DE691921C - Zuendsatz - Google Patents
ZuendsatzInfo
- Publication number
- DE691921C DE691921C DE1937D0075425 DED0075425D DE691921C DE 691921 C DE691921 C DE 691921C DE 1937D0075425 DE1937D0075425 DE 1937D0075425 DE D0075425 D DED0075425 D DE D0075425D DE 691921 C DE691921 C DE 691921C
- Authority
- DE
- Germany
- Prior art keywords
- primers
- acid
- lead
- diazotriazole
- trinitroresorcinate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RNTNMCHXGXIGBW-UHFFFAOYSA-N 5-diazotriazole-4-carboxylic acid Chemical compound [N+](=[N-])=C1C(=NN=N1)C(=O)O RNTNMCHXGXIGBW-UHFFFAOYSA-N 0.000 claims description 6
- WETZJIOEDGMBMA-UHFFFAOYSA-L lead styphnate Chemical compound [Pb+2].[O-]C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C([O-])=C1[N+]([O-])=O WETZJIOEDGMBMA-UHFFFAOYSA-L 0.000 claims description 4
- 230000035945 sensitivity Effects 0.000 claims description 3
- -1 Diazotriazolcarbonsäure Chemical compound 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 4
- 239000002360 explosive Substances 0.000 description 3
- 150000003518 tetracenes Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229940007424 antimony trisulfide Drugs 0.000 description 2
- NVWBARWTDVQPJD-UHFFFAOYSA-N antimony(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Sb+3].[Sb+3] NVWBARWTDVQPJD-UHFFFAOYSA-N 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 2
- 229910021346 calcium silicide Inorganic materials 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- MHWLNQBTOIYJJP-UHFFFAOYSA-N mercury difulminate Chemical compound [O-][N+]#C[Hg]C#[N+][O-] MHWLNQBTOIYJJP-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000004655 tetrazenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B43/00—Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Air Bags (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
Zündsätze. Zur Herstellung von Tost- und korrosionssicheren, insbesondere quecksilberfreien Zündsätzen verwendete man bisher vorzugsweise die sogenannten Tetrazene, die in geringen Mengen den üblichen Zündsatzbestandteilen, beispielsweise dem Bleitrinitroresorcinat, zugesetzt, ein hervorragendes Sensibilisierungsmittel darstellen.Primers. For the production of rust and corrosion-proof, in particular Mercury-free ignition charges have so far preferably been used so-called Tetracenes, which in small amounts the usual primer components, for example added to lead trinitroresorcinate, it is an excellent sensitizer represent.
Es stellte sich nun heraus, daß man zwecks Erhöhung der Empfindlichkeit von Bleitrinitroresorcinatzündsätzen nicht allein auf die obengenannten Tetrazene angewiesen is-t, sondern auch durch Verwendung anderer stickstoffreicher Verbindungen zum gleichen Ziele gelangen kann.It turned out that in order to increase the sensitivity of lead trinitroresorcinate primers not only to the tetracenes mentioned above is dependent, but also by using other nitrogen-rich compounds can achieve the same goal.
Erfindungsgemäß wird als Initialzündstoff die an sich bekannte Diazotriazolcarbonsäure verwendet, die durch Diazotieren.von Amidotriazolcarbonsäure zu gewinnen ist.According to the invention, the known diazotriazole carboxylic acid is used as the initial igniter used, which is to be obtained by Diazotieren.von Amidotriazolcarbonsäure.
Als Ausgangsprodukt dient Amidotriazolcarbonsäure
Es handelt sich bei der Diazotriazolcarbonsäure, die in Zündsätzen das übliche Knallquecksilber und ähnliche Sprengstoffe zu ersetzen verma, um einen in .der Sprengstoff-e, technik unbekannten Stoff, der- keinen -Vorgänger hat, und welcher die Sprengstofftechnik ganz wesentlich bereichert, die hinsichtlich der knallquecksilberfreien Zündsätze bisher nur auf die Tetrazene angewiesen war.It is in the Diazotriazolcarbonsäure that verma replace the usual mercury fulminate and similar explosives in Zündsätzen to one in .the explosives, engineering unknown substance, DER no -Vorgänger has and which very much enriched the explosive technique that respect the mercury-free primers was previously only dependent on the tetracenes.
Als besondere Vorzüge des neuen Zündsatzhestandteiles gegenüber den Tetrazenen sei noch erwähnt, daß diese bei Verarbeitung zu Zündsätzen in spitzigen verfilzten Nadeln vorliegen, die vor dem Mischen erst durchgesiebt werden müssen, und deren Zerkleinerung infolge hoher Brisanz unangenehme Folgen -haben kann,. während die gemäß der Erfindung verwendete Diazotriazolcarbonsäure in einzelnen prismatischen Blättchen erhalten werden kann, die viel besser rieseln und sich ohne weiteres für Zündsätze verwenden und leichter mischen lassen.As special advantages of the new primer component compared to the Tetrazenes should also be mentioned that they are sharp when processed into ignition charges there are matted needles that have to be sieved before mixing, and the crushing of which can have unpleasant consequences as a result of high levels of volatility. while the diazotriazole carboxylic acid used according to the invention in individual prismatic Rolling papers can be obtained that trickle down much better and are easy to use for Use primers and let them mix more easily.
Für die neue Zusammensetzung der Zündsätze kommen im allgemeinen vorzugsweise
die nachstehenden Mischungsverhältnisse in Betracht:
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1937D0075425 DE691921C (en) | 1937-06-04 | 1937-06-05 | Zuendsatz |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE493385X | 1937-06-04 | ||
| DE1937D0075425 DE691921C (en) | 1937-06-04 | 1937-06-05 | Zuendsatz |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE691921C true DE691921C (en) | 1940-06-07 |
Family
ID=25944631
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1937D0075425 Expired DE691921C (en) | 1937-06-04 | 1937-06-05 | Zuendsatz |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE691921C (en) |
-
1937
- 1937-06-05 DE DE1937D0075425 patent/DE691921C/en not_active Expired
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