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DE69902485D1 - METHOD FOR PRODUCING ACYLPHOSPHINES AND DERIVATIVES - Google Patents

METHOD FOR PRODUCING ACYLPHOSPHINES AND DERIVATIVES

Info

Publication number
DE69902485D1
DE69902485D1 DE69902485T DE69902485T DE69902485D1 DE 69902485 D1 DE69902485 D1 DE 69902485D1 DE 69902485 T DE69902485 T DE 69902485T DE 69902485 T DE69902485 T DE 69902485T DE 69902485 D1 DE69902485 D1 DE 69902485D1
Authority
DE
Germany
Prior art keywords
mono
preparation
acylphosphines
derivatives
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69902485T
Other languages
German (de)
Other versions
DE69902485T2 (en
DE69902485T3 (en
Inventor
George Leppard
Eugen Eichenberger
Rene Kaeser
Gebhard Hug
Urs Schwendimann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25690294&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69902485(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of DE69902485D1 publication Critical patent/DE69902485D1/en
Publication of DE69902485T2 publication Critical patent/DE69902485T2/en
Application granted granted Critical
Publication of DE69902485T3 publication Critical patent/DE69902485T3/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5036—Phosphines containing the structure -C(=X)-P or NC-P
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/5337—Phosphine oxides or thioxides containing the structure -C(=X)-P(=X) or NC-P(=X) (X = O, S, Se)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Saccharide Compounds (AREA)

Abstract

A description is given of processes for the preparation of mono- and bisacylphosphines and of mono- and bisacylphosphine oxides and mono- and bisacylphosphine sulfides, which comprises first reacting organic P-monohalogenophosphines or P,P-dihalogenophosphines, or mixtures thereof, with an alkali metal or magnesium in combination with lithium, where appropriate in the presence of a catalyst, and then carrying out the reaction with acid halides and, in the case of the process for the preparation of oxides, carrying out an oxidation step and, in the case of the preparation of sulfides, reacting the phosphines so obtained with sulfur. It is characteristic, inter alia, that the processes are carried out without isolation of the intermediates.
DE69902485T 1998-11-30 1999-11-20 PROCESS FOR THE PREPARATION OF ACYLPHOSPHINS AND DERIVATIVES Expired - Lifetime DE69902485T3 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CH237698 1998-11-30
CH237698 1998-11-30
CH243498 1998-12-08
CH243498 1998-12-08
PCT/EP1999/008968 WO2000032612A1 (en) 1998-11-30 1999-11-20 Process for preparing acylphosphines and derivatives

Publications (3)

Publication Number Publication Date
DE69902485D1 true DE69902485D1 (en) 2002-09-12
DE69902485T2 DE69902485T2 (en) 2003-05-08
DE69902485T3 DE69902485T3 (en) 2007-03-15

Family

ID=25690294

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69902485T Expired - Lifetime DE69902485T3 (en) 1998-11-30 1999-11-20 PROCESS FOR THE PREPARATION OF ACYLPHOSPHINS AND DERIVATIVES

Country Status (14)

