DE4406160A1 - Use of gluconic acid amides as surfactants for cleaning and rinsing hard surfaces - Google Patents
Use of gluconic acid amides as surfactants for cleaning and rinsing hard surfacesInfo
- Publication number
- DE4406160A1 DE4406160A1 DE19944406160 DE4406160A DE4406160A1 DE 4406160 A1 DE4406160 A1 DE 4406160A1 DE 19944406160 DE19944406160 DE 19944406160 DE 4406160 A DE4406160 A DE 4406160A DE 4406160 A1 DE4406160 A1 DE 4406160A1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- salt
- acid
- sulfate
- gluconic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 5
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 title abstract description 51
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 title abstract description 27
- 239000000174 gluconic acid Substances 0.000 title description 26
- 235000012208 gluconic acid Nutrition 0.000 title description 26
- 150000001408 amides Chemical class 0.000 claims description 25
- 125000000217 alkyl group Chemical group 0.000 claims description 17
- 239000003599 detergent Substances 0.000 claims description 9
- 239000012459 cleaning agent Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 150000002431 hydrogen Chemical group 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 abstract description 5
- 239000002736 nonionic surfactant Substances 0.000 abstract description 5
- 125000000129 anionic group Chemical group 0.000 abstract description 2
- 229950006191 gluconic acid Drugs 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 48
- 229910052799 carbon Inorganic materials 0.000 description 44
- 150000002191 fatty alcohols Chemical class 0.000 description 41
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 25
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 24
- 235000014113 dietary fatty acids Nutrition 0.000 description 17
- 239000000194 fatty acid Substances 0.000 description 17
- 229930195729 fatty acid Natural products 0.000 description 17
- 150000004665 fatty acids Chemical class 0.000 description 16
- -1 alkyl ether sulfates Chemical class 0.000 description 15
- 235000013162 Cocos nucifera Nutrition 0.000 description 13
- 244000060011 Cocos nucifera Species 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 5
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 229960003237 betaine Drugs 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229940071118 cumenesulfonate Drugs 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000013543 active substance Substances 0.000 description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 3
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 2
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000003605 opacifier Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000001384 succinic acid Substances 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- CFOQKXQWGLAKSK-KTKRTIGZSA-N (13Z)-docosen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCCO CFOQKXQWGLAKSK-KTKRTIGZSA-N 0.000 description 1
- BZANQLIRVMZFOS-ZKZCYXTQSA-N (3r,4s,5s,6r)-2-butoxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound CCCCOC1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O BZANQLIRVMZFOS-ZKZCYXTQSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- IKYKEVDKGZYRMQ-PDBXOOCHSA-N (9Z,12Z,15Z)-octadecatrien-1-ol Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCCO IKYKEVDKGZYRMQ-PDBXOOCHSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- GHPCICSQWQDZLM-UHFFFAOYSA-N 1-(4-chlorophenyl)sulfonyl-1-methyl-3-propylurea Chemical compound CCCNC(=O)N(C)S(=O)(=O)C1=CC=C(Cl)C=C1 GHPCICSQWQDZLM-UHFFFAOYSA-N 0.000 description 1
- CFOQKXQWGLAKSK-UHFFFAOYSA-N 13-docosen-1-ol Natural products CCCCCCCCC=CCCCCCCCCCCCCO CFOQKXQWGLAKSK-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- PHOQVHQSTUBQQK-SQOUGZDYSA-N D-glucono-1,5-lactone Chemical compound OC[C@H]1OC(=O)[C@H](O)[C@@H](O)[C@@H]1O PHOQVHQSTUBQQK-SQOUGZDYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004435 Oxo alcohol Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 1
- TUTWLYPCGCUWQI-UHFFFAOYSA-N decanamide Chemical compound CCCCCCCCCC(N)=O TUTWLYPCGCUWQI-UHFFFAOYSA-N 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- UZZYXUGECOQHPU-UHFFFAOYSA-M n-octyl sulfate Chemical compound CCCCCCCCOS([O-])(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-M 0.000 description 1
- 229940067739 octyl sulfate Drugs 0.000 description 1
- ALSTYHKOOCGGFT-MDZDMXLPSA-N oleyl alcohol Chemical compound CCCCCCCC\C=C\CCCCCCCCO ALSTYHKOOCGGFT-MDZDMXLPSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- LBIYNOAMNIKVKF-FPLPWBNLSA-N palmitoleyl alcohol Chemical compound CCCCCC\C=C/CCCCCCCCO LBIYNOAMNIKVKF-FPLPWBNLSA-N 0.000 description 1
- LBIYNOAMNIKVKF-UHFFFAOYSA-N palmitoleyl alcohol Natural products CCCCCCC=CCCCCCCCCO LBIYNOAMNIKVKF-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000029219 regulation of pH Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- UZZYXUGECOQHPU-UHFFFAOYSA-N sulfuric acid monooctyl ester Natural products CCCCCCCCOS(O)(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 235000019263 trisodium citrate Nutrition 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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Abstract
Description
Gegenstand der Erfindung ist die Verwendung von Gluconsäureamiden als oberflächenaktive Substanzen in Reinigungs- und Spülmitteln zum Reinigen und Spülen harter Oberflächen.The invention relates to the use of gluconic amides as surface-active substances in cleaning agents and detergents for cleaning and rinsing hard surfaces.
