DE3733234A1 - POLYSACCHARIDES FROM THE ENDOSPERM OF PROSOPIS JULIFLORA SEEDS, METHOD FOR THEIR PRODUCTION AND THEIR USE - Google Patents
POLYSACCHARIDES FROM THE ENDOSPERM OF PROSOPIS JULIFLORA SEEDS, METHOD FOR THEIR PRODUCTION AND THEIR USEInfo
- Publication number
- DE3733234A1 DE3733234A1 DE19873733234 DE3733234A DE3733234A1 DE 3733234 A1 DE3733234 A1 DE 3733234A1 DE 19873733234 DE19873733234 DE 19873733234 DE 3733234 A DE3733234 A DE 3733234A DE 3733234 A1 DE3733234 A1 DE 3733234A1
- Authority
- DE
- Germany
- Prior art keywords
- prosopis
- polysaccharides
- juliflora
- endosperm
- polysaccharide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 150000004676 glycans Chemical class 0.000 title claims abstract description 31
- 229920001282 polysaccharide Polymers 0.000 title claims abstract description 31
- 239000005017 polysaccharide Substances 0.000 title claims abstract description 31
- 240000007909 Prosopis juliflora Species 0.000 title claims abstract description 13
- 235000008198 Prosopis juliflora Nutrition 0.000 title claims abstract description 9
- 238000000034 method Methods 0.000 title claims description 5
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000002562 thickening agent Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 240000009222 Prosopis chilensis Species 0.000 claims abstract description 7
- 235000001560 Prosopis chilensis Nutrition 0.000 claims abstract description 7
- 235000014460 Prosopis juliflora var juliflora Nutrition 0.000 claims abstract description 4
- 150000002148 esters Chemical class 0.000 claims abstract description 4
- 230000008719 thickening Effects 0.000 claims description 25
- 244000303965 Cyamopsis psoralioides Species 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 241001494501 Prosopis <angiosperm> Species 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 5
- 239000008107 starch Substances 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- 239000004753 textile Substances 0.000 claims description 5
- 240000006304 Brachychiton acerifolius Species 0.000 claims description 4
- 229920000161 Locust bean gum Polymers 0.000 claims description 4
- -1 carboxyalkyl ethers Chemical class 0.000 claims description 4
- 235000012907 honey Nutrition 0.000 claims description 4
- 235000010420 locust bean gum Nutrition 0.000 claims description 4
- 239000000711 locust bean gum Substances 0.000 claims description 4
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 4
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 3
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 3
- 244000275012 Sesbania cannabina Species 0.000 claims description 3
- 235000013305 food Nutrition 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 claims description 2
- 229920001817 Agar Polymers 0.000 claims description 2
- 235000017399 Caesalpinia tinctoria Nutrition 0.000 claims description 2
- 241001312569 Ribes nigrum Species 0.000 claims description 2
- 241000388430 Tara Species 0.000 claims description 2
- 239000008272 agar Substances 0.000 claims description 2
- 235000010419 agar Nutrition 0.000 claims description 2
- 150000005215 alkyl ethers Chemical class 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 235000010418 carrageenan Nutrition 0.000 claims description 2
- 239000000679 carrageenan Substances 0.000 claims description 2
- 229920001525 carrageenan Polymers 0.000 claims description 2
- 229940113118 carrageenan Drugs 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 238000005553 drilling Methods 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 239000003129 oil well Substances 0.000 claims description 2
- 150000002902 organometallic compounds Chemical class 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 229920000193 polymethacrylate Polymers 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims 1
- 229920000926 Galactomannan Polymers 0.000 description 15
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 244000037364 Cinnamomum aromaticum Species 0.000 description 3
- 235000014489 Cinnamomum aromaticum Nutrition 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 235000021374 legumes Nutrition 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 241000283690 Bos taurus Species 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 2
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000005188 flotation Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 229930182830 galactose Natural products 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- RNJIWICOCATEFH-WCWDXBQESA-N (2e)-2-(1-oxobenzo[e][1]benzothiol-2-ylidene)benzo[e][1]benzothiol-1-one Chemical compound C1=CC=CC2=C(C(C(=C3/C(C4=C5C=CC=CC5=CC=C4S3)=O)/S3)=O)C3=CC=C21 RNJIWICOCATEFH-WCWDXBQESA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- TURGQPDWYFJEDY-UHFFFAOYSA-N 1-hydroperoxypropane Chemical compound CCCOO TURGQPDWYFJEDY-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241000282832 Camelidae Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000522254 Cassia Species 0.000 description 1
