DE4225985C2 - Human hair conditioning preparations - Google Patents
Human hair conditioning preparationsInfo
- Publication number
- DE4225985C2 DE4225985C2 DE4225985A DE4225985A DE4225985C2 DE 4225985 C2 DE4225985 C2 DE 4225985C2 DE 4225985 A DE4225985 A DE 4225985A DE 4225985 A DE4225985 A DE 4225985A DE 4225985 C2 DE4225985 C2 DE 4225985C2
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- Germany
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000003750 conditioning effect Effects 0.000 title claims description 10
- 238000002360 preparation method Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 claims description 25
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 10
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- RECMXJOGNNTEBG-UHFFFAOYSA-N 1-phenylmethoxyethanol Chemical compound CC(O)OCC1=CC=CC=C1 RECMXJOGNNTEBG-UHFFFAOYSA-N 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 4
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 3
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- LHENQXAPVKABON-UHFFFAOYSA-N 1-methoxypropan-1-ol Chemical compound CCC(O)OC LHENQXAPVKABON-UHFFFAOYSA-N 0.000 claims description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 2
- 241000723347 Cinnamomum Species 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 235000017803 cinnamon Nutrition 0.000 claims description 2
- 229960005323 phenoxyethanol Drugs 0.000 claims description 2
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000012736 aqueous medium Substances 0.000 claims 2
- 235000019437 butane-1,3-diol Nutrition 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 150000003751 zinc Chemical class 0.000 claims 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000004480 active ingredient Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 208000001840 Dandruff Diseases 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 229940043810 zinc pyrithione Drugs 0.000 description 2
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 2
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000009982 effect on human Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 150000002315 glycerophosphates Chemical class 0.000 description 1
- -1 glycol monoalkyl ether Chemical class 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000003893 lactate salts Chemical class 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L magnesium chloride Substances [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000019161 pantothenic acid Nutrition 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- LJXQPZWIHJMPQQ-UHFFFAOYSA-N pyrimidin-2-amine Chemical compound NC1=NC=CC=N1 LJXQPZWIHJMPQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- 210000002105 tongue Anatomy 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
Die vorliegende Erfindung betrifft ein Mittel zum Behandeln von menschlichen Haaren mit einer verbesserten Konditionierwirkung, d. h., das der Frisur Fülle und Griff (Volumen) sowie einen gu ten Halt verleiht und das Haar elastisch und glänzend erhält.The present invention relates to an agent for treating human hair with an improved conditioning effect, d. that is, the hairstyle fullness and grip (volume) as well as a good gives hold and keeps hair elastic and shiny.
Haarkonditionierende Mittel sind seit langem bekannt und im Han del. Sie vermögen jedoch vielfach nicht, dem menschlichen Haar die gewünschten Eigenschaften vollständig zu vermitteln, sondern es bedarf dazu häufig kompliziert aufgebauter, zuweilen sogar aus mehreren Phasen bestehender Zusammensetzungen.Hair conditioning agents have long been known and in the Han del. However, in many cases they are not capable of human hair to convey the desired properties completely, but This often requires complex structures, sometimes even multi-phase compositions.
Die Erfindung geht daher von der Aufgabenstellung aus, eine ein fach zusammengesetzte und daher kostengünstig herstellbare, gleichwohl hochwirksame Zusammensetzung zum Konditionieren von menschlichen Haaren zu schaffen, die dem Haar die eingangs de finierten gewünschten Eigenschaften verleiht.The invention is therefore based on the task, one professionally composed and therefore inexpensive to manufacture, nevertheless highly effective composition for conditioning to create human hair that the hair de gives the desired properties.
Diese Aufgabe wird dadurch gelöst, daß man auf das Haar eine Zu sammensetzung aufbringt, die mindestens ein physiologisch ver trägliches Salz, das Calcium-, Magnesium- und/oder Zinkionen in einer Menge von 0,1 bis 5,0, vorzugsweise 0,5 bis 3,0 Gew.-%, berechnet auf die Gesamtzusammensetzung des Mittels, in wäßrigem Medium freisetzt, sowie mindestens eine Verbindung aus der Gruppe 1,3-Butandiol, 1-Methoxypropanol, Benzylalkohol, Benzyl oxyethanol, Phenoxyethanol und Zimtalkohol in einer Menge von 0,5 bis 50 Gew.-%, vorzugsweise 1 bis 30 Gew.-%, insbesondere 2 bis 15% Gew.-%, bezogen auf die Gesamtzusammensetzung des Mit tels, und mindestens eine organische Säure, insbesondere Milchsäure, Weinsäure oder Citronensäure in einer Menge zwischen etwa 1 und 7,5, vorzugsweise 2,5 bis 5 Gew.-%, bezogen auf die Gesamtzusammensetzung, enthält, wobei das Mittel einen pH-Wert zwischen 2,5 und 6, vorzugsweise zwischen 3 und 6, aufweist.This object is achieved in that one has a hair brings up composition that has at least one physiologically ver inert salt that contains calcium, magnesium and / or zinc ions an amount of 0.1 to 5.0, preferably 0.5 to 3.0% by weight, calculated on the total composition of the agent, in aqueous Releases medium, as well as at least one connection from the Group 1,3-butanediol, 1-methoxypropanol, benzyl alcohol, benzyl oxyethanol, phenoxyethanol and cinnamon alcohol in an amount of 0.5 to 50% by weight, preferably 1 to 30% by weight, in particular 2 up to 15% by weight, based on the total composition of the means, and at least one organic acid, in particular Lactic acid, tartaric acid or citric acid in an amount between about 1 and 7.5, preferably 2.5 to 5 wt .-%, based on the Total composition, wherein the agent has a pH between 2.5 and 6, preferably between 3 and 6.
Als bevorzugte Verbindung der aufgezählten Alkohole seien insbe sondere 1,3-Butandiol, Benzylalkohol und Benzyloxyethanol ge nannt; als besonders geeignet hat sich eine Kombination aus 1,3-Butandiol und Benzylalkohol bzw. Benzyloxyethanol erwiesen.In particular, the preferred compound of the alcohols listed is special 1,3-butanediol, benzyl alcohol and benzyloxyethanol ge called; a combination of has proven to be particularly suitable 1,3-butanediol and benzyl alcohol or benzyloxyethanol proved.
Die erfindungsgemäß zum Einsatz gelangenden Calcium-, Magnesium- und/oder Zinkionen liefernden Verbindungen können in Form ihrer physiologisch verträglichen Salze eingesetzt werden. Als solche seien insbesondere Magnesium-, Calcium-, und Zinkchlorid und -nitrat, Magnesiumsulfat, Zinksulfat, etc. genannt; jedoch kön nen selbstverständlich auch wasserlösliche organische Salze, z. B. Lactate, Acetate, Propionate, Gluconate, Citrate, Glycero phosphate, Pantothenate, Tartrate, Sorbate, etc., eingesetzt werden. The calcium, magnesium, and / or zinc ion-providing compounds can be in the form of their physiologically acceptable salts are used. As such be especially magnesium, calcium, and zinc chloride and - called nitrate, magnesium sulfate, zinc sulfate, etc.; however, naturally also water-soluble organic salts, e.g. B. lactates, acetates, propionates, gluconates, citrates, glycero phosphates, pantothenates, tartrates, sorbates, etc., are used become.
Bevorzugte organische Säuren sind, wie bereits ausgeführt, ins besondere Milchsäure sowie Citronensäure und Weinsäure.Preferred organic acids are, as already stated, ins special lactic acid as well as citric acid and tartaric acid.
Im Prinzip sind jedoch alle organischen Säuren, die mit den Calcium-, Magnesium- bzw. Zinkionen keine unlöslichen Verbin dungen bilden, einsatzfähig.In principle, however, are all organic acids with the Calcium, magnesium and zinc ions are not an insoluble compound form solutions, operational.
Die erfindungsgemäßen Haarkonditioniermittel können alle für diesen Zweck üblichen und mit den genannten zweiwertigen Katio nen verträglichen Substanzen enthalten. Als solche seien insbe sondere die verschiedenen Silikonderivate, beispielsweise die flüchtigen und nichtflüchtigen Silikone, deren Einsatz in haar konditionierenden Mitteln seit langem bekannt und beschrieben ist, Polymere mit haarkonditionierenden Eigenschaften, Verdic kungsmittel, Perlglanzmittel, UV-Absorber, Antischuppenmittel, Konservierungsmittel, etc. genannt.The hair conditioning agents according to the invention can all be used for this purpose usual and with the above-mentioned bivalent cat contain compatible substances. As such, esp especially the various silicone derivatives, for example the volatile and non-volatile silicones, their use in hair conditioning agents have long been known and described is, polymers with hair conditioning properties, Verdic agents, pearlescent agents, UV absorbers, anti-dandruff agents, Preservatives, etc. called.
Der Einsatz solcher Stoffe gehört zum Stand der Technik und be darf an dieser Stelle deshalb keiner Wiederholung; es wird auf die einschlägigen Handbücher, beispielsweise K. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2. Auflage (1989, Hüthig Buchverlag), S. 722 bis 737, verwiesen.The use of such substances is state of the art and be therefore no repetition at this point; it gets on the relevant manuals, for example K. Schrader, "Basics and formulations of cosmetics", 2nd edition (1989, Hüthig Buchverlag), pp. 722 to 737.
Aus der EP-A 449 133 sind bereits haarkosmetische Zusammenset zungen bekannt, die einen Dialkylenglykolmonoalkylether in Kom bination mit einer Verbindung, die di- oder polyvalente Metall ionen in wäßriger Lösung freigibt, enthalten. Aus dieser Ver öffentlichung läßt sich jedoch keinerlei Hinweis im Hinblick auf die sich davon wesentlich unterscheidende erfindungsgemäße Kombination und deren überraschende Wirkung ableiten.Hair cosmetic compositions are already known from EP-A 449 133 tongues known that a dialkylene glycol monoalkyl ether in com combination with a compound that is di- or polyvalent metal releases ions in aqueous solution. From this ver However, there is no indication of publicity regarding the invention which differs substantially therefrom Derive combination and their surprising effect.
Gleiches gilt für die in der DE-A 23 24 797 beschriebenen Haar pflegemittel, die Kombinationen aus mindestens einem kationi schen Polymeren und mindestens einem zweiwertigen Metallsalz enthalten.The same applies to the hair described in DE-A 23 24 797 care products, the combinations of at least one cationi polymers and at least one divalent metal salt contain.
Aus der US-PS 5 041 439 sind weiterhin topisch anzuwendende Haarwuchsmittel bekannt, die als Penetrationsvermittler für den Iminopyrimidin-Wirkstoff eine Kombination aus C₃-C₄-Diolen oder C₃-C₆-Triolen und Isocetylalkohol enthalten. In Beispiel 11 ist ein Shampoo beschrieben, das neben dem obengenannten Wirkstoff noch Propylenglykol und Zinkpyrithion enthält.From US-PS 5 041 439 are still topically applicable Hair restorer known as a penetration mediator for the Iminopyrimidine active ingredient a combination of C₃-C₄ diols or C₃-C₆ triols and isocetyl alcohol contain. In example 11 is described a shampoo in addition to the above active ingredient still contains propylene glycol and zinc pyrithione.
Der Antischuppenwirkstoff Zinkpyrithion ist jedoch kein in wäß rigem Medium Zinkionen freisetzendes Salz im Sinne der Erfindung. However, the anti-dandruff active ingredient zinc pyrithione is not in water Salt releasing salt in the sense of Invention.
Die erfindungsgemäßen Haarkonditioniermittel können als wäßrige Lösungen, Lotionen, Emulsionen bzw. Dispersionen oder Gele vor liegen oder auch als Aerosolzusammensetzungen, beispielsweise als Aerosolschaum, konfektioniert sein. Auch die Anwendung als Zweikomponenten-Zusammensetzung ist möglich, wenn auch in der Regel nicht nötig.The hair conditioners according to the invention can be aqueous Solutions, lotions, emulsions or dispersions or gels lie or as aerosol compositions, for example as aerosol foam. Also use as Two-component composition is possible, albeit in the Usually not necessary.
Die Applikation auf das Haar erfolgt in üblicher Weise, bei spielsweise nach der Haarwäsche, Färbung oder Dauerwelle.The application to the hair is done in the usual way, at for example after shampooing, coloring or perm.
Im folgenden wird anhand von Ausführungsbeispielen diese überra schende Wirkung bewiesen.In the following, this will be outlined using exemplary embodiments proven effect.
Mit den in Tabelle 1 definierten Zusammensetzungen wurde jeweils der haarkonditionierende Effekt, insbesondere die volumengebende und Stylingwirkung an menschlichem Haar, an jeweils 5 Probandin nen beurteilt, wobei die Ergebnisse entsprechend der folgenden Werteskala dargestellt sind:With the compositions defined in Table 1 in each case the hair conditioning effect, especially the volume-giving effect and styling effect on human hair, on 5 subjects each assessed, the results according to the following Value scale are shown:
Die angegebenen Zahlen beziehen sich dabei jeweils auf Gewichts prozent.The numbers given relate to weight percent.
Aus diesen Resultaten läßt sich die überraschende Wirksamkeit der erfindungsgemäßen Zusammensetzungen klar ersehen.The surprising effectiveness can be derived from these results the compositions of the invention can be clearly seen.
Aus der JP-A 59 088 413 sind Haarspülmittel bekannt, die neben bestimmten Keratinhydrolysaten Calcium- und Magnesiumionen lie fernde Substanzen enthalten.JP-A 59 088 413 hair rinsing agents are known, which in addition certain keratin hydrolyzates calcium and magnesium ions contain remote substances.
Außerdem kann diesen Zusammensetzungen noch Propylenglykol zuge setzt werden.In addition, propylene glycol can also be added to these compositions be set.
Es wurde eine Zusammensetzung nach Beispiel 3 der Tabelle 1, die zusätzlich 10 Gew.-% 1,2-Propylenglykol enthielt (3A), mit einer identischen Zusammensetzung, die jedoch statt 1,2-Propylenglykol erfindungsgemäß zusätzlich 10 Gew.-% 1,3-Butandiol enthielt (3B), im Hinblick auf ihre haarkonditionierende Wirkung, wie oben beschrieben, verglichen.It was a composition according to Example 3 of Table 1, the additionally contained 10% by weight of 1,2-propylene glycol (FIG. 3A), with a identical composition, but instead of 1,2-propylene glycol according to the invention additionally contained 10% by weight of 1,3-butanediol (3B), in terms of their hair conditioning effect, as above described, compared.
Für Zusammensetzung 3A wurde eine Klassifizierung , für Zusammensetzung 3B die Klassifizierung ermittelt. Dies zeigt, daß die bekannten Propylenglykol enthaltenden Zusammensetzungen nach dieser JP-A die Erfindung nicht nahelegen können.A classification was made for composition 3A, for composition 3B the classification determined. This shows that the known propylene glycol containing Compositions according to this JP-A not the invention can suggest.
Claims (5)
- a) mindestens ein physiologisch verträgliches Salz, das Calcium-, Magnesium- und/oder Zinkionen in einer Menge von 0,1 bis 5,0 Gew.-Prozent, berechnet auf die Gesamt zusammensetzung des Mittels, in wäßrigem Medium frei setzt, sowie
- b) mindestens eine Verbindung aus der Gruppe 1,3-Butan diol, 1-Methoxypropanol, Benzylalkohol, Benzyloxyethanol, Phenoxyethanol und Zimtalkohol in einer Menge von 1 bis 50 Gewichtsprozent, bezogen auf die Gesamtzusammensetzung des Mittels, und
- c) mindestens eine organische Säure in einer Menge von 1 bis 7,5 Gew.-%, bezogen auf die Gesamtzusammensetzung des Mittels, enthält, wobei
- d) das Mittel einen pH-Wert zwischen 2,5 und 6 aufweist.
- a) at least one physiologically compatible salt that releases calcium, magnesium and / or zinc ions in an amount of 0.1 to 5.0 percent by weight, calculated on the total composition of the agent, in an aqueous medium, and
- b) at least one compound from the group 1,3-butane diol, 1-methoxypropanol, benzyl alcohol, benzyloxyethanol, phenoxyethanol and cinnamon alcohol in an amount of 1 to 50 percent by weight, based on the total composition of the agent, and
- c) contains at least one organic acid in an amount of 1 to 7.5 wt .-%, based on the total composition of the agent, wherein
- d) the agent has a pH between 2.5 and 6.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4225985A DE4225985C2 (en) | 1992-08-06 | 1992-08-06 | Human hair conditioning preparations |
| DE9210516U DE9210516U1 (en) | 1992-08-06 | 1992-08-06 | Human hair conditioning preparations |
| JP5131868A JPH072627A (en) | 1992-08-06 | 1993-06-02 | Conditioning composition for hair |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4225985A DE4225985C2 (en) | 1992-08-06 | 1992-08-06 | Human hair conditioning preparations |
| DE9210516U DE9210516U1 (en) | 1992-08-06 | 1992-08-06 | Human hair conditioning preparations |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE4225985A1 DE4225985A1 (en) | 1994-02-10 |
