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DE69810864D1 - Verfahren für die Hydroisomerisierung von langkettigen n-Paraffinen und ein zu diesem Zweck geeignetes Katalysator - Google Patents

Verfahren für die Hydroisomerisierung von langkettigen n-Paraffinen und ein zu diesem Zweck geeignetes Katalysator

Info

Publication number
DE69810864D1
DE69810864D1 DE69810864T DE69810864T DE69810864D1 DE 69810864 D1 DE69810864 D1 DE 69810864D1 DE 69810864 T DE69810864 T DE 69810864T DE 69810864 T DE69810864 T DE 69810864T DE 69810864 D1 DE69810864 D1 DE 69810864D1
Authority
DE
Germany
Prior art keywords
paraffins
ranging
hydroisomerization
chain
long
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69810864T
Other languages
English (en)
Other versions
DE69810864T2 (de
Inventor
Cristina Flego
Vincenzo Calemma
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eni SpA
Original Assignee
Agip Petroli SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agip Petroli SpA filed Critical Agip Petroli SpA
Application granted granted Critical
Publication of DE69810864D1 publication Critical patent/DE69810864D1/de
Publication of DE69810864T2 publication Critical patent/DE69810864T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69810864T 1997-10-09 1998-10-09 Verfahren für die Hydroisomerisierung von langkettigen n-Paraffinen und ein zu diesem Zweck geeignetes Katalysator Expired - Lifetime DE69810864T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT97MI002288A IT1295300B1 (it) 1997-10-09 1997-10-09 Procedimento per l'idroisomerizzazione di n-paraffine a catena lunga e catalizzatore adatto allo scopo

Publications (2)

Publication Number Publication Date
DE69810864D1 true DE69810864D1 (de) 2003-02-27
DE69810864T2 DE69810864T2 (de) 2003-10-16

Family

ID=11378014

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69810864T Expired - Lifetime DE69810864T2 (de) 1997-10-09 1998-10-09 Verfahren für die Hydroisomerisierung von langkettigen n-Paraffinen und ein zu diesem Zweck geeignetes Katalysator

Country Status (17)

Country Link
US (1) US20030130554A1 (de)
EP (1) EP0908231B1 (de)
JP (1) JP3043721B2 (de)
KR (1) KR100297276B1 (de)
CN (1) CN1094969C (de)
AT (1) ATE231413T1 (de)
AU (1) AU730150B2 (de)
BR (1) BR9804486B1 (de)
CA (1) CA2246729C (de)
DE (1) DE69810864T2 (de)
DK (1) DK0908231T3 (de)
ES (1) ES2187881T3 (de)
IT (1) IT1295300B1 (de)
PT (1) PT908231E (de)
RU (1) RU2152918C2 (de)
SI (1) SI0908231T1 (de)
ZA (1) ZA989203B (de)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0980908A1 (de) 1998-08-15 2000-02-23 ENITECNOLOGIE S.p.a. Verfahren und Katalysatoren zur Verbesserung von Kohlenwasserstoffen mit einem Siedepunkt im Naphthabereich
IT1312337B1 (it) * 1999-05-07 2002-04-15 Agip Petroli Composizione catalitica per l'upgrading di idrocarburi aventi punti di ebollizione nell'intervallo della nafta
EP1101813B1 (de) 1999-11-19 2014-03-19 ENI S.p.A. Verfahren zur Herstellung von Mitteldestillaten aus geradkettigen Paraffinen
US7358411B2 (en) * 2003-06-30 2008-04-15 Shell Oil Company Hydrocracking of diphenylalkanes
ITMI20062193A1 (it) * 2006-11-15 2008-05-16 Eni Spa Processo per produrre frazioni idrocarburiche da miscele di origine biologica
CN101617029A (zh) * 2007-02-20 2009-12-30 国际壳牌研究有限公司 生产链烷烃的方法
IT1392194B1 (it) 2008-12-12 2012-02-22 Eni Spa Processo per la produzione di idrocarburi, utili per autotrazione, da miscele di origine biologica
IT1396939B1 (it) 2009-12-09 2012-12-20 Eni Spa Composizione idrocarburica utile come carburante o combustibile
WO2015107487A1 (en) 2014-01-20 2015-07-23 Eni S.P.A. Process for the production of hydrocarbon fractions from mixtures of a biological origin
CN114956942B (zh) * 2022-06-01 2023-12-22 南京工业大学 一种催化正十六烷加氢异构化的工艺

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0321307B1 (de) * 1987-12-18 1993-04-21 Exxon Research And Engineering Company Verfahren zur Isomerisierung von Wachs zu Schmierbasisölen
ES2043004T3 (es) * 1988-03-23 1993-12-16 Engelhard Corp Catalizador y procedimiento de hidrotratamiento.
IT1256084B (it) * 1992-07-31 1995-11-27 Eniricerche Spa Catalizzatore per la idroisomerizzazione di normal-paraffine a catena lunga e procedimento per la sua preparazione
US5370788A (en) * 1992-12-18 1994-12-06 Texaco Inc. Wax conversion process
IT1265320B1 (it) * 1993-12-22 1996-10-31 Eniricerche Spa Procedimento per la preparazione di silico-allumine amorfe cataliticamente attive
US5866748A (en) * 1996-04-23 1999-02-02 Exxon Research And Engineering Company Hydroisomerization of a predominantly N-paraffin feed to produce high purity solvent compositions

Also Published As

Publication number Publication date
ES2187881T3 (es) 2003-06-16
US20030130554A1 (en) 2003-07-10
IT1295300B1 (it) 1999-05-04
DK0908231T3 (da) 2003-04-07
PT908231E (pt) 2003-04-30
DE69810864T2 (de) 2003-10-16
CN1094969C (zh) 2002-11-27
ITMI972288A1 (it) 1999-04-09
ATE231413T1 (de) 2003-02-15
AU8838698A (en) 1999-04-29
BR9804486B1 (pt) 2010-02-09
RU2152918C2 (ru) 2000-07-20
JP3043721B2 (ja) 2000-05-22
SI0908231T1 (en) 2003-06-30
CA2246729A1 (en) 1999-04-09
KR19990036954A (ko) 1999-05-25
CA2246729C (en) 2002-01-15
EP0908231A1 (de) 1999-04-14
JPH11193249A (ja) 1999-07-21
BR9804486A (pt) 2000-05-23
CN1221776A (zh) 1999-07-07
ZA989203B (en) 1999-04-22
AU730150B2 (en) 2001-03-01
KR100297276B1 (ko) 2001-09-06
EP0908231B1 (de) 2003-01-22

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Legal Events

Date Code Title Description
8327 Change in the person/name/address of the patent owner

Owner name: ENI S.P.A., ROM/ROMA, IT

8364 No opposition during term of opposition