- 240000008886 Ceratonia siliqua Species 0.000 description 1
- 235000013912 Ceratonia siliqua Nutrition 0.000 description 1
- 241000272194 Ciconiiformes Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 244000105017 Vicia sativa Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000005189 alkyl hydroxy group Chemical group 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010014 continuous dyeing Methods 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000000434 metal complex dye Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000213 tara gum Substances 0.000 description 1
- 235000010491 tara gum Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/006—Heteroglycans, i.e. polysaccharides having more than one sugar residue in the main chain in either alternating or less regular sequence; Gellans; Succinoglycans; Arabinogalactans; Tragacanth or gum tragacanth or traganth from Astragalus; Gum Karaya from Sterculia urens; Gum Ghatti from Anogeissus latifolia; Derivatives thereof
- C08B37/0087—Glucomannans or galactomannans; Tara or tara gum, i.e. D-mannose and D-galactose units, e.g. from Cesalpinia spinosa; Tamarind gum, i.e. D-galactose, D-glucose and D-xylose units, e.g. from Tamarindus indica; Gum Arabic, i.e. L-arabinose, L-rhamnose, D-galactose and D-glucuronic acid units, e.g. from Acacia Senegal or Acacia Seyal; Derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/001—Special chemical aspects of printing textile materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/016—Macromolecular compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Textile Engineering (AREA)
- Molecular Biology (AREA)
- Organic Chemistry (AREA)
- Emergency Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
Description
Die Mimosacee Prosopis juliflora (auch Prosopis chilensis oder Ceratonia chilensis oder Mimosa juliflora genannt) ist ein Strauch oder Baum, der auch in trockenen Gegenden gedeiht, gegenüber Brackwasser und Industrieabwässern besonders resistent ist und beispielsweise in Indien und Brasilien angebaut wird um Straßen zu säumen, Dünen am Wandern zu hindern, Brennholz und Grünfutter für Kamele und Rinder zu liefern. Die Früchte (Schoten) fallen im reifen Zustand ab und das herumstreifende Vieh nimmt dieses Zusatzfutter auf. Sonst finden die Schoten keine Verwendung. Nach Literaturangaben ("The Wealth of India" Band 8, 1969, 245-249) sollen in Amerika die vom Samen befreiten Schoten zu Mehl vermahlen werden, das für Kuchen und zur Getränkeherstellung verwendet werden kann. The Mimosacee Prosopis juliflora (also Prosopis chilensis or Ceratonia chilensis or Mimosa juliflora)) a shrub or tree that thrives in dry areas, especially against brackish water and industrial waste water is resistant and for example in India and Brazil is grown to line roads, dunes on hiking to prevent firewood and green fodder for camels and cattle to deliver. The fruits (pods) fall when ripe and the roaming cattle take this additional feed on. Otherwise the pods are of no use. According to literature ("The Wealth of India" Volume 8, 1969, 245-249) In America, the pods freed from the seeds are said to be flour be ground, for cakes and for beverage production can be used.
Es wurde gefunden, daß das Polysaccharid aus dem Endosperm des Samens von Prosopis juliflora besonders interessante chemische und physikalische Eigenschaften besitzt.It was found that the polysaccharide from the endosperm of the seeds of Prosopis juliflora particularly interesting possesses chemical and physical properties.
Es ist bekannt, daß die Endosperm-Zellen vieler Leguminosensamen Polysaccharide enthalten, die Galactomannane darstellen. Diese sind wie Stärke pflanzliche Reservepolysaccharide. Bei der Keimung der Samen werden sie enzymatisch abgebaut und dienen als Nährstoffe für den Keimling. Der Sammelbegriff Galactomannan bzw. Polygalactomannan umfaßt alle Polysaccharide, die aus Galactose, bzw. Mannose-Bausteinen aufgebaut sind und darüber hinaus im untergeordneten Maß auch andere Zuckerbausteine aufweisen können. Je nach Herkunft gibt es eine verhältnismäßig große Anzahl von Galactomannanen, die sich chemisch und in ihren physikalischen Eigenschaften unterscheiden.It is known that the endosperm cells of many legume seeds Contain polysaccharides, which are galactomannans. Like starch, these are herbal reserve polysaccharides. When the seeds germinate, they become enzymatic degraded and serve as nutrients for the seedling. The collective term galactomannan or polygalactomannan includes all polysaccharides made from galactose or mannose building blocks are built up and also in the subordinate Other sugar modules can also have a degree. Depending on the origin, there is a relatively large one Number of galactomannans that are chemically and in their distinguish physical properties.