Country Link
US (3) US6888031B1 (en)
EP (1) EP1135399B2 (en)
JP (1) JP4265871B2 (en)
KR (1) KR100653117B1 (en)
CN (1) CN1211388C (en)
AT (1) ATE221893T1 (en)
AU (1) AU760237B2 (en)
CA (1) CA2349637C (en)
CZ (1) CZ302512B6 (en)
DE (1) DE69902485T3 (en)
ES (1) ES2180347T5 (en)
SK (1) SK286152B6 (en)
TW (1) TW492972B (en)
WO (1) WO2000032612A1 (en)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2349637C (en) * 1998-11-30 2008-12-23 Ciba Specialty Chemicals Holding Inc. Process for preparing acylphosphines and derivatives
GB2360283B (en) * 2000-02-08 2002-08-21 Ciba Sc Holding Ag Monoacylarylphosphines and acylphosphine oxides and sulphides
GB2365430B (en) * 2000-06-08 2002-08-28 Ciba Sc Holding Ag Acylphosphine photoinitiators and intermediates
US7148382B2 (en) 2001-08-21 2006-12-12 Ciba Specialty Chemicals Corporation Bathochromic mono- and bis-acylphosphine oxides and sulfides and their use as photoinitiators
DE10206117A1 (en) 2002-02-13 2003-08-14 Basf Ag Acyl and bisacylphosphine derivatives
DE10244684A1 (en) 2002-09-24 2004-04-01 Basf Ag Process for the preparation of acylphosphine oxides
WO2004050668A1 (en) * 2002-12-04 2004-06-17 Ciba Specialty Chemicals Holding Inc. Process for the synthesis of cycloorganylphosphanes and di(alkali metal/alkaline earth metal) oligophosphanediides
DE10315671A1 (en) * 2003-04-04 2004-10-14 Basf Ag Process for the preparation of acylphosphine oxide solids
DE602004002877T2 (en) * 2003-07-18 2007-05-24 Ciba Speciality Chemicals Holding Inc. PROCESS FOR THE PREPARATION OF ACYLPHOSPHINES AND THEIR DERIVATIVES
TW200523265A (en) * 2003-07-31 2005-07-16 Basf Ag A process for the preparation of acylphosphines
ATE496928T1 (en) * 2004-11-23 2011-02-15 Basf Se BISACYLPHOSPHANES AND THEIR USE AS PHOTOINITIATORS, PROCESS FOR PRODUCING ACYLPHOSPHANES
EP1838721B1 (en) * 2005-01-17 2011-12-21 Basf Se Process for preparing acylphosphanes and their oxides and sulphides
DE102005005946A1 (en) * 2005-02-10 2006-08-17 Basf Ag Process for the preparation of tertiary phosphines
CN102203136B (en) 2008-11-03 2013-11-13 巴斯夫欧洲公司 Photoinitiator mixtures
WO2010121387A1 (en) * 2009-04-20 2010-10-28 ETH Zürich Polymer nanoparticles
CN102875598B (en) * 2011-07-11 2016-09-07 深圳市有为化学技术有限公司 (diphenyl phosphinyl groups) (mesitylene base) ketone and the preparation method of (phosphniline epoxide) double (mesitylene base ketone)
CN102875597B (en) * 2011-07-11 2017-05-03 深圳市有为化学技术有限公司 Aromatic ketone phosphine oxide heterocompound
CN102675365A (en) * 2012-05-16 2012-09-19 湖北固润科技股份有限公司 Synthesis method for ultraviolet photoinitiator XBPO
GB201213163D0 (en) 2012-07-24 2012-09-05 Lambson Ltd Photopolymerisation processes and novel compounds therefor
EP2903995B1 (en) 2012-10-01 2019-01-16 ETH Zürich A process for the preparation of acylphosphanes
WO2014140356A1 (en) 2013-03-15 2014-09-18 Freefly Systems Inc. Method for enabling manual adjustment of a pointing direction of an actively stabilized camera
CN104592298B (en) * 2014-12-31 2016-07-06 湖北固润科技股份有限公司 A kind of acylphosphanes efficiency light initiator and preparation method thereof
CN105541913B (en) * 2015-12-03 2017-08-25 天津久日新材料股份有限公司 A kind of preparation method of 2,4,6 trimethyl benzoyl diphenyl base phosphine oxide
CN105732709A (en) * 2016-03-16 2016-07-06 三峡大学 Photo-initiator 2,4,6-trimethylbenzoyldicyclohexyloxyphosphine and preparation method and application thereof
CN105732710A (en) * 2016-03-16 2016-07-06 三峡大学 Preparation method and application of photo-initiator diphenyl tetra(2,4,6-trimethylbenzoyl)oxyphosphine
CN107304220B (en) * 2016-04-22 2020-03-31 江苏英力科技发展有限公司 Method for synthesizing 2,4, 6-trimethylbenzoyl-diphenylphosphine oxide by one-pot method
EP3296301A1 (en) 2016-09-19 2018-03-21 ETH Zürich A versatile process for the preparation of acylphosphines
JP6916484B2 (en) * 2017-03-28 2021-08-11 国立大学法人千葉大学 Method for producing acylphosphine
EP3409680B1 (en) 2017-05-30 2021-01-06 IGM Group B.V. Synthesis of bis(acyl)phosphines by activation of unreactive metal phosphides
EP3539924A1 (en) 2018-03-14 2019-09-18 ETH Zurich Novel vinyl phosphines and photo-initiators obtainable therefrom
CN110734461A (en) * 2018-07-20 2020-01-31 深圳市有为化学技术有限公司 Preparation of compound 2,4, 6-trimethylbenzoyldiphenylphosphine oxide
US20220106340A1 (en) * 2018-12-07 2022-04-07 Anqing Lighting Optoelectronics Technology Co., Ltd Acylphosphine oxide compounds and preparation methods thereof
CN111138491B (en) * 2019-12-31 2022-08-05 天津久日新材料股份有限公司 Method for preparing photoinitiator TPO and simultaneously producing benzyl chloride as byproduct
CN111087425B (en) 2020-01-10 2022-04-19 天津大学 A large particle size phenyl bis(2,4,6-trimethylbenzoyl) phosphine oxide crystal form and crystallization method thereof
CN112279940B (en) * 2020-04-17 2023-06-27 山东科技大学 Acylphosphine photoinitiator and preparation method thereof
CN112159429B (en) * 2020-10-29 2022-06-21 天津久日新材料股份有限公司 Preparation method of bis (2,4, 6-trimethylbenzoyl) phenylphosphine oxide
JP7600464B1 (en) 2024-10-03 2024-12-16 サカタインクス株式会社 Active energy ray curable inkjet printing ink

