[go: up one dir, main page]

DE69817780D1 - Katalysatoren und katalytische oxidations-verfahren - Google Patents

Katalysatoren und katalytische oxidations-verfahren

Info

Publication number
DE69817780D1
DE69817780D1 DE69817780T DE69817780T DE69817780D1 DE 69817780 D1 DE69817780 D1 DE 69817780D1 DE 69817780 T DE69817780 T DE 69817780T DE 69817780 T DE69817780 T DE 69817780T DE 69817780 D1 DE69817780 D1 DE 69817780D1
Authority
DE
Germany
Prior art keywords
catalysts
catalytic oxidation
oxidation processes
processes
catalytic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69817780T
Other languages
English (en)
Other versions
DE69817780T2 (de
Inventor
Hadley Busch
Simon Robert Collinson
Jay Hubin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Application granted granted Critical
Publication of DE69817780D1 publication Critical patent/DE69817780D1/de
Publication of DE69817780T2 publication Critical patent/DE69817780T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
    • C07F13/005—Compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Epoxy Compounds (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Detergent Compositions (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69817780T 1997-03-07 1998-03-06 Katalysatoren und katalytische oxidations-verfahren Expired - Lifetime DE69817780T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US4062997P 1997-03-07 1997-03-07
US40629P 1997-03-07
PCT/IB1998/000302 WO1998039098A1 (en) 1997-03-07 1998-03-06 Catalysts and methods for catalytic oxidation

Publications (2)

Publication Number Publication Date
DE69817780D1 true DE69817780D1 (de) 2003-10-09
DE69817780T2 DE69817780T2 (de) 2004-07-15

Family

ID=21912044

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69817780T Expired - Lifetime DE69817780T2 (de) 1997-03-07 1998-03-06 Katalysatoren und katalytische oxidations-verfahren
DE69838111T Expired - Lifetime DE69838111T2 (de) 1997-03-07 1998-03-06 Katalysatoren und Verfahren zur katalytischen Oxidation

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69838111T Expired - Lifetime DE69838111T2 (de) 1997-03-07 1998-03-06 Katalysatoren und Verfahren zur katalytischen Oxidation

Country Status (19)

Country Link
US (7) US20070093379A1 (de)
EP (2) EP0966323B1 (de)
JP (1) JP4476364B2 (de)
CN (1) CN1261823B (de)
AR (2) AR006290A1 (de)
AT (2) ATE248650T1 (de)
AU (1) AU731371B2 (de)
BR (1) BR9812424B1 (de)
CA (1) CA2282406C (de)
CZ (1) CZ302258B6 (de)
DE (2) DE69817780T2 (de)
ES (2) ES2289202T3 (de)
HU (1) HU225021B1 (de)
ID (1) ID23801A (de)
MA (1) MA24593A1 (de)
MX (1) MXPA99008248A (de)
TR (1) TR199902475T2 (de)
WO (1) WO1998039098A1 (de)
ZA (1) ZA981883B (de)

Families Citing this family (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA981883B (en) * 1997-03-07 1998-09-01 Univ Kansas Catalysts and methods for catalytic oxidation
US20080125344A1 (en) * 2006-11-28 2008-05-29 Daryle Hadley Busch Bleach compositions
JP2002530284A (ja) 1998-11-13 2002-09-17 ザ、プロクター、エンド、ギャンブル、カンパニー 架橋テトラアザマクロサイクル類の製造方法
US6667288B2 (en) * 1998-11-13 2003-12-23 Procter & Gamble Company Bleach compositions
AU2026100A (en) * 1998-11-30 2000-06-19 Procter & Gamble Company, The Process for preparing cross-bridged tetraaza macrocycles
WO2000052124A1 (en) * 1999-03-02 2000-09-08 The Procter & Gamble Company Stabilized bleach compositions
US6653270B2 (en) 1999-03-02 2003-11-25 Procter & Gamble Company Stabilized bleach compositions
AU4061900A (en) * 1999-04-01 2000-10-23 Procter & Gamble Company, The Transition metal bleaching agents
GB0004990D0 (en) 2000-03-01 2000-04-19 Unilever Plc Composition and method for bleaching a substrate
GB9930697D0 (en) * 1999-12-24 2000-02-16 Unilever Plc Method of treating a textile
GB9930695D0 (en) * 1999-12-24 2000-02-16 Unilever Plc Composition and method for bleaching a substrate
GB0013643D0 (en) 2000-05-31 2000-07-26 Unilever Plc Targeted moieties for use in bleach catalysts
CA2419629A1 (en) * 2000-09-25 2002-04-04 The Procter & Gamble Company Mri image enhancement compositions
GB0030877D0 (en) 2000-12-18 2001-01-31 Unilever Plc Enhancement of air bleaching catalysts
GB0103871D0 (en) 2001-02-16 2001-04-04 Unilever Plc Bleaching composition of enhanced stability and a process for making such a composition
GB0106285D0 (en) 2001-03-14 2001-05-02 Unilever Plc Air bleaching catalysts with moderating agent
CA2439524A1 (en) 2001-03-14 2002-09-19 Unilever Plc Bleaching catalysts with unsaturated surfactant and antioxidants
CA2483393A1 (en) 2002-05-02 2003-11-13 The Procter & Gamble Company Detergent compositions and components thereof
WO2005095408A1 (ja) * 2004-03-30 2005-10-13 Nagoya Institute Of Technology ケージ状配位子を有する多核金属錯体
GB0412893D0 (en) 2004-06-10 2004-07-14 Univ Hull Novel antiviral macrocycle derivatives and metal complexes, incorporating bridged macrocycles
EP1700907A1 (de) 2005-03-11 2006-09-13 Unilever N.V. Flüssige bleichmittelzusammensetzung
US7514577B2 (en) * 2006-05-31 2009-04-07 Exxonmobil Chemical Patents Inc. Pd- and Pt-substituted polyoxometalates and process for their preparation
JP5336360B2 (ja) 2006-07-07 2013-11-06 オーエムジー・ユーケー・テクノロジー・リミテッド 液体の硬化
US7820868B2 (en) 2007-01-19 2010-10-26 Exxonmobil Chemical Patents Inc. Transition metal substituted polyoxometalates and process for their preparation
US7645907B2 (en) * 2007-03-23 2010-01-12 Exxonmobil Chemical Patents Inc. Transition metal substituted polyoxometalates and process for their preparation
WO2009079578A1 (en) * 2007-12-17 2009-06-25 Elements Specialties, Inc. Low voc waterbased coatings with efflorescence resistance
EP2103735A1 (de) 2008-03-18 2009-09-23 Unilever PLC Katalytische Substratbleichung
US8172863B2 (en) * 2008-04-28 2012-05-08 Bridgepoint Medical, Inc. Methods and apparatus for crossing occlusions in blood vessels
GB0810881D0 (en) 2008-06-16 2008-07-23 Unilever Plc Improvements relating to fabric cleaning
EP2228429A1 (de) 2009-03-13 2010-09-15 Unilever PLC Abschattungsfärbung und Katalysatorkombination
JP5538760B2 (ja) * 2009-07-03 2014-07-02 清蔵 宮田 酸化触媒、還元触媒及び排気ガス浄化触媒
TW201121975A (en) 2009-10-30 2011-07-01 Sumitomo Chemical Co Nitrogen-containing aromatic compounds and metal complexes
CN102639625B (zh) * 2009-12-02 2014-03-19 巴斯夫欧洲公司 金属配合物作为氧气吸收剂/清除剂成分在包装应用中的用途
EP2343336A1 (de) 2010-01-06 2011-07-13 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Härtungsflüssigkeiten
SI2582744T1 (sl) 2010-06-16 2014-06-30 Akzo Nobel Chemicals International B.V. Raztopina pospeševala in postopek za utrjevanje strdljivih smol
EP2441820A1 (de) 2010-10-14 2012-04-18 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Waschmittelpartikel
WO2012079624A1 (en) 2010-12-15 2012-06-21 Ppg Europe Bv Drier composition and use thereof
EP2474578A1 (de) 2011-01-06 2012-07-11 Rahu Catalytics Limited Zusammensetzungen zur Hautbildungsverhinderung
PH12013501439A1 (en) 2011-01-31 2019-09-02 Unilever Nv Alkaline liquid detergent compositions
DE102011010818A1 (de) 2011-02-10 2012-08-16 Clariant International Ltd. Verwendung von Übergangsmetallkomplexen als Bleichkatalysatoren in Wasch- und Reinigungsmitteln
US20120205581A1 (en) 2011-02-16 2012-08-16 Robert Richard Dykstra Compositions and methods of bleaching
EP2675880B1 (de) * 2011-02-16 2016-12-14 The Procter and Gamble Company Flüssige reinigungszusammensetzungen
ES2421162T3 (es) 2011-04-04 2013-08-29 Unilever Nv Procedimiento de lavado de telas
BR112013028716A2 (pt) 2011-05-13 2017-01-24 Unilever Nv detergente de lavanderia líquido concentrado aquoso, composição, método de lavagem de tecidos de poliéster e seu uso
EP2522715A1 (de) 2011-05-13 2012-11-14 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Konzentrierte wässrige Waschmittelzusammensetzungen
EP2522714A1 (de) 2011-05-13 2012-11-14 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Konzentrierte wässrige Waschmittelzusammensetzungen
HUE052479T2 (hu) 2011-09-26 2021-04-28 Ppg Europe B V Bevonó kompozíció és alkalmazása
CN103174011A (zh) * 2011-11-24 2013-06-26 东华大学 四氮双环十四烷金属配合物在纺织品低温练漂助剂中的应用
BR112014013942B1 (pt) 2011-12-20 2021-03-02 Unilever Ip Holdings B.V composição detergente líquida isotrópica
US9233364B2 (en) 2012-04-25 2016-01-12 University Of Florida Research Foundation, Inc. Multimetallic assembly, methods of making multimetallic assembly, methods of oxidizing water, methods of O-atom transfer catalysts, and methods of carbon dioxide reduction
ES2556490T3 (es) 2012-05-16 2016-01-18 Unilever N.V. Composiciones detergentes de lavado de ropa que comprenden polietilenimina polialcoxilada
EP2948535B1 (de) 2013-01-23 2018-03-07 Unilever Plc. Ungefärbte wäschezusatzmaterial zur förderung der anti-wiederablagerung von partikelförmigem dreck
CN103113417B (zh) * 2013-02-18 2015-10-28 常州大学 钴-氨基酸配合物催化剂、制备方法及其应用
EP2770044A1 (de) 2013-02-20 2014-08-27 Unilever PLC In Schichten aufgebautes Gel mit Aminoxid
DE102013010549A1 (de) 2013-06-15 2014-12-18 Clariant International Ltd. Bleichmittel-Co-Granulate
