[go: up one dir, main page]

DE69507626D1 - Verfahren zur herstellung vom syndiotaktischem polymer von prochiralen olefinen - Google Patents

Verfahren zur herstellung vom syndiotaktischem polymer von prochiralen olefinen

Info

Publication number
DE69507626D1
DE69507626D1 DE69507626T DE69507626T DE69507626D1 DE 69507626 D1 DE69507626 D1 DE 69507626D1 DE 69507626 T DE69507626 T DE 69507626T DE 69507626 T DE69507626 T DE 69507626T DE 69507626 D1 DE69507626 D1 DE 69507626D1
Authority
DE
Germany
Prior art keywords
producing
syndiotactic polymer
prochiral olefins
prochiral
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69507626T
Other languages
English (en)
Other versions
DE69507626T2 (de
Inventor
Peter Nickias
Thomas Newman
Karen Borodychuk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of DE69507626D1 publication Critical patent/DE69507626D1/de
Application granted granted Critical
Publication of DE69507626T2 publication Critical patent/DE69507626T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69507626T 1994-10-03 1995-09-07 Verfahren zur herstellung vom syndiotaktischem polymer von prochiralen olefinen Expired - Fee Related DE69507626T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/316,748 US5536797A (en) 1994-10-03 1994-10-03 Syndiotactic prochiral olefin polymerization process
PCT/US1995/011437 WO1996010592A1 (en) 1994-10-03 1995-09-07 Syndiotactic prochiral olefin polymerization process

Publications (2)

Publication Number Publication Date
DE69507626D1 true DE69507626D1 (de) 1999-03-11
DE69507626T2 DE69507626T2 (de) 1999-09-30

Family

ID=23230493

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69507626T Expired - Fee Related DE69507626T2 (de) 1994-10-03 1995-09-07 Verfahren zur herstellung vom syndiotaktischem polymer von prochiralen olefinen

Country Status (11)

Country Link
US (1) US5536797A (de)
EP (1) EP0784639B1 (de)
JP (1) JPH10506932A (de)
KR (1) KR100357358B1 (de)
CN (1) CN1082057C (de)
BR (1) BR9509493A (de)
CA (1) CA2200956A1 (de)
DE (1) DE69507626T2 (de)
MX (1) MX9702453A (de)
TW (1) TW371305B (de)
WO (1) WO1996010592A1 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5670680A (en) * 1996-04-26 1997-09-23 The Dow Chemical Company Method for producing octahydrofluorenyl metal complexes
US6100352A (en) * 1996-05-29 2000-08-08 Idemitsu Kosan Co., Ltd. Process for producing polymer
US6362293B1 (en) 1998-04-07 2002-03-26 The Dow Chemical Company Syndiotactic vinylidene aromatic polymerization process
US6232414B1 (en) * 1999-03-31 2001-05-15 Phillips Petroleum Company Process to make a monovinylaromatic polymer and said monovinylaromatic polymer
US6232415B1 (en) * 1999-03-31 2001-05-15 Phillips Petroleum Company Process to produce a monovinylaromatic/ monoolefin polymer and said monovinylaromatic/monoolefin polymer
KR100902998B1 (ko) * 2001-06-29 2009-06-15 이 아이 듀폰 디 네모아 앤드 캄파니 지르코늄 촉매를 사용한 베타-디카르보닐의 히드록실화
WO2004108775A1 (en) * 2003-06-05 2004-12-16 Dow Global Technologies Inc. Activated multinuclear transition metal catalyst compositions
WO2011025784A1 (en) 2009-08-31 2011-03-03 Dow Global Technologies Inc. Catalyst and process for polymerizing an olefin and polyolefin prepared thereby
CN111971311B (zh) 2018-03-30 2024-01-23 陶氏环球技术有限责任公司 高度可溶的烷基取代的碳鎓硼酸盐作为烯烃聚合的助催化剂
JP2021519362A (ja) 2018-03-30 2021-08-10 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合活性化剤
SG11202008654WA (en) 2018-03-30 2020-10-29 Dow Global Technologies Llc Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations
CN111918717B (zh) * 2018-03-30 2024-04-09 陶氏环球技术有限责任公司 烯烃聚合活化剂
SG11202008667SA (en) 2018-03-30 2020-10-29 Dow Global Technologies Llc Binuclear olefin polymerization activators

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5045517A (en) * 1987-06-17 1991-09-03 The Dow Chemical Company Catalyst and process for preparation of syndiotactic polystyrene
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5066741A (en) * 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5252677A (en) * 1990-11-20 1993-10-12 Mitsubishi Petrochemical Company Limited Functionalized olefin polymers
US5206197A (en) * 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5886117A (en) * 1991-08-05 1999-03-23 The Dow Chemical Company Process using borane derived catalysts for preparation of syndiotactic vinyl aromatic polymers
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
WO1994000500A1 (en) * 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers
DE69307472T2 (de) * 1992-11-10 1997-05-15 Mitsubishi Chem Corp Verfahren zur Herstellung von Alpha-Olefinpolymeren
EP0659774B1 (de) * 1993-12-27 1999-03-03 Idemitsu Kosan Company Limited Verfahren zur Herstellung eines Stryrolpolymer
DE69505293T2 (de) * 1994-03-31 1999-03-11 Idemitsu Kosan Co. Ltd., Tokio/Tokyo Verfahren zur Herstellung eines Styrolpolymers

Also Published As

Publication number Publication date
JPH10506932A (ja) 1998-07-07
CA2200956A1 (en) 1996-04-11
BR9509493A (pt) 1997-10-14
MX9702453A (es) 1997-06-28
WO1996010592A1 (en) 1996-04-11
EP0784639A1 (de) 1997-07-23
US5536797A (en) 1996-07-16
KR100357358B1 (ko) 2003-01-24
CN1082057C (zh) 2002-04-03
EP0784639B1 (de) 1999-01-27
CN1159813A (zh) 1997-09-17
TW371305B (en) 1999-10-01
KR970706319A (ko) 1997-11-03
DE69507626T2 (de) 1999-09-30

Similar Documents

Publication Publication Date Title
DE59504613D1 (de) Verfahren zur Herstellung von Aldehyden
ATE172447T1 (de) Integriertes verfahren zur herstellung von buten- 1
DE69628712D1 (de) Verfahren zur Herstellung von Dihalogenazolopyrimidinen
DE59607656D1 (de) Verfahren zur Herstellung von Alkylhydrogenchlorsilanen
DE69725675D1 (de) Verfahren zur Herstellung von Metallocenen
DE69510596D1 (de) Verfahren zur Herstellung von Organooxysilane
DE69513623D1 (de) Verfahren zur herstellung von isobutenpolymer
DE69507626D1 (de) Verfahren zur herstellung vom syndiotaktischem polymer von prochiralen olefinen
DE59509333D1 (de) Verfahren zur Herstellung von 3-Acryloxypropylalkoxysilanen
DE69501412D1 (de) Verfahren zur Herstellung von Isocanaten
DE59505473D1 (de) Verfahren zur Herstellung von Glykoloylaniliden
DE59406530D1 (de) Verfahren zur Herstellung von Polymerpolyesterolen
DE69605384D1 (de) Verfahren zur Herstellung von einem alpha-Alkylcinnamaldehyd
DE59501150D1 (de) Verfahren zur Herstellung von Polyisoolefinen
DE69520322D1 (de) Verfahren zur Herstellung von L-Ketohexose
DE69530176D1 (de) Verfahren zur Herstellung von Protein
DE69405705D1 (de) Verfahren zur Herstellung von einem optisch aktiven Diaminohexanonderivat
DE59607308D1 (de) Verfahren zur Herstellung von SiH-haltigen Organylchlorsilanen
DE59600661D1 (de) Verfahren zur Herstellung von d,I-Menthol
DE69631977D1 (de) Verfahren zur herstellung von lenkzahnstangen
DE59501307D1 (de) Verfahren zur Herstellung von Fluoranilinen
DE69600385D1 (de) Verfahren zur Herstellung von Aminonitropyridinen
DE59500563D1 (de) Verfahren zur Herstellung von N-Alkenylcarbonsäureamiden
DE69520817D1 (de) Verfahren zur Herstellung von Olefinpolymeren
DE69513008D1 (de) Verfahren zur Herstellung von Hydroxyalkoxybenzophenonen

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee