DE3814208A1 - USE OF UNCOLORED AND / OR COLORED SUBSTRATES - Google Patents
USE OF UNCOLORED AND / OR COLORED SUBSTRATESInfo
- Publication number
- DE3814208A1 DE3814208A1 DE19883814208 DE3814208A DE3814208A1 DE 3814208 A1 DE3814208 A1 DE 3814208A1 DE 19883814208 DE19883814208 DE 19883814208 DE 3814208 A DE3814208 A DE 3814208A DE 3814208 A1 DE3814208 A1 DE 3814208A1
- Authority
- DE
- Germany
- Prior art keywords
- cotton
- treated
- compound
- colored
- polymeric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000758 substrate Substances 0.000 title description 11
- 229920000642 polymer Polymers 0.000 claims description 12
- 229920000742 Cotton Polymers 0.000 claims description 11
- 239000000975 dye Substances 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 8
- 239000013543 active substance Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000004043 dyeing Methods 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 125000001302 tertiary amino group Chemical group 0.000 claims description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 2
- 230000009286 beneficial effect Effects 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 239000000047 product Substances 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- 150000007514 bases Chemical class 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 239000003086 colorant Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- RFQSMLBZXQOMKK-UHFFFAOYSA-N [3-[(4,8-diamino-6-bromo-1,5-dioxonaphthalen-2-yl)amino]phenyl]-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)C1=CC=CC(NC=2C(C3=C(N)C=C(Br)C(=O)C3=C(N)C=2)=O)=C1 RFQSMLBZXQOMKK-UHFFFAOYSA-N 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- VPYJNCGUESNPMV-UHFFFAOYSA-N triallylamine Chemical group C=CCN(CC=C)CC=C VPYJNCGUESNPMV-UHFFFAOYSA-N 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5242—Polymers of unsaturated N-containing compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5278—Polyamides; Polyimides; Polylactames; Polyalkyleneimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Detergent Compositions (AREA)
Description
Gegenstand der Erfindung ist die Verwendung von ungefärbten und/oder gefärbten hydroxy- und/oder thiolgruppenhaltigen und/oder Stickstoffatome enthaltenden Substraten, die mit mindestens einer polymeren Verbindung behandelt wurden, welche polymere Verbindung mindestens eine basische Gruppe aufweist, zur Aufnahme von Farbstoffen, welche während des Wasch vorganges von nicht genügend waschechten Färbungen in die Waschflotte abgelöst wurden.The invention relates to the use of undyed and / or colored hydroxy and / or thiol group-containing and / or nitrogen atoms containing substrates with at least one polymeric compound were treated, which polymeric compound at least one basic Group has, for the absorption of dyes, which during washing process of insufficiently washfast dyeings in the wash liquor were replaced.
Gegenstand der Erfindung ist somit ein Waschverfahren mit handels üblichen Waschmitteln, beispielsweise in der Haushaltwäsche in den üb lichen Waschmaschinen, dadurch gekennzeichnet, daß man dem Waschgut einen "Mitläufer", d.h. ein Substrat zugibt, das gemäß Anspruch 1 mit polymeren basischen Verbindungen präpariert wurde, dessen Aufgabe darin besteht, Farbstoffe, insbesondere anionische Farbstoffe aufzunehmen, die während des Waschvorganges von nicht genügend waschechten Färbungen in die Waschflotte abwandern, d.h. abbluten und nachher das Waschgut an schmutzen und/oder eine Nuancenänderung verursachen. Diese präparierten Substrate verhindern somit ein farbliches Anschmutzen der Wäsche. Der präparierte "Mitläufer" kann ungefärbt oder gefärbt sein. Ein präparier tes gefärbtes Substrat hat vorteilhaft eine Farbtiefe von nicht mehr als 1/1 Richttypstärke, besonders geeignet sind solche in hellen Tönen, z.B. Pastelltönen.The invention thus relates to a washing process with commercially available detergents, for example in household laundry in the usual washing machines, characterized in that the laundry is added to a "follower", ie a substrate which has been prepared according to claim 1 with polymeric basic compounds, whose task is to take up dyes, in particular anionic dyes, which migrate into the wash liquor from inadequate washfast dyeings during the washing process, ie bleed off and subsequently dirty the laundry and / or cause a change in shade. These prepared substrates thus prevent the laundry from being soiled in color. The prepared "follower" can be undyed or colored. A Dissecting tes colored substrate advantageously has a color depth of not more than 1/1 type directional strength, particularly suitable are those in bright colors, such as pastel colors.
Als "Mitläufer" sind Flächen oder Fasergebilde, Gewebe, Gewirke, Folien, Non-Wowens, Papiere zu verstehen. Vorteilhaft verwendet man na türliche und/oder synthetische Substrate, insbesondere nicht gefärbte behandelte Baumwolle, nicht gefärbte behandelte regenerierte Cellulose oder nicht gefärbte behandelte natürliche oder synthetische Polyamide. Vorteilhaft verwendet man Substrate, insbesondere Baumwolle, die mit einer polymeren Verbindung behandelt wurden, die mindestens eine primäre, sekundäre oder tertiäre Aminogruppe und/oder mindestens eine quaternäre Ammoniumgruppe aufweist, vorzugsweise mindestens eine und vorteilhaft mehrere positive Ladungen aufweisen.Surfaces or fiber structures, woven fabrics, knitted fabrics, Understand transparencies, non-wowens, papers. One advantageously uses na door and / or synthetic substrates, especially non-colored substrates treated cotton, uncolored treated regenerated cellulose or non-colored treated natural or synthetic polyamides. It is advantageous to use substrates, especially cotton, with treated with a polymeric compound that has at least one primary, secondary or tertiary amino group and / or at least one quaternary Has ammonium group, preferably at least one and advantageous have multiple positive charges.
Die polymeren Verbindungen, die mindestens eine basische Gruppe enthal ten, können nach bekannten Methoden auf das Substrat aufgebracht werden, z.B. durch Foulardieren, Tauchen, Sprühen, Pflatschen oder im Auszieh verfahren und zwar in einer Menge von 2-200 g/l, vorteilhaft 10 bis 50 g/l, bezogen auf 100% Aktivsubstanz der polymeren basischen Verbindung, wobei ein Flottenverhältnis von 1 : 1-1 : 30 am geeignetsten ist. Das Verhältnis vom Waschgut zum präparierten "Mitläufer" ist vorteilhaft auf 1 kg Waschgut 5 bis 80 gr und vorteilhaft 10 bis 30 gr "Mitläufer" bzw. präpariertes Substrat.The polymeric compounds which contain at least one basic group can be applied to the substrate by known methods, e.g. by padding, dipping, spraying, splashing or taking off proceed in an amount of 2-200 g / l, advantageously 10 to 50 g / l, based on 100% active substance of the polymeric basic compound, a liquor ratio of 1: 1-1: 30 is most suitable. The ratio of the laundry to the prepared "follower" is advantageous on 1 kg of laundry 5 to 80 gr and advantageously 10 to 30 gr "follower" or prepared substrate.
Geeignete polymere Verbindungen, die mindestens eine basische Gruppe aufweisen, sind beispielsweise bekannt aus der schweizerischen Ausle gungsschrift 6 62 919, insbesondere Beispiel 1, Abschnitte 1 und 2 und in Beispiel 1, das Endprodukt in den Abschnitten 1, 2 und 3, ferner aus der englischen Offenlegungsschrift A 21 42 642, aus der DOS 34 46 282, in der bereits mit den dort genannten polymeren basischen Verbindungen vorbe handelte Baumwolle beschrieben, aber nicht für den erfindungsgemäßen Zweck verwendet wird, ferner aus den DOS 35 25 104, 34 46 284, 32 16 913, 37 20 508, ferner aus den veröffentlichten europäischen Patentanmeldungen Nos. 1 40 309, 1 45 220, 95 233 oder 1 42 337, oder aus den veröffentlichten japanischen PatentanmeldungenSuitable polymeric compounds that have at least one basic group have, for example, are known from the Swiss Ausle tion 6 62 919, in particular example 1, sections 1 and 2 and in Example 1, the final product in sections 1, 2 and 3, further from the English Offenlegungsschrift A 21 42 642, from DOS 34 46 282, in the already with the polymeric basic compounds mentioned there traded cotton described, but not for the invention Purpose is used, also from DOS 35 25 104, 34 46 284, 32 16 913, 37 20 508, also from the published European patent applications Nos. 1 40 309, 1 45 220, 95 233 or 1 42 337, or from the published ones Japanese patent applications
Nos. 51-57′793
56-9′999
56-53′292
56-134′284
57-11′288
57-82′591
57-92′012
60-7′079
45-1′457
49-31′631Nos. 51-57′793
56-9′999
56-53′292
56-134′284
57-11'288
57-82′591
57-92′012
60-7'079
45-1'457
49-31'631
Als polymere basische Verbindungen ist eine Mischung M) mit syner gistischen Eigenschaften, welche ein Textilhilfsmittel T) und eine poly mere Verbindung P) enthält, worin T) ein Produkt ist, das man mit Hilfe einer zweistufigen Reaktion erhält, indem man 1) ein Epihalogenhydrin mit wäßrigem Ammoniak bei 50-90°C bei einem Ausgangsverhältnis von 4 Mol Epihalogenhydrin zu 8-10 Mol Ammoniak umsetzt und 2) das gemäß 1) erhal tene Produkt, nach Entfernen des Ammoniaküberschusses mit 0,1 bis 0,5 Mol Epihalogenhydrin weiter umsetzt und P) ein wasserlösliches Homopolymer von Mono- oder Diallylamin ist oder ein wasserlösliches Copolymer ist, das aus Mono-, Di- oder Triallylamineinheiten besteht. A mixture M) with syner is a polymeric basic compound gistic properties, which a textile auxiliary T) and a poly contains compound P), in which T) is a product which can be obtained with the aid of a two-step reaction by 1) using an epihalohydrin aqueous ammonia at 50-90 ° C with an initial ratio of 4 mol Epihalogenrin reacted to 8-10 mol of ammonia and 2) get that according to 1) tene product, after removing the excess ammonia with 0.1 to 0.5 mol Epihalohydrin and P) a water-soluble homopolymer is mono- or diallylamine or is a water-soluble copolymer, which consists of mono-, di- or triallylamine units.
Ebenso geeignete polymere basische Verbindungen ist eine Mischung M1) mit synergistischen Eigenschaften, welche eine identische Mischung M) wie zuvor angegeben, enthält (enthaltend T) und P) ) und zusätzlich eine polymere Verbindung Pi) enthält, erhalten durch Umsetzen von Epihalogen hydrin oder einer Vorstufe von Epihalogenhydrin mit einem Polyalkylen polyamin.Likewise suitable polymeric basic compounds is a mixture M 1 ) with synergistic properties, which contains an identical mixture M) as stated above (containing T) and P)) and additionally contains a polymeric compound Pi), obtained by reacting epihalohydrin or a precursor of epihalohydrin with a polyalkylene polyamine.
Weitere geeignete polymere Verbindungen, welche mindestens eine basische Gruppe aufweisen, sind polymere Produkte, erhalten durch Umsetzen von Epihalogenhydrin mit Alkylaminen, z.B. Methylamin oder Dimethylamin, wie sie in den US-Patentschriften 45 05 775 und 46 24 743 beschrieben werden.Other suitable polymeric compounds which have at least one basic Have group are polymeric products obtained by reacting Epihalohydrin with alkylamines, e.g. Methylamine or dimethylamine, such as they are described in U.S. Patents 4,505,775 and 4,624,743.
Die erfindungsgemäß verwendeten "Mitläufer", also wie zuvor defi nierte Substrate, die mit einer polymeren Verbindung, die mindestens eine basische Gruppe aufweisen, behandelt wurden, sind demnach basisch auf geladen.The "followers" used according to the invention, ie as before, defi nated substrates with a polymeric compound containing at least one have basic group, have been treated, are therefore based on loaded.
In den folgenden Beispielen bedeuten die Teile Gewichtsteile, die Prozente Gewichtsprozente und die Temperaturen sind in Celsiusgraden angegeben.In the following examples, parts by weight mean that Percentages by weight and the temperatures are in degrees Celsius specified.