Bekannt und industriell verwertet werden hauptsächlich die in den Endosperm-Abschnitten und Samen verschiedener Leguminosen (Hülsenfrüchtlern) wie Guar, Johannisbrot, Tara, Honigbohne, Flammenbaum, Sesbania und Cassia-Arten vorkommenden Galactomannane.They are mainly known and used industrially in the endosperm sections and seeds of various legumes (Legumes) such as guar, carob, tare, Honey bean, flame tree, sesbania and cassia species occurring Galactomannans.
Es ist bekannt, daß diese Polysaccharide sich insbesondere als Verdickungsmittel eignen. Die DE-OS 33 35 593 beschreibt Gelier- und Verdickungsmittel auf der Basis von Cassia-Galactomannanen. Substituierte Alkylether von Cassia-Polysacchariden und deren Verwendung als Verdickungsmittel werden in der DE-OS 33 47 469 offenbart. In der US-PS 24 77 544 werden Carboxyalkylether von Polygalactomannanen beschrieben, die aus Guargummi, Johannisbrotkernmehl, honey locus, flame tree und dergleichen stammen, sowie deren Verwendung als Verdickungsmittel in Druckpasten.It is known that these polysaccharides in particular are suitable as thickeners. DE-OS 33 35 593 describes Gelling and thickening agents based on Cassia galactomannans. Substituted alkyl ethers of cassia polysaccharides and their use as thickeners are disclosed in DE-OS 33 47 469. In the U.S. Patent No. 2,477,544 discloses carboxyalkyl ethers of polygalactomannans from guar gum, locust bean gum, honey locus, flame tree and the like, and their use as thickeners in printing pastes.
Die erfindungsgemäßen Polysaccharide aus dem Endosperm des Samens von Prosopis juliflora sind Polygalactomannane aus Galactose und Mannose im Verhältnis von etwa 1 : 1. Es wurde überraschenderweise festgestellt, daß dieses Polygalactomannan gut kaltwasserlöslich ist und eine relativ hohe Viskosität besitzt. Wegen seiner klaren Löslichkeit in kaltem Wasser eignet es sich hervorragend als Verdickungsmittel für wäßrige Systeme. Im Gegensatz zu den bisher bekannten Verdickungsmitteln wie Guar (kalt, trüb löslich), Johannisbrotkernmehl (heiß, trüb löslich), Tarakernmehl (nur heiß, trüb löslich) und Cassiakernmehl (nur heiß, trüb löslich) muß das Prosopis Galactomannan nicht erst zur Verbesserung der Löslichkeit derivatisiert werden, sondern ist in Wasser bereits als unverändertes Galactomannan kalt, klar löslich.The polysaccharides according to the invention from the endosperm of the Prosopis juliflora seeds are made from polygalactomannans Galactose and mannose in a ratio of about 1: 1 Surprisingly found that this polygalactomannan is well soluble in cold water and a relatively high Has viscosity. Because of its clear solubility in cold water, it is an excellent thickener for aqueous systems. In contrast to the previous ones known thickeners such as guar (cold, cloudy soluble), Locust bean gum (hot, turbidly soluble), tara gum (only hot, cloudy soluble) and cassia seed flour (only hot, cloudy soluble), the Prosopis Galactomannan does not have to Improve solubility but be derivatized is cold in water as unchanged galactomannan, clearly soluble.
Eine 1%ige Lösung in Wasser des erfindungsgemäßen Galactomannans weist bei Raumtemperatur eine Viskosität von etwa 3000 m·Pas auf.A 1% solution in water of the galactomannan according to the invention has a viscosity of approximately at room temperature 3000 mPas on.
