DE3027472C2 - Gold-containing preparation for coating metallic parts - Google Patents
Gold-containing preparation for coating metallic partsInfo
- Publication number
- DE3027472C2 DE3027472C2 DE3027