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DE69607516D1 - Process for the production of mixed porous and spherical silicon aluminum oxides - Google Patents

Process for the production of mixed porous and spherical silicon aluminum oxides

Info

Publication number
DE69607516D1
DE69607516D1 DE69607516T DE69607516T DE69607516D1 DE 69607516 D1 DE69607516 D1 DE 69607516D1 DE 69607516 T DE69607516 T DE 69607516T DE 69607516 T DE69607516 T DE 69607516T DE 69607516 D1 DE69607516 D1 DE 69607516D1
Authority
DE
Germany
Prior art keywords
mixed
oxides
production
aluminum oxides
silicon aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69607516T
Other languages
German (de)
Other versions
DE69607516T2 (en
Inventor
Luigi Balducci
Raffaele Ungarelli
Paolo Chiurlo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Enichem SpA
Original Assignee
Enichem SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem SpA filed Critical Enichem SpA
Publication of DE69607516D1 publication Critical patent/DE69607516D1/en
Application granted granted Critical
Publication of DE69607516T2 publication Critical patent/DE69607516T2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/14—Methods for preparing oxides or hydroxides in general
    • C01B13/32—Methods for preparing oxides or hydroxides in general by oxidation or hydrolysis of elements or compounds in the liquid or solid state or in non-aqueous solution, e.g. sol-gel process
    • C01B13/328—Methods for preparing oxides or hydroxides in general by oxidation or hydrolysis of elements or compounds in the liquid or solid state or in non-aqueous solution, e.g. sol-gel process by processes making use of emulsions, e.g. the kerosine process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/32—Spheres
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Silicon Compounds (AREA)
  • Catalysts (AREA)
  • Colloid Chemistry (AREA)

Abstract

The present invention relates to a process for the preparation of mixed porous oxides with a spherical morphology and the oxides themselves thus obtained. This process consists in emulsifying, in an acid environment, a mixed sol with a dispersing medium, gelifying the microemulsion thus formed by contact with an alkaline solution and subjecting the gel obtained to thermal aging in the presence of the emulsifying liquid and gelation base of the sol or in a water medium, under controlled conditions of pH and temperature. The above mixed oxides can be widely applied as carriers for catalysts or as precursors of ceramic materials. <IMAGE>
DE69607516T 1995-06-01 1996-04-30 Process for the production of mixed porous and spherical silicon aluminum oxides Expired - Lifetime DE69607516T2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI951139A IT1275412B (en) 1995-06-01 1995-06-01 PROCEDURE FOR THE PREPARATION OF MIXED POROUS SILICA-ALUMINUM OXIDES IN SPHERICAL FORM

Publications (2)

Publication Number Publication Date
DE69607516D1 true DE69607516D1 (en) 2000-05-11
DE69607516T2 DE69607516T2 (en) 2000-08-31

Family

ID=11371720

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69607516T Expired - Lifetime DE69607516T2 (en) 1995-06-01 1996-04-30 Process for the production of mixed porous and spherical silicon aluminum oxides

Country Status (7)

Country Link
US (1) US5731261A (en)
EP (1) EP0745557B1 (en)
AT (1) ATE191433T1 (en)
DE (1) DE69607516T2 (en)
DK (1) DK0745557T3 (en)
ES (1) ES2143678T3 (en)
IT (1) IT1275412B (en)

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Also Published As

Publication number Publication date
ATE191433T1 (en) 2000-04-15
EP0745557A1 (en) 1996-12-04
IT1275412B (en) 1997-08-05
ES2143678T3 (en) 2000-05-16
DK0745557T3 (en) 2000-08-14
ITMI951139A1 (en) 1996-12-01
DE69607516T2 (en) 2000-08-31
ITMI951139A0 (en) 1995-06-01
US5731261A (en) 1998-03-24
EP0745557B1 (en) 2000-04-05

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