DE4424823A1 - Strongly foaming detergent mixt. for powder and liq. washing agents - Google Patents
Strongly foaming detergent mixt. for powder and liq. washing agentsInfo
- Publication number
- DE4424823A1 DE4424823A1 DE19944424823 DE4424823A DE4424823A1 DE 4424823 A1 DE4424823 A1 DE 4424823A1 DE 19944424823 DE19944424823 DE 19944424823 DE 4424823 A DE4424823 A DE 4424823A DE 4424823 A1 DE4424823 A1 DE 4424823A1
- Authority
- DE
- Germany
- Prior art keywords
- fatty acid
- acid
- detergent mixtures
- mixtures according
- additives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 36
- 238000005187 foaming Methods 0.000 title claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 title description 21
- 238000005406 washing Methods 0.000 title description 4
- 239000000843 powder Substances 0.000 title description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 46
- 239000000194 fatty acid Substances 0.000 claims abstract description 46
- 229930195729 fatty acid Natural products 0.000 claims abstract description 46
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 44
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 25
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims abstract description 12
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 35
- 239000004094 surface-active agent Substances 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract description 2
- 239000000654 additive Substances 0.000 description 24
- -1 ether sulfates Chemical class 0.000 description 21
- 244000060011 Cocos nucifera Species 0.000 description 13
- 235000013162 Cocos nucifera Nutrition 0.000 description 13
- 239000006260 foam Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000003945 anionic surfactant Substances 0.000 description 5
- 238000004851 dishwashing Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 235000002639 sodium chloride Nutrition 0.000 description 5
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 235000019197 fats Nutrition 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920001661 Chitosan Polymers 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 235000000346 sugar Nutrition 0.000 description 3
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- DLRVVLDZNNYCBX-UHFFFAOYSA-N Polydextrose Polymers OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(O)O1 DLRVVLDZNNYCBX-UHFFFAOYSA-N 0.000 description 2
- 108010009736 Protein Hydrolysates Proteins 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 230000010933 acylation Effects 0.000 description 2
- 238000005917 acylation reaction Methods 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 239000003531 protein hydrolysate Substances 0.000 description 2
- 238000006268 reductive amination reaction Methods 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 150000003626 triacylglycerols Chemical class 0.000 description 2
- 239000002888 zwitterionic surfactant Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- GHPCICSQWQDZLM-UHFFFAOYSA-N 1-(4-chlorophenyl)sulfonyl-1-methyl-3-propylurea Chemical compound CCCNC(=O)N(C)S(=O)(=O)C1=CC=C(Cl)C=C1 GHPCICSQWQDZLM-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical class CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-M 2-methylbenzenesulfonate Chemical compound CC1=CC=CC=C1S([O-])(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- PVXPPJIGRGXGCY-DJHAAKORSA-N 6-O-alpha-D-glucopyranosyl-alpha-D-fructofuranose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@](O)(CO)O1 PVXPPJIGRGXGCY-DJHAAKORSA-N 0.000 description 1
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- QNAYBMKLOCPYGJ-UHFFFAOYSA-N Alanine Chemical class CC([NH3+])C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-N 0.000 description 1
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- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
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- 238000002156 mixing Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 239000001259 polydextrose Substances 0.000 description 1
- 235000013856 polydextrose Nutrition 0.000 description 1
- 229940035035 polydextrose Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
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- 229920000136 polysorbate Polymers 0.000 description 1
- 229940068965 polysorbates Drugs 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
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- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/16—Sulfonic acids or sulfuric acid esters; Salts thereof derived from divalent or polyvalent alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
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- Detergent Compositions (AREA)
Abstract
Description
Die Erfindung betrifft Detergensgemische mit synergistischer Verstärkung des Schaumvermögens, enthaltend Fettsäure-N-al kylpolyhydroxyalkylamide und Fettsäuremonoglycerid(ether)sul fate sowie deren Verwendung zur Herstellung oberflächenakti ver Mittel.The invention relates to detergent mixtures with synergistic Enhancement of foaming power containing fatty acid N-al kylpolyhydroxyalkylamides and fatty acid monoglyceride (ether) sul fate and their use for the production of surface active agents ver means.
Fettsäure-N-alkylpolyhydroxyalkylamide und insbesondere Fett säure-N-methylglucamide stellen nichtionische Tenside dar, die wegen ihres guten anwendungstechnischen Profils bei spielsweise zur Herstellung von Handgeschirrspülmitteln ein gesetzt werden.Fatty acid N-alkylpolyhydroxyalkylamides and in particular fat acid N-methylglucamides are nonionic surfactants, because of their good performance profile For example, for the production of hand dishwashing detergents be set.