RU2016105678A (ru) 2013-07-25 2017-08-30 ОЭмДжи ЮКей ТЕКНОЛОДЖИ ЛИМИТЕД Инкапсулированные катализаторы
WO2015022502A1 (en) 2013-08-16 2015-02-19 Chemsenti Limited Composition
BR112017019942A2 (pt) 2015-04-02 2018-06-12 Unilever Nv composição líquida para lavagem de roupas e uso de polímero para a liberação de sujeira
AR104940A1 (es) * 2015-06-10 2017-08-23 Chemsenti Ltd Método para generar dióxido de cloro
AR104939A1 (es) * 2015-06-10 2017-08-23 Chemsenti Ltd Método oxidativo para generar dióxido de cloro
US10947480B2 (en) 2016-05-17 2021-03-16 Conopeo, Inc. Liquid laundry detergent compositions
US20190144782A1 (en) 2016-05-17 2019-05-16 Conopco, Inc., D/B/A Unilever Liquid laundry detergent compositions
WO2017202923A1 (en) 2016-05-27 2017-11-30 Unilever Plc Laundry composition
KR101851981B1 (ko) * 2016-11-25 2018-04-25 (주) 에프엔지리서치 피부 외피용 조성물
DE102016015660A1 (de) 2016-12-31 2018-07-05 Weylchem Wiesbaden Gmbh Granulate, deren Verwendung und Wasch- und Reinigungsmittel enthaltend diese
WO2018127390A1 (en) 2017-01-06 2018-07-12 Unilever N.V. Stain removing composition
KR101851979B1 (ko) * 2017-03-23 2018-06-07 (주) 에프엔지리서치 중금속 및 포름알데히드 제거능을 가지는 세제 조성물
RU2639588C9 (ru) * 2017-03-31 2018-02-19 Общество с ограниченной ответственностью "Экология-С" Дезинфицирующее средство
DE102017004742A1 (de) * 2017-05-17 2018-11-22 Weylchem Wiesbaden Gmbh Beschichtete Granulate, deren Verwendung und Wasch- und Reinigungsmittel enthaltend diese
WO2019038186A1 (en) 2017-08-24 2019-02-28 Unilever Plc IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS
WO2019038187A1 (en) 2017-08-24 2019-02-28 Unilever Plc IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS
CN109046465B (zh) * 2018-07-25 2021-03-26 华东师范大学 一种介孔硅材料固载手性金催化剂的制备及应用
US11518834B2 (en) 2019-01-02 2022-12-06 Polynt Composites USA, Inc. Radically polymerizable compositions
CN110773147B (zh) * 2019-10-17 2022-04-22 万华化学集团股份有限公司 一种丙烯环氧化制备环氧丙烷的催化剂及其制备方法
CZ309741B6 (cs) 2020-06-24 2023-09-06 Univerzita Pardubice Nátěrová hmota obsahující sikativy na bázi sloučenin vanadu s kompenzujícími anionty sulfonových kyselin
CN111785981B (zh) * 2020-06-30 2022-03-18 青岛大学 一种钯-钯钨铬纳米催化剂及其制备方法和应用
EP3967742A1 (de) 2020-09-15 2022-03-16 WeylChem Performance Products GmbH Bleichkatalysatorhaltige zusammensetzungen, verfahren zu ihrer herstellung und bleich- und reinigungsmittel damit
US20240368378A1 (en) 2021-08-30 2024-11-07 Borchers Gmbh Process for improving resin performance
EP4408942A1 (de) 2021-09-30 2024-08-07 Borchers GmbH Verfahren zur verbesserung der harzleistung mit lewis-säuren
CN113842890B (zh) * 2021-10-28 2023-11-28 南华大学 一种黏土矿基金属锰螯合物的制备方法及其应用
US20250059379A1 (en) 2021-12-22 2025-02-20 Borchers Gmbh Paints containing driers based on vanadium compounds bearing various acid anions
CN115709087B (zh) * 2022-11-28 2024-05-03 安徽精公检测检验中心有限公司 一种四氧化三钴负载磷酸锰催化剂及其制备方法和应用
GB2628610A (en) 2023-03-30 2024-10-02 Reckitt Benckiser Vanish Bv Bleach catalyst and composition comprising said catalyst
GB2628608A (en) 2023-03-30 2024-10-02 Reckitt Benckiser Vanish Bv Bleach catalyst with improved performance and composition comprising said catalyst

