-20
US6277931B1 (en) 2001-08-21
CA2247703C (en) 2007-04-17
ATE244733T1 (de) 2003-07-15
WO2000017244A1 (en) 2000-03-30
KR20010075250A (ko) 2001-08-09
AU5403699A (en) 2000-04-10
CN1138792C (zh) 2004-02-18
DE69909502T2 (de) 2004-06-09
EP1124864A1 (de) 2001-08-22
EP1124864B1 (de) 2003-07-09
JP4576049B2 (ja) 2010-11-04
KR100615758B1 (ko) 2006-08-25
ES2203165T3 (es) 2004-04-01
CN1319107A (zh) 2001-10-24
BR9913881A (pt) 2001-07-24
CA2247703A1 (en) 2000-03-22

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