DE682558C - Process for the production of mother-of-pearl or similar gloss effects in cast bodies from phenol-aldehyde condensation products and gloss pigments - Google Patents
Process for the production of mother-of-pearl or similar gloss effects in cast bodies from phenol-aldehyde condensation products and gloss pigmentsInfo
- Publication number
- DE682558C DE682558C DEA75804D DEA0075804D DE682558C DE 682558 C DE682558 C DE 682558C DE A75804 D DEA75804 D DE A75804D DE A0075804 D DEA0075804 D DE A0075804D DE 682558 C DE682558 C DE 682558C
- Authority
- DE
- Germany
- Prior art keywords
- phenol
- pearl
- condensation products
- mother
- aldehyde condensation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000049 pigment Substances 0.000 title claims description 15
- 239000007859 condensation product Substances 0.000 title claims description 9
- 230000000694 effects Effects 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 238000000034 method Methods 0.000 title claims description 6
- 239000002932 luster Substances 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- -1 aromatic alcohols Chemical class 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 238000005266 casting Methods 0.000 claims 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- HUTDDBSSHVOYJR-UHFFFAOYSA-H bis[(2-oxo-1,3,2$l^{5},4$l^{2}-dioxaphosphaplumbetan-2-yl)oxy]lead Chemical compound [Pb+2].[Pb+2].[Pb+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O HUTDDBSSHVOYJR-UHFFFAOYSA-H 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical class CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001278 adipic acid derivatives Chemical class 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 201000009032 substance abuse Diseases 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
- C08J3/21—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase
- C08J3/215—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase at least one additive being also premixed with a liquid phase
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Description
Verfahren zur Herstellung von Perlmutter- oder ähnlichen Glanzeffekten in Gußkörpern aus Phenol-Aldehyd-Kondensationsprodukten und Glanzpigmenten Es ist aus der Kuristhornindustrie bekannt, Perlmuttereffekte unter Zuhilfenahme von sogenannten Glanzpigmenten, insbesondere Bleiphosphat, hervorzurufen. Man hat auch schon vorgeschlagen, derartige Glanzpigmente für die Herstellung von Perlmutter- oder ähnlichen Glanzeffekten in Phenol-Aldehyd-Kondensationsprodukten zu verwenden. Dies stößt aber dann auf Schwierigkeiten, wenn die Phenol-Aldehyd-Kondensationsprodukte im flüssigen Zustande zur Anwendung kommen, weil hier das spezifisch schwere Bleiphosphat o. dgl. in der Masse zu Boden sinkt, bevor sie zum Erstarren gebracht wird, und auch leicht ein Zusammenballen des Glanzpigments eintritt, wodurch für den angestrebten Effekt wirkungslose Nester gebildet werden.Process for the production of mother-of-pearl or similar gloss effects in cast bodies made of phenol-aldehyde condensation products and luster pigments It is known from the Kuristhorn industry, mother-of-pearl effects with the help of so-called Cause luster pigments, especially lead phosphate. It has already been suggested such luster pigments for the production of mother-of-pearl or similar luster effects to be used in phenol-aldehyde condensation products. But this then comes up Difficulties when the phenol-aldehyde condensation products are in the liquid state come to use because here the specifically heavy lead phosphate o. The like. In the Mass sinks to the ground before it is solidified, and also easily sinks Agglomeration of the luster pigment occurs, as a result of which the desired effect is ineffective Nests are formed.
Es hat sich nun überraschenderweise gezeigt, daß die Herstellung von Perlmutter-oder ähnlichen Glanzeffekten in Gußkörpern aus Plienol-Aldehyd-Kondensationsprodukten dann sehr gut gelingt, wenn man die Glanzpigmente zunächst beispielsweise mit Hilfe einer Farbenreibmühle oder eines Walzwerks mit Glykol oder anderen zähflüssigen aliphatischen oder aromatischen Alkoholen, mit Ausnahme des Glycerins, oder deren Derivaten homogen verreibt und den Phenol-Aldehyd-Kondensationsprodukten zusetzt, während diese sich im flüssigen Zustand befinden, worauf das Gießen und die Härtung der Harze in bekannter Weise vorgenommen wird. Als Dispersions- oder Emulgiermittel kommen außer Glykol z. B. in Betracht: Benzylalkohol, Glykolmonoäthyläther, Diäthylenglykol, Polyäthylenglykol, Polyglycerin, Diäthylenglykol- und Polyäthylenglykoläther; ferner Phthalsäureester, Adipinsäureester, Naphthensäureester. DieseDispersions-oder Emulgiermittel müssen einerseits genügend zähflüssig sein oder genügend hohes spezifisches Gewicht besitzen, um das Glanzpigment in Schwebe zu halten, und müssen andererseits mit dem Phenol-Aldehyd-Kondensationsprodukt homogene Mischungen zu ergeben vermögen.It has now surprisingly been shown that the production of Mother-of-pearl or similar gloss effects in cast bodies made from plienol-aldehyde condensation products then works very well if you first use the luster pigments, for example a paint grinder or a rolling mill with glycol or other viscous ones aliphatic or aromatic alcohols, with the exception of glycerine, or their Disperses derivatives homogeneously and adds them to the phenol-aldehyde condensation products, while these are in the liquid state, followed by pouring and hardening the resins is made in a known manner. As a dispersing or emulsifying agent except glycol z. B. possible: benzyl alcohol, glycol monoethyl ether, diethylene glycol, Polyethylene glycol, polyglycerine, diethylene glycol and polyethylene glycol ethers; further Phthalic acid esters, adipic acid esters, naphthenic acid esters. These dispersants or emulsifiers must on the one hand be sufficiently viscous or sufficiently high specific weight own to keep the luster pigment in suspension, and on the other hand must with capable of giving the phenol-aldehyde condensation product homogeneous mixtures.