Family Cites Families (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3919102A (en) * 1971-03-16 1975-11-11 Henkel & Cie Gmbh Composition and method for activating oxygen utilizing N-acylated tetraaza-bicyclo-nonandiones
US4156683A (en) * 1973-03-26 1979-05-29 Schering Corporation Complexes of macrocyclic compounds
EP0001719A1 (de) * 1977-10-26 1979-05-02 The Australian National University Metallkomplexe, ihre Herstellung und Verwendung bei der Produktion von Wasserstoffperoxid
US4257955A (en) * 1978-10-06 1981-03-24 Board Of Trustees, Michigan State University Lanthanide rare earth series cryptate compounds and process for the preparation of metal cryptates in general
US4888032A (en) * 1980-01-23 1989-12-19 The Ohio State University Research Foundation Salts of cationic-metal dry cave complexes
FR2541666B1 (fr) * 1983-02-25 1985-06-21 Rhone Poulenc Spec Chim Procede de dismutation de silanes
US5162508A (en) * 1987-12-18 1992-11-10 Compagnie Oris Industrie Rare earth cryptates, processes for their preparation, synthesis intermediates and application as fluorescent tracers
US5126464A (en) * 1988-10-21 1992-06-30 The Research Foundation Of State University Of New York Polyazamacrocycles and their metal complexes and oxidations using same
US5428180A (en) * 1988-10-21 1995-06-27 The Research Foundation Of State University Of New York Oxidations using polyazamacrocycle metal complexes
DE4009119A1 (de) * 1990-03-19 1991-09-26 Schering Ag 1,4,7,10-tetraazacyclododecan-butyltriole, verfahren zu ihrer herstellung und diese enthaltende pharmazeutische mittel
US5272056A (en) * 1991-01-03 1993-12-21 The Research Foundation Of State University Of New York Modification of DNA and oligonucleotides using metal complexes of polyaza ligands
FR2672051B1 (fr) * 1991-01-24 1993-05-21 Guerbet Sa Nouveaux ligands macrocycliques azotes, procede de preparation, complexes polymetalliques, composition de diagnostic et therapeutique.
GB9124581D0 (en) * 1991-11-20 1992-01-08 Unilever Plc Bleach catalyst composition,manufacture and use thereof in detergent and/or bleach compositions
US5194416A (en) * 1991-11-26 1993-03-16 Lever Brothers Company, Division Of Conopco, Inc. Manganese catalyst for activating hydrogen peroxide bleaching
US5153161A (en) * 1991-11-26 1992-10-06 Lever Brothers Company, Division Of Conopco, Inc. Synthesis of manganese oxidation catalyst
US5480990A (en) * 1991-12-10 1996-01-02 The Dow Chemical Company Bicyclopolyazamacrocyclocarboxylic acid complexes for use as contrast agents
SK2295A3 (en) * 1992-07-08 1995-07-11 Unilever Nv Liquid cleaning agents
ATE144441T1 (de) * 1992-08-06 1996-11-15 Smithkline Beecham Plc Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen
EP0588413A1 (de) * 1992-09-15 1994-03-23 Unilever N.V. Waschmittel
DE69323516T3 (de) * 1992-09-16 2003-03-27 Unilever N.V., Rotterdam Bleichmittel
JPH08503978A (ja) * 1992-12-03 1996-04-30 ユニリーバー・ナームローゼ・ベンノートシヤープ 液体洗浄製品
US5480575A (en) * 1992-12-03 1996-01-02 Lever Brothers, Division Of Conopco, Inc. Adjuncts dissolved in molecular solid solutions
GB9305599D0 (en) * 1993-03-18 1993-05-05 Unilever Plc Detergent compositions
US5329024A (en) * 1993-03-30 1994-07-12 National Starch And Chemical Investment Holding Corporation Epoxidation of olefins via certain manganese complexes
US5429769A (en) * 1993-07-26 1995-07-04 Lever Brothers Company, Division Of Conopco, Inc. Peroxycarboxylic acids and manganese complex catalysts