Das erfindungsgemäße Polygalactomannan kann aus dem Samen durch die bekannten Schälmethoden zur Abtrennung von Keimling und Schale gewonnen werden. Es kann durch Vermahlung aus dem Endosperm in einfacher Weise freigesetzt werden.The polygalactomannan according to the invention can be obtained from the seed through the well-known peeling methods for separating seedlings and shell are obtained. It can be done by grinding can be released from the endosperm in a simple manner.
Gegenstand der Erfindung ist somit das von Keimling und Schale im wesentlichen freie Polysaccharid aus dem Endosperm des Samens von Prosopis juliflora (Syn.: Prosopis chilensis, Ceratonia chilensis, Mimosa juliflora).The invention thus relates to the seedling and Shell essentially free polysaccharide from the endosperm of the seeds of Prosopis juliflora (syn .: Prosopis chilensis, Ceratonia chilensis, Mimosa juliflora).
Obwohl der Vorteil des erfindungsgemäßen Polysaccharids gerade darin liegt, daß es nicht derivatisiert zu werden braucht, umfaßt die Erfindung selbstverständlich auch dessen Ether- und Esterderivate sowie dessen teilweise depolymerisierten Abkömmlinge.Although the advantage of the polysaccharide according to the invention precisely because it does not get derivatized needs, the invention of course also includes its Ether and ester derivatives and their partially depolymerized Descendants.
Bevorzugte Etherderivate sind die C₁-C₄-Alkylether und die entsprechenden substituierten Alkylether, beispielsweise Carboxy-C₁-C₄-Alkylether und Hydroxy-C₁-C₄-Alkylether. Ein besonders geeignetes Etherderivat ist der Hydroxypropylether. Preferred ether derivatives are the C₁-C₄ alkyl ethers and corresponding substituted alkyl ethers, for example Carboxy-C₁-C₄-alkyl ether and hydroxy-C₁-C₄-alkyl ether. A hydroxypropyl ether is a particularly suitable ether derivative.
Das erfindungsgemäße Polysaccharid kann in an sich bekannter Weise aus dem Samen von Prosopis juliflora gewonnen werden, wobei man das Endosperm freisetzt und dieses vermahlt. Ein besonders reines Produkt erhält man, wenn man das Endosperm freisetzt und mit heißem Wasser extrahiert, den Wasserextrakt filtriert und anschließend das Polysaccharid mit einem Alkohol, insbesondere einem C₁-C₄-Alkohol wie Ethanol oder Isopropanol, ausfällt und trocknet.The polysaccharide according to the invention can be known per se Wise obtained from the seeds of Prosopis juliflora be, whereby the endosperm is released and this is ground. You get a particularly pure product if you the endosperm is released and extracted with hot water, filter the water extract and then the polysaccharide with an alcohol, especially a C₁-C₄ alcohol such as ethanol or isopropanol, precipitates and dries.
Die Herstellung von Derivaten des erfindungsgemäßen Polygalactomannans erfolgt nach an sich bekannter Weise. Übliche Methoden sind beispielsweise in der EP 146 911 beschrieben. Es werden so kaltwasserlösliche, hochviskose Ether- und Esterderivate erhalten.The production of derivatives of the polygalactomannan according to the invention takes place in a manner known per se. Usual Methods are described, for example, in EP 146 911. So it becomes cold water soluble, highly viscous Obtain ether and ester derivatives.
Für manche Verwendungszwecke ist es vorteilhaft, die ursprüngliche Viskosität durch Depolymerisation zu erniedrigen, wodurch Produkte entstehen, die bei gleicher Viskosität der wäßrigen Lösung mehr Masseeinsatz ermöglichen. Die Depolymerisation solcher Polygalactomannane ist an sich bekannt und kann thermisch, oxidativ, hydrolytisch oder enzymatisch durchgeführt werden. Die Erfindung umfaßt auch das Polysaccharid aus dem Endosperm des Samens von Prosopis juliflora in teilweise depolymerisierter Form.For some uses, it is advantageous to use the original one Lower viscosity by depolymerization, which creates products with the same viscosity allow the aqueous solution to use more mass. The Depolymerization of such polygalactomannans is in itself known and can be thermal, oxidative, hydrolytic or be carried out enzymatically. The invention also includes the polysaccharide from the endosperm of the Prosopis seed juliflora in partially depolymerized form.
Die erfindungsgemäßen Polysaccharide sind besonders gut geeignet zur Verwendung als Verdickungsmittel für wäßrige Systeme. So eignen sie sich sehr gut zur Verdickung von Druckpasten im Textildruck, bei der Flotation von Erzen, als Dispergiermittel bei der Papierherstellung und -veredelung, zur Verdickung von Lebensmitteln, zur Verdickung von Bohrflüssigkeiten und zur Aufbereitung von Ölbohrstellen.The polysaccharides according to the invention are particularly good suitable for use as a thickener for aqueous Systems. So they are very suitable for thickening Printing pastes in textile printing, in the flotation of ores, as a dispersing agent in papermaking and finishing, to thicken food, to thicken Drilling fluids and for the preparation of oil wells.
Da die erfindungsgemäßen Polysaccharide gur wasserlöslich sind und daher nicht notwendigerweise derivatisiert werden müssen, weisen sie eine ausgezeichnete biologische Abbaubarkeit auf und sind in dieser Hinsicht den bekannten kaltwasserlöslichen Derivaten von Polysacchariden wie Carboxymethylcellulose, Hydroxypropylguar etc. überlegen. Since the polysaccharides according to the invention are water-soluble are and are therefore not necessarily derivatized they have excellent biodegradability and are in this respect the well-known cold water soluble Derivatives of polysaccharides such as carboxymethyl cellulose, Consider hydroxypropyl guar etc.
Wie andere Galactomannane können auch die erfindungsgemäßen Polygalactomannane mit sogenannten "crosslinkern" Vernetzungsreaktionen eingehen und die Erfindung umfaßt daher auch die solchermaßen vernetzten Produkte. Als "crosslinker" sind insbesondere Borsäure und ihre Salze, sowie Salze und metallorganische Verbindungen von Al, Sb, Cr, Fe, Co, Cu, Mg, Mn, Ni, Ti, V, Zn, Sn, Zr geeignet, die zu besonders starken Vernetzungsreaktionen führen. Im Vergleich zu anderen Polygalactomannanen zeichnen sich die erfindungsgemäßen Polygalactomannane nach solchen Vernetzungsreaktionen in wäßriger Lösung durch eine besonders starke Gelbildung aus.Like other galactomannans, the ones according to the invention can also be used Polygalactomannans with so-called "crosslinkers" crosslinking reactions enter and the invention therefore includes also the products networked in this way. As a "crosslinker" are in particular boric acid and its salts, and salts and organometallic compounds of Al, Sb, Cr, Fe, Co, Cu, Mg, Mn, Ni, Ti, V, Zn, Sn, Zr suitable, too special strong cross-linking reactions. Compared to other polygalactomannans are characterized by the invention Polygalactomannans after such cross-linking reactions in aqueous solution due to particularly strong gel formation out.
Die erfindungsgemäßen Verbindungen besitzen besonders vorteilhafte Eigenschaften bei Anwendung als Verdickungsmittel, z. B. in Druckpasten für den wäßrigen Textildruck und das Kontinuefärben textiler Substrate. Die Druckpasten können substantive Farbstoffe, Säure- und Metallkomplexfarbstoffe, Dispersionsfarbstoffe, basische Farbstoffe u. a. enthalten.The compounds according to the invention have particularly advantageous compounds Properties when used as a thickener, e.g. B. in printing pastes for aqueous textile printing and the continuous dyeing of textile substrates. The printing pastes substantive dyes, acid and metal complex dyes, Disperse dyes, basic dyes and. a. contain.
Der Einsatz als Verdickungsmittel für wäßrige Systeme ist jedoch nicht nur auf Textilhilfsmittel beschränkt. Im Food/Petfood-Bereich können die erfindungsgemäßen Natursubstanzen zum Verdicken benutzt werden. Ihr Anwendungsbereich erstreckt sich auf Verdicker für Klebstoffe, Borspülungen, Papierstreichmassen, Sprengstofflösungen, Pflanzenbehandlungsmittel, für keramische Massen und Fertigputze sowie Flotationshilfsmittel.The use as a thickener for aqueous systems is but not only limited to textile auxiliaries. in the The natural substances according to the invention can be used in the food / petfood sector be used for thickening. Your area of application extends to thickeners for adhesives, boron rinses, Paper coating slips, explosives solutions, plant treatment agents, for ceramic masses and finished plasters as well Flotation aids.
Die erfindungsgemäßen Polysaccharide können, insbesondere bei ihrer Verwendung als Verdickungsmittel, in Abmischung mit anderen Verdickungsmitteln verwendet werden, beispielsweise einem oder mehreren Verdickungsmitteln aus der Gruppe bestehend aus Stärke, Guar, Xanthan, Carrageenan, Agar, Johannisbrotkernmehl, Tara, Honigbohne, Flammenbaum, Sesbania, Cassiarten, Derivaten solcher Polysaccharide wie Alkylether, substituierte Alkylether, Carboxyalkylether und Phosphorsäureester, sowie Poly(meth)acrylaten. The polysaccharides according to the invention can, in particular when used as a thickener, in a mixture can be used with other thickeners, for example one or more thickeners from the group consisting of starch, guar, xanthan, carrageenan, agar, Locust bean gum, tara, honey bean, flame tree, Sesbania, Cassi species, derivatives of such polysaccharides as Alkyl ethers, substituted alkyl ethers, carboxyalkyl ethers and Phosphoric acid esters, and poly (meth) acrylates.
Die Erfindung wird anhand dieser Verwendung in den nachfolgenden Beispielen erläutert.The invention is based on this use in the following Examples explained.
Zwei Küpendruckpasten wurden nachfolgender Rezeptur hergestellt:The following recipe was produced for two vat print pastes:
Stammverdickung:
x g Kombination zweier
Verdickungsmittelpulver
150 g Pottasche
130 g Natrium-formaldehyd-sulfoxylat
60 g Glycerin
y g Wasser
1000 gTrunk thickening:
x g combination of two thickener powders
150 g potash
130 g sodium formaldehyde sulfoxylate
60 g glycerin
y g water
1000 g
Druckpaste:
100 g C. I. Vat-Brown 5
900 g Stammverdickung
1000 gPrinting paste:
100 g CI Vat-Brown 5
900 g trunk thickening
1000 g
Die Stammverdickung I bestand aus einer Verdickungsmittelpulverkombination vonThe stock thickening I consisted of a thickener powder combination from
30 g Carboxymethylstärke
60 g depolymerisiertem Galactomannan
auf Basis Guar30 g carboxymethyl starch
60 g depolymerized guar-based galactomannan
während für die Stammverdickung IIwhile for stem thickening II
30 g Carboxymethylstärke
35 g depolymerisiertes Calactomannan
auf Basis Prosopis30 g carboxymethyl starch
35 g depolymerized calactomannan based on prosopis
kombiniert wurden.were combined.
Trotz der unterschiedlichen Pulverkonzentrationen erbrachten die beiden Stammverdickungen die gleiche Viskosität (Meßgerät: Brookfield RVT - 20°C - 20 UpM - Spindel 4). Despite the different powder concentrations the two stock thickenings have the same viscosity (Measuring device: Brookfield RVT - 20 ° C - 20 rpm - spindle 4).
Der Druckvergleich erfolgte auf Baumwoll-Cretonne mittels einer Rotationsdruckmaschine (System Stork, Typ RD-4).The pressure comparison was made on cotton cretonne using a rotary printing press (System Stork, type RD-4).
Die Fixierung der Drucke wurde im Sattdampf vorgenommen (10 Min. - 102°C).The prints were fixed in saturated steam (10 min. 102 ° C).
Der Vergleich der Drucke, bereitet aus den Stammverdickungen I und II, zeigt, daß bezüglich der Druckkriterien: Farbtiefe, Egalität, Brillanz, Penetration die aus der körperärmeren Stammverdickung II hergestellte Druckpaste gleichen Druckausfall erbrachte wie die aus Stammverdickung I bereitete Druckfarbe.The comparison of the prints, prepared from the thickening of the trunk I and II, shows that regarding the printing criteria: Color depth, levelness, brilliance, penetration from the Lower-body strain thickening II produced printing paste same pressure drop as that from trunk thickening I prepared printing ink.
Für den Druck mit Säurefarbstoffen auf Polyamid-Lycra wurden drei Farbpasten nach folgender Rezeptur bereitet:For printing with acid dyes on polyamide lycra prepares three color pastes according to the following recipe:
15 g C. I. Acid Blue 204
235 g Wasser
50 g Glyecin A® (BASF)
50 g Harnstoff
600 g Verdickungslösung
50 g Ammonsulfat 1 : 2
1000 g15 g CI Acid Blue 204
235 g water
50 g Glyecin A® (BASF)
50 g urea
600 g of thickening solution
50 g ammonium sulfate 1: 2
1000 g
Die Verdickungslösung der Farbpaste 1 wurde 4%ig bereitet, während die Verdickungslösungen 2 und 3 8%ig bereitet werden mußten, um gleiche Viskosität wie Farbpaste 1 aufzuweisen.The thickening solution of color paste 1 was prepared at 4%, while the thickening solutions 2 and 3 had to be prepared at 8% in order to have the same viscosity as color paste 1 .
Die Verdickungslösungen bestanden aus:The thickening solutions consisted of:
Verdickungslösung 1:
depolymerisiertem Galactomannan auf
Basis Prosopis
Verdickungslösung 2:
depolymerisiertem Galactomannan auf
Basis Guar
Verdickungslösung 3:
alkoxyliertem Galactomannan auf Basis
GuarThickening solution 1:
Depolymerized galactomannan based on prosopis
Thickening solution 2:
Depolymerized guar-based galactomannan
Thickening solution 3:
alkoxylated galactomannan based on guar
Gedruckt wurde auf einer Buser Flachdruckmaschine.The printing was done on a Buser flat printing machine.
Die Fixierung der Drucke erfolgte 20 Minuten lang im Sattdampf bei 102°C.The prints were fixed in saturated steam for 20 minutes at 102 ° C.
Im Vergleich der drei Drucke zeigt der mit der erfindungsgemäßen, körperärmeren Verdickung bereitete Druck weniger Frostingeffekt als der mit depolymerisiertem Galactomannan auf Basis Guar abgeschlagene Druck. In der Auswaschbarkeit der Drucke erbrachte der mit Verdickungslösung 1 (erfindungsgemäße Verdickung) bereitete Druck ein ebenso gutes Resultat wie der Druck mit Verdickungslösung 3 (alkoxyliertes Galactomannan auf Basis Guar). Auch in der Brillanz zeigte sich die erfindungsgemäße Verdickung sowohl dem depolymerisierten wie auch dem ethoxyliertem Galactomannan auf Basis Guar überlegen.In comparison of the three prints, the one with the inventive Lower-body thickening caused less pressure Frosting effect than that with depolymerized galactomannan pressure knocked off on guar base. In the washability the prints produced with the thickening solution 1 (invention Thickening) prepared pressure just as well Result like printing with thickening solution 3 (alkoxylated Galactomannan based on guar). Even in brilliance the thickening according to the invention showed both that depolymerized as well as the ethoxylated galactomannan superior based on guar.
Claims (9)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873733234 DE3733234A1 (en) | 1987-10-01 | 1987-10-01 | POLYSACCHARIDES FROM THE ENDOSPERM OF PROSOPIS JULIFLORA SEEDS, METHOD FOR THEIR PRODUCTION AND THEIR USE |
| EP88908153A EP0380528A1 (en) | 1987-10-01 | 1988-09-30 | Polysaccharides from the endosperm of seeds of prosopis juliflora, process for extracting them, and their use |
| PCT/DE1988/000608 WO1989002900A1 (en) | 1987-10-01 | 1988-09-30 | Polysaccharides from the endosperm of seeds of prosopis juliflora, process for extracting them, and their use |
| JP63507556A JPH03500302A (en) | 1987-10-01 | 1988-09-30 | Polysaccharide from the endosperm of Namurinus seeds, its recovery method and its application |
| ES8802986A ES2012125A6 (en) | 1987-10-01 | 1988-09-30 | Polysaccharides from the endosperm of seeds of prosopis juliflora, process for extracting them, and their use. |
| IN942/CAL/88A IN170235B (en) | 1987-10-01 | 1988-11-11 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873733234 DE3733234A1 (en) | 1987-10-01 | 1987-10-01 | POLYSACCHARIDES FROM THE ENDOSPERM OF PROSOPIS JULIFLORA SEEDS, METHOD FOR THEIR PRODUCTION AND THEIR USE |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3733234A1 true DE3733234A1 (en) | 1989-04-13 |
Family
ID=6337412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19873733234 Ceased DE3733234A1 (en) | 1987-10-01 | 1987-10-01 | POLYSACCHARIDES FROM THE ENDOSPERM OF PROSOPIS JULIFLORA SEEDS, METHOD FOR THEIR PRODUCTION AND THEIR USE |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0380528A1 (en) |
| JP (1) | JPH03500302A (en) |
| DE (1) | DE3733234A1 (en) |
| ES (1) | ES2012125A6 (en) |
| IN (1) | IN170235B (en) |
| WO (1) | WO1989002900A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19537616A1 (en) * | 1995-07-25 | 1997-01-30 | Dyckerhoff Ag | Injection agent and injection suspensions prepared using the injection agent |
| DE19630879A1 (en) * | 1996-07-31 | 1998-02-05 | Hanno Lutz Prof Dr Baumann | Production of blood-compatible material, for implants, containers etc. |
| DE19717828A1 (en) * | 1997-04-26 | 1998-10-29 | Arnold Prof Dr Wartenberg | Production of pigments for artists' paint etc. |
| US6033469A (en) * | 1995-07-25 | 2000-03-07 | Dyckerhuff Ag | Injection preparation suspension free of sodium bentonite |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2041391C (en) * | 1990-05-17 | 1999-01-19 | Chung-Wai Chiu | Bulking agents and processes for preparing them from food gums |
| ES2136038B1 (en) * | 1998-02-03 | 2000-07-01 | Consejo Superior Investigacion | DIETARY FIBER CONTAINING GALACTOMANANS. |
| TW200503762A (en) * | 2003-05-09 | 2005-02-01 | Toho Chem Ind Co Ltd | Cation-modified galactomannan polysaccharide and cosmetic composition containing the same |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3347469A1 (en) * | 1983-12-29 | 1985-07-11 | Diamalt AG, 8000 München | Substituted alkyl ethers of Cassia polysaccharides, and the use thereof as thickeners |
-
1987
- 1987-10-01 DE DE19873733234 patent/DE3733234A1/en not_active Ceased
-
1988
- 1988-09-30 ES ES8802986A patent/ES2012125A6/en not_active Expired - Fee Related
- 1988-09-30 WO PCT/DE1988/000608 patent/WO1989002900A1/en not_active Application Discontinuation
- 1988-09-30 EP EP88908153A patent/EP0380528A1/en not_active Withdrawn
- 1988-09-30 JP JP63507556A patent/JPH03500302A/en active Pending
- 1988-11-11 IN IN942/CAL/88A patent/IN170235B/en unknown
Non-Patent Citations (1)
| Title |
|---|
| C.A., Vol.99, 1983, Zitat 193419u * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19537616A1 (en) * | 1995-07-25 | 1997-01-30 | Dyckerhoff Ag | Injection agent and injection suspensions prepared using the injection agent |
| DE19537616C2 (en) * | 1995-07-25 | 1998-01-22 | Dyckerhoff Ag | Sodium bentonite-free injection medium suspension |
| US6033469A (en) * | 1995-07-25 | 2000-03-07 | Dyckerhuff Ag | Injection preparation suspension free of sodium bentonite |
| DE19630879A1 (en) * | 1996-07-31 | 1998-02-05 | Hanno Lutz Prof Dr Baumann | Production of blood-compatible material, for implants, containers etc. |
| DE19717828A1 (en) * | 1997-04-26 | 1998-10-29 | Arnold Prof Dr Wartenberg | Production of pigments for artists' paint etc. |
Also Published As
| Publication number | Publication date |
|---|---|
| IN170235B (en) | 1992-02-29 |
| EP0380528A1 (en) | 1990-08-08 |
| WO1989002900A1 (en) | 1989-04-06 |
| JPH03500302A (en) | 1991-01-24 |
| ES2012125A6 (en) | 1990-03-01 |
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Owner name: DIAMALT GMBH, 8000 MUENCHEN, DE |
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