Man hat zwar auch schon daran gedacht, die oben gerügten Übelstände zu vermeiden. Der deshalb gemachte Vorschlag ging dahin, einzelne gefärbte Massebrocken, durch deren Vereinigung ein gemaserter Kunstgegenstand hergestellt werden sollte, j e mit einem andersfarbigen Klebmittel zu urnhüllen und sie alsdann zu verpressen. Auf diese Weise lassen sich aber perlmutterartige Effekte, bei denen das Glanzpigment homogen in der Masse verteilt sein muß, nicht erreichen. Andererseits hat man vorgeschlagen, bei der Herstellung von Anstrichmitteln die Pigmente zunächst mit einem Teil des Bindemit= tels innig zu vermischen und dann die..... haltene Masse mit dem übrigen Teil ä' Bindemittels zu vereinigen. Bei der Hers lung von Anstrichmassen liegen aber Verhältnisse grundsätzlich anders als beAir, Herstellung von Kunstmassen aus Gußharzen: Denn bei diesen muß zum Zwecke der Härtung der Harze ein längeres Erhitzen: der mit dem Glanzpigment versetzten, zunächst flüssigen Stoffe stattfinden, und es bestand die Gefahr, daß sich während dieser Zeit die spezifisch schweren Glanzpigmente bereits wieder absetzen würden, bevor die Kunstharze erhärteten. Es war nicht vorauszusehen, daß diese Gefahr würde umgangen werden können, wenn man die Glanzpigmente -zunächst mit einemDispersionsmittel der oben angegebenen Art vereinigte und dann erst den flüssigen Kunstharzen zusetzte.It is true that one has already thought of avoiding the abuses criticized above. The proposal made therefore was to encase individual colored chunks of mass, through the combination of which a grained art object should be produced, with a different colored adhesive and then to press them. In this way, however, mother-of-pearl-like effects in which the luster pigment must be homogeneously distributed in the mass cannot be achieved. On the other hand, it has been proposed, in the production of paints, first of all to mix the pigments intimately with part of the binder and then to combine the ..... retained mass with the remaining part of the binder. When it comes to the manufacture of paints, however, the situation is fundamentally different from that of beAir, the manufacture of synthetic compounds from cast resins: for these, in order to harden the resins, the initially liquid substances with the luster pigment must be heated for a longer period of time, and there was a risk that during this time the specifically heavy luster pigments would settle again before the synthetic resins hardened. It was not anticipated that this danger would be avoided if the luster pigments - united first with a dispersion medium of the type mentioned above and only then zusetzte the liquid resins.
Zur Ausführung des Verfahrens kann man z. B. so verfahren, daß man gleiche Teile trockenes Bleiphosphat und Glykol auf einer gewöhnlichen Farbreibmühle so lange vermahlt, bis eine dicke, homogene, kornfreie, ölartige Emulsion entstanden ist. Von dieser führt man r bis zo°/o in ein flüssiges Kunstharz ein, daß dann, wie üblich, weiterverarbeitet wird. Man erhält so nach der Härtung .des Harzes einen Körper mit einem shr schönen perlmutterartigen Effekt, der in einer Gleichmäßigkeit nach anderen Ver-KUhren unter Zuhilfenahme von trockenem "oder pastenförmigem Bleiphosphat allein nicht .erhalten werden kann. Die Körnchengröße 'des Pigments nach der Vereinigung mit dem Harz ist von wesentlicher Bedeutung für die Ausführung des Verfahrens.To carry out the method you can, for. B. proceed so that one equal parts dry lead phosphate and glycol on an ordinary paint grinder Ground until a thick, homogeneous, grain-free, oil-like emulsion is formed is. From this one introduces r to zo ° / o into a liquid synthetic resin, that then, as usual, is further processed. After hardening, the resin is obtained in this way Body with a beautiful mother-of-pearl-like effect that is uniform according to other methods with the aid of dry or pasty lead phosphate alone cannot .be obtained. The 'granule size' of the pigment after association using the resin is essential to running the process.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEA75804D DE682558C (en) | 1935-04-13 | 1935-04-13 | Process for the production of mother-of-pearl or similar gloss effects in cast bodies from phenol-aldehyde condensation products and gloss pigments |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEA75804D DE682558C (en) | 1935-04-13 | 1935-04-13 | Process for the production of mother-of-pearl or similar gloss effects in cast bodies from phenol-aldehyde condensation products and gloss pigments |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE682558C true DE682558C (en) | 1939-10-17 |
Family
ID=6946575
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEA75804D Expired DE682558C (en) | 1935-04-13 | 1935-04-13 | Process for the production of mother-of-pearl or similar gloss effects in cast bodies from phenol-aldehyde condensation products and gloss pigments |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE682558C (en) |
-
1935
- 1935-04-13 DE DEA75804D patent/DE682558C/en not_active Expired
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