DE434979C - Process for the protection of animal fibers when treated with alkaline liquids - Google Patents
Process for the protection of animal fibers when treated with alkaline liquidsInfo
- Publication number
- DE434979C DE434979C DEF55156D DEF0055156D DE434979C DE 434979 C DE434979 C DE 434979C DE F55156 D DEF55156 D DE F55156D DE F0055156 D DEF0055156 D DE F0055156D DE 434979 C DE434979 C DE 434979C
- Authority
- DE
- Germany
- Prior art keywords
- treated
- alkaline liquids
- animal fibers
- protection
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007788 liquid Substances 0.000 title claims description 6
- 239000000835 fiber Substances 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- NGDNCZPCIZNCQS-UHFFFAOYSA-N ctk3j8699 Chemical compound Cl=S NGDNCZPCIZNCQS-UHFFFAOYSA-N 0.000 claims description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 150000008282 halocarbons Chemical class 0.000 claims 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 210000002268 wool Anatomy 0.000 description 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- CBCZQJLYYRPMRI-UHFFFAOYSA-N 2-benzylnaphthalene-1-sulfonic acid Chemical compound C1=CC2=CC=CC=C2C(S(=O)(=O)O)=C1CC1=CC=CC=C1 CBCZQJLYYRPMRI-UHFFFAOYSA-N 0.000 description 2
- JCUKCAHTOJDIDR-UHFFFAOYSA-N 4,4-dichloro-2,3-dihydro-1H-naphthalene Chemical compound ClC1(CCCC2=CC=CC=C12)Cl JCUKCAHTOJDIDR-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- PGYZAKRTYUHXRA-UHFFFAOYSA-N 2,10-dinitro-12h-[1,4]benzothiazino[3,2-b]phenothiazin-3-one Chemical compound S1C2=CC(=O)C([N+]([O-])=O)=CC2=NC2=C1C=C1SC3=CC=C([N+](=O)[O-])C=C3NC1=C2 PGYZAKRTYUHXRA-UHFFFAOYSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical compound OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 125000004151 quinonyl group Chemical group 0.000 description 1
- 239000012261 resinous substance Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
- D06P3/141—Wool using vat or sulfur dyes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
Verfahren zum Schutze tierischer Fasern bei der Behandlung mit alkalischen Flüssigkeiten. Da.B Zuckerarten oder Zuckerarten enthaltende Produkte, wie Sulfitpech, eine Schutzwirkung auf Wolle und ähnliche tierische Fasern ausüben in dem Sinne, daß die Wolle der Einwirkung alkalischer Flüssigkeiten besser widersteht, ist bekannt. Weiterhin sollen nach Patent 359228 auch aromatische Diamine, Chinone und Oxyverbindungen sowie deren Kernsubstitutionsprodukte, worunter auch deren Carbon- und Sulfosäuren sowie Tannin fallen, den gleichen Zweck erfüllen. Auch Aldehyde -und Ketone und deren Bisulfite sind vorgeschlagen worden. Zusammengefaßt ergibt sich, daß offenbar reaktionsfähige Gruppen, nämlich Aldehyd-, Keton-und Chinongruppen, Amino-, Diamino-, alkoholische und phenolische Oxygruppen als Träger der Schutzwirkung erforderlich sind.Process for the protection of animal fibers when treated with alkaline Liquids. Da.B types of sugar or products containing types of sugar, such as sulphite pitch, have a protective effect on wool and similar animal fibers in the sense that It is known that wool is more resistant to the action of alkaline liquids. Furthermore, according to patent 359228, aromatic diamines, quinones and oxy compounds should also be used as well as their core substitution products, including their carboxylic and sulfonic acids as well as falling tannins serve the same purpose. Also aldehydes and ketones and their bisulfites have been proposed. In summary, it appears that reactive groups, namely aldehyde, ketone and quinone groups, amino, diamino, alcoholic and phenolic oxy groups are required as carriers of the protective effect are.
Überraschend und nicht zu erwarten war daher die Beobachtung, daß auch gewisse aromatische und hydroaromatische Substanzen, insbesondere harzartige Körper, die der obenerwähnten, anscheinend wesentlichen Gruppen ganz entbehren eine hohe Schutzwirkung auszuüben vermögen. Wie gefunden wurde, vermögen sulfonierte oder carboxylierte, insbesondere harzartige Kohlenwasserstoffe, vor allem die Benzylnaphthalinliarzsulfosäure, bzw. deren Salze in hohem :Maße Wolle und ähnliche Faserstoffe gegen" die schädigende Einwirkung von Alkalien zu schützen. Ähnlich wirkt z. B. das bei der Natronzellstoffabrikation abfallende flüssige Carboxylgruppen enthaltende Harz bzw. dessen wasserlösliche Salze. Diesen und anderen ähnlich wirkenden Carboxyl- oder Sulfogrupp,en enthaltenden harzartigen Substanzen gemeinsam ist aber das Fehlen reaktionsfähiger Gruppen im Sinne der bisherigen Patentliteratur.So surprising and not to be expected was the observation that also certain aromatic and hydroaromatic substances, especially resinous Bodies that do not belong to any of the apparently essential groups mentioned above able to exert a high protective effect. As has been found, are capable of sulfonated or carboxylated, especially resinous hydrocarbons, especially benzylnaphthalene resin sulfonic acid, or their salts to a large extent: wool and similar fibers against "the damaging Protect from exposure to alkalis. Similarly acts z. B. in the soda pulp production falling liquid resin containing carboxyl groups or its water-soluble resin Salts. These and other similarly acting carboxyl or sulfo groups containing What is common, however, is the lack of reactive groups in the resinous substances Meaning of the previous patent literature.
Beispiele. i. Benzylnaphthalinharzsulfosäure:als Schutzmittel bei der Wollwäscherei: ioo kg fettreiches Wollgarn werden in einem 35° C warmen Bade mit io Prozent Soda und 2 Prozent benzylnaphthalinharzsulfosaurem Natron 14 Stunde gewaschen, hierauf in lauwarmem Wasser nachgespült; getrocknet hat diese so behandelte Wolle eine wesentlich höhere Reißfestigkeit als nur mit Soda unter glichen Verhältnissen gewaschenes Wollgarn.Examples. i. Benzylnaphthalene resin sulfonic acid: as a protective agent The wool laundry: 100 kg of high-fat wool yarn are bathed in a 35 ° C warm bath with 10 percent soda and 2 percent benzylnaphthalene resin sulfonic acid soda for 14 hours washed, then rinsed in lukewarm water; has dried this so treated Wool has a much higher tear resistance than just soda under the same conditions washed wool yarn.
2. i o kg Halbwollzanella werden auf einer Unterflottenrollenkufe mit i o Prozent hochkonzentriertem Schwefelschwarz, welches vorher mit der doppelten Menge Soda und der gleichen Menge Hydrosulfit konz. verküpt wurde, bei einer Temperatur von 20" C unter Zusatz- von 2 Prozent benzylnaphthalinliarzsulfosaurem Natron 1;'4 Stunde ausgefärbt, abgequetscht, gespült und dann auf frischem Bad mit 5 Prozent eines gewöhnlichen sauren Schwarz unter Zusatz von i o Prozent Glaubersalz, 5 Prozent Essigsäure, r Prozent benzylnaphthaaharzsulfosaurem Natron ausgefärbt. Der Stoff hat im Vergleich zur selben Färbeoperation ohne benzyln.aphthalinharzsulfosaures Natron eine wesentlich höhere Reißfestigkeit in Kette und Schuß.2. 10 kg of semi-wool zanella are placed on a sub-fleet roller runner with i o percent highly concentrated sulfur black, which previously with twice the amount Amount of soda and the same amount of hydrosulphite conc. was kept at one temperature of 20 "C with the addition of 2 percent benzylnaphthalenesulfonic acid soda 1; '4 Hour colored, squeezed off, rinsed and then on a fresh bath with 5 percent an ordinary acidic black with the addition of 10 percent Glauber's salt, 5 Percent acetic acid, r percent benzylnaphtha resin sulfonic acid soda colored. Of the Compared to the same dyeing operation, the fabric has no benzyln.aphthalene resin sulfonic acid Soda has a much higher tear resistance in warp and weft.
Wie benzylnaphthalinsulfosaures Alkali können ferner z. B. verwendet werden die durch vorherige, ,gleichzeitige oder nachfolgende Sulfonierung wasserlöslich gemachten Umsetzungsprodukte aus Dichlortetrahydronaphthalin und Naphthalin, Dichlorteträhydronaphthalin und Tetrahydronaphthalin, -Chlorparaffin und Naphthalin, Naphthensäure und Paraffin, Kolophonium und Anthracen, Benaylnaphthalinharz und Butylalkohol, Cyklohexanol und Naphthalin, Naphthalin und Butylalkohol, Petroleum und Luft, Naphthalin, Petroleum und Chlor, Naphthalin und Chlorschwefel usf. Die sulfonierten Produkte werden zweckmäßig in Form der trocknen Natronsalze verwendet.As alkali benzylnaphthalenesulfonic acid, z. B. used become water-soluble through previous, simultaneous or subsequent sulfonation made reaction products of dichlorotetrahydronaphthalene and naphthalene, dichlorotetrahydronaphthalene and tetrahydronaphthalene, chloroparaffin and naphthalene, naphthenic acid and paraffin, Rosin and anthracene, benaylnaphthalene resin and butyl alcohol, cyclohexanol and Naphthalene, naphthalene and butyl alcohol, petroleum and air, naphthalene, petroleum and chlorine, naphthalene and chlorosulfur, etc. The sulfonated products become useful used in the form of dry sodium salts.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF55156D DE434979C (en) | 1923-12-21 | 1923-12-21 | Process for the protection of animal fibers when treated with alkaline liquids |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF55156D DE434979C (en) | 1923-12-21 | 1923-12-21 | Process for the protection of animal fibers when treated with alkaline liquids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE434979C true DE434979C (en) | 1926-10-05 |
Family
ID=7107584
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF55156D Expired DE434979C (en) | 1923-12-21 | 1923-12-21 | Process for the protection of animal fibers when treated with alkaline liquids |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE434979C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2730428A (en) * | 1950-10-21 | 1956-01-10 | Tepha Ges Fur Pharmazeutische | Method and composition for washing and bleaching fibrous materials |
-
1923
- 1923-12-21 DE DEF55156D patent/DE434979C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2730428A (en) * | 1950-10-21 | 1956-01-10 | Tepha Ges Fur Pharmazeutische | Method and composition for washing and bleaching fibrous materials |
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