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2962089D1 (en) 1978-07-14 1982-03-18 Basf Ag Light-curable moulding, impregnating and coating compositions and shaped articles prepared therefrom
DE2909994A1 (en) 1979-03-14 1980-10-02 Basf Ag ACYLPHOSPHINOXIDE COMPOUNDS, THEIR PRODUCTION AND USE
DE3020092A1 (en) 1980-05-27 1981-12-10 Basf Ag, 6700 Ludwigshafen ACYLPHOSPHINE COMPOUNDS AND THEIR USE
DE3034697A1 (en) 1980-09-15 1982-05-06 Basf Ag, 6700 Ludwigshafen ACYLPHOSPHINE SULFIDE COMPOUNDS, THEIR PRODUCTION AND USE
DE3443221A1 (en) 1984-11-27 1986-06-05 ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld BISACYLPHOSPHINOXIDE, THEIR PRODUCTION AND USE
US5218009A (en) * 1989-08-04 1993-06-08 Ciba-Geigy Corporation Mono- and di-acylphosphine oxides
RU2091385C1 (en) 1991-09-23 1997-09-27 Циба-Гейги АГ Bisacylphosphine oxides, composition and method of application of coatings
ZA941879B (en) 1993-03-18 1994-09-19 Ciba Geigy Curing compositions containing bisacylphosphine oxide photoinitiators
TW381106B (en) * 1994-09-02 2000-02-01 Ciba Sc Holding Ag Alkoxyphenyl-substituted bisacylphosphine oxides
AU682793B2 (en) * 1994-09-08 1997-10-16 Ciba Specialty Chemicals Holding Inc. Novel acylphosphine oxides
TW323274B (en) * 1994-10-13 1997-12-21 Ciba Sc Holding Ag
CA2349637C (en) * 1998-11-30 2008-12-23 Ciba Specialty Chemicals Holding Inc. Process for preparing acylphosphines and derivatives
GB2360283B (en) * 2000-02-08 2002-08-21 Ciba Sc Holding Ag Monoacylarylphosphines and acylphosphine oxides and sulphides

Also Published As

Publication number Publication date
KR100653117B1 (en) 2006-12-21
WO2000032612A1 (en) 2000-06-08
US20060128959A1 (en) 2006-06-15
US7214830B2 (en) 2007-05-08
CZ302512B6 (en) 2011-06-29
SK7272001A3 (en) 2001-12-03
CZ20011875A3 (en) 2001-09-12
US6888031B1 (en) 2005-05-03
ES2180347T3 (en) 2003-02-01
SK286152B6 (en) 2008-04-07
EP1135399B1 (en) 2002-08-07
JP4265871B2 (en) 2009-05-20
KR20010093124A (en) 2001-10-27
ATE221893T1 (en) 2002-08-15
US20040248855A1 (en) 2004-12-09
ES2180347T5 (en) 2007-04-01
CN1211388C (en) 2005-07-20
US7094931B2 (en) 2006-08-22
EP1135399B2 (en) 2006-08-09
CN1328564A (en) 2001-12-26
CA2349637A1 (en) 2000-06-08
TW492972B (en) 2002-07-01
JP2002531460A (en) 2002-09-24
DE69902485T2 (en) 2003-05-08
CA2349637C (en) 2008-12-23
DE69902485T3 (en) 2007-03-15
EP1135399A1 (en) 2001-09-26
AU760237B2 (en) 2003-05-08
AU1384500A (en) 2000-06-19

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Legal Events

Date Code Title Description
8363 Opposition against the patent
8366 Restricted maintained after opposition proceedings
8328 Change in the person/name/address of the agent

Representative=s name: PFENNING MEINIG & PARTNER GBR, 80339 MUENCHEN

8327 Change in the person/name/address of the patent owner

Owner name: CIBA HOLDING INC., BASEL, CH

8328 Change in the person/name/address of the agent

Representative=s name: MAIWALD PATENTANWALTSGESELLSCHAFT MBH, 80335 MUENC