| DE4225985C2 true DE4225985C2 (en) | 1995-04-06 |
Family
ID=25917259
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE9210516U Expired - Lifetime DE9210516U1 (en) | 1992-08-06 | 1992-08-06 | Human hair conditioning preparations |
| DE4225985A Expired - Fee Related DE4225985C2 (en) | 1992-08-06 | 1992-08-06 | Human hair conditioning preparations |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE9210516U Expired - Lifetime DE9210516U1 (en) | 1992-08-06 | 1992-08-06 | Human hair conditioning preparations |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH072627A (en) |
| DE (2) | DE9210516U1 (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9419715D0 (en) * | 1994-09-30 | 1994-11-16 | Boots Co Plc | Hair stimulant composition |
| US6241971B1 (en) | 1997-09-25 | 2001-06-05 | The Procter & Gamble Company | Hair styling compositions comprising mineral salt, lipophilic material, and low levels of surfactant |
| JP2002540132A (en) * | 1999-03-25 | 2002-11-26 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Low volatile organic compound hairspray composition with the advantages of improved styling |
| FR2795317B1 (en) * | 1999-06-25 | 2001-08-24 | Oreal | HAIR COSMETIC PROCESS USING METALLIC-LIKE PARTICLES TO GIVE SHINE HAIR |
| JP3638490B2 (en) * | 2000-01-07 | 2005-04-13 | 花王株式会社 | Treatment composition for dyeing hair |
| WO2003086335A1 (en) * | 2002-04-08 | 2003-10-23 | Purac Biochem B.V. | Hair care composition for restoring the elasticity of hair |
| DE10341179A1 (en) | 2003-09-06 | 2005-03-31 | Beiersdorf Ag | Cosmetic or dermatological preparations containing synergistic combination of alpha- or beta-hydroxyacid and alkanediol, useful for combating acne and/or Propionibacterium acnes infection |
| ATE521329T1 (en) | 2004-05-05 | 2011-09-15 | Unilever Nv | ACID-BUFFERED PERSONAL CARE COMPOSITIONS |
| DE102007041494A1 (en) * | 2007-08-31 | 2009-03-05 | Henkel Ag & Co. Kgaa | Cosmetic cleanser with low pH |
| FR2965173B1 (en) * | 2010-09-24 | 2013-04-05 | Oreal | PROCESS FOR TREATING KERATIN FIBERS USING A NON-DETERGENT COSMETIC COMPOSITION COMPRISING AT LEAST ONE CALCIUM SALT |
| FR2965174B1 (en) | 2010-09-24 | 2013-04-12 | Oreal | COSMETIC COMPOSITION COMPRISING AT LEAST ONE HYGROSCOPIC SALT, AT LEAST ONE AROMATIC POLYOL ETHER AND AT LEAST ONE DIOL, COSMETIC PROCESSING PROCESS |
| DE102015223821A1 (en) * | 2015-12-01 | 2017-06-01 | Henkel Ag & Co. Kgaa | "Powerful hair treatment products with structurally strengthening effect" |
| JP7596367B2 (en) * | 2019-10-18 | 2024-12-09 | ユニリーバー・アイピー・ホールディングス・ベスローテン・ヴェンノーツハップ | Hair treatment method |
| US20240180801A1 (en) * | 2021-04-15 | 2024-06-06 | Conopco, Inc., D/B/A Unilever | Hair treatment method |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5041439A (en) * | 1986-06-13 | 1991-08-20 | The Procter & Gamble Company | Penetrating topical pharmaceutical compositions |
| GB8726438D0 (en) * | 1987-11-11 | 1987-12-16 | Dow Corning | Hair conditioning composition |
| US5077042A (en) * | 1988-03-25 | 1991-12-31 | Johnson Products Co., Inc. | Conditioning hair relaxer system with conditioning activator |
-
1992
- 1992-08-06 DE DE9210516U patent/DE9210516U1/en not_active Expired - Lifetime
- 1992-08-06 DE DE4225985A patent/DE4225985C2/en not_active Expired - Fee Related
-
1993
- 1993-06-02 JP JP5131868A patent/JPH072627A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE9210516U1 (en) | 1993-12-09 |
| DE4225985A1 (en) | 1994-02-10 |
| JPH072627A (en) | 1995-01-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: KAO CORP., TOKIO/TOKYO, JP |
|
| 8328 | Change in the person/name/address of the agent |
Free format text: HOFFMANN, EITLE & PARTNER PATENT- UND RECHTSANWAELTE, 81925 MUENCHEN |
|
| 8339 | Ceased/non-payment of the annual fee |