DE69516332T2 - Farbphotographisches Element, das neue Epoxy-Abfänger für restlichen Purpurrot-Kuppler enthält - Google Patents
Farbphotographisches Element, das neue Epoxy-Abfänger für restlichen Purpurrot-Kuppler enthältInfo
- Publication number
- DE69516332T2 DE69516332T2 DE1995616332 DE69516332T DE69516332T2 DE 69516332 T2 DE69516332 T2 DE 69516332T2 DE 1995616332 DE1995616332 DE 1995616332 DE 69516332 T DE69516332 T DE 69516332T DE 69516332 T2 DE69516332 T2 DE 69516332T2
- Authority
- DE
- Germany
- Prior art keywords
- group
- alkyl
- compound
- compounds
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
- C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/34—Compounds containing oxirane rings with hydrocarbon radicals, substituted by sulphur, selenium or tellurium atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D303/40—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
- C07D303/42—Acyclic compounds having a chain of seven or more carbon atoms, e.g. epoxidised fats
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D303/46—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by amide or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/025—Boronic and borinic acid compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/65502—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a three-membered ring
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/392—Additives
- G03C7/39208—Organic compounds
- G03C7/3924—Heterocyclic
- G03C7/39268—Heterocyclic the nucleus containing only oxygen as hetero atoms
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/392—Additives
- G03C7/39296—Combination of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Epoxy Compounds (AREA)
Claims (13)
1. Verbindung, gekennzeichnet durch die Strukturformel:
wobei
R ein H-Atom, eine Alkyl- oder Arylgruppe ist;
L&sub1; eine Alkyl- oder Arylgruppe ist;
L&sub2; -O-, -CO-, -S-, -SO&sub2; -, -PO&sub2;-, -CO&sub2;-, -NHCO- oder -NHSO&sub2;- ist, wobei
L&sub2; in beiden Richtungen orientiert sein kann;
L&sub3; eine Alkylgruppe ist;
m 0 oder 1 ist;
p 0 oder 1 ist;
und X ist
-NHSO&sub2;R', -SO&sub2;NHR',
oder
wobei R' ein H-Atom, eine Alkyl- oder Arylgruppe ist, mit dem Vorbehalt, dass
dort, wo L&sub2; eine ionisierbare Gruppe ist, X auch eine Alkyl- oder Arylgruppe
sein kann.
2. Verbindung nach Anspruch 1, dadurch gekennzeichnet, dass m und p jeweils 1
sind, L&sub1; eine Phenylgruppe ist, L&sub2; -O-, -CO-, -SO&sub2;-, -PO&sub2;- oder -SO&sub2;- ist, L&sub3;
eine lineare oder verzweigte Alkylgruppe darstellt, X
-NHSO&sub2;R', -SO&sub2;NHR',
oder
ist und R' eine Alkyl- oder Arylgruppe ist.
3. Verbindung nach Anspruch 1, dadurch gekennzeichnet, dass X
-NHSO&sub2;R', -SO&sub2;NHR',
oder
ist, wobei R' ein H-Atom, eine Alkyl- oder Arylgruppe ist, mit dem Vorbehalt,
dass dort, wo L&sub2; eine ionisierbare Gruppe ist, X auch eine Alkyl- oder
Arylgruppe sein kann; und wobei die Verbindung einen Schmelzpunkt unterhalb von
etwa 50ºC aufweist.
4. Verbindung nach Anspruch 3, gekennzeichnet durch die allgemeine
Strukturformel SI-B:
wobei R* ein H-Atom oder eine Alkyl- oder Arylgruppe ist; n zwischen 1 und 20
liegen kann; q 1, 2 oder 3 ist und R" jeweils ein H-Atom, eine Alkoxidgruppe,
Phosphatgruppe, Sulfatgruppe, Sulfonamidgruppe, Sulfongruppe, Halogen oder
eine Alkylgruppe ist; mit dem Vorbehalt, dass sich die anhängende
Sulfonamid
gruppe in meta- oder para-Position zur -CO&sub2;-Brückengruppe befindet, und mit
dem weiteren Vorbehalt, dass, wenn die anhangende Sulfonamidgruppe die
para-Position einnimmt, jede R"-Gruppe ein H-Atom ist, oder mindestens eine
anhängende R"-Gruppe, die nicht H ist, befindet sich bezüglich der -NHSO&sub2;-
Brückengruppe in meta- oder ortho-Position, oder R* ist nicht H.