US5417959A (en) * 1993-10-04 1995-05-23 Mallinckrodt Medical, Inc. Functionalized aza-crytand ligands for diagnostic imaging applications
US5434069A (en) * 1993-11-12 1995-07-18 Lever Brothers Company, Division Of Conopco, Inc. Capsule comprising oil surrounding hydrophobic or hydrophilic active and polymeric shell surrounding oil
US5441660A (en) * 1993-11-12 1995-08-15 Lever Brothers Company Compositions comprising capsule comprising oil surrounding hydrophobic or hydrophilic active and polymeric shell surrounding oil
US5550301A (en) * 1994-04-04 1996-08-27 Sun Company, Inc. (R&M) Dried catalytic systems for decomposition of organic hydroperoxides
US5460743A (en) * 1994-05-09 1995-10-24 Lever Brothers Company, Division Of Conopco, Inc. Liquid cleaning composition containing polyvinyl ether encapsulated particles
US5480577A (en) * 1994-06-07 1996-01-02 Lever Brothers Company, Division Of Conopco, Inc. Encapsulates containing surfactant for improved release and dissolution rates
JP4489190B2 (ja) * 1997-03-07 2010-06-23 ザ、プロクター、エンド、ギャンブル、カンパニー 金属ブリーチ触媒およびブリーチアクチベーターおよび／または有機過カルボン酸を含有したブリーチ組成物
US20030017941A1 (en) * 1997-03-07 2003-01-23 The Procter & Gamble Company Catalysts and methods for catalytic oxidation
US6225464B1 (en) * 1997-03-07 2001-05-01 The Procter & Gamble Company Methods of making cross-bridged macropolycycles
US6218351B1 (en) * 1998-03-06 2001-04-17 The Procter & Gamble Compnay Bleach compositions
HU226087B1 (en) * 1997-03-07 2008-04-28 Procter & Gamble Laundry and cleaning compositions containing bleach catalyst
US6387862B2 (en) * 1997-03-07 2002-05-14 The Procter & Gamble Company Bleach compositions
ZA981883B (en) * 1997-03-07 1998-09-01 Univ Kansas Catalysts and methods for catalytic oxidation
IT1292128B1 (it) * 1997-06-11 1999-01-25 Bracco Spa Processo per la preparazione di chelanti macrociclici e loro chelati con ioni metallici paramagnetici
IT1293778B1 (it) * 1997-07-25 1999-03-10 Bracco Spa 1,4,7,10-tetraazabiciclo(8.2.2.)tetradecan-2 one, sua preparazione e suo uso per la preparazione di tetraazamacrocicli
IT1297035B1 (it) * 1997-12-30 1999-08-03 Bracco Spa Derivati dell'acido 1,4,7,10-tetraazaciclododecan-1,4-diacetico
IT1297034B1 (it) * 1997-12-30 1999-08-03 Bracco Spa Acido 1,4,7,10-tetraazaciclododecan-1,4-diacetico
JP2002530284A (ja) * 1998-11-13 2002-09-17 ザ、プロクター、エンド、ギャンブル、カンパニー 架橋テトラアザマクロサイクル類の製造方法
US6667288B2 (en) * 1998-11-13 2003-12-23 Procter & Gamble Company Bleach compositions
AUPP803899A0 (en) * 1999-01-05 1999-01-28 Australian National University, The Cryptate compounds and methods for diagnosis and therapy.
US6566308B1 (en) * 1999-01-29 2003-05-20 Basf Aktiengesellschaft Emulsifiable concentrate containing one or more pesticides and adjuvants
US6653270B2 (en) * 1999-03-02 2003-11-25 Procter & Gamble Company Stabilized bleach compositions
GB9930695D0 (en) * 1999-12-24 2000-02-16 Unilever Plc Composition and method for bleaching a substrate
JP2004509967A (ja) * 2000-09-25 2004-04-02 ザ、プロクター、エンド、ギャンブル、カンパニー 医学及び治療法の適用に使用するための金属錯体
US20040048763A1 (en) * 2002-08-27 2004-03-11 The Procter & Gamble Co. Bleach compositions
US20050192195A1 (en) * 2002-08-27 2005-09-01 Busch Daryle H. Catalysts and methods for catalytic oxidation
US7026415B2 (en) * 2004-02-17 2006-04-11 Equistar Chemicals, Lp Clathrochelates as olefin polymerization catalyst components
US7306785B2 (en) * 2004-09-23 2007-12-11 General Electric Company Multifunctional cross-bridged tetraaza macrocyclic compounds and methods of making and using