Reinigungs- und Spülmittel bestehen meist aus wäßrigen Lösungen von syn thetischen, anionischen und/oder nichtionischen Tensiden und üblichen Zu satzstoffen. Reinigungsmittel werden besonders zum Reinigen harter Ober flächen z. B. von Glas, lackierten und polierten Oberflächen, keramischen Materialien, PVC, Linoleum etc. verwendet. Ein weiteres wichtiges Anwen dungsgebiet für Spülmittel ist das manuelle Spülen von Eß- und Kochge schirr.Detergents and detergents mostly consist of aqueous solutions from syn thetic, anionic and / or nonionic surfactants and customary Zu substitutes. Detergents are especially useful for cleaning hard surfaces areas z. B. of glass, painted and polished surfaces, ceramic Materials, PVC, linoleum etc. are used. Another important application The area of application for detergents is the manual washing of food and cooking utensils dishes.
Als Aniontenside werden dabei üblicherweise Alkylbenzolsulfonate, α-Ole finsulfonate, Fettalkylsulfate und Fettalkylethersulfate, eingesetzt.Anionic surfactants are usually alkylbenzenesulfonates, α-ols finsulfonates, fatty alkyl sulfates and fatty alkyl ether sulfates used.
Die vorliegende Erfindung betrifft die Verwendung einer bestimmten Klasse nichtionischer Tenside, der Gluconsäureamide, als oberflächenaktive Sub stanzen in Reinigungs- und Spülmitteln zum Reinigen und Spülen harter Oberflächen. Gluconsäureamide sind zugänglich durch Umsetzung von Aminen mit Gluconsäurelacton oder anderen reaktiven Gluconsäurederivaten. Die Synthese ist z. B. in US 2,752,334 beschrieben. Diese Substanzen stellen Tenside auf Basis nachwachsender Rohstoffe dar.The present invention relates to the use of a particular class nonionic surfactants, the gluconic acid amide, as a surface-active sub punch hard in cleaning agents and detergents for cleaning and rinsing Surfaces. Gluconic amides can be obtained by reacting amines with gluconic acid lactone or other reactive gluconic acid derivatives. The Synthesis is e.g. B. described in US 2,752,334. Make these substances Are surfactants based on renewable raw materials.
Gegenstand der Erfindung ist die Verwendung von Gluconsäureamiden der For mel I The invention relates to the use of gluconic amides of For mel I
in der R¹ und R² unabhängig voneinander Wasserstoffe oder Methylgruppen bedeuten, n und m unabhängig voneinander Null oder ganze Zahlen von 1 bis 18 darstellen, R³ Wasserstoff, eine Methyl- oder eine Ethylgruppe dar stellt und R⁴ für eine lineare oder verzweigte, gesättigte oder ungesät tigte C₆-C₂₂-Alkylgruppe steht, als oberflächenaktive Substanzen in Spül- und Reinigungsmitteln zum Spülen und Reinigen harter Oberflächen.in which R¹ and R² independently of one another are hydrogen or methyl groups mean, n and m independently of one another zero or integers from 1 to 18 represents, R³ represents hydrogen, a methyl or an ethyl group represents and R⁴ for a linear or branched, saturated or unsaturated C₆-C₂₂-alkyl group stands as surface-active substances in rinsing and cleaning agents for rinsing and cleaning hard surfaces.
Der Rest R⁴ in Formel (I) kann sich von linearen oder verzweigten, gesät tigten oder ungesättigten Alkoholen mit 6 bis 22 Kohlenstoffatomen und 0, 1, 2 oder 3 Doppelbindungen ableiten. Typische Vertreter sind Capronalko hol, Caprylalkohol, Caprinalkohol, Myristylalkohol, Laurylalkohol, Cetyl alkohol, Palmitoleylalkohol, Stearylalkohol, Oleylalkohol, Elaidylalkohol, Petroselylalkohol, Linolylalkohol, Linolenylalkohol, Behenylalkohol oder Erucylalkohol.The rest R⁴ in formula (I) can be sown by linear or branched saturated or unsaturated alcohols with 6 to 22 carbon atoms and 0, Derive 1, 2 or 3 double bonds. Typical representatives are Capronalko hol, caprylic alcohol, capric alcohol, myristyl alcohol, lauryl alcohol, cetyl alcohol, palmitoleyl alcohol, stearyl alcohol, oleyl alcohol, elaidyl alcohol, Petroselyl alcohol, linolyl alcohol, linolenyl alcohol, behenyl alcohol or Erucyl alcohol.
Vorzugsweise besteht der Rest R⁴ aus 12 bis 18 C-Atomen. R³ steht vorzugs weise für Wasserstoff und n und m sind vorzugsweise Null. Soll jedoch eine bessere Wasserlöslichkeit der Gluconsäureamide erzielt werden, dann sind n und/oder m ungleich Null, vorzugsweise liegen dann ethoxylierte Produkte vor, d. h. R¹ und R² sind jeweils Wasserstoffe. The radical R⁴ preferably consists of 12 to 18 carbon atoms. R³ is preferred for hydrogen and n and m are preferably zero. But should one better water solubility of the gluconic amides can be achieved, then n and / or m not equal to zero, then preferably ethoxylated products before, d. H. R1 and R2 are each hydrogen.
Die Gluconsäureamide der Formel I sind in den Reinigungs- und Spülmitteln in einer Menge von 0,1 bis 50 Gew.-%, bezogen auf das gesamte Mittel, ent halten. Vorzugsweise sind zusätzlich Aniontenside enthalten, z. B. C₈- C₁₈-Alkylsulfate, C₈-C₁₈-Alkylethersulfate, C₈-C₁₈-Alkansulfonate, C₈- C₁₈-α-Olefinsulfonate, sulfonierte C₈-C₁₈-Fettsäuren, C₁-C₄-Alkylester, C₆-C₁₈-Alkylbenzolsulfonate, Sulfonbernsteinsäuremono- und -di-C₁-C₁₂- Alkylester, C₈-C₁₈-Alkylpolyglykolethercarboxylate, C₈-C₁₈-N-Acyltauride, C₈-C₁₈-N-Sarkosinate oder C₈-C₁₈-Alkylisethionate, die ebenfalls in einer Menge von 0,1 bis 50 Gew.-%, bezogen auf das gesamte Mittel, enthalten sein können. Für alle Aniontenside gilt, daß sie im allgemeinen in Form ihrer Ammonium-, Alkanolammonium-, Alkali- oder Magnesiumsalze vorliegen.The gluconic amides of the formula I are in the cleaning and rinsing agents in an amount of 0.1 to 50% by weight, based on the total agent hold. Anionic surfactants are preferably additionally contained, e.g. B. C₈- C₁₈-alkyl sulfates, C₈-C₁₈-alkyl ether sulfates, C₈-C₁ans-alkanesulfonates, C₈- C₁₈-α-olefin sulfonates, sulfonated C₈-C₁₈ fatty acids, C₁-C₄ alkyl esters, C₆-C₁₈-alkylbenzenesulfonates, sulfonic succinic acid mono- and -di-C₁-C₁₂- Alkyl esters, C₈-C₁₈-alkyl polyglycol ether carboxylates, C₈-C₁₈-N-acyl taurides, C₈-C₁₈-N-sarcosinates or C₈-C₁₈ alkyl isethionates, which are also in one Amount of 0.1 to 50 wt .-%, based on the total agent included could be. It applies to all anionic surfactants that they are generally in the form their ammonium, alkanolammonium, alkali or magnesium salts are present.
Auch weitere nichtionische Tenside können in einer Menge von 0,1 bis 40 Gew.-%, bezogen auf das gesamte Mittel, enthalten sein. Als nichtionische Tenside eignen sich z. B. Alkyl- oder Alkenyloligoglycoside der Formel R⁵O-[Z]x, in der R⁵ für einen Alkyl- oder Alkenylrest mit 8-22 C-Atomen, Z für einen Zuckerrest mit 5 oder 6 C-Atomen, insbesondere einen Glucose rest, und x für Zahlen von 1-10 steht, C₈-C₁₈-Fettsäuremono- und -di- C₁-C₄-Alkanolamide, C₈-C₁₈-Fettsäureglucamide, Anlagerungsprodukte von Ethylenoxid und/oder Propylenoxid an C₈-C₁₈-Fettalkohole und an Mono- und Di-C₈-C₁₈-Fettsäureglyceride.Other nonionic surfactants can also be used in an amount of 0.1 to 40 % By weight, based on the total agent, may be present. As a non-ionic Surfactants are suitable for. B. alkyl or alkenyl oligoglycosides of the formula R⁵O- [Z] x, in which R⁵ represents an alkyl or alkenyl radical with 8-22 C atoms, Z for a sugar residue with 5 or 6 carbon atoms, especially a glucose rest, and x represents numbers from 1-10, C₈-C₁₈ fatty acid mono- and di C₁-C₄ alkanolamides, C₈-C₁₈ fatty acid glucamides, addition products of Ethylene oxide and / or propylene oxide on C₈-C₁₈ fatty alcohols and on mono- and Di-C₈-C₁₈ fatty acid glycerides.
In weiteren Ausführungsformen können die erfindungsgemäßen Reinigungsmit tel zusätzliche oberflächenaktive Substanzen, z. B. Betaintenside oder Fettaminoxide enthalten. Fakultativ können weiterhin die in flüssigen Rei nigungsmitteln für harte Oberflächen, z. B. Allzweckreinigern und manuellen Geschirrspülmitteln, enthaltenen üblichen Hilfsstoffe enthalten sein; bei diesen Stoffen handelt es sich um Builder, z. B. Glutarsäure, Bernstein säure, Adipinsäure, Weinsäure, Benzolhexacarbonsäure, Gluconsäure, Tri natriumcitrat; Lösungsmittel, wie z. B. Ethanol; Hydrotrope, z. B. Cumol sulfonat, Octylsulfat, Butylglucosid, Butylenglykol; Reinigungsverstärker; Viskositätsregler, z. B. synthetische Polymere wie Polyacrylate; pH-Regula toren, z. B. Citronensäure, Triethanolamin oder NaOH; Konservierungsmittel, z. B. Glutaraldehyd; Farb- und Duftstoffe sowie Trübungsmittel oder auch Hautschutzmittel wie sie in EP-A-522 756 beschrieben sind. In further embodiments, the cleaning agents according to the invention tel additional surface-active substances, e.g. B. betaine surfactants or Contain fatty amine oxides. Optionally, those in liquid Rei cleaning agents for hard surfaces, e.g. B. All-purpose cleaners and manual Dishwashing detergents, conventional auxiliaries contained; at these substances are builders, e.g. B. glutaric acid, amber acid, adipic acid, tartaric acid, benzene hexacarboxylic acid, gluconic acid, tri sodium citrate; Solvents such as B. ethanol; Hydrotropes, e.g. B. Cumene sulfonate, octyl sulfate, butyl glucoside, butylene glycol; Cleaning booster; Viscosity regulator, e.g. B. synthetic polymers such as polyacrylates; pH regulation goals, e.g. B. citric acid, triethanolamine or NaOH; Preservatives, e.g. B. glutaraldehyde; Dyes and fragrances as well as opacifiers or Skin protection agents as described in EP-A-522 756.
Die folgenden Beispiele sollen den Gegenstand näher erläutern, ohne ihn jedoch hierauf zu beschränken.The following examples are intended to illustrate the subject without it however, to be limited to this.
Der pH-Wert der Reinigungsmittelformulierungen kann über einen weiteren Bereich variiert werden, da die Gluconsäureamide über einen weiteren Be reich hydrolysestabil sind, bevorzugt ist jedoch ein pH-Bereich von 5,5 bis 9,5.The pH value of the detergent formulations can be adjusted further Range can be varied because the gluconic amides have a further Be are stable to hydrolysis, but a pH range of 5.5 is preferred to 9.5.
Alle Formulierungen können neben den aufgeführten Bestandteilen die in Allzweckreinigern üblicherweise eingesetzten Komponenten wie Builder, Par füm, Farbstoffe oder Verdickungsmittel bzw. die in manuellen Geschirrspül mitteln üblicherweise eingesetzten Komponenten wie Parfümstoffe, Farbstof fe, Trübungsmittel, Verdickungsmittel oder Hautschutzkomponenten enthal ten. Der pH-Wert der Formulierungen liegt im allgemeinen zwischen 5,5 und 9,5, pH-Werte außerhalb dieses Bereiches sind jedoch ebenfalls möglich.In addition to the ingredients listed, all formulations can be found in All-purpose cleaners commonly used components such as Builder, Par fo, dyes or thickeners or those in manual dishwashing means usually used components such as perfume, dye contain opacifiers, thickeners or skin protection components The pH of the formulations is generally between 5.5 and 9.5, however, pH values outside this range are also possible.
In den Beispielen bedeuten:
NRE: Narrow range ethoxylate (Ethoxylat mit eingeengter
Homologenverteilung)
Hostapur SAS 60: C₁₃-C₁₈-sec-Alkansulfonsäure, Na-Salz der Fa. Hoechst
PEG 400: Polyethylenglykol, MG = 400.000
PEG 200: Polyethylenglykol, MG = 200.000
EO: Ethylenoxid
PO: Propylenoxid
APG 225: C8/10-Alkylpolyglucosid mit einem DP von 1,6
DP: mittlerer Oligomerisierungsgrad bei Alkylpoly- bzw.
oligoglycosiden
In the examples:
NRE: Narrow range ethoxylate (ethoxylate with narrow homolog distribution)
Hostapur SAS 60: C₁₃-C₁₈-sec-alkanesulfonic acid, Na salt from Hoechst
PEG 400: polyethylene glycol, MW = 400,000
PEG 200: polyethylene glycol, MW = 200,000
EO: ethylene oxide
PO: propylene oxide
APG 225: C 8/10 alkyl polyglucoside with a DP of 1.6
DP: average degree of oligomerization in the case of alkyl poly- or oligoglycosides
20% C12/14-Fettalkoholether(3EO)sulfat-Na-Salz
10% C12/14-Fettalkoholsulfat-Na-Salz
4% Gluconsäure-C12/14-amid
2% Kokosfettsäureamidopropylbetain
9% Ethanol
Rest auf 100% Wasser20% C 12/14 fatty alcohol ether (3EO) sulfate Na salt
10% C 12/14 fatty alcohol sulfate Na salt
4% gluconic acid C 12/14 amide
2% coconut fatty acid amidopropyl betaine
9% ethanol
Rest on 100% water
20% C12/14-Fettalkoholether(3EO)sulfat-Na-Salz
10% C12/14-Fettalkoholsulfat-Na-Salz
5% Gluconsäure-C12/14-amid
2% Lauryldimethylaminoxid
7% Ethanol
Rest auf 100% Wasser20% C 12/14 fatty alcohol ether (3EO) sulfate Na salt
10% C 12/14 fatty alcohol sulfate Na salt
5% gluconic acid C 12/14 amide
2% lauryldimethylamine oxide
7% ethanol
Rest on 100% water
18% C12/14-Fettalkoholether(3EO)sulfat-Na-Salz
8% C12/14-Fettsäuremethylestersulfonat-Na-Salz
8% Gluconsäurekokosamid
2% Lauryldimethylaminoxid
7% Ethanol
Rest auf 100% Wasser18% C 12/14 fatty alcohol ether (3EO) sulfate Na salt
8% C 12/14 fatty acid methyl ester sulfonate Na salt
8% gluconic coconut amide
2% lauryldimethylamine oxide
7% ethanol
Rest on 100% water
20% C₁₂-Alkylbenzolsulfonat-Mg-Salz
8% C12/14-Fettalkoholsulfat-Mg-Salz
6% Gluconsäure-C12/16-2EO-amid
2% Lauryldimethylaminoxid
5% Ethanol
3% Cumolsulfonat
Rest auf 100% Wasser20% C₁₂ alkyl benzene sulfonate Mg salt
8% C 12/14 fatty alcohol sulfate Mg salt
6% gluconic acid C 12/16 -2EO amide
2% lauryldimethylamine oxide
5% ethanol
3% cumene sulfonate
Rest on 100% water
12% C12/14-Fettalkoholether(3EO)sulfat-Na-Salz
4% C12/14-Fettalkoholsulfat-Na-Salz
2% Gluconsäure-C₁₂-amid
2% C12/14-Alkylpolyglucosid mit einem DP von 1.4
3% Ethanol
Rest auf 100% Wasser12% C 12/14 fatty alcohol ether (3EO) sulfate Na salt
4% C 12/14 fatty alcohol sulfate Na salt
2% gluconic acid C₁₂ amide
2% C 12/14 alkyl polyglucoside with a DP of 1.4
3% ethanol
Rest on 100% water
12% C12/14-Fettalkoholether(3EO)sulfat-Na-Salz
3% Gluconsäure-C8/10-amid
2% C12/14-Alkylpolyglucosid mit einem DP von 1.4
4% Ethanol
Rest auf 100% Wasser12% C 12/14 fatty alcohol ether (3EO) sulfate Na salt
3% gluconic acid C 8/10 amide
2% C 12/14 alkyl polyglucoside with a DP of 1.4
4% ethanol
Rest on 100% water
13% C12/14-Fettalkoholsulfat-Na-Salz
3% Gluconsäurekokos-3EO-amid
3% C12/14-Alkylpolyglucosid mit einem DP von 1.4
3% Ethanol
3% PEG 400
Rest auf 100% Wasser13% C 12/14 fatty alcohol sulfate Na salt
3% gluconic acid coconut 3EO amide
3% C 12/14 alkyl polyglucoside with a DP of 1.4
3% ethanol
3% PEG 400
Rest on 100% water
12% C12/18-Fettalkohol-(3EO)-ether-sulfat-Na-Salz
4% C12/18-Fettalkoholsulfat
2% Gluconsäure-C12/14-amid
2% Kokosfettsäuremonoalkanolamid
2% 1,2-Propylenglykol
Rest auf 100% Wasser12% C 12/18 fatty alcohol (3EO) ether sulfate Na salt
4% C 12/18 fatty alcohol sulfate
2% gluconic acid C 12/14 amide
2% coconut fatty acid monoalkanolamide
2% 1,2-propylene glycol
Rest on 100% water
15% C₁₂-Alkylbenzolsulfonat-Mg-Salz
5% C12/14-Fettalkoholsulfat
3% Gluconsäure-C12/14-fettsäureamid
5% Na-Sulfobernsteinsäurediisooctylester
3% Ethanol
2% PEG 600
Rest auf 100% Wasser15% C₁₂ alkyl benzene sulfonate Mg salt
5% C 12/14 fatty alcohol sulfate
3% gluconic acid C 12/14 fatty acid amide
5% diisooctyl Na sulfosuccinate
3% ethanol
2% PEG 600
Rest on 100% water
15% C12/14-Fettalkoholether(3EO)sulfat-Mg-Salz
1,5% Gluconsäure-C12/14-amid
2% Kokosfettsäureamidopropylbetain
Rest auf 100% Wasser15% C 12/14 fatty alcohol ether (3EO) sulfate Mg salt
1.5% gluconic acid C 12/14 amide
2% coconut fatty acid amidopropyl betaine
Rest on 100% water
15% C12/14-Fettalkoholether(3EO)sulfat-Mg-Salz
1,5% Gluconsäure-N-C12/14-N-methylamid
1,5% Laurylfettsäure-N-methylglucamid
2% Ethanol
Rest auf 100% Wasser15% C 12/14 fatty alcohol ether (3EO) sulfate Mg salt
1.5% gluconic acid-NC 12/14 -N-methylamide
1.5% lauryl fatty acid N-methylglucamide
2% ethanol
Rest on 100% water
15% C12/14-Fettalkoholether-(3EO)-sulfat-Na-Salz (NRE-Ethoxylat)
4% C12/14-Fettalkoholsulfat-Na-Salz
3% Gluconsäuredecylamid
4% Ethanol
Rest auf 100% Wasser
15% C 12/14 fatty alcohol ether (3EO) sulfate Na salt (NRE ethoxylate)
4% C 12/14 fatty alcohol sulfate Na salt
3% gluconic acid decylamide
4% ethanol
Rest on 100% water
12% C12/14-Fettalkoholether-(2-5EO)-sulfat-Na-Salz (NRE-Ethoxylat)
4% C12/14-Fettalkoholsulfat-Na-Salz
3% Gluconsäurelaurylamid
3% C12/14-Alkylpolyxylosid mit einem DP von 1.4
4% Ethanol
Rest auf 100% Wasser12% C 12/14 fatty alcohol ether (2-5EO) sulfate Na salt (NRE ethoxylate)
4% C 12/14 fatty alcohol sulfate Na salt
3% gluconic acid laurylamide
3% C 12/14 alkyl polyxyloside with a DP of 1.4
4% ethanol
Rest on 100% water
10% C12/14-Fettalkoholether-(3EO)-sulfat-Na-Salz
4% C12/14-Fettalkoholsulfat-Na-Salz
2% Gluconsäurekokosamid
2% C12/14-Alkylpolyglucosid mit einem DP von 1.5
2% Kokosfettsäuretaurid-Na-Salz
4% Ethanol
Rest auf 100% Wasser10% C 12/14 fatty alcohol ether (3EO) sulfate Na salt
4% C 12/14 fatty alcohol sulfate Na salt
2% gluconic coconut amide
2% C 12/14 alkyl polyglucoside with a DP of 1.5
2% coconut fatty acid, sodium salt
4% ethanol
Rest on 100% water
12% C12/14-Fettalkoholether(3EO)sulfat-Na-Salz
4% C12/14-Fettalkoholsulfat-Na-Salz
2% Gluconsäure-C8/18-3EO-amid
2% C12/14-Alkylpolyglucosid mit einem DP von 1.5
2% Kokosfettsäureamidopropylbetain
4% Ethanol
Rest auf 100% Wasser12% C 12/14 fatty alcohol ether (3EO) sulfate Na salt
4% C 12/14 fatty alcohol sulfate Na salt
2% gluconic acid C 8/18 -3EO amide
2% C 12/14 alkyl polyglucoside with a DP of 1.5
2% coconut fatty acid amidopropyl betaine
4% ethanol
Rest on 100% water
12% C12/14-Fettalkoholether(3EO)sulfat-Na-Salz
6% Kokosfettsäuremonoglycerid + 10 EO
2% Gluconsäure-C₁₂-amid
2% C12/14-Alkylpolyglucosid mit einem DP von 1.5
4% Ethanol
Rest auf 100% Wasser12% C 12/14 fatty alcohol ether (3EO) sulfate Na salt
6% coconut fatty acid monoglyceride + 10 EO
2% gluconic acid C₁₂ amide
2% C 12/14 alkyl polyglucoside with a DP of 1.5
4% ethanol
Rest on 100% water
12% C12/14-Oxoalkoholether-(2EO)-sulfat-Na-Salz
6% Kokosfettsäuremonoglycerid + 10 EO
2% Gluconsäurekokosamid
2% C12/14-Alkylpolyglucosid mit einem DP von 1.5
4% Ethanol
Rest auf 100% Wasser12% C 12/14 oxo alcohol ether (2EO) sulfate Na salt
6% coconut fatty acid monoglyceride + 10 EO
2% gluconic coconut amide
2% C 12/14 alkyl polyglucoside with a DP of 1.5
4% ethanol
Rest on 100% water
14% C12/14-Fettalkoholether(2,5EO)sulfat-Na-Salz (NRE)
6% C10/14-Fettalkohol + 8 EO
2% Gluconsäure-C12/14-amid
3% C12/14-Alkylpolyglucosid mit einem DP von 1.5
1,5% Amidoethyl-N-2-hydroxyethylglycinat
6% Ethanol
Rest auf 100% Wasser14% C 12/14 fatty alcohol ether (2.5EO) sulfate Na salt (NRE)
6% C 10/14 fatty alcohol + 8 EO
2% gluconic acid C 12/14 amide
3% C 12/14 alkyl polyglucoside with a DP of 1.5
1.5% amidoethyl-N-2-hydroxyethylglycinate
6% ethanol
Rest on 100% water
14% C12/14-Fettalkoholether-(1,2EO)-sulfat-Na-Salz (NRE)
6% C10/14-Fettalkohol + 1,2 PO + 8 EO
2% Gluconsäure-C10-12-amid
3% C12/14-Alkylpolyglucosid mit einem DP von 1.5
1,5% Amidoethyl-N-2-hydroxyethylglycinat
6% Ethanol
Rest auf 100% Wasser14% C 12/14 fatty alcohol ether (1,2EO) sulfate Na salt (NRE)
6% C 10/14 fatty alcohol + 1.2 PO + 8 EO
2% gluconic acid C 10-12 amide
3% C 12/14 alkyl polyglucoside with a DP of 1.5
1.5% amidoethyl-N-2-hydroxyethylglycinate
6% ethanol
Rest on 100% water
29% C12/14-Fettalkoholether-(1,2EO)-sulfat-Mg-Salz (NRE)
10% C12/14-Fettalkoholsulfat-Mg-Salz
10% C10/14-Fettalkohol + 1,2 PO + 8 EO
8% Gluconsäure-C16/18-3EO-amid
3% C12/14-Alkylpolyglucosid mit einem DP von 1.5
12% C₄-Alkylpolyglucosid mit einem DP von 1.5
8% PEG 200
10% Ethanol
Rest auf 100% Wasser
29% C 12/14 fatty alcohol ether (1,2EO) sulfate Mg salt (NRE)
10% C 12/14 fatty alcohol sulfate Mg salt
10% C 10/14 fatty alcohol + 1.2 PO + 8 EO
8% gluconic acid C 16/18 -3EO amide
3% C 12/14 alkyl polyglucoside with a DP of 1.5
12% C₄-alkyl polyglucoside with a DP of 1.5
8% PEG 200
10% ethanol
Rest on 100% water
45,0 Gew.-% APG 225
13,0 Gew.-% C₁₂-Fettsäuremethylester + 13 EO
3,0 Gew.-% Gluconsäure-C6/10-amid
5,0 Gew.-% Palmkernfettsäure
1,0 Gew.-% Zitronensäure
10,0 Gew.-% Cumolsulfonat
X Gew.-% Kalilauge zur Einstellung des pH-Wertes des Fertig
produktes auf pH 8
ad 100,0 Gew.-% Wasser, Farb- und Duftstoffe45.0 wt% APG 225
13.0% by weight of C₁₂ fatty acid methyl ester + 13 EO
3.0% by weight of gluconic acid C 6/10 amide
5.0% by weight of palm kernel fatty acid
1.0% by weight of citric acid
10.0% by weight cumene sulfonate
X% by weight of potassium hydroxide solution to adjust the pH of the finished product to pH 8
ad 100.0% by weight of water, colors and fragrances
2,0 Gew.-% APG 225
0,5 Gew.-% Butylpolyglucosid
0,5 Gew.-% Gluconsäure-C8/10-amid + 1,7 EO
1,0 Gew.-% Palmkernfettsäure
2,0 Gew.-% Dicarbonsäuregemisch (Glutar-, Adipin- und Bernstein
säure)
0,05 Gew.-% Polyethylenoxid, MG 600 000
2,0 Gew.-% Butylglykol
X Gew.-% Natronlauge zur Einstellung auf pH 8
ad 100,0 Gew.-% Wasser, Farb- und Duftstoffe, Konservierungsmittel2.0% by weight APG 225
0.5% by weight of butyl polyglucoside
0.5% by weight gluconic acid C 8/10 amide + 1.7 EO
1.0% by weight of palm kernel fatty acid
2.0% by weight dicarboxylic acid mixture (glutaric, adipic and succinic acid)
0.05% by weight polyethylene oxide, MW 600,000
2.0% by weight of butyl glycol
X% by weight sodium hydroxide solution to adjust to pH 8
ad 100.0 wt .-% water, colors and fragrances, preservatives
0,6 Gew.-% C₁₀-Alkylpolyglucosid
0,05 Gew.-% Gluconsäure-C8/10-1,7EO-amid
0,001 Gew.-% Kokosfettsäure
9,0 Gew.-% Ethanol
X Gew.-% Ammoniak zur Einstellung auf pH 8,5
ad 100,0 Gew.-% Wasser0.6% by weight of C₁₀ alkyl polyglucoside
0.05 wt% gluconic acid C 8/10 -1.7EO amide
0.001% by weight coconut fatty acid
9.0% by weight of ethanol
X% by weight ammonia to adjust to pH 8.5
ad 100.0 wt .-% water
12 Gew.-% C₁₀-Alkylpolyglucosid
6 Gew.-% C8/10-Fettalkohol + 4 EO
1 Gew.-% Gluconsäure-C12/14+6EO-amid
2 Gew.-% C12/14-Fettalkoholsulfat
5 Gew.-% Ethanol
X Gew.-% Natronlauge zur Einstellung auf pH 7-7,5
ad 100,0 Gew.-% Wasser12 wt .-% C₁₀ alkyl polyglucoside
6% by weight of C 8/10 fatty alcohol + 4 EO
1% by weight gluconic acid C 12/14 + 6EO amide
2% by weight of C 12/14 fatty alcohol sulfate
5% by weight ethanol
X% by weight sodium hydroxide solution to adjust to pH 7-7.5
ad 100.0 wt .-% water
12 Gew.-% C₁₀-Alkylpolyxylosid
