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DE69516332T2 - Farbphotographisches Element, das neue Epoxy-Abfänger für restlichen Purpurrot-Kuppler enthält - Google Patents

Farbphotographisches Element, das neue Epoxy-Abfänger für restlichen Purpurrot-Kuppler enthält

Info

Publication number
DE69516332T2
DE69516332T2 DE1995616332 DE69516332T DE69516332T2 DE 69516332 T2 DE69516332 T2 DE 69516332T2 DE 1995616332 DE1995616332 DE 1995616332 DE 69516332 T DE69516332 T DE 69516332T DE 69516332 T2 DE69516332 T2 DE 69516332T2
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DE
Germany
Prior art keywords
group
alkyl
compound
compounds
aryl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE1995616332
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English (en)
Other versions
DE69516332D1 (de
Inventor
Krishnan Chari
Sundaram Krishnamurthy
Wendell Franklyn Smith
Paul Patrick Spara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/255,512 external-priority patent/US5543276A/en
Priority claimed from US08/429,269 external-priority patent/US5597685A/en
Priority claimed from US08/427,764 external-priority patent/US5627017A/en
Priority claimed from US08/427,763 external-priority patent/US5620632A/en
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Application granted granted Critical
Publication of DE69516332D1 publication Critical patent/DE69516332D1/de
Publication of DE69516332T2 publication Critical patent/DE69516332T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/12Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/12Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/16Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/34Compounds containing oxirane rings with hydrocarbon radicals, substituted by sulphur, selenium or tellurium atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/38Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D303/40Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
    • C07D303/42Acyclic compounds having a chain of seven or more carbon atoms, e.g. epoxidised fats
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/38Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D303/46Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by amide or nitrile radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D405/00Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02Boron compounds
    • C07F5/025Boronic and borinic acid compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/655Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
    • C07F9/65502Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a three-membered ring
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/392Additives
    • G03C7/39208Organic compounds
    • G03C7/3924Heterocyclic
    • G03C7/39268Heterocyclic the nucleus containing only oxygen as hetero atoms
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/392Additives
    • G03C7/39296Combination of additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Epoxy Compounds (AREA)

Claims (13)