Die Verwendung dieser Stoffe ist Gegenstand einer Vielzahl von Veröffentlichungen. Aus der Europäischen Patentanmeldung EP-A1 0 285 768 (Hüls) ist beispielsweise ihr Einsatz als Verdickungsmittel bekannt. In der Französischen Offenlegungs schrift FR-A 1 580 491 (Henkel) werden wäßrige Detergensge mische auf Basis von Sulfaten und/oder Sulfonaten, Niotensi den und gegebenenfalls Seifen beschrieben, die Fettsäure-N-al kylglucamide als Schaumregulatoren enthalten.The use of these substances is the subject of a multitude of publications. From the European patent application EP-A1 0 285 768 (Hüls) is for example their use as Thickener known. In the French disclosure FR-A 1 580 491 (Henkel) describes aqueous detergent compositions mixtures based on sulfates and / or sulfonates, noniotensi and, optionally, soaps containing fatty acid N-al kylglucamide contained as foam regulators.
Gegenstand der Internationalen Patentanmeldungen WO 92/6153; 6156; 6157; 6158; 6159 und 6160 (Procter & Gamble) sind Mi schungen von Fettsäure-N-alkylglucamiden mit anionischen Tensiden, Tensiden mit Sulfat- und/oder Sulfonatstruktur, Ethercarbonsäuren, Ethersulfaten, Methylestersulfonaten und nichtionischen Tensiden. Die Verwendung dieser Stoffe in den unterschiedlichsten Wasch-, Spül- und Reinigungsmitteln wird in den Internationalen Patentanmeldungen WO 92/6152; 6154; 6155; 6161; 6162; 6164; 6170; 6171 und 6172 (Procter & Gamble) beschrieben.Subject of International Patent Applications WO 92/6153; 6156; 6157; 6158; 6159 and 6160 (Procter & Gamble) are Mi mixtures of fatty acid N-alkylglucamides with anionic ones Surfactants, surfactants with sulphate and / or sulphonate structure, Ethercarbonsäuren, ether sulfates, methyl ester sulfonates and nonionic surfactants. The use of these substances in the different washing, rinsing and cleaning agents in International Patent Applications WO 92/6152; 6154; 6155; 6161; 6162; 6164; 6170; 6171 and 6172 (Procter & Gamble).
In der Praxis hat sich jedoch gezeigt, daß die Fettsäure-N- alkylpolyhydroxyalkylamide auch in Kombination mit anderen vorzugsweise anionischen Tensiden ein Schaumvermögen und ins besondere eine Schaumstabilität in hartem Wasser aufweisen, die nicht immer zufriedenstellend sind.In practice, however, it has been found that the fatty acid N- alkylpolyhydroxyalkylamides also in combination with others preferably anionic surfactants, a foaming power and ins have foam stability in hard water, which are not always satisfactory.
Die Aufgabe der Erfindung hat somit darin bestanden, Deter gensgemische auf Basis von Fettsäure-N-alkylpolyhydroxyalkyl amiden zur Verfügung zu stellen, die über ein verbessertes Schaumvermögen verfügen, ohne daß dieser Vorteil durch Lei stungseinbußen in anderen anwendungstechnisch relevanten Ei genschaften bezahlt werden muß. The object of the invention has thus been, Deter mixtures based on fatty acid-N-alkylpolyhydroxyalkyl to provide amides that have an improved Foaming properties without Lei Impact losses in other application-relevant egg properties must be paid.
Gegenstand der Erfindung sind starkschäumende Detergensge mische, enthaltendThe invention relates to high-foaming Detergensge mix, containing
- (a) Fettsäure-N-alkylpolyhydroxyalkylamide und(a) fatty acid N-alkylpolyhydroxyalkylamides and
- (b) Fettsäuremonoglycerid(ether)sulfate(b) fatty acid monoglyceride (ether) sulfate
im Gewichtsverhältnis 80 : 20 bis 20 : 80, vorzugsweise 50 50 bis 25 : 75 und insbesondere 40 : 60 bis 30 : 70.in the weight ratio 80:20 to 20:80, preferably 50 50 to 25: 75 and especially 40: 60 to 30: 70.
Obschon Mischungen auf Basis von Fettsäure-N-alkylpolyhy droxyalkylamiden, insbesondere Fettsäure-N-methylglucamiden und anionischen Tensiden bereits bekannt gewesen sind, wurde überraschenderweise hinsichtlich des Schaumvermögens inner halb bestimmter Mischungsverhältnisse eine starke synergisti sche Wechselwirkung mit Monoglyceridsulfaten festgestellt; dies betrifft insbesondere die Schaumstabilität in hartem Wasser. Die Erfindung schließt die Erkenntnis ein, daß auch hinsichtlich Netzvermögen und Waschleistung eine Verbesserung erzielt wird und die ökotoxikologischen Eigenschaften wenig stens auf dem Niveau der Einzelstoffe erhalten bleiben.Although mixtures based on fatty acid N-alkylpolyhy droxyalkylamiden, in particular fatty acid N-methylglucamiden and anionic surfactants have already been known Surprisingly, in terms of foaming power inside Half of certain mixing ratios a strong synergisti interaction with monoglyceride sulfates; This concerns in particular the foam stability in hard Water. The invention includes the insight that also an improvement in terms of wetting power and washing performance achieved and the ecotoxicological properties little at least at the level of the individual substances.
Bei den Fettsäure-N-alkylpolyhydroxyalkylamiden handelt es sich um bekannte Stoffe, die üblicherweise durch reduktive Aminierung eines reduzierenden Zuckers mit Ammoniak, einem Alkylamin oder einem Alkanolamin und nachfolgende Acylierung mit einer Fettsäure, einem Fettsäurealkylester oder einem Fettsäurechlorid erhalten werden können. Hinsichtlich der Verfahren zu ihrer Herstellung sei auf die US-Patentschriften US 1985424, US 2016962 und US 2703798 sowie die Internatio nale Patentanmeldung WO 92/06984 verwiesen. Eine Übersicht zu diesem Thema von H.Kelkenberg findet sich in Tens. Surf. Det. 25, 8 (1988).The fatty acid N-alkyl polyhydroxyalkylamides are to known substances, usually by reductive Amination of a reducing sugar with ammonia, a Alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a Fatty acid chloride can be obtained. With regard to the A method for their preparation is based on the US patents US 1985424, US 2016962 and US 2703798 and the Internatio nal patent application WO 92/06984. An overview of This topic from H.Kelkenberg can be found in Tens. Surf. Det. 25, 8 (1988).
Vorzugsweise leiten sich die Fettsäure-N-alkylpolyhydroxyal kylamide von reduzierenden Zuckern mit 5 oder 6 Kohlenstoff atomen, insbesondere von der Glucose ab. Die bevorzugten Fettsäure-N-alkylpolyhydroxyalkylamide stellen daher Fett säure-N-alkylglucamide dar, wie sie durch die Formel (II) wiedergegeben werden:Preferably, the fatty acid N-alkylpolyhydroxyal are derived Kylamide of reducing sugars with 5 or 6 carbon atoms, in particular from glucose. The preferred ones Fatty acid N-alkylpolyhydroxyalkylamides are therefore fatty acid N-alkylglucamides, as represented by the formula (II) be reproduced:
Vorzugsweise werden als Fettsäure-N-alkylpolyhydroxyalkyl amide Glucamide der Formel (II) eingesetzt, in der R² für Wasserstoff oder eine Amingruppe steht und R¹CO für den Acylrest der Capronsäure, Caprylsäure, Caprinsäure, Laurin säure, Myristinsäure, Palmitinsäure, Palmoleinsäure, Stea rinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petrose linsäure, Linolsäure, Linolensäure, Arachinsäure, Gadolein säure, Behensäure oder Erucasäure bzw. derer technischer Mi schungen steht. Besonders bevorzugt sind Fettsäure-N-alkyl glucamide der Formel (II), die durch reduktive Aminierung von Glucose mit Methylamin und anschließende Acylierung mit Laurinsäure oder C12/14-Kokosfettsäure bzw. einem entspre chenden Derivat erhalten werden. Weiterhin können sich die Polyhydroxyalkylamide auch von Maltose und Palatinose ablei ten.The fatty acid N-alkylpolyhydroxyalkylamides used are preferably glucamides of the formula (II) in which R² is hydrogen or an amine group and R¹CO is the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, Isostearic acid, oleic acid, elaidic acid, petrose linsäure, linoleic acid, linolenic acid, arachidic acid, gadoleic acid, behenic acid or erucic acid or whose technical Mi is mixtures. Particular preference is given to fatty acid N-alkyl glucamides of the formula (II) which are obtained by reductive amination of glucose with methylamine and subsequent acylation with lauric acid or C 12/14 coconut fatty acid or a corresponding derivative. Furthermore, the polyhydroxyalkylamides can also be derived from maltose and palatinose.
Monoglyceridsulfate und Monoglyceridethersulfate stellen be kannte anionische Tenside dar, die nach den einschlägigen Methoden der präparativen organischen Chemie erhalten werden können. Üblicherweise geht man zu ihrer Herstellung von Tri glyceriden aus, die gegebenenfalls nach Ethoxylierung zu den Monoglyceriden umgeestert und nachfolgend sulfatiert und neu tralisiert werden. Gleichfalls ist es möglich, die Partial glyceride mit geeigneten Sulfatierungsmitteln, vorzugsweise gasförmiges Schwefeltrioxid oder Chlorsulfonsäure umzusetzen [vgl. WO 92/09 569, WO 92/09 570, Henkel]. Die neutralisier ten Stoffe können - falls gewünscht - einer Ultrafiltration unterworfen werden, um den Elektrolytgehalt auf ein gewünsch tes Maß zu vermindern.Monoglyceride sulfates and monoglyceride ether sulfates provide knew anionic surfactants, according to the relevant Methods of preparative organic chemistry can be obtained can. Usually one goes to their production of tri glycerides, optionally after ethoxylation to the Monoglycerides transesterified and subsequently sulfated and new be tralized. Likewise, it is possible the partial glycerides with suitable sulfating agents, preferably react gaseous sulfur trioxide or chlorosulfonic acid [see. WO 92/09 569, WO 92/09 570, Henkel]. The neutralize If necessary, these substances can be subjected to ultrafiltration be subjected to the electrolyte content to a desired to reduce this measure.
