DE370237C - Process for the protection of animal fibers when treated with alkaline liquids - Google Patents
Process for the protection of animal fibers when treated with alkaline liquidsInfo
- Publication number
- DE370237C DE370237C DEA33877D DEA0033877D DE370237C DE 370237 C DE370237 C DE 370237C DE A33877 D DEA33877 D DE A33877D DE A0033877 D DEA0033877 D DE A0033877D DE 370237 C DE370237 C DE 370237C
- Authority
- DE
- Germany
- Prior art keywords
- alkaline
- dyeing
- protection
- animal
- alkaline liquids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 title claims description 16
- 241001465754 Metazoa Species 0.000 title claims description 11
- 239000007788 liquid Substances 0.000 title claims description 8
- 238000000034 method Methods 0.000 title claims description 5
- 238000004043 dyeing Methods 0.000 claims description 12
- 235000000346 sugar Nutrition 0.000 claims description 10
- 229920002678 cellulose Polymers 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 5
- 239000000988 sulfur dye Substances 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 239000008103 glucose Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims 1
- 210000001367 artery Anatomy 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 9
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- 210000002268 wool Anatomy 0.000 description 8
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 7
- 239000008101 lactose Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000000975 dye Substances 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- 150000008163 sugars Chemical class 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 210000004209 hair Anatomy 0.000 description 4
- 239000010985 leather Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 229920005552 sodium lignosulfonate Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000009992 mercerising Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229960002737 fructose Drugs 0.000 description 2
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000000984 vat dye Substances 0.000 description 2
- 241001479434 Agfa Species 0.000 description 1
- 241000283153 Cetacea Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 208000006558 Dental Calculus Diseases 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 101100316117 Rattus norvegicus Unc50 gene Proteins 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 241001584775 Tunga penetrans Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 238000005517 mercerization Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/53—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/123—Polyaldehydes; Polyketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/055—Cellulose or derivatives thereof with the residual liquors derived of the sulfatic process for the preparation of cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/647—Nitrogen-containing carboxylic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/30—Material containing basic nitrogen containing amide groups furs feathers, dead hair, furskins, pelts
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
Verfahren zum Schutze der tierischen Faser bei der Behandlung mit alkalischen Flüssigkeiten. Durch; das Hauptpaitent 357831 wird ein Verfahren! zum Mercerisieren von halbseidenen und halbwollenen Geweben mit Alkalien unter Zusatz von Sulfitzellulöseabdaugie geschützt. Weiter wurde vorgeschlagen, zum Schutze der tierischen Faser gegen die Schädigungen durch "Alkalien -au-eh in anderen Fällen, z. B. beim Färben, beim Entbasten der Seide; bei beliebiger Behandlung von Fell oder Leder, Sulfitzedlulose zu verwenden.Method for the protection of animal fiber when treated with alkaline liquids. By; the main patent 357831 will be a process! to the Mercerization of semi-silk and semi-woolen fabrics with added alkalis Protected from sulfite cellulose digestion. It was further suggested to protect the animal fiber against the damage caused by "alkalis -au-eh in other cases, z. B. when dyeing, deboning the silk; with any treatment of fur or leather to use sulphite delulose.
Um das Zustandekommen dieser Wirkung aufzuklären, wurde Sulfitzelluloseablauge durch Dialyse in die in ihr enthaltenen kolloiden und, kristalloiden Bestandteile zerlegt, die dann getrennt auf ihre Schutzwirkung geprüft wurden. Hierbei ergab sich überraschenderweise eine ungefähr gleiche Wirkung der beiden Fraktionen, was zu dem Schlüsse führt, daß die Fasersichutzwirkung der Sulfitzelluloseablauge nicht auf dem Vorhandensein einer bestimmten Verbindung, auch nicht ausschließlich auf der Anwesenheit von Kolloiden beruht, sondern sich zusammensetzt aus den Einzelwirkungen der in ihr enthaltenen Kolloide und Zuckerarten. Diese Erkenntnis bildet den Anlaß, die Zuckerarten als Faserschutzmittel zu verwenden. Das kann überall dort geschehen, wo die tierische Faser, wie Wolle, Haare, Federn, Seide, Felle, Pelze, Leder mit alkalischen Flüssigkeiten behandelt wird., wie es z. B. beim Waschen, beim Mercerisieren von Halbwolle oder Halbseide, beim Färben. beim Entbasten der Seide, bei der Veredelung von Fellen, beim Gerben u. dgl. unter Umständen der Fall ist.To explain how this effect came about, sulphite cellulose waste liquor was used by dialysis into the colloidal and crystalloid components it contains disassembled, which were then tested separately for their protective effect. This resulted Surprisingly, the two fractions had roughly the same effect leads to the conclusion that the fiber protection effect of the sulphite cellulose waste liquor is not on the presence of a particular connection, not even exclusively the presence of colloids is based, but is made up of the individual effects the colloids and sugars it contains. This knowledge forms the occasion to use the sugars as fiber preservatives. That can happen anywhere where the animal fiber, such as wool, hair, feathers, silk, hides, furs, leather with alkaline liquids is treated. B. when washing, when mercerising of half wool or half silk, when dyeing. when deboning the silk, when refining it of skins, tanning and the like may be the case.
Tierische Faser in schwefelailkalihaltigem Bade .mit Schwefelfarbstoffen oder aus der alkalischen Küpe in Gegenwart vom Glukose zu färben, ohne die Faser zu zerstören, ist bekannt. Es wurde nun gefunden, daB auch andere Zuckerarten, wie Fruktose, Laktose, Maltose, die tierische 'Faser gegen die zerstörende Wirkung von Alkalisulfiden schützen, und d'aß man allgemein, um die tierische Faser gegen eine Schädigung bei der Behandlung mit alkalischen Flüssigkeiten zu schützen, diesen Zuckerarten zusetzen kann. Man kann die Zucker für sich verwenden oder im Gemisch mit anderen Schutzmitteln, wie etwa ligninsulfosararem Natrium; die Schutzwirkung der Sulfitzelluloseablauge wird durch Zuckerzusatz verstärkt. Beispiel i Waschen der Wolle.Animal fiber in a bath containing sulfuric acid, with sulfur dyes or from the alkaline vat in the presence of glucose to dye without the fiber to destroy is known. It has now been found that other types of sugar, such as Fructose, lactose, maltose, the animal 'fiber against the destructive effects of Protect alkali sulphides, and it is generally accepted that animal fibers are protected against a To protect against damage during treatment with alkaline liquids Can add sugars. You can use the sugars on their own or in a mixture with other protectants such as low-lignosulfosar sodium; the protective effect the sulphite cellulose waste liquor is strengthened by the addition of sugar. example i washing the wool.
Man behandelt unentschw.eißte Walle eine halbe Stunde bei 5o° in einem Bade, welches 8 Prozent kalziniertes Soda, 4Prozent ligninsulfosaures Natrium und 4 Prozent Maltose vom Gewicht derWare enthält, quetscht ab und spült, bis das Wasser klar abläuft. Die Wolle erweist sich als genügend entfettet, ohne daß ihre wertvollen Eigenschaften, -wie Glanz und Elastizität, gelitten haben. In ähnlicher Weise verfährt man, wenn man Maltose allein oder einen anderen Zucker als Faserschutzmittel benutzt.One treats indecisive whales for half an hour at 50 ° in one go Bath, which contains 8 percent soda ash, 4 percent sodium lignosulfonate and Contains 4 percent maltose by weight of the goods, squeezes and rinses until the water runs clearly. The wool proves to be sufficiently degreased without losing its valuable Properties such as gloss and elasticity have suffered. Proceed in a similar way if you use maltose alone or another sugar as a fiber preservative.
Beispiel 2: Gleichzeitiges Mercerisieren der Baumwolle und Entbasten der Seide.Example 2: Simultaneous mercerising of cotton and deboning the silk.
112n setzt dem aus Natronlauge von 240 Be bestehenden Mercerisierbade auf den Liter Flüssigkeit i So bis Zoo g Laktose oder 5 bis ioo g Laktose und 75 bis ioo g IigninsulfosauresNatrium hinzu und mercerisiert das aus Baumwolle uncl Rohseide bestehende Gewebe mittels einiger Passagen auf dein Jigger. Die Baumwolle erleidet keine nennenswerte Schrumpfung, gewinnt aber erhöhte Verwandtschaft zu Farbstoffen. Die Seide wird bei vollständiger Erhaltung ihrer wertvollen Eigenschaften entbastet.112n sets the mercerising bath consisting of caustic soda of 240 Be per liter of liquid i So to Zoo g of lactose or 5 to 100 g of lactose and 75 Add up to 100 g of ligninsulfosauresodium and mercerize the cotton uncl Raw silk existing fabric by means of a few passages on your jigger. The cotton does not suffer any noticeable shrinkage, but gains increased kinship Dyes. The silk is in full preservation of its valuable properties deboned.
Beispiel 3 Färben von Halbwolle mit Schwefelfarbstoffen. Für 3o kg Ware setzt man goo 1 Wasser zur Korrektur zunächst goog kalziniertes Soda hinzu; dann löst man 3 kg Schwefelschwarzbraun \ extra konzentriertes Agfa mit der doppelten Menge kristallisiertem Schwefelnatrium unter Aufkochen auf, gibt die Lösung in das Bad, setzt 12 kg Maltose .oder 8 kg ligninsulfosaures Natrium und 4 kg Maltose und schließlich 27 kg Natriumsulfat kristallisiert hinzu, geht mit der gutgenetztes Ware ein und färbt eine Stunde bei 30 bis _-o=. Die Baumwolle färbt sich hierbei tiefbraun, die Wolle -wird nur spurenweise angefärbt. Zur Erzielung einer seitengleichen Färbung -wird die Wolle hierauf mit Säure-oder Chromfarbstoffen nachgefärbt.Example 3 Dyeing of half wool with sulfur dyes. For 30 kg To correct the goods, goo 1 water is first added to goog calcined soda; then dissolve 3 kg of sulfur black-brown extra concentrated Agfa with twice the amount Amount of crystallized sodium sulphide with boiling, the solution is in the Bath, puts 12 kg of maltose. Or 8 kg of sodium lignosulfonate and 4 kg of maltose and Finally, 27 kg of sodium sulfate crystallized, goes with the well-wetted Goods one and colors one hour at 30 to _-o =. The cotton is colored here deep brown, the wool is only stained in traces. To achieve a match on both sides Dyeing - the wool is then dyed with acid or chrome dyes.
Beispiel 4: Färben von Seide oder Halbseide mit Schwefelfarbstoffen. Das Färben geschieht wie im vorstehenden Beispiel, jedoch bei höherer Temperatur, etwa 5o bis 8o°. Die Farbstoffe ziehen hierbei gut auf Seide; auf Halbseide erhält man fasergleiche Färbungen. Beispiel 5 ,'ärbeti von Wolle oder Seide finit Küpenfarbstoffen in der Hvdrosulfitnatronküpe. Für 251:g Garn: I. Ansatz der Stammküpe.Example 4: Dyeing silk or semi-silk with sulfur dyes. The dyeing is done as in the previous example, but at a higher temperature, about 5o to 8o °. The dyes pull well on silk; on half silk fiber-like dyeings. Example 5, 'arbeti of wool or silk finite vat dyes in the soda sulfite vat. For 251: g of yarn: I. Attachment of the trunk vat.
2,5 kg Indigo rein Pulver oder die entsprechende Menge der Teigmarken. -werden finit 251 Wasser von etwa 6o° angerührt, dann werden 3 1 Natronlauge 40° Be zugesetzt und langsam unter Umrühren 2,5 kg Natriu,m-hydrosulfit konzentriertes Pulver eingestreut. Man erwärmt auf So bis 65° und hält bei dieser Temperatur, bis (in etwa 'j Std.) Lösung eingetreten ist.2.5 kg pure indigo powder or the corresponding amount of the dough brands. - if finitely 251 water of about 60 ° are mixed, then 3 1 sodium hydroxide solution 40 ° Be added and slowly, while stirring, 2.5 kg sodium, m-hydrosulfite concentrated Sprinkled with powder. The temperature is raised to 65 ° and held at this temperature until (about 1 hour) Solution has occurred.
Il. Ansatz der Färbeküpe.Il. Approach of the dye vat.
3 0001 Wasser werden auf 5o° erwärmt, mit 5o ccm Natronlauge 4o° Be und i5o bis aoo g N atriurnhydrosulfit konzentriertes Pulver versetzt, dann gibt man die Stammküpenlösung und schließlich 3o kg Laktose oder 15 kg ligninsulfosaures Natrium und 15 kg Laktose hinzu, geht mit der gut genetzten und geschleuderten Ware ein und färbt eine halbe Stunde bei 5o°. Man quetscht ab, läßt an der Luft oxydieren, spült und trocknet.3,000 l of water are heated to 50 °, with 50 cc of sodium hydroxide solution to 40 ° Be and 150 to 100 g of sodium hydrosulfite concentrated powder are added, then added the stock vat solution and finally 30 kg of lactose or 15 kg of ligninsulfosaures Sodium and 15 kg of lactose are added to the well-wetted and flung goods and stains for half an hour at 5o °. You squeeze, let it oxidize in the air, rinses and dries.
An Stelle von Indigo kann man auch andere Küpenfarbstoffe, wie Küpenrot B, IIelindonbraun, Thioindigoscharlach usw. verwenden. Man beobachtet hierbei nicht nur keine Faserschwächung, sondern infolge des Zuckerzusatzes auch ein Ausbleiben der sonst durch eine überalkalische Küpe hervorgerufenen Übelstände, wie mangelhafte Reib- und Waschechtheit der Färbungen.Instead of indigo you can also use other vat dyes, such as vat red Use B, IIelindon brown, thioindigoscharlach, etc. One does not observe here only no fiber weakening, but also a lack of it due to the addition of sugar the evils otherwise caused by an over-alkaline vat, such as defective ones Rubbing and washing fastness of the dyeings.
Beispiel 6: Sogenanntes Töten der Felle. Die Behandlung der Felle mit alkalischen Flüssigkeiten, um das Grannenhaar aufnahmefähiger für Farbstoffe zu machen, birgt die Gefahr in sich, d'aß das Haar spröde, brüchig und krumm., das Leder hart und weniger zügig wird. Um dies zu vermeiden, setzt man Maltose, Laktose, Lävulose oder andere Zucker, gegebenenfalls neben ligninsulfosaurem Natrium der alkalischen Lösung zu.Example 6: So-called killing of the pelts. Treatment of the skins with alkaline liquids to make the guard hair more receptive to dyes There is a risk that the hair will be brittle, brittle and crooked Leather becomes hard and less swift. To avoid this, maltose, lactose, Levulose or other sugars, optionally in addition to sodium lignosulfonate alkaline solution too.
a) Man löst ioo g Maltose oder 50 g Maltose + So. g ligninsulfosaures -Natrium in 11 Natronlauge i ° BM. Diese Lösung läßt man über Nacht einwirken und wäscht gut aus.a) Dissolve ioo g maltose or maltose + 50 g So. ligninsulfosaures g Sodium hydroxide solution in 1 1 i ° BM. This solution is left to act overnight and washed off well.
b) Die Felle werden in eine Lösung gelegt, bestehend aus io g kalziniertem Soda, 15 g L aktose und 15 g ligninsulfosaurern Natrium auf den Liter Wasser. Hierin bleiben sie 3 Stunden bei 35 bis 4o°, dann werden sie gut gespült, mit verdünnter Essigsäure abgesäuert und nochmals gespült.b) The pelts are placed in a solution consisting of 10 g of calcined soda, 15 g of lactose and 15 g of sodium lignosulfonate per liter of water. Here they stay for 3 hours at 35 to 40 °, then they are rinsed well, acidified with dilute acetic acid and rinsed again.
" Beispiel 7: Färben von Fellen."Example 7: dyeing of fur.
Die gemäß vorigem Beispiel getöteten Felle werden nach dem Spülen 6 .Stunden mit 2 g Kaliumbichromat, I g Weinstein, 0,25 g Kupfersulfat im Liter Wasser vorgebeizt. Nach gutem Spülen kommen sie für q. Stunden in das Färbebart, welches auf 11 Wasser 2,5 g Ursol P, o,5 g Ursol D, 2,5 ccm Ammoniak, 25prozentig, 6o ccm Wasserstoffsuperoxyd, 3prozentig, 0,75 g Maltose, 0,75 g ligninsulfosaures Natrium enthält. Die Felle werden nach dem Färben gespült, getrocknet und geläutert. Die wertvollen Eigenschaften des Haares und des Leders bleiben erhalten.The pelts killed according to the previous example are pre-pickled after rinsing for 6 hours with 2 g of potassium dichromate, 1 g of tartar, 0.25 g of copper sulfate per liter of water. After a good rinse, they come for q. Hours in the Färbebart which g in 1 1 water 2.5 Ursol P, o, 5 g Ursol D, 2.5 cc of ammonia, 25prozentig, 6o cc hydrogen peroxide, 3prozentig, 0.75 g of maltose, 0.75 g of sodium ligninsulfosaures contains. After dyeing, the skins are rinsed, dried and refined. The valuable properties of the hair and leather are retained.
Claims (1)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEA33877D DE370237C (en) | 1920-08-04 | 1920-08-04 | Process for the protection of animal fibers when treated with alkaline liquids |
| GB3377/21A GB183868A (en) | 1920-08-04 | 1921-01-27 | Process for protecting animal fibres in treating them with alkaline liquids |
| NL18035A NL9332C (en) | 1920-08-04 | 1921-02-14 | |
| FR538492D FR538492A (en) | 1920-08-04 | 1921-07-19 | Process for protecting animal fiber against the harmful influence of alkaline solutions |
| US492492A US1419497A (en) | 1920-08-04 | 1921-08-15 | Method of protecting animal fibers from the injurious effect of alkaline liquids |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEA33877D DE370237C (en) | 1920-08-04 | 1920-08-04 | Process for the protection of animal fibers when treated with alkaline liquids |
| GB3377/21A GB183868A (en) | 1920-08-04 | 1921-01-27 | Process for protecting animal fibres in treating them with alkaline liquids |
| NL18035A NL9332C (en) | 1920-08-04 | 1921-02-14 | |
| FR538492T | 1921-07-19 | ||
| US492492A US1419497A (en) | 1920-08-04 | 1921-08-15 | Method of protecting animal fibers from the injurious effect of alkaline liquids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE370237C true DE370237C (en) | 1923-03-01 |
Family
ID=40454709
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEA33877D Expired DE370237C (en) | 1920-08-04 | 1920-08-04 | Process for the protection of animal fibers when treated with alkaline liquids |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US1419497A (en) |
| DE (1) | DE370237C (en) |
| FR (1) | FR538492A (en) |
| GB (1) | GB183868A (en) |
| NL (1) | NL9332C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE743564C (en) * | 1934-01-12 | 1943-12-29 | Oranienburger Chem Fab Ag | Process for dyeing raw vegetable fibers with substantive dyes using fiber-disintegrating agents at the boiling point |
| US2730428A (en) * | 1950-10-21 | 1956-01-10 | Tepha Ges Fur Pharmazeutische | Method and composition for washing and bleaching fibrous materials |
| US3005677A (en) * | 1956-03-15 | 1961-10-24 | Bayer Ag | Oxidation dyeings and prints |
-
1920
- 1920-08-04 DE DEA33877D patent/DE370237C/en not_active Expired
-
1921
- 1921-01-27 GB GB3377/21A patent/GB183868A/en not_active Expired
- 1921-02-14 NL NL18035A patent/NL9332C/xx active
- 1921-07-19 FR FR538492D patent/FR538492A/en not_active Expired
- 1921-08-15 US US492492A patent/US1419497A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US1419497A (en) | 1922-06-13 |
| NL9332C (en) | 1923-07-16 |
| FR538492A (en) | 1922-06-10 |
| GB183868A (en) | 1922-07-27 |
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