Ein Gewebe aus 100% Baumwolle wird mit 60 g/l des Produktes aus der DE-OS 35 25 104, Beispiel 1, Abschnitt 1 und 2, oder Abschnitt 1-3, (berechnet auf 100% Aktivsubstanz) auf einem Foulard imprägniert und bei 100° ge trocknet. Der so hergestellte "Mitläufer" wird nun zu einer Haushalt- Buntwäsche, bestehend aus einem gefärbten und einem ungefärbten Baumwoll -Textilgewebe, die mit einem Reaktivfarbstöff, CI Reactive Violet 23, gefärbt wurde, zugegeben. Das Gewicht der Buntwäsche beträgt 3 kg und das Waschflottenverhältnis 1 : 4. Als Waschmittel wird ein handelsübliches Produkt für eine 60°-Wäsche in einer Menge von 6 g/ltr. verwendet.A fabric made of 100% cotton is made with 60 g / l of the product from DE-OS 35 25 104, Example 1, Sections 1 and 2, or Section 1-3, (calculated impregnated to 100% active substance) on a padder and at 100 ° dries. The "follower" thus produced is now a household Colored linen, consisting of a dyed and an undyed cotton -Textile fabric made with a reactive dye, CI Reactive Violet 23, was colored added. The weight of the colored laundry is 3 kg and that Washing liquor ratio 1: 4. A commercially available detergent is used Product for a 60 ° wash in an amount of 6 g / ltr. used.
Der Anteil des "Mitläufers" zum Gewicht des Waschgutes liegt bei 1% (in der Regel zwischen 0,5-1%), d.h. es wird etwa 30 g "Mitläufer" ein gesetzt. The share of the "follower" to the weight of the laundry is 1% (usually between 0.5-1%), i.e. it becomes about 30 g "follower" set.
Es wird nun mit den Waschprogrammen für 60°C Wäsche in einer handelsüb lichen Haushaltwaschmaschine gewaschen und getrocknet.It is now with the washing programs for 60 ° C laundry in a commercial Washed and dried household washing machine.
Nach dem Trocknen ist ersichtlich, daß der "Mitläufer" einen Teil des freigewordenen Farbstoffs der ungenügend echten Färbung aufnimmt.After drying it can be seen that the "follower" is a part of the liberated dye absorbs the insufficiently genuine coloring.
Wird der im Beispiel 1 präparierte "Mitläufer" mit einem Baumwollgewebe, das mit einem Direktfarbstöff CI Direct Blue 251 gefärbt wurde, der Haus halt-Buntwäsche mitgegeben, stellt man ebenfalls fest, daß der "Mitläu fer" vom freigewaschenen Farbstoff angeschmutzt wurde.If the "follower" prepared in Example 1 is made with a cotton fabric, that was dyed with a direct dye CI Direct Blue 251, the house Given colored laundry, it is also found that the "Mitläu fer "was soiled by the washed dye.
Ein Mitläufer wird mit dem polymeren Produkt aus der DE-OS 37 23 508, Beispiel 1 nach den Angaben von Beispiel 1 präpariert.A follower is with the polymeric product from DE-OS 37 23 508, Example 1 prepared according to the instructions in Example 1.
Das Waschgut besteht ausThe laundry consists of
60-70% Baumwolle, gefärbt mit dem Farbstoff CI Direct Blue 251,
10% Nylon, gefärbt mit dem Farbstoff des Beispiels 1 aus der DE-OS
24 00 654,
15% DACRON, gefärbt mit CI Dispers Yellow 23,
5% Orlon, gefärbt mit dem Farbstoff CI Basic Blue 45.60-70% cotton, dyed with the dye CI Direct Blue 251,
10% nylon, dyed with the dye of Example 1 from DE-OS 24 00 654,
15% DACRON, colored with CI Dispers Yellow 23,
5% Orlon, dyed with the CI Basic Blue 45 dye.
Das Waschgut wird zusammen mit dem "Mitläufer" bei 60° gewaschen. Der mitgewaschene "Mitläufer" ist auch hier angeschmutzt, wobei das Waschgut klarere Farben zeigt.The laundry is washed together with the "follower" at 60 °. The washed-along "follower" is also soiled here, whereby the Laundry shows clearer colors.
