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DE69829331D1 - Katalysator für die Olefinpolymerisation und Verfahren zur Herstellung eines Olefinpolymers - Google Patents

Katalysator für die Olefinpolymerisation und Verfahren zur Herstellung eines Olefinpolymers

Info

Publication number
DE69829331D1
DE69829331D1 DE69829331T DE69829331T DE69829331D1 DE 69829331 D1 DE69829331 D1 DE 69829331D1 DE 69829331 T DE69829331 T DE 69829331T DE 69829331 T DE69829331 T DE 69829331T DE 69829331 D1 DE69829331 D1 DE 69829331D1
Authority
DE
Germany
Prior art keywords
olefin
catalyst
producing
polymerization
olefin polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69829331T
Other languages
English (en)
Other versions
DE69829331T2 (de
Inventor
Seiji Maehama
Akihiro Yano
Morihiko Sato
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Tosoh Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tosoh Corp filed Critical Tosoh Corp
Application granted granted Critical
Publication of DE69829331D1 publication Critical patent/DE69829331D1/de
Publication of DE69829331T2 publication Critical patent/DE69829331T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69829331T 1997-05-27 1998-05-27 Katalysator für die Olefinpolymerisation und Verfahren zur Herstellung eines Olefinpolymers Expired - Lifetime DE69829331T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP13663297 1997-05-27
JP13663297A JP3458656B2 (ja) 1997-05-27 1997-05-27 オレフィン重合用触媒およびオレフィン重合体の製造方法

Publications (2)

Publication Number Publication Date
DE69829331D1 true DE69829331D1 (de) 2005-04-21
DE69829331T2 DE69829331T2 (de) 2006-03-02

Family

ID=15179855

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69829331T Expired - Lifetime DE69829331T2 (de) 1997-05-27 1998-05-27 Katalysator für die Olefinpolymerisation und Verfahren zur Herstellung eines Olefinpolymers

Country Status (5)

Country Link
US (1) US6034187A (de)
EP (1) EP0881232B1 (de)
JP (1) JP3458656B2 (de)
CA (1) CA2238609C (de)
DE (1) DE69829331T2 (de)

Families Citing this family (77)

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US6559090B1 (en) 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6399535B1 (en) 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6632911B1 (en) * 1999-11-05 2003-10-14 Japan Polychem Corporation Ethylene/α-olefin copolymer and film made thereof
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
JP2002194018A (ja) * 2000-12-22 2002-07-10 Tosoh Corp オレフィン重合用触媒およびオレフィン重合体の製造方法
US6734131B2 (en) 2001-04-30 2004-05-11 W. R. Grace & Co.-Conn. Heterogeneous chromium catalysts and processes of polymerization of olefins using same
US6946420B2 (en) 2001-04-30 2005-09-20 W. R. Grace & Co.-Conn Coordination catalyst systems employing chromium support-agglomerate and method of their preparation
EP1399491B1 (de) 2001-04-30 2006-08-23 W.R. Grace & Co.-Conn. Geträgerte dualübergangsmetallkatalysatorsysteme
WO2002088198A1 (en) 2001-04-30 2002-11-07 W.R. Grace & Co.-Conn. Method of making supported transition metal polymerization catalysts and compositions formed therefrom
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
US6646072B2 (en) * 2002-01-23 2003-11-11 Equistar Chemicals, Lp Process for making polyolefin compositions containing exfoliated clay
US6602966B1 (en) 2002-07-11 2003-08-05 Equistar Chemicals, Lp In-reactor process for making ethylene polymer nanocomposite materials
EP1620479B1 (de) 2002-10-15 2013-07-24 ExxonMobil Chemical Patents Inc. Polyolefinklebstoffzusammensetzungen und daraus hergestellte gegenstände
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US6982306B2 (en) * 2003-11-26 2006-01-03 Chevron Phillips Chemical Company, L.P. Stannoxy-substituted metallocene catalysts for olefin and acetylene polymerization
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
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US20050288461A1 (en) * 2004-06-25 2005-12-29 Jensen Michael D Polymerization catalysts for producing polymers with low levels of long chain branching
US7148298B2 (en) * 2004-06-25 2006-12-12 Chevron Phillips Chemical Company, L.P. Polymerization catalysts for producing polymers with low levels of long chain branching
US7399874B2 (en) 2004-10-29 2008-07-15 Exxonmobil Chemical Patents Inc. Catalyst compound containing divalent tridentate ligand
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US7517939B2 (en) * 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US7619047B2 (en) * 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7576163B2 (en) * 2006-03-31 2009-08-18 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing polymers with low levels of long chain branching
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
US7928162B2 (en) 2007-09-13 2011-04-19 Exxonmobil Research And Engineering Company In-line process for producing plasticized polymers and plasticized polymer blends
EP2112176A1 (de) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Olefinpolymerisationskatalysatoren, deren Herstellung und Benutzung
CN103254514B (zh) 2007-12-20 2015-11-18 埃克森美孚研究工程公司 全同立构聚丙烯和乙烯-丙烯共聚物的共混物
US7939610B2 (en) 2008-05-22 2011-05-10 Exxonmobil Research And Engineering Company Polymerization processes for broadened molecular weight distribution
JP5470745B2 (ja) * 2008-05-22 2014-04-16 東ソー株式会社 変性粘土鉱物、オレフィン重合用触媒およびポリオレフィンの製造方法
CN102112499B (zh) 2008-08-01 2014-02-05 埃克森美孚化学专利公司 催化剂体系和用于烯烃聚合的方法
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
US8399586B2 (en) 2008-09-05 2013-03-19 Exxonmobil Research And Engineering Company Process for feeding ethylene to polymerization reactors
CA2645516C (en) * 2008-12-01 2016-09-06 Victoria Ker Anti-statics
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CN102257017B (zh) 2008-12-18 2014-02-12 尤尼威蒂恩技术有限责任公司 用于聚合反应种子床处理的方法
US20120028865A1 (en) 2010-07-28 2012-02-02 Sudhin Datta Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers
US8378042B2 (en) * 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
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US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
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US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
JP6295614B2 (ja) * 2013-11-11 2018-03-20 東ソー株式会社 エチレン系重合体製造触媒及びエチレン系重合体の製造方法
US9809656B2 (en) 2013-12-09 2017-11-07 Univation Technologies, Llc Feeding polymerization additives to polymerization processes
EP4212323A1 (de) 2014-06-16 2023-07-19 Univation Technologies, LLC Ein verfahren zur herstellung eines blasgeformten artikels
SG10202001582WA (en) 2014-06-16 2020-05-28 Univation Tech Llc Polyethylene resins
WO2016195824A1 (en) 2015-05-29 2016-12-08 Exxonmobil Chemical Patents Inc. Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
WO2017052847A1 (en) 2015-09-24 2017-03-30 Exxonmobil Chemical Patents Inc. Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports
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CA3180272A1 (en) 2020-05-29 2021-12-02 Bo Liu Single reactor bimodal polyethylene with improved modulus for extrusion blow molding drum applications
KR20230018434A (ko) 2020-05-29 2023-02-07 다우 글로벌 테크놀로지스 엘엘씨 화학적으로 전환된 촉매
JP2023527125A (ja) 2020-05-29 2023-06-27 ダウ グローバル テクノロジーズ エルエルシー 減衰ハイブリッド触媒
US20230203216A1 (en) 2020-05-29 2023-06-29 Dow Global Technologies Llc Catalyst systems and processes for producing polyethylene using the same
KR20230018409A (ko) 2020-05-29 2023-02-07 다우 글로벌 테크놀로지스 엘엘씨 촉매계 및 이를 사용한 폴리에틸렌의 제조 방법
JP2023538501A (ja) 2020-08-05 2023-09-08 ダウ グローバル テクノロジーズ エルエルシー 再生ポリマーを含む熱可塑性組成物及びそれから製造される物品
EP4192889A1 (de) 2020-08-05 2023-06-14 Dow Global Technologies LLC Thermoplastische zusammensetzungen mit bimodalem polyethylen und daraus hergestellte artikel
EP4437013A1 (de) 2021-11-23 2024-10-02 Dow Global Technologies LLC Siloconverbrückte anthracenylsubstituierte bis-biphenyl-phenoxy organometallische verbindung enthaltende trägerkatalysatorsysteme
WO2023096868A1 (en) 2021-11-23 2023-06-01 Dow Global Technologies Llc Supported catalyst systems containing a germanium bridged, anthracenyl substituted bis-biphenyl-phenoxy organometallic compound for making polyethylene and polyethylene copolymer resins in a gas phase polymerization reactor
KR20240101863A (ko) 2021-11-23 2024-07-02 다우 글로벌 테크놀로지스 엘엘씨 기상 중합 반응기에서 폴리에틸렌 및 폴리에틸렌 공중합체 수지를 제조하기 위한 탄소-가교, 안트라세닐 치환된 비스-바이페닐-페녹시 유기금속성 화합물을 함유하는 지지 촉매 시스템
WO2023239560A1 (en) 2022-06-09 2023-12-14 Formosa Plastics Corporaton, U.S.A. Clay composite support-activators and catalyst compositions

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GB1480530A (en) * 1973-12-14 1977-07-20 Du Pont Homogeneous highly filled polyolefin compositions
EP0658576B1 (de) * 1993-12-17 1998-07-29 Tosoh Corporation Olefinpolymerisationkatalysator und Verfahren zur Olefinpolymerisation
JP3033452B2 (ja) * 1993-12-17 2000-04-17 東ソー株式会社 オレフィン重合用触媒およびオレフィンの重合方法
JP3305478B2 (ja) * 1994-02-21 2002-07-22 三菱化学株式会社 オレフィン重合用触媒およびこれを用いたオレフィンの重合方法
EP0727443B1 (de) * 1995-02-20 2001-01-17 Tosoh Corporation Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten

Also Published As

Publication number Publication date
JPH10324708A (ja) 1998-12-08
DE69829331T2 (de) 2006-03-02
EP0881232A1 (de) 1998-12-02
CA2238609A1 (en) 1998-11-27
EP0881232B1 (de) 2005-03-16
JP3458656B2 (ja) 2003-10-20
CA2238609C (en) 2007-01-02
US6034187A (en) 2000-03-07

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