5. Verbindung nach Anspruch 1, gekennzeichnet durch die allgemeine
Strukturformel:
wobei
R ein H-Atom oder eine Alkyl- oder Arylgruppe ist;
R' ein H-Atom oder eine Alkyl- oder Arylgruppe ist;
und n zwischen 2 und 20 liegt.
6. Verbindung nach Anspruch 1, gekennzeichnet durch die Formeln:
7. Fotografisches Element, gekennzeichnet durch einen Träger, der
(a) mit einer lichtempfindlichen ersten Schicht beschichtet, die
(i) eine Silberhalogenidemulsion und
(ii) in dieser dispergiert einen Purpurkuppler umfasst, und
(b) mit einer zweiten Schicht beschichtet ist, die eine Epoxy-Verbindung nach
Anspruch 1 bis 6 enthält.
8. Fotografisches Element nach Anspruch 7, dadurch gekennzeichnet, dass die
lichtempfindliche erste Schicht zusätzlich einen Bildstabilisator der folgenden
Formel STG-A umfasst:
wobei R&sub1; eine Alkylgruppe, Cycloalkylgruppe, Alkenylphenylgruppe,
Arylgruppe, heterocyclische Gruppe, Acylgruppe, überbrückte
Kohlenwasserstoffgruppe, Alkylsulfonylgruppe oder Arylsulfonylgruppe ist; R&sub2;
eine Gruppe ist, die als Substituent am Benzolring fungieren kann; r eine ganze
Zahl zwischen 0 und 4 ist und A eine Gruppe von Nichtmetallatomen darstellt,
die für die Bildung eines 5- bis 8-gliedrigen Rings, unter Einschluss des
Stickstoffatoms, erforderlich ist.
9. Fotografisches Element nach Anspruch 8, dadurch gekennzeichnet, dass A
eine elektronenziehende Gruppe umfasst.
10. Fotografisches Element nach Anspruch 8, dadurch gekennzeichnet, dass A
eine Sulfoxidgruppe umfasst.
11. Verfahren zur Herstellung einer Feststoffteilchendispersion einer
Epoxy-Verbindung der Formel SI nach Anspruch 1, 2, 5 oder 6, gekennzeichnet durch
folgende Schritte:
(a) Bildung einer grobkörnigen wässrigen Aufschlämmung von
Feststoffteilchen der Verbindung und
(b) Vermahlung der Aufschlämmung in Gegenwart einer hydrophoben,
fotografisch inerten, flüssigen zweiten Komponente mit einem logP(berechnet)
Wert grösser als etwa 6,0, für eine Zeitdauer, die für die Bildung von
Teilchen der gewünschten mittleren Teilchengrösse ausreicht.
12. Verfahren nach Anspruch 11, dadurch gekennzeichnet, dass die Menge der in
Schritt (b) eingesetzten zweiten Komponente kleiner oder gleich einem Viertel
des Gewichts der Verbindung der Formel ST ist.
13. Verfahren zur Bildung einer wässrigen Dispersion einer Epoxy-Verbindung nach
Anspruch 3 oder 4, dadurch gekennzeichnet, dass die Verbindung in flüssigem
Zustand der wässrigen Lösung zugesetzt wird und die Verbindung unmittelbar
in der wässrigen Lösung dispergiert wird.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/255,512 US5543276A (en) | 1994-06-08 | 1994-06-08 | Color photographic element containing new epoxy scavengers for residual magenta coupler |
US08/429,269 US5597685A (en) | 1995-04-25 | 1995-04-25 | Color photographic element having improved image stability |
US08/427,764 US5627017A (en) | 1995-04-25 | 1995-04-25 | Low melting point ionizable epoxy scavengers for residual magenta couplers |
US08/427,763 US5620632A (en) | 1995-04-25 | 1995-04-25 | Dispersions of epoxy scavengers exhibiting improved raw stock keeping |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69516332D1 DE69516332D1 (de) | 2000-05-25 |
DE69516332T2 true DE69516332T2 (de) | 2000-11-30 |
Family
ID=27500538
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1995616332 Expired - Fee Related DE69516332T2 (de) | 1994-06-08 | 1995-06-07 | Farbphotographisches Element, das neue Epoxy-Abfänger für restlichen Purpurrot-Kuppler enthält |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0686873B1 (de) |
JP (1) | JPH0853431A (de) |
DE (1) | DE69516332T2 (de) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5698422A (en) * | 1995-01-06 | 1997-12-16 | Xerox Corporation | Toner and developer compositions |
EP1793272A4 (de) | 2004-08-24 | 2008-01-23 | Fujifilm Corp | Lichtempfindliches material für die silberhalogenid-farbfotografie und verfahren zur bilderzeugung |
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JPS57204037A (en) | 1981-06-10 | 1982-12-14 | Fuji Photo Film Co Ltd | Color photographic sensitive material |
JPS587632A (ja) | 1981-07-07 | 1983-01-17 | Fuji Photo Film Co Ltd | ハロゲン化銀カラ−感光材料 |
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JPS58113935A (ja) | 1981-12-26 | 1983-07-07 | Konishiroku Photo Ind Co Ltd | ハロゲン化銀カラ−写真感光材料 |
JPH0234372B2 (ja) | 1982-04-02 | 1990-08-02 | Konishiroku Photo Ind | Harogenkaginkaraashashinkankozairyo |
JPS58205151A (ja) | 1982-05-24 | 1983-11-30 | Fuji Photo Film Co Ltd | ハロゲン化銀カラ−感光材料 |
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JPS5950439A (ja) | 1982-09-16 | 1984-03-23 | Fuji Photo Film Co Ltd | ハロゲン化銀写真感光材料 |
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JPS6057838A (ja) | 1983-09-09 | 1985-04-03 | Konishiroku Photo Ind Co Ltd | ハロゲン化銀カラ−写真感光材料 |
JPS60138548A (ja) | 1983-12-26 | 1985-07-23 | Fuji Photo Film Co Ltd | ハロゲン化銀カラ−写真感光材料 |
JPS60170854A (ja) | 1984-02-15 | 1985-09-04 | Fuji Photo Film Co Ltd | カラ−写真感光材料 |
JPS60185950A (ja) | 1984-02-23 | 1985-09-21 | Fuji Photo Film Co Ltd | ハロゲン化銀カラ−感光材料 |
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JPS6128948A (ja) | 1984-07-19 | 1986-02-08 | Fuji Photo Film Co Ltd | ハロゲン化銀カラ−写真感光材料 |
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JPS6165245A (ja) | 1984-09-06 | 1986-04-03 | Fuji Photo Film Co Ltd | ハロゲン化銀カラ−写真感光材料 |
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DE3530357A1 (de) | 1985-08-24 | 1987-02-26 | Agfa Gevaert Ag | Farbfotografisches aufzeichnungsmaterial |
JPS62125349A (ja) | 1985-11-27 | 1987-06-06 | Fuji Photo Film Co Ltd | ハロゲン化銀カラ−写真感光材料 |
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EP0284240B2 (de) | 1987-03-09 | 1993-06-16 | EASTMAN KODAK COMPANY (a New Jersey corporation) | Photographische Silberhalogenidmaterialien und Verfahren, das einen Pyrazoloazolkuppler enthält |
DE3871835T2 (de) | 1987-03-09 | 1993-02-04 | Eastman Kodak Co | Photographische silberhalogenidmaterialien und verfahren, das einen pyrazoloazolkuppler enthaelt. |
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US4923784A (en) | 1987-11-24 | 1990-05-08 | Eastman Kodak Company | Photographic elements containing a bleach accelerator precursor |
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US4859578A (en) | 1988-06-21 | 1989-08-22 | Eastman Kodak Company | Photographic recording material providing improved granularity properties |
US4962018A (en) | 1988-06-21 | 1990-10-09 | Eastman Kodak Company | Photographic materials containing DIR compounds and process of imaging |
US4912025A (en) | 1988-06-21 | 1990-03-27 | Eastman Kodak Company | Photographic recording material for accelerated development |
US5468604A (en) * | 1992-11-18 | 1995-11-21 | Eastman Kodak Company | Photographic dispersion |
US5300394A (en) * | 1992-12-16 | 1994-04-05 | Eastman Kodak Company | Dispersions for imaging systems |
US5508147A (en) | 1993-01-04 | 1996-04-16 | Eastman Kodak Company | Color photographic element with improved resistance to thermal and photochemical yellowing and method thereof |
-
1995
- 1995-06-07 EP EP19950108781 patent/EP0686873B1/de not_active Expired - Lifetime
- 1995-06-07 DE DE1995616332 patent/DE69516332T2/de not_active Expired - Fee Related
- 1995-06-08 JP JP14227395A patent/JPH0853431A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
EP0686873B1 (de) | 2000-04-19 |
EP0686873A1 (de) | 1995-12-13 |
DE69516332D1 (de) | 2000-05-25 |
JPH0853431A (ja) | 1996-02-27 |
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