Typische Beispiele für im Sinne der Erfindung geeignete Mono glerid(ether)sulfate sind die Umsetzungsprodukte von Laurin säuremonoglycerid, Kokosfettsäuremonoglycerid, Palmitin säureonoglycerid, Stearinsäuremonoglycerid, Ölsäuremonogly cerid und Talgfettsäuremonoglycerid sowie deren Ethylenoxid addukten mit Schwefeltrioxid oder Chlorsulfonsäure in Form ihrer Natriumsalze. Vorzugsweise werden Monoglyceridsulfate der Formel (III) eingesetzt, in der R²CO für einen linearen Acylrest mit 8 bis 18 Kohlenstoffatomen steht, der sich von technischen Kokosfettsäureschnitten ableitet. Die bevorzugten Monoglyceridsulfate sind daher Kokosmonoglyceridsulfate.Typical examples of suitable mono within the meaning of the invention gleride (ether) sulfates are the reaction products of laurin acid monoglyceride, coconut fatty acid monoglyceride, palmitin acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyme cerid and tallow fatty acid monoglyceride and their ethylene oxide Adducts with sulfur trioxide or chlorosulfonic acid in the form their sodium salts. Preferably, monoglyceride sulfates of the formula (III), in which R²CO is a linear Acyl radical having 8 to 18 carbon atoms, which is different from derives technical coconut fatty acid cuts. The preferred ones Monoglyceride sulfates are therefore coconut monoglyceride sulfates.
Die Herstellung der Mischungen, die vorzugsweise wäßrig sind und dann einen Feststoffgehalt von 5 bis 70, vorzugsweise 25 bis 50 Gew.-% aufweisen, erfolgt in der Regel durch Verrühren wäßriger Lösungen, Pasten oder Konzentrate der Einsatzstoffe, falls erforderlich bei leicht erhöhter Temperatur. Es ist je doch ebenfalls möglich, sprühgetrocknete Pulver der beiden Komponenten zu vermischen und anschließend anzupassen oder Lösungen beider Inhaltsstoffe gemeinsam einer Sprühtrocknung und/oder Granulation zu unterwerfen. In allen diesen Fällen handelt es sich um rein mechanische Verfahren, eine chemische Reaktion findet nicht statt.The preparation of the mixtures, which are preferably aqueous and then a solids content of 5 to 70, preferably 25 to 50 wt .-%, is usually done by stirring aqueous solutions, pastes or concentrates of the starting materials, if necessary at slightly elevated temperature. It is ever but also possible, spray-dried powder of the two Mix components and then adjust or Solutions of both ingredients together a spray drying and / or granulation. In all these cases are purely mechanical processes, a chemical Reaction does not take place.
Die erfindungsgemäßen Detergensgemische weisen eine synergi stische Verstärkung des Schaumvermögens, insbesondere im Hin blick auf die Schaumstabilität auf. Ein weiterer Gegenstand der Erfindung betrifft daher ihre Verwendung zur Herstellung von oberflächenaktiven Mitteln, als da sind:The detergent mixtures according to the invention have a synergi tical reinforcement of the foaming power, especially in Hin look at the foam stability. Another item The invention therefore relates to its use for the production of surfactants, as there are:
- - Pulverförmige Universalwaschmittel, enthaltend 10 bis 30 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Detergensgemische sowie übliche Hilfs- und Zusatzstoffe.- Powdered universal detergents containing 10 to 30 Gew. -% - related to the means - of the invention Detergent mixtures and customary auxiliaries and additives.
- - Flüssige Universalwaschmittel, enthaltend 10 bis 70 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Detergensgemische sowie übliche Hilfs- und Zusatzstoffe. Liquid universal detergents containing 10 to 70 Gew. -% - related to the means - of the invention Detergent mixtures and customary auxiliaries and additives.
- - Flüssige Feinwaschmittel, enthaltend 10 bis 50 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Deter gensgemische sowie übliche Hilfs- und Zusatzstoffe.Liquid mild detergents containing 10 to 50% by weight - Based on the means - of the invention Deter gensgemische and customary auxiliaries and additives.
- - Avivagemittel, enthaltend 10 bis 50 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Detergensgemische so wie übliche Hilfs- und Zusatzstoffe.- Lubricant, containing 10 to 50 wt .-% - based on the agent - the detergent mixtures according to the invention so as usual auxiliaries and additives.
- - Handgeschirrspülmittel, enthaltend 10 bis 50 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Deter gensgemische sowie übliche Hilfs- und Zusatzstoffe.Hand dishwashing detergent containing 10 to 50% by weight - Based on the means - of the invention Deter gensgemische and customary auxiliaries and additives.
- - Klarspüler, enthaltend 10 bis 50 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Detergensgemische so wie übliche Hilfs- und Zusatzstoffe.Rinse aid containing 10 to 50 wt .-% - based on the agent - the detergent mixtures according to the invention so as usual auxiliaries and additives.
- - Flüssige Reinigungs- und Desinfektionsmittel, enthaltend 10 bis 30 Gew.-% - bezogen auf das Mittel - der erfin dungsgemäßen Detergensgemische sowie übliche Hilfs- und Zusatzstoffe.- Liquid detergents and disinfectants, containing 10 to 30 wt .-% - based on the means - the inventions Detergent mixtures according to the invention as well as customary auxiliaries and Additives.
- - Stückseifen vom Kombibar-Typ, enthaltend 1 bis 2 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Deter gensgemische sowie übliche Hilfs- und Zusatzstoffe.Kombibar type bar soaps containing 1 to 2% by weight - Based on the means - of the invention Deter gensgemische and customary auxiliaries and additives.
- - Syndetseifen, enthaltend 1 bis 2 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Detergensgemische sowie übliche Hilfs- und Zusatzstoffe. - Syndetseifen containing 1 to 2 wt .-% - based on the agent - the detergent mixtures according to the invention as well as usual auxiliaries and additives.
- - Haarshampoos, enthaltend 10 bis 30 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Detergensgemische so wie übliche Hilfs- und Zusatzstoffe.- Hair shampoos, containing 10 to 30 wt .-% - based on the agent - the detergent mixtures according to the invention so as usual auxiliaries and additives.
- - Haarspülungen, enthaltend 10 bis 30 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Detergensgemische so wie übliche Hilfs- und Zusatzstoffe.- Hair rinses, containing 10 to 30 wt .-% - based on the agent - the detergent mixtures according to the invention so as usual auxiliaries and additives.
- - Haarfärbemittel, enthaltend 10 bis 30 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Detergensgemische sowie übliche Hilfs- und Zusatzstoffe.- Hair dye containing 10 to 30 wt .-% - related to the agent - the detergent mixtures according to the invention as well as usual auxiliaries and additives.
- - Haarwellmittel, enthaltend 10 bis 30 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Detergensgemische sowie übliche Hilfs- und Zusatzstoffe.- Hair wave agent containing 10 to 30 wt .-% - related to the agent - the detergent mixtures according to the invention as well as usual auxiliaries and additives.
- - Schaumbäder, enthaltend 10 bis 30 Gew.-% - bezogen auf das Mittel - der erfindungsgemäßen Detergensgemische so wie übliche Hilfs- und Zusatzstoffe.- Foam baths containing 10 to 30 wt .-% - based on the agent - the detergent mixtures according to the invention so as usual auxiliaries and additives.
- - Textil- und Faserhilfsmittel, enthaltend 1 bis 30 Gew.-%Textile and fiber auxiliaries containing 1 to 30% by weight
- - bezogen auf das Mittel - der erfindungsgemäßen Deter gensgemische sowie übliche Hilfs- und Zusatzstoffe.- Based on the means - of the invention Deter gensgemische and customary auxiliaries and additives.
- - Lederfettungsmittel, enthaltend 1 bis 30 Gew.-% - be zogen auf das Mittel - der erfindungsgemäßen Detergens gemische sowie übliche Hilfs- und Zusatzstoffe.- Leather fatliquoring agent containing 1 to 30 wt .-% - be attracted to the agent - the detergent of the invention mixtures and customary auxiliaries and additives.
- - Flotationshilfsmittel, enthaltend 1 bis 30 Gew.-% - be zogen auf das Mittel - der erfindungsgemäßen Detergens gemische sowie übliche Hilfs- und Zusatzstoffe. - Flotationshilfsmittel containing 1 to 30 wt .-% - Be attracted to the agent - the detergent of the invention mixtures and customary auxiliaries and additives.
- - Hilfsmittel für die Feststoffentwässerung, enthaltend 1 bis 30 Gew.-% - bezogen auf das Mittel - der erfindungs gemäßen Detergensgemische sowie übliche Hilfs- und Zu satzstoffe.- Aid for the dewatering of solids, containing 1 to 30 wt .-% - based on the agent - the Invention proper detergent mixtures as well as usual auxiliary and Zu set materials.
Besonders bevorzugt ist in diesem Zusammenhang die Verwendung der erfindungsgemäßen Detergensgemische zur Herstellung von manuellen Geschirrspülmitteln und Haarshampoos.Particularly preferred in this context is the use the detergent mixtures according to the invention for the preparation of manual dishwashing detergents and hair shampoos.
Die oben genannten Mittel können als Hilfs- und Zusatzstoffe in erster Linie weitere anionische, nichtionische, kationi sche, amphotere und/oder zwitterionische Tenside enthalten.The above agents can be used as auxiliaries and additives primarily other anionic, nonionic, cationic containing, amphoteric and / or zwitterionic surfactants.
Typische Beispiele für anionische Tenside sind Alkylbenzol sulfonate, Alkansulfonate, Olefinsulfonate, Alkylethersul fonate, Glycerinethersulfonate, α-Methylestersulfonate, Sul fofettsäuren, Alkylsulfate, Fettalkoholethersulfate, Glyce rinethersulfate, Hydroxymischethersulfate, Monoglycerid- (ether)sulfate, Fettsäureamid(ether)sulfate, Mono- und Dial kylsulfosuccinate, Mono- und Dialkylsulfosuccinamate, Sulfo triglyceride, Amidseifen, Ethercarbonsäuren und deren Salze, Fettsäureisethionate, Fettsäuresarcosinate, Fettsäuretauride, Acyllactylate, Alkyloligoglucosidsulfate, Proteinfettsäure kondensate (insbesondere pflanzliche Produkte auf Sojabasis) und Alkyl(ether)phosphate. Sofern die anionischen Tenside Polyglycoletherketten enthalten, können sie eine konventio nelle, vorzugsweise jedoch eine eingeengte Homologenvertei lung aufweisen. Typical examples of anionic surfactants are alkylbenzene sulfonates, alkanesulfonates, olefinsulfonates, alkylethersul fonates, glycerol ether sulfonates, α-methyl ester sulfonates, Sul fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glyce amine ether sulfates, hydroxymethylene ether sulfates, monoglyceride (ether) sulfate, fatty acid amide (ether) sulfate, mono- and dial Kylsulfosuccinate, mono- and dialkylsulfosuccinamates, sulfo triglycerides, amide soaps, ether carboxylic acids and their salts, Fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, Acyl lactylates, alkyl oligoglucoside sulfates, protein fatty acid condensates (in particular soy-based herbal products) and alkyl (ether) phosphates. If the anionic surfactants Polyglycoletherketten contain, they can a konventio but preferably a narrow homology distribution have.
Typische Beispiele für nichtionische Tenside sind Fettalko holpolyglycolether, Alkylphenolpolyglycolether, Fettsäurepo lyglycolester, Fettsäureamidpolygylcolether, Fettaminpoly glycolether, alkoxylierte Triglyceride, Alk(en)yloligoglyko side, Fettsäure-N-alkylglucamide, Proteinhydrolysate (ins besondere pflanzliche Produkte auf Sojabasis) Polyolfett säureester, Zuckerester, Sorbitanester und Polysorbate. So fern die nichtionischen Tenside Polyglycoletherketten ent halten, können sie eine konventionelle, vorzugsweise jedoch eine eingeengte Homologenverteilung aufweisen.Typical examples of nonionic surfactants are fatty alcohol holpolyglycol ethers, alkylphenol polyglycol ethers, fatty acid po lyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyols Glycol ethers, alkoxylated triglycerides, alk (en) yloligoglyco side, fatty acid N-alkylglucamide, protein hydrolysates (ins special vegetable soy-based products) Polyol fat acid esters, sugar esters, sorbitan esters and polysorbates. so far the nonionic surfactants polyglycol ether chains ent they can be conventional, but preferably have a narrow homolog distribution.
Typische Beispiele für kationische Tenside sind quartäre Am moniumverbindungen und Esterquats, insbesondere quaternierte Fettsäuretrialkanolaminester-Salze.Typical examples of cationic surfactants are quaternary amines monium compounds and esterquats, in particular quaternized Fettsäuretrialkanolaminester salts.
Typische Beispiele für amphotere bzw. zwitterionische Tenside sind Alkylbetaine, Alkylamidobetaine, Aminopropionate, Amino glycinate, Imidazoliniumbetaine und Sulfobetaine.Typical examples of amphoteric or zwitterionic surfactants are alkylbetaines, alkylamidobetaines, aminopropionates, amino glycinates, imidazolinium betaines and sulfobetaines.
Bei den genannten Tensiden handelt es sich ausschließlich um bekannte Verbindungen. Hinsichtlich Struktur und Herstellung dieser Stoffe sei auf einschlägige Übersichtsarbeiten bei spielsweise J.Falbe (ed.), "Surfactants in Consumer Pro ducts", Springer Verlag, Berlin, 1987, S. 54-124 oder J.Falbe (ed.), "Katalysatoren, Tenside und Mineralöladditive", Thieme Verlag, Stuttgart, 1978, S. 123-217 verwiesen. The surfactants mentioned are exclusively known compounds. Regarding structure and production these substances are included in relevant reviews For example J.Falbe (ed.), "Surfactants in Consumer Pro ducts ", Springer Verlag, Berlin, 1987, pp. 54-124 or J. Falbe (ed.), "Catalysts, Surfactants and Mineral Oil Additives", Thieme Verlag, Stuttgart, 1978, pp. 123-217.
Wasch-, Spül-, Reinigungs- und Avivagemittel auf Basis der erfindungsgemäßen Detergensgemische können als Hilfs- und Zusatzstoffe beispielsweise Builder, Salze, Bleichmittel, Bleichaktivatoren, optische Aufheller, Vergrauungsinhibito ren, Lösungsvermittler und Enzyme enthalten.Washing, rinsing, cleaning and softening preparations based on Detergent mixtures according to the invention can be used as auxiliary and Additives, for example builders, salts, bleaches, Bleach activators, optical brighteners, grayness inhibitors ren, solubilizers and enzymes.
Übliche Builder sind Natriumaluminiumsilicate (Zeolithe), Phosphate, Phosphonate, Ethylendiamintetraessigsäure, Ni trilotriacetat, Citronensäure und/oder Polycarboxylate. Als Salze bzw. Stellmittel kommen beispielsweise Natriumsulfat, Natriumcarbonat oder Natriumsilicat (Wasserglas) in Betracht. Als typische Einzelbeispiele für weitere Zusatzstoffe sind Natriumborat, Stärke, Saccharose, Polydextrose, TAED, Stil benverbindungen, Methylcellulose, Toluolsulfonat, Cumolsul fonat, langkettige Seifen, Silicone, Mischether, Lipasen und Proteasen zu nennen.Common builders are sodium aluminum silicates (zeolites), Phosphates, phosphonates, ethylenediaminetetraacetic acid, Ni tri-tri-acetate, citric acid and / or polycarboxylates. When Salts or adjusting agents are, for example, sodium sulfate, Sodium carbonate or sodium silicate (water glass) into consideration. As typical individual examples of other additives are Sodium Borate, Starch, Sucrose, Polydextrose, TAED, Style benverbindungen, methyl cellulose, toluenesulfonate, cumolsul fonat, long-chain soaps, silicones, mixed ethers, lipases and To name proteases.
Haarshampoos, Haarlotionen oder Schaumbäder können als Hilfs- und Zusatzstoffe Emulgatoren wie etwa alkoxylierte Fettalko hole oder Sorbitanester enthalten. Als Überfettungsmittel können Substanzen wie beispielsweise polyethoxylierte Lano linderivate, Lecithinderivate und Fettsäurealkanolamide ver wendet werden, wobei die letzteren gleichzeitig als Schaum stabilisatoren dienen. Geeignete Verdickungsmittel sind bei spielsweise Polysaccharide, insbesondere Xanthan-Gum, Guar- Guar, Agar-Agar, Alginate und Tylosen, Carboxymethylcellulose und Hydroxyethylcellulose, ferner höhermolekulare Polyethy lenglycolmono- und -diester von Fettsäuren, Polyacrylate, Polyvinylalkohol und Polyvinylpyrrolidon sowie Elektrolyte wie Kochsalz und Ammoniumchlorid. Unter biogenen Wirkstoffen sind beispielsweise Pflanzenextrakte, Eiweißhydrolysate und Vitaminkomplexe zu verstehen. Gebräuchliche Filmbildner sind beispielsweise Chitosan, mikrokristallines Chitosan, quater niertes Chitosan, Polyvinylpyrrolidon, Vinylpyrrolidon-Vinyl acetat-Copolymerisate, Polymere der Acrylsäurereihe, quater näre Cellulose-Derivate und ähnliche Verbindungen. Als Kon servierungsmittel eignen sich beispielsweise Phenoxyethanol, Formaldehydlösung, Parabene, Pentadiol oder Sorbinsäure. Als Perlglanzmittel kommen beispielsweise Glycoldistearinsäure ester wie Ethylenglycoldistearat, aber auch Fettsäuremono glycolester in Betracht. Als Farbstoffe können die für kos metische Zwecke geeigneten und zugelassenen Substanzen ver wendet werden, wie sie beispielsweise in der Publikation "Kosmetische Färbemittel" der Farbstoffkommission der Deut schen Forschungsgemeinschaft, veröffentlicht im Verlag Che mie, Weinheim, 1984, S. 81-106 zusammengestellt sind. Diese Farbstoffe werden üblicherweise in Konzentrationen von 0,001 bis 0,1 Gew.-%, bezogen auf die gesamte Mischung, eingesetzt.Hair shampoos, hair lotions or bubble baths can be used as auxiliary and additives emulsifiers such as alkoxylated fatty alcohol hole or sorbitan ester. As superfatting agent can substances such as polyethoxylated Lano linderivatives, lecithin derivatives and fatty acid alkanolamides ver be used, the latter at the same time as foam serve stabilizers. Suitable thickening agents are included For example, polysaccharides, in particular xanthan gum, guar- Guar, agar-agar, alginates and tyloses, carboxymethylcellulose and hydroxyethylcellulose, and higher molecular weight polyethy glycol mono and diesters of fatty acids, polyacrylates, Polyvinyl alcohol and polyvinylpyrrolidone and electrolytes such as table salt and ammonium chloride. Among biogenic agents are, for example, plant extracts, protein hydrolysates and To understand vitamin complexes. Common film makers are for example chitosan, microcrystalline chitosan, quater ned chitosan, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers of the acrylic acid series, quater nary cellulose derivatives and similar compounds. As Kon Serving agents are, for example, phenoxyethanol, Formaldehyde solution, parabens, pentadiol or sorbic acid. When Pearlescing agents are, for example, glycol distearic acid esters such as ethylene glycol distearate, but also fatty acid mono glycol esters into consideration. As dyes, the for kos for metabolic purposes suitable and authorized substances ver be used, for example, in the publication "Cosmetic Dyes" of the Dye Commission of Deut research community published by Che Weinheim, 1984, pp. 81-106. These Dyes are usually used in concentrations of 0.001 to 0.1 wt .-%, based on the total mixture used.
Der Gesamtanteil der Hilfs- und Zusatzstoffe kann 1 bis 50, vorzugsweise 5 bis 40 Gew.-% - bezogen auf die Mittel - be tragen.The total amount of auxiliaries and additives can be 1 to 50, preferably 5 to 40% by weight, based on the mean, of be carry.
Die folgenden Beispiele sollen den Gegenstand der Erfindung näher erläutern, ohne ihn darauf einzuschränken.The following examples are intended to form the subject of the invention explain it in more detail without restricting it to it.
- A) C12/14-Kokosfettsäure-N-methylglucamidA) C 12/14 coconut fatty acid N-methylglucamide
- B) C12/14-Kokosmonoglyceridsulfat-NatriumsalzB) C 12/14 coconut monoglyceride sulfate sodium salt
- C) Dodecylbenzolsulfonat-NatriumsalzC) Dodecylbenzenesulfonate sodium salt
- D) alpha-Talgfettsäuremethylestersulfonat-NatriumsalzD) alpha tallow fatty acid methyl ester sulfonate sodium salt
- E) Ethercarbonsäure-Natriumsalz auf Basis C12/14-Kokosfett alkohol- 7 EO-AdduktE) Ethercarboxylic acid sodium salt based on C 12/14 coconut fat alcohol 7 EO adduct
Die Untersuchung des Schaumvermögens erfolgte gemäß Ross- Miles-Test DIN 53901, Teil 2) in einer 1 Gew.-%igen wäßrigen Lösung (Wasserhärte 16°d, Temperatur 20°C). Die Ergebnisse zu Basisschaum und Schaumzerfall sind in Tabelle 1 zusammenge faßt. Die Prozentangaben verstehen sich als Gew.-%. The foaming capacity was investigated in accordance with Miles test DIN 53901, part 2) in a 1 wt .-% aqueous Solution (water hardness 16 ° d, temperature 20 ° C). The results too Base foam and foam decomposition are summarized in Table 1 summarizes. The percentages are by weight.
Texapon® N70: Kokosfettalkohol-2EO-sulfat-Na-Salz
Texapon® K14S: Kokosfettalkohol-3,6EO-sulfat-Na-Salz
Plantaren® 1200: Kokosalkyloligoglucosid
Dehyton® K: Betain auf Basis Kokosfettsäureamid
Nutrilan: KollagenhydrolysatTexapon® N70: Coconut fatty alcohol 2EO sulfate Na salt
Texapon® K14S: Coconut Fat Alcohol 3,6EO Sulfate Na Salt
Plantaren® 1200: cocoalkyl oligoglucoside
Dehyton® K: Betaine based on coconut fatty acid amide
Nutrilan: collagen hydrolyzate
Alle Produkte stellen Verkaufsprodukte der Henkel KGaA, Düsseldorf/FRG dar.All products are sales products of Henkel KGaA, Dusseldorf / FRG dar.
Claims (7)
- (a) Fettsäure-N-alkylpolyhydroxyalkylamide und
- (b) Fettsäuremonoglycerid(ether)sulfate
- (a) fatty acid N-alkylpolyhydroxyalkylamides and
- (b) fatty acid monoglyceride (ether) sulfate
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19944424823 DE4424823A1 (en) | 1994-07-14 | 1994-07-14 | Strongly foaming detergent mixt. for powder and liq. washing agents |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19944424823 DE4424823A1 (en) | 1994-07-14 | 1994-07-14 | Strongly foaming detergent mixt. for powder and liq. washing agents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4424823A1 true DE4424823A1 (en) | 1996-01-18 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19944424823 Withdrawn DE4424823A1 (en) | 1994-07-14 | 1994-07-14 | Strongly foaming detergent mixt. for powder and liq. washing agents |
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| Country | Link |
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| DE (1) | DE4424823A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996027366A1 (en) * | 1995-03-03 | 1996-09-12 | Henkel Kommanditgesellschaft Auf Aktien | Cosmetic and/or pharmaceutical preparations |
| US6165972A (en) * | 1998-09-04 | 2000-12-26 | Clariant Gmbh | Solid surfactant mixtures comprising fatty acid polyhydroxyamides |
-
1994
- 1994-07-14 DE DE19944424823 patent/DE4424823A1/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996027366A1 (en) * | 1995-03-03 | 1996-09-12 | Henkel Kommanditgesellschaft Auf Aktien | Cosmetic and/or pharmaceutical preparations |
| US6165972A (en) * | 1998-09-04 | 2000-12-26 | Clariant Gmbh | Solid surfactant mixtures comprising fatty acid polyhydroxyamides |
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