DE69530100D1 - Polymerisationkatalysatorsysteme, ihre herstellung und ihre verwendung - Google Patents
Polymerisationkatalysatorsysteme, ihre herstellung und ihre verwendungInfo
- Publication number
- DE69530100D1 DE69530100D1 DE69530100T DE69530100T DE69530100D1 DE 69530100 D1 DE69530100 D1 DE 69530100D1 DE 69530100 T DE69530100 T DE 69530100T DE 69530100 T DE69530100 T DE 69530100T DE 69530100 D1 DE69530100 D1 DE 69530100D1
- Authority
- DE
- Germany
- Prior art keywords
- production
- polymerization catalyst
- catalyst systems
- systems
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002685 polymerization catalyst Substances 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61904—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with another component of C08F4/60
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/330,893 US5529965A (en) | 1994-10-28 | 1994-10-28 | Polymerization catalyst systems, their production and use |
US330893 | 1994-10-28 | ||
PCT/US1995/011482 WO1996013530A1 (en) | 1994-10-28 | 1995-09-11 | Polymerization catalyst systems, their production and use |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69530100D1 true DE69530100D1 (de) | 2003-04-30 |
DE69530100T2 DE69530100T2 (de) | 2004-03-04 |
Family
ID=23291766
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69530100T Expired - Fee Related DE69530100T2 (de) | 1994-10-28 | 1995-09-11 | Polymerisationkatalysatorsysteme, ihre herstellung und ihre verwendung |
Country Status (9)
Country | Link |
---|---|
US (1) | US5529965A (de) |
EP (1) | EP0788520B1 (de) |
JP (1) | JP3206755B2 (de) |
KR (2) | KR100414776B1 (de) |
CN (1) | CN1112372C (de) |
CA (1) | CA2202555A1 (de) |
DE (1) | DE69530100T2 (de) |
ES (1) | ES2194924T3 (de) |
WO (1) | WO1996013530A1 (de) |
Families Citing this family (88)
Publication number | Priority date | Publication date | Assignee | Title |
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JP3355572B2 (ja) * | 1994-08-23 | 2002-12-09 | 新日本石油株式会社 | オレフィン類重合触媒およびそれを用いたポリオレフィンの製造方法 |
US6140432A (en) * | 1995-07-13 | 2000-10-31 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
US6124230A (en) * | 1995-07-13 | 2000-09-26 | Exxon Chemical Patents, Inc. | Polymerization catalyst systems, their production and use |
FI952098A7 (fi) * | 1995-05-02 | 1996-11-03 | Borealis As | LLDPE-polymeerien valmistusmenetelmä |
FI105818B (fi) | 1996-03-13 | 2000-10-13 | Borealis Tech Oy | Prosessi olefiinimonomeerien polymeroimiseksi |
DE19615953A1 (de) * | 1996-04-22 | 1997-10-23 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums |
US5959044A (en) * | 1996-07-08 | 1999-09-28 | Villar; Juan Carlos | Method of controlling continuous ethylene-limited metallocene-catalyzed copolymerization systems |
US6759499B1 (en) | 1996-07-16 | 2004-07-06 | Exxonmobil Chemical Patents Inc. | Olefin polymerization process with alkyl-substituted metallocenes |
US6642316B1 (en) | 1998-07-01 | 2003-11-04 | Exxonmobil Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polym |
US6635715B1 (en) | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
US7232871B2 (en) | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
US6921794B2 (en) | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
US5990035A (en) * | 1997-10-21 | 1999-11-23 | Koeppl; Alexander | Polymerization catalyst systems, their preparation, and use |
HUP0102238A3 (en) | 1998-03-26 | 2002-06-28 | Dow Chemical Co | Ion exchanged aluminium-magnesium or fluorinated magnesium silicate aerogels and catalyst supports therefrom |
US6376416B1 (en) * | 1998-07-21 | 2002-04-23 | Japan Polychem Corporation | Olefin polymerization catalyst and process for producing olefin polymer |
US6653254B1 (en) * | 1999-02-22 | 2003-11-25 | Fina Technology, Inc | Ziegler-Natta catalyst with metallocene for olefin polymerization |
DE19951841A1 (de) | 1999-10-28 | 2001-05-03 | Bayer Ag | Katalysator auf Basis von Verbindungen der Seltenen Erdmetalle |
EP1237954B1 (de) * | 1999-11-01 | 2006-01-04 | W. R. Grace & Co.-Conn | Aktive, heterogene, geträgerte bi- oder tri-dendate polymerisationskatalysatoren |
EP1101777A1 (de) | 1999-11-22 | 2001-05-23 | UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION (a Delaware corporation) | Metallmischkatalysatoren |
DE60125908T2 (de) * | 2000-04-28 | 2007-09-06 | Mitsui Chemicals, Inc. | Geformter gegenstand aus einem thermoplastischen harz und zusammensetzung |
US6720396B2 (en) * | 2000-11-30 | 2004-04-13 | Univation Technologies, Llc | Polymerization process |
US20020137861A1 (en) * | 2000-12-04 | 2002-09-26 | Woo Min Song | Polymerization process |
ATE485319T1 (de) | 2001-04-12 | 2010-11-15 | Exxonmobil Chem Patents Inc | Verfahren zur polymerisation von propylen und ethylen in lösung |
WO2003040201A1 (en) | 2001-11-06 | 2003-05-15 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
US6927256B2 (en) | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
US6943215B2 (en) | 2001-11-06 | 2005-09-13 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
US6906160B2 (en) | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
US20050003950A1 (en) * | 2001-11-30 | 2005-01-06 | Mink Robert I. | Method of making mixed ziegler-natta/metallocece catalysts |
EP1336625A1 (de) * | 2002-02-14 | 2003-08-20 | Novolen Technology Holdings C.V. | Herstellung eines Zielger Natta Katalyse-Systems auf einem speziellen Träger und dessen Verwendung für die Polymerisation von 1-Alkenen |
US6875828B2 (en) * | 2002-09-04 | 2005-04-05 | Univation Technologies, Llc | Bimodal polyolefin production process and films therefrom |
DE60304595T3 (de) | 2002-10-02 | 2012-01-12 | Dow Global Technologies Inc. | Flüssige und gelartige niedermolekulare ethylenpolymere |
US6884749B2 (en) | 2002-10-17 | 2005-04-26 | Equistar Chemicals L.P. | Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof |
CN100374494C (zh) | 2002-10-17 | 2008-03-12 | 陶氏环球技术公司 | 高度填充的聚合物组合物 |
US7459500B2 (en) | 2002-11-05 | 2008-12-02 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
US7579407B2 (en) | 2002-11-05 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
JP4742221B2 (ja) | 2003-03-21 | 2011-08-10 | ダウ グローバル テクノロジーズ エルエルシー | モルホロジー制御オレフィン重合プロセス |
US6953764B2 (en) | 2003-05-02 | 2005-10-11 | Dow Global Technologies Inc. | High activity olefin polymerization catalyst and process |
US7531601B2 (en) | 2003-08-19 | 2009-05-12 | Dow Global Technologies, Inc. | Interpolymers suitable for use in hot melt adhesives and processes to prepare same |
KR100681302B1 (ko) * | 2005-12-16 | 2007-02-09 | 대림산업 주식회사 | 올레핀 중합용 촉매 및 이를 이용한 올레핀의 중합방법 |
EP1803747A1 (de) | 2005-12-30 | 2007-07-04 | Borealis Technology Oy | Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt |
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CN103930452B (zh) | 2011-11-08 | 2016-08-31 | 尤尼威蒂恩技术有限责任公司 | 采用催化剂体系生产聚烯烃的方法 |
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EP4039366A1 (de) | 2012-12-28 | 2022-08-10 | Univation Technologies, LLC | Geträgerter katalysator mit verbesserten fliesseigeschaften |
ES2949819T3 (es) | 2013-02-07 | 2023-10-03 | Univation Tech Llc | Preparación de poliolefina |
ES2667196T3 (es) | 2013-03-15 | 2018-05-10 | Univation Technologies, Llc | Ligandos tridentados basados en nitrógeno para catalizadores de la polimerización de olefinas |
EP2970526B1 (de) | 2013-03-15 | 2017-08-09 | Univation Technologies, LLC | Liganden für katalysatoren |
EP3287473B1 (de) | 2013-06-05 | 2019-10-16 | Univation Technologies, LLC | Schutz von phenolgruppen |
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US10471641B2 (en) | 2015-01-21 | 2019-11-12 | Univation Technologies, Llc | Methods for controlling polymer chain scission |
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CN109983039B (zh) | 2016-09-27 | 2022-02-18 | 尤尼威蒂恩技术有限责任公司 | 用于聚乙烯生产中长链支化控制的方法 |
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EP3621996B1 (de) | 2017-05-10 | 2023-01-18 | Univation Technologies, LLC | Katalysatorsysteme und verfahren zu ihrer verwendung |
US11161922B2 (en) | 2017-10-31 | 2021-11-02 | Exxonmobil Chemical Patents Inc. | Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents |
EP3704163A4 (de) | 2017-10-31 | 2020-12-23 | ExxonMobil Chemical Patents Inc. | Toluolfreie kieselsäuregeträgerte, strukturell einheitliche metallocenkatalysatoren aus in-situ-geträgerter alumoxanbildung in aliphatischen lösungsmitteln |
CN111356704B (zh) * | 2017-10-31 | 2023-05-05 | 埃克森美孚化学专利公司 | 来自在脂肪族溶剂中原位形成负载的mao的无甲苯的二氧化硅负载的单中心茂金属催化剂 |
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US5032562A (en) * | 1989-12-27 | 1991-07-16 | Mobil Oil Corporation | Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution |
TW198726B (de) * | 1989-12-29 | 1993-01-21 | Mitsui Petroleum Chemicals Ind | |
US5145818A (en) * | 1989-12-29 | 1992-09-08 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for the polymerization of olefins |
US5266544A (en) * | 1989-12-29 | 1993-11-30 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for the polymerization of olefins |
TW206240B (de) * | 1990-02-13 | 1993-05-21 | Mitsui Petroleum Chemicals Ind | |
FR2659336B1 (fr) * | 1990-03-12 | 1993-05-07 | Bp Chemicals Snc | Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
FR2659337B1 (fr) * | 1990-03-12 | 1992-06-05 | Bp Chemicals Snc | Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines. |
DE69226564T3 (de) * | 1991-05-20 | 2004-04-08 | Mitsui Chemicals, Inc. | Katalysator und Verfahren für Olefinpolymerisation |
CA2077744C (en) * | 1991-09-30 | 2003-04-15 | Edwar Shoukri Shamshoum | Homogeneous-heterogeneous catalyst system for polyolefins |
US5332707A (en) * | 1992-07-31 | 1994-07-26 | Amoco Corporation | Olefin polymerization and copolymerization catalyst |
EP0585512B1 (de) * | 1992-08-31 | 1999-01-13 | Fina Research S.A. | Katalysatorkomponente für Olefinpolymerisation |
EP0586168B1 (de) * | 1992-09-04 | 2000-07-05 | BP Chemicals Limited | Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen |
US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
-
1994
- 1994-10-28 US US08/330,893 patent/US5529965A/en not_active Expired - Fee Related
-
1995
- 1995-09-11 CN CN95195912A patent/CN1112372C/zh not_active Expired - Fee Related
- 1995-09-11 EP EP95932462A patent/EP0788520B1/de not_active Expired - Lifetime
- 1995-09-11 KR KR1019970702761A patent/KR100414776B1/ko not_active Expired - Fee Related
- 1995-09-11 ES ES95932462T patent/ES2194924T3/es not_active Expired - Lifetime
- 1995-09-11 WO PCT/US1995/011482 patent/WO1996013530A1/en active IP Right Grant
- 1995-09-11 JP JP51454896A patent/JP3206755B2/ja not_active Expired - Fee Related
- 1995-09-11 KR KR10-2003-7006985A patent/KR100436382B1/ko not_active Expired - Fee Related
- 1995-09-11 CA CA002202555A patent/CA2202555A1/en not_active Abandoned
- 1995-09-11 DE DE69530100T patent/DE69530100T2/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR100436382B1 (ko) | 2004-06-17 |
JPH10508624A (ja) | 1998-08-25 |
EP0788520A1 (de) | 1997-08-13 |
JP3206755B2 (ja) | 2001-09-10 |
CN1162320A (zh) | 1997-10-15 |
CA2202555A1 (en) | 1996-05-09 |
CN1112372C (zh) | 2003-06-25 |
DE69530100T2 (de) | 2004-03-04 |
EP0788520B1 (de) | 2003-03-26 |
KR970707176A (ko) | 1997-12-01 |
US5529965A (en) | 1996-06-25 |
KR20040004447A (ko) | 2004-01-13 |
ES2194924T3 (es) | 2003-12-01 |
WO1996013530A1 (en) | 1996-05-09 |
KR100414776B1 (ko) | 2004-05-20 |
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