Also Published As

Publication number Publication date
DE69817780T2 (de) 2004-07-15
CN1261823B (zh) 2010-10-27
US20100041545A1 (en) 2010-02-18
US20110143925A1 (en) 2011-06-16
AR006290A1 (es) 1999-08-25
WO1998039098A1 (en) 1998-09-11
ZA981883B (en) 1998-09-01
AU6226498A (en) 1998-09-22
EP1338337A3 (de) 2004-02-04
EP0966323A1 (de) 1999-12-29
CA2282406C (en) 2006-05-30
CA2282406A1 (en) 1998-09-11
CN1261823A (zh) 2000-08-02
JP2001513817A (ja) 2001-09-04
US20100210451A1 (en) 2010-08-19
HUP0001906A3 (en) 2001-11-28
BR9812424B1 (pt) 2011-08-23
TR199902475T2 (xx) 2000-04-21
AR038614A2 (es) 2005-01-19
DE69838111T2 (de) 2008-04-10
JP4476364B2 (ja) 2010-06-09
US20090176645A1 (en) 2009-07-09
ES2203928T3 (es) 2004-04-16
ID23801A (id) 2000-05-11
MA24593A1 (fr) 1999-04-01
BR9812424A (pt) 2002-01-22
EP0966323B1 (de) 2003-09-03
CZ302258B6 (cs) 2011-01-19
CZ313899A3 (cs) 2000-08-16
ATE367202T1 (de) 2007-08-15
US20070298962A1 (en) 2007-12-27
HUP0001906A2 (hu) 2000-10-28
US20070093379A1 (en) 2007-04-26
MXPA99008248A (es) 2004-08-12
DE69838111D1 (de) 2007-08-30
US20110028310A1 (en) 2011-02-03
EP1338337B1 (de) 2007-07-18
AU731371B2 (en) 2001-03-29
ES2289202T3 (es) 2008-02-01
EP1338337A2 (de) 2003-08-27
ATE248650T1 (de) 2003-09-15
HU225021B1 (en) 2006-05-29

Similar Documents

Publication Publication Date Title
ATE248650T1 (de) Katalysatoren und katalytische oxidations- verfahren
DE69814200D1 (de) Oxydationkatalysator-System und Oxydationsverfahren
BR9709798A (pt) Catalisador de alvejamento e oxidacão sistema de oxidacão catalítica e composicão de alvejamento
DE69817832T2 (de) Bleich- und Oxidationskatalysator
PL342499A1 (en) Deeply reduced oxidation catalyst and its application in catalysing liquid-phase oxidation reactions
EP0939672A4 (de) Katalysator zur teiloxidation
DE69730764D1 (de) Katalysator und Verfahren zur katalytischen Reduzierung von Stickstoffoxiden
BR9507984A (pt) Catalisador de alvejamento e de oxidação e composição alvejante
DE69823710D1 (de) Legierter Edelmetallabgaskatalysator
NO20001552D0 (no) Katalysator og fremgangsmåter hvor slike benyttes
DE19782282T1 (de) Selektive katalytische Reduktion zur Entfernung von Stickoxiden und zugehöriger Katalysatorkörper
DE59711456D1 (de) Abgaskatalysator
DK0912231T3 (da) Oxidationskatalysator
DE69700964D1 (de) Katalytischer Umwandler
DE69638041D1 (de) Nichtselektiver Oxidationskatalysator und seine Verwendungen
DE69907808D1 (de) Katalysator zur selektiven Reduktion von Stickstoffoxiden
FI952716L (fi) Hapetuskatalyyttejä
DE69717651D1 (de) Molybdän-haltige oxidationskatalysatoren
DE19882624T1 (de) Katalytischer Konverter
ATE314145T1 (de) Selektive oxidation und katalysator dafür
NO20002522D0 (no) Katalysatorer for ammoniakkoksidasjon
AU3838799A (en) Catalytic process for the oxidation of ammonia and catalyst assembly
DK38392A (da) Ammonia oxidation catalyst
FI965034L (fi) Hapetuskatalyytti
DE69302680D1 (de) Oxidationskatalysatoren