8 Gew.-% C₁₂-Fettalkohol + 6 EO
1 Gew.-% Gluconsäure-C12/14+6EO-amid
5 Gew.-% Ethanol
X Gew.-% Kalilauge zur Einstellung auf pH 7-7,5
ad 100,0 Gew.-% Wasser12 wt .-% C₁₀ alkyl polyxyloside
8 wt .-% C₁₂ fatty alcohol + 6 EO
1% by weight gluconic acid C 12/14 + 6EO amide
5% by weight ethanol
X% by weight potassium hydroxide solution to adjust to pH 7-7.5
ad 100.0 wt .-% water
10 Gew.-% C8/10-Alkylpolyglucosid
6 Gew.-% C₁₂-Fettsäuremethylester + 15 EO
2 Gew.-% Gluconsäure-C8/10+2EO-amid
2 Gew.-% Hostapur SAS 60
3 Gew.-% Cumolsulfonat
1,5 Gew.-% Kokosfettsäure
5 Gew.-% Ethanol
X Gew.-% NaOH zur Einstellung auf pH 7-7,5
ad 100,0 Gew.-% Wasser10% by weight of C 8/10 alkyl polyglucoside
6 wt .-% C₁₂ fatty acid methyl ester + 15 EO
2% by weight of gluconic acid C 8/10 + 2EO amide
2% by weight of Hostapur SAS 60
3% by weight cumene sulfonate
1.5% by weight coconut fatty acid
5% by weight ethanol
X% by weight NaOH to adjust to pH 7-7.5
ad 100.0 wt .-% water
Claims (2)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19944406160 DE4406160A1 (en) | 1994-02-25 | 1994-02-25 | Use of gluconic acid amides as surfactants for cleaning and rinsing hard surfaces |
| PCT/EP1995/000568 WO1995023203A1 (en) | 1994-02-25 | 1995-02-16 | Use of glyconic-acid amides as surfactants for cleaning and rinsing hard surfaces |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19944406160 DE4406160A1 (en) | 1994-02-25 | 1994-02-25 | Use of gluconic acid amides as surfactants for cleaning and rinsing hard surfaces |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4406160A1 true DE4406160A1 (en) | 1995-08-31 |
Family
ID=6511210
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19944406160 Withdrawn DE4406160A1 (en) | 1994-02-25 | 1994-02-25 | Use of gluconic acid amides as surfactants for cleaning and rinsing hard surfaces |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE4406160A1 (en) |
| WO (1) | WO1995023203A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007008868A1 (en) | 2007-02-21 | 2008-08-28 | Henkel Ag & Co. Kgaa | Automatic dishwasher detergent containing a sugar acid amide, e.g. N-octyl-D-gluconamide, useful especially for removing tenacious and-or burnt-on dirt from hard surfaces or textiles |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19918185A1 (en) * | 1999-04-22 | 2000-10-26 | Cognis Deutschland Gmbh | Hard surface detergent, typically in form of high foaming viscous gel, includes oligoglycoside derivative, glycerin fatty acid ester and sulfate or betaine component |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2523962B1 (en) * | 1982-03-24 | 1987-09-04 | Centre Nat Rech Scient | NOVEL ALDONIC ACID AMIDES, THEIR PREPARATION AND COMPOSITIONS CONTAINING THEM |
| US5389279A (en) * | 1991-12-31 | 1995-02-14 | Lever Brothers Company, Division Of Conopco, Inc. | Compositions comprising nonionic glycolipid surfactants |
| JPH05221946A (en) * | 1992-02-13 | 1993-08-31 | Toho Chem Ind Co Ltd | New nonionic surfactant |
-
1994
- 1994-02-25 DE DE19944406160 patent/DE4406160A1/en not_active Withdrawn
-
1995
- 1995-02-16 WO PCT/EP1995/000568 patent/WO1995023203A1/en active Application Filing
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007008868A1 (en) | 2007-02-21 | 2008-08-28 | Henkel Ag & Co. Kgaa | Automatic dishwasher detergent containing a sugar acid amide, e.g. N-octyl-D-gluconamide, useful especially for removing tenacious and-or burnt-on dirt from hard surfaces or textiles |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1995023203A1 (en) | 1995-08-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |