DE69534327D1 - Elektrochemische Wasserstoffspeicherlegierungen - Google Patents
Elektrochemische WasserstoffspeicherlegierungenInfo
- Publication number
- DE69534327D1 DE69534327D1 DE69534327T DE69534327T DE69534327D1 DE 69534327 D1 DE69534327 D1 DE 69534327D1 DE 69534327 T DE69534327 T DE 69534327T DE 69534327 T DE69534327 T DE 69534327T DE 69534327 D1 DE69534327 D1 DE 69534327D1
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen storage
- electrochemical hydrogen
- storage alloys
- alloys
- electrochemical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
- C01B3/0042—Intermetallic compounds; Metal alloys; Treatment thereof only containing magnesium and nickel; Treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
- C01B3/0047—Intermetallic compounds; Metal alloys; Treatment thereof containing a rare earth metal; Treatment thereof
- C01B3/0057—Intermetallic compounds; Metal alloys; Treatment thereof containing a rare earth metal; Treatment thereof also containing nickel
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/383—Hydrogen absorbing alloys
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S420/00—Alloys or metallic compositions
- Y10S420/90—Hydrogen storage
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US259793 | 1988-10-19 | ||
US08/259,793 US5506069A (en) | 1993-10-14 | 1994-06-14 | Electrochemical hydrogen storage alloys and batteries fabricated from Mg containing base alloys |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69534327D1 true DE69534327D1 (de) | 2005-08-25 |
DE69534327T2 DE69534327T2 (de) | 2006-04-20 |
Family
ID=22986412
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69532204T Expired - Lifetime DE69532204T2 (de) | 1994-06-14 | 1995-05-30 | ELEKTROCHEMISCHE WASSERSTOFFSPEICHERLEGIERUNGEN UND BATTERIEN AUS Mg ENTHALTENDEN BASISLEGIERUNGEN |
DE69534327T Expired - Lifetime DE69534327T2 (de) | 1994-06-14 | 1995-05-30 | Elektrochemische Wasserstoffspeicherlegierungen |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69532204T Expired - Lifetime DE69532204T2 (de) | 1994-06-14 | 1995-05-30 | ELEKTROCHEMISCHE WASSERSTOFFSPEICHERLEGIERUNGEN UND BATTERIEN AUS Mg ENTHALTENDEN BASISLEGIERUNGEN |
Country Status (9)
Country | Link |
---|---|
US (1) | US5506069A (de) |
EP (2) | EP1045464B1 (de) |
JP (2) | JPH10501370A (de) |
KR (1) | KR100331128B1 (de) |
AU (1) | AU697537B2 (de) |
CA (1) | CA2191114C (de) |
DE (2) | DE69532204T2 (de) |
RU (1) | RU2141150C1 (de) |
WO (1) | WO1995034918A1 (de) |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5536591A (en) | 1990-04-26 | 1996-07-16 | Ovonic Battery Company, Inc. | Electrochemical hydrogen storage alloys for nickel metal hydride batteries |
EP0750050A4 (de) * | 1993-12-22 | 1997-09-24 | Toshiba Kk | Wasserstoffabsorbierende legierung und alkalische sekundärzelle diese verwendend |
US5616432A (en) * | 1994-06-14 | 1997-04-01 | Ovonic Battery Company, Inc. | Electrochemical hydrogen storage alloys and batteries fabricated from Mg containing base alloys |
US5962165A (en) * | 1994-07-22 | 1999-10-05 | Kabushiki Kaisha Toshiba | Hydrogen-absorbing alloy, method of surface modification of the alloy, negative electrode for battery and alkaline secondary battery |
US6682609B1 (en) | 1994-07-22 | 2004-01-27 | Kabushiki Kaisha Toshiba | Hydrogen absorbing alloy, method of surface modification of the alloy, negative electrode for battery and alkaline secondary battery |
JPH09199122A (ja) * | 1996-01-22 | 1997-07-31 | Toshiba Corp | 水素吸蔵合金および二次電池 |
EP0799324B1 (de) * | 1994-12-22 | 2001-08-29 | Energy Conversion Devices, Inc. | Mechanische legierung auf magnesiumbasis für thermischen wasserstoffspeicher |
EP0832501B1 (de) * | 1995-05-08 | 2003-09-17 | Ovonic Battery Company, Inc. | Elektrochemische wasserstoffeinlagerungslegierungen und batterien, die mit mg-basislegierungen hergestellt sind |
US5840440A (en) * | 1995-11-20 | 1998-11-24 | Ovonic Battery Company, Inc. | Hydrogen storage materials having a high density of non-conventional useable hydrogen storing sites |
AT403632B (de) * | 1996-03-08 | 1998-04-27 | Hermann Dipl Ing Dr Kronberger | Elektrodenmaterial für metallhydridzellen |
US5853919A (en) * | 1996-06-19 | 1998-12-29 | Kabushiki Kaisha Toshiba | Hydrogen-absorbing alloy, electrode and alkaline secondary battery |
JPH10275631A (ja) * | 1996-12-27 | 1998-10-13 | Canon Inc | 粉末材料、電極構造体、それらの製造方法及び二次電池 |
US6130006A (en) * | 1997-06-17 | 2000-10-10 | Kabushiki Kaisha Toshiba | Hydrogen-absorbing alloy |
JPH11217640A (ja) * | 1998-01-29 | 1999-08-10 | Agency Of Ind Science & Technol | マグネシウム系水素吸蔵合金 |
JP2000082461A (ja) * | 1998-07-06 | 2000-03-21 | Canon Inc | Mg系負極活物質、その製造法、水素吸蔵合金電極およびアルカリ二次電池 |
JP2001217000A (ja) * | 1999-02-26 | 2001-08-10 | Toshiba Battery Co Ltd | ニッケル・水素二次電池 |
WO2002014567A1 (en) * | 2000-08-16 | 2002-02-21 | Ovonic Battery Company, Inc. | High power nickel-metal hydride batteries and high power alloys/electrodes for use therein |
JP2002241884A (ja) * | 2001-02-20 | 2002-08-28 | Mitsui Mining & Smelting Co Ltd | 水素吸蔵合金 |
US20040016769A1 (en) * | 2002-03-15 | 2004-01-29 | Redmond Scott D. | Hydrogen storage, distribution, and recovery system |
US7169489B2 (en) | 2002-03-15 | 2007-01-30 | Fuelsell Technologies, Inc. | Hydrogen storage, distribution, and recovery system |
US7399325B1 (en) | 2002-03-15 | 2008-07-15 | Fuelsell Technologies, Inc. | Method and apparatus for a hydrogen fuel cassette distribution and recovery system |
US7011768B2 (en) | 2002-07-10 | 2006-03-14 | Fuelsell Technologies, Inc. | Methods for hydrogen storage using doped alanate compositions |
US20040065171A1 (en) * | 2002-10-02 | 2004-04-08 | Hearley Andrew K. | Soild-state hydrogen storage systems |
US20040142203A1 (en) * | 2003-01-07 | 2004-07-22 | Woolley Christopher P. | Hydrogen storage medium |
CN1315213C (zh) * | 2003-06-17 | 2007-05-09 | 李华伦 | 镁锰叠层电池组 |
US7211541B2 (en) * | 2003-12-11 | 2007-05-01 | Ovonic Hydrogen Systems Llc | Mg—Ni hydrogen storage composite having high storage capacity and excellent room temperature kinetics |
US20060057019A1 (en) | 2004-09-16 | 2006-03-16 | Kwo Young | Hydrogen storage alloys having reduced PCT hysteresis |
EP1838887B1 (de) * | 2004-12-07 | 2012-04-18 | The University of Queensland | Magnesiumlegierungen für die wasserstoffspeicherung |
JP4828986B2 (ja) * | 2006-03-30 | 2011-11-30 | 株式会社東芝 | 水素吸蔵合金、水素貯蔵膜および水素貯蔵タンク |
ES2763903T3 (es) | 2009-07-26 | 2020-06-01 | Forever Young Int Inc | Composición formadora de gel en partículas exotérmica expandible |
CN101716676B (zh) * | 2009-12-21 | 2011-11-16 | 南京工业大学 | 一种a2b型钛基储氢合金及其制备方法 |
US9435489B2 (en) | 2010-02-24 | 2016-09-06 | Hydrexia Pty Ltd | Hydrogen release system |
US9061907B2 (en) | 2011-09-21 | 2015-06-23 | The United States of America as represented by the Secretary of Commerce The National Institute of Standards and Technology | Two-component structures providing fast-low temperature charging of Mg with hydrogen |
DE102013008659A1 (de) * | 2013-05-18 | 2014-11-20 | Forschungszentrum Jülich GmbH | Elektrochemisches Speichermaterial und elektrochemische Speichereinrichtung zur Speicherung elektrischer Energie, umfassend ein solches Speichermaterial |
RU2542256C2 (ru) * | 2013-06-20 | 2015-02-20 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Способ защиты порошков гидридообразующих сплавов для хранения водорода, предотвращающий пассивацию компонентами воздуха и других газообразных сред |
US10587012B2 (en) | 2015-03-26 | 2020-03-10 | Basf Corporation | Electrolyte compositions comprising ionic liquids and metal hydride batteries comprising same |
WO2017011881A1 (en) * | 2015-07-23 | 2017-01-26 | Hydrexia Pty Ltd | Mg-based alloy for hydrogen storage |
JP7021102B2 (ja) | 2016-03-28 | 2022-02-16 | ビーエーエスエフ コーポレーション | 充電式電池用のシリコンに基づく固体電解質 |
IL267354B2 (en) | 2016-12-13 | 2023-04-01 | Forever Young Int Inc | Scalable exothermic composition |
CN109112376B (zh) * | 2018-09-25 | 2020-07-14 | 南昌大学 | 一种Mg-Al-Zn-Mn-Gd耐蚀稀土镁合金的制备方法 |
CN110380011A (zh) * | 2019-08-08 | 2019-10-25 | 吉林大学 | 长寿命储氢合金薄膜/镍箔复合电极材料的一体化制备 |
CN110656269A (zh) * | 2019-10-25 | 2020-01-07 | 冯波 | 一种镁合金锻件及其制备工艺 |
CN111674491A (zh) * | 2020-05-12 | 2020-09-18 | 宁波吉胜铸业有限公司 | 一种车用铝壳体 |
CN113512674B (zh) * | 2021-04-20 | 2022-06-21 | 安泰科技股份有限公司 | 一种改性Mg-Ni-La纳米晶储氢合金及其制备方法 |
CN113981285A (zh) * | 2021-09-02 | 2022-01-28 | 四川昆仑新能源科技有限公司 | 镁钴合金氢化物之制造方法 |
CN114083871B (zh) * | 2021-11-15 | 2023-05-26 | 太原科技大学 | 具有非均匀层状结构的Al-3%Cu合金的制备方法 |
CN114160784B (zh) * | 2021-11-22 | 2024-08-20 | 上海大学 | 一种含有Nd4Mg80Ni8合金与纯Mg的水解制氢复合材料、其制备方法及其应用 |
CN115011852A (zh) * | 2022-04-20 | 2022-09-06 | 青岛科技大学 | 一种海水电池用镁合金阳极材料及其制备方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5946881B2 (ja) * | 1979-05-10 | 1984-11-15 | 精二郎 須田 | 新規な水素吸収剤 |
US4623597A (en) * | 1982-04-28 | 1986-11-18 | Energy Conversion Devices, Inc. | Rechargeable battery and electrode used therein |
SU1134538A1 (ru) * | 1983-08-18 | 1985-01-15 | МГУ им.М.В.Ломоносова | Состав дл аккумулировани водорода |
US4582117A (en) * | 1983-09-21 | 1986-04-15 | Electric Power Research Institute | Heat transfer during casting between metallic alloys and a relatively moving substrate |
JPS61199045A (ja) * | 1985-02-27 | 1986-09-03 | Chuo Denki Kogyo Kk | 水素吸蔵合金 |
CA1273827A (en) * | 1985-03-29 | 1990-09-11 | Michael A. Tenhover | Energy storage devices and amorphous metal alloy electrodes for use in alkaline environments |
JPS62114747A (ja) * | 1985-11-15 | 1987-05-26 | O C C:Kk | 結晶が鋳造方向に長く伸びた一方向凝固組織を有する金属条の連続鋳造法 |
NZ230311A (en) * | 1988-09-05 | 1990-09-26 | Masumoto Tsuyoshi | High strength magnesium based alloy |
US5407761A (en) * | 1991-08-14 | 1995-04-18 | Ovinic Battery Company, Inc. | Electrochemical hydrogen storage alloys and batteries fabricated from these alloys having significantly improved capacity |
US5277999A (en) * | 1991-08-14 | 1994-01-11 | Ovonic Battery Company, Inc. | Electrochemical hydrogen storage alloys and batteries fabricated these alloys having significantly improved performance characteristics |
DE4039278A1 (de) * | 1990-12-08 | 1992-06-11 | Goldschmidt Ag Th | Verfahren zur herstellung aktiver, reversibel h(pfeil abwaerts)2(pfeil abwaerts) aufnehmender magnesiumhydrid-magnesium-wasserstoff-speichersysteme |
CN1031416C (zh) * | 1992-01-08 | 1996-03-27 | 南开大学 | 镁基储氢合金电极及其制备方法 |
-
1994
- 1994-06-14 US US08/259,793 patent/US5506069A/en not_active Expired - Lifetime
-
1995
- 1995-05-30 JP JP8502210A patent/JPH10501370A/ja active Pending
- 1995-05-30 DE DE69532204T patent/DE69532204T2/de not_active Expired - Lifetime
- 1995-05-30 EP EP00110393A patent/EP1045464B1/de not_active Expired - Lifetime
- 1995-05-30 KR KR1019960707164A patent/KR100331128B1/ko not_active IP Right Cessation
- 1995-05-30 AU AU26542/95A patent/AU697537B2/en not_active Ceased
- 1995-05-30 DE DE69534327T patent/DE69534327T2/de not_active Expired - Lifetime
- 1995-05-30 EP EP95921469A patent/EP0765531B1/de not_active Expired - Lifetime
- 1995-05-30 CA CA002191114A patent/CA2191114C/en not_active Expired - Fee Related
- 1995-05-30 RU RU97100726A patent/RU2141150C1/ru not_active IP Right Cessation
- 1995-05-30 WO PCT/US1995/006760 patent/WO1995034918A1/en active IP Right Grant
-
2002
- 2002-12-18 JP JP2002367199A patent/JP2003217578A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
EP1045464B1 (de) | 2005-07-20 |
CA2191114A1 (en) | 1995-12-21 |
AU697537B2 (en) | 1998-10-08 |
KR100331128B1 (ko) | 2002-06-20 |
US5506069A (en) | 1996-04-09 |
AU2654295A (en) | 1996-01-05 |
EP1045464A1 (de) | 2000-10-18 |
DE69532204D1 (de) | 2004-01-08 |
DE69534327T2 (de) | 2006-04-20 |
CA2191114C (en) | 2007-03-27 |
RU2141150C1 (ru) | 1999-11-10 |
JP2003217578A (ja) | 2003-07-31 |
EP0765531A1 (de) | 1997-04-02 |
WO1995034918A1 (en) | 1995-12-21 |
DE69532204T2 (de) | 2004-09-09 |
KR970704250A (ko) | 1997-08-09 |
EP0765531B1 (de) | 2003-11-26 |
JPH10501370A (ja) | 1998-02-03 |
EP0765531A4 (de) | 1997-10-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8328 | Change in the person/name/address of the agent |
Representative=s name: TEMPELHOF, T., RECHTSANW., 48163 MUENSTER |