1. Verbindung, gekennzeichnet durch die Strukturformel:
wobei
R ein H-Atom, eine Alkyl- oder Arylgruppe ist;
L&sub1; eine Alkyl- oder Arylgruppe ist;
L&sub2; -O-, -CO-, -S-, -SO&sub2; -, -PO&sub2;-, -CO&sub2;-, -NHCO- oder -NHSO&sub2;- ist, wobei
L&sub2; in beiden Richtungen orientiert sein kann;
L&sub3; eine Alkylgruppe ist;
m 0 oder 1 ist;
p 0 oder 1 ist;
und X ist
-NHSO&sub2;R', -SO&sub2;NHR',
oder
wobei R' ein H-Atom, eine Alkyl- oder Arylgruppe ist, mit dem Vorbehalt, dass dort, wo L&sub2; eine ionisierbare Gruppe ist, X auch eine Alkyl- oder Arylgruppe sein kann.
2. Verbindung nach Anspruch 1, dadurch gekennzeichnet, dass m und p jeweils 1 sind, L&sub1; eine Phenylgruppe ist, L&sub2; -O-, -CO-, -SO&sub2;-, -PO&sub2;- oder -SO&sub2;- ist, L&sub3; eine lineare oder verzweigte Alkylgruppe darstellt, X
-NHSO&sub2;R', -SO&sub2;NHR',
oder
ist und R' eine Alkyl- oder Arylgruppe ist.
3. Verbindung nach Anspruch 1, dadurch gekennzeichnet, dass X
-NHSO&sub2;R', -SO&sub2;NHR',
oder
ist, wobei R' ein H-Atom, eine Alkyl- oder Arylgruppe ist, mit dem Vorbehalt, dass dort, wo L&sub2; eine ionisierbare Gruppe ist, X auch eine Alkyl- oder Arylgruppe sein kann; und wobei die Verbindung einen Schmelzpunkt unterhalb von etwa 50ºC aufweist.
4. Verbindung nach Anspruch 3, gekennzeichnet durch die allgemeine Strukturformel SI-B:
wobei R* ein H-Atom oder eine Alkyl- oder Arylgruppe ist; n zwischen 1 und 20 liegen kann; q 1, 2 oder 3 ist und R" jeweils ein H-Atom, eine Alkoxidgruppe, Phosphatgruppe, Sulfatgruppe, Sulfonamidgruppe, Sulfongruppe, Halogen oder eine Alkylgruppe ist; mit dem Vorbehalt, dass sich die anhängende Sulfonamid gruppe in meta- oder para-Position zur -CO&sub2;-Brückengruppe befindet, und mit dem weiteren Vorbehalt, dass, wenn die anhangende Sulfonamidgruppe die para-Position einnimmt, jede R"-Gruppe ein H-Atom ist, oder mindestens eine anhängende R"-Gruppe, die nicht H ist, befindet sich bezüglich der -NHSO&sub2;- Brückengruppe in meta- oder ortho-Position, oder R* ist nicht H.
5. Verbindung nach Anspruch 1, gekennzeichnet durch die allgemeine Strukturformel:
wobei
R ein H-Atom oder eine Alkyl- oder Arylgruppe ist;
R' ein H-Atom oder eine Alkyl- oder Arylgruppe ist;
und n zwischen 2 und 20 liegt.
6. Verbindung nach Anspruch 1, gekennzeichnet durch die Formeln:
7. Fotografisches Element, gekennzeichnet durch einen Träger, der (a) mit einer lichtempfindlichen ersten Schicht beschichtet, die (i) eine Silberhalogenidemulsion und
(ii) in dieser dispergiert einen Purpurkuppler umfasst, und
(b) mit einer zweiten Schicht beschichtet ist, die eine Epoxy-Verbindung nach Anspruch 1 bis 6 enthält.
8. Fotografisches Element nach Anspruch 7, dadurch gekennzeichnet, dass die lichtempfindliche erste Schicht zusätzlich einen Bildstabilisator der folgenden Formel STG-A umfasst:
wobei R&sub1; eine Alkylgruppe, Cycloalkylgruppe, Alkenylphenylgruppe, Arylgruppe, heterocyclische Gruppe, Acylgruppe, überbrückte Kohlenwasserstoffgruppe, Alkylsulfonylgruppe oder Arylsulfonylgruppe ist; R&sub2; eine Gruppe ist, die als Substituent am Benzolring fungieren kann; r eine ganze Zahl zwischen 0 und 4 ist und A eine Gruppe von Nichtmetallatomen darstellt, die für die Bildung eines 5- bis 8-gliedrigen Rings, unter Einschluss des Stickstoffatoms, erforderlich ist.
9. Fotografisches Element nach Anspruch 8, dadurch gekennzeichnet, dass A eine elektronenziehende Gruppe umfasst.
10. Fotografisches Element nach Anspruch 8, dadurch gekennzeichnet, dass A eine Sulfoxidgruppe umfasst.
11. Verfahren zur Herstellung einer Feststoffteilchendispersion einer Epoxy-Verbindung der Formel SI nach Anspruch 1, 2, 5 oder 6, gekennzeichnet durch folgende Schritte:
(a) Bildung einer grobkörnigen wässrigen Aufschlämmung von Feststoffteilchen der Verbindung und
(b) Vermahlung der Aufschlämmung in Gegenwart einer hydrophoben, fotografisch inerten, flüssigen zweiten Komponente mit einem logP(berechnet) Wert grösser als etwa 6,0, für eine Zeitdauer, die für die Bildung von Teilchen der gewünschten mittleren Teilchengrösse ausreicht.
12. Verfahren nach Anspruch 11, dadurch gekennzeichnet, dass die Menge der in Schritt (b) eingesetzten zweiten Komponente kleiner oder gleich einem Viertel des Gewichts der Verbindung der Formel ST ist.
13. Verfahren zur Bildung einer wässrigen Dispersion einer Epoxy-Verbindung nach Anspruch 3 oder 4, dadurch gekennzeichnet, dass die Verbindung in flüssigem Zustand der wässrigen Lösung zugesetzt wird und die Verbindung unmittelbar in der wässrigen Lösung dispergiert wird.
DE1995616332 1994-06-08 1995-06-07 Farbphotographisches Element, das neue Epoxy-Abfänger für restlichen Purpurrot-Kuppler enthält Expired - Fee Related DE69516332T2 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/255,512 US5543276A (en) 1994-06-08 1994-06-08 Color photographic element containing new epoxy scavengers for residual magenta coupler
US08/429,269 US5597685A (en) 1995-04-25 1995-04-25 Color photographic element having improved image stability
US08/427,764 US5627017A (en) 1995-04-25 1995-04-25 Low melting point ionizable epoxy scavengers for residual magenta couplers
US08/427,763 US5620632A (en) 1995-04-25 1995-04-25 Dispersions of epoxy scavengers exhibiting improved raw stock keeping

Publications (2)

Publication Number Publication Date
DE69516332D1 DE69516332D1 (de) 2000-05-25
DE69516332T2 true DE69516332T2 (de) 2000-11-30

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DE1995616332 Expired - Fee Related DE69516332T2 (de) 1994-06-08 1995-06-07 Farbphotographisches Element, das neue Epoxy-Abfänger für restlichen Purpurrot-Kuppler enthält

Country Status (3)

Country Link
EP (1) EP0686873B1 (de)
JP (1) JPH0853431A (de)
DE (1) DE69516332T2 (de)

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Also Published As

Publication number Publication date
EP0686873B1 (de) 2000-04-19
EP0686873A1 (de) 1995-12-13
DE69516332D1 (de) 2000-05-25
JPH0853431A (ja) 1996-02-27

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