Claims (5)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19883814208 DE3814208A1 (en) | 1988-04-27 | 1988-04-27 | USE OF UNCOLORED AND / OR COLORED SUBSTRATES |
| EP19890810306 EP0341205A3 (en) | 1988-04-27 | 1989-04-25 | A dye scavenger |
| JP10477189A JPH01321977A (en) | 1988-04-27 | 1989-04-26 | Method for reducing or preventing discoloration of textile materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19883814208 DE3814208A1 (en) | 1988-04-27 | 1988-04-27 | USE OF UNCOLORED AND / OR COLORED SUBSTRATES |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3814208A1 true DE3814208A1 (en) | 1989-11-09 |
Family
ID=6353000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19883814208 Withdrawn DE3814208A1 (en) | 1988-04-27 | 1988-04-27 | USE OF UNCOLORED AND / OR COLORED SUBSTRATES |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0341205A3 (en) |
| JP (1) | JPH01321977A (en) |
| DE (1) | DE3814208A1 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5534182A (en) * | 1993-07-12 | 1996-07-09 | Rohm And Haas Company | Process and laundry formulations for preventing the transfer of dye in laundry processes |
| US5380447A (en) * | 1993-07-12 | 1995-01-10 | Rohm And Haas Company | Process and fabric finishing compositions for preventing the deposition of dye in fabric finishing processes |
| CA2180070A1 (en) * | 1995-07-11 | 1997-01-12 | Thomas Cleveland Kirk | Washing composition and use of polymer to clean and provide soil resistance to an article |
| CA2180071A1 (en) * | 1995-07-11 | 1997-01-12 | Thomas Cleveland Kirk | Fabric washing composition and method for inhibiting deposition of dye |
| US6830593B1 (en) | 1998-08-03 | 2004-12-14 | The Procter & Gamble Company | Fabric care compositions |
| ATE290584T1 (en) | 1998-09-16 | 2005-03-15 | Unilever Nv | LAUNDRY CARE COMPOSITION |
| EP0990695A1 (en) | 1998-09-30 | 2000-04-05 | Witco Surfactants GmbH | Fabric softener with dye transfer inhibiting properties |
| US6887524B2 (en) | 2000-10-13 | 2005-05-03 | The Procter & Gamble Company | Method for manufacturing laundry additive article |
| US6833336B2 (en) | 2000-10-13 | 2004-12-21 | The Procter & Gamble Company | Laundering aid for preventing dye transfer |
| EP1239025A3 (en) * | 2001-03-03 | 2003-09-03 | Clariant GmbH | Detergent composition and laundry treatment compositon comprising dye transfer inhibiting and dye fixing agent |
| DE10150724A1 (en) | 2001-03-03 | 2003-04-17 | Clariant Gmbh | Washing agents such as detergents contain dye transfer inhibitors which are polyamine/cyanamide/amidosulfuric acid, cyanamide/aldehyde/ammonium salt or amine/epichlorhydrin reaction products |
| US7256166B2 (en) | 2002-01-18 | 2007-08-14 | The Procter & Gamble Company | Laundry articles |
| DE102004043728A1 (en) | 2004-09-10 | 2005-06-30 | Clariant Gmbh | Liquid detergent containing dye fixative |
| DE102004051010A1 (en) | 2004-10-20 | 2005-06-23 | Clariant Gmbh | Liquid laundry and other detergents, e.g. for wool, delicate or heavy wash, contain anionic and nonionic surfactants and color fixative, e.g. diallyl-dimethyl-ammonium chloride polymer or reaction product of cyanamide, aldehyde and amine |
| DE102004051715A1 (en) | 2004-10-23 | 2005-06-30 | Clariant Gmbh | Stable liquid detergent or cleansing compositions, especially for washing textiles, containing anionic and nonionic surfactants, soap and dye fixing agent, e.g. diallyl dimethylammonium chloride (co)polymer |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH673195B5 (en) * | 1981-05-14 | 1990-08-31 | Sandoz Ag | |
| JPS60110987A (en) * | 1983-11-15 | 1985-06-17 | 日東紡績株式会社 | Enhancement of dyeing fastness |
-
1988
- 1988-04-27 DE DE19883814208 patent/DE3814208A1/en not_active Withdrawn
-
1989
- 1989-04-25 EP EP19890810306 patent/EP0341205A3/en not_active Withdrawn
- 1989-04-26 JP JP10477189A patent/JPH01321977A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0341205A3 (en) | 1991-05-08 |
| EP0341205A2 (en) | 1989-11-08 |
| JPH01321977A (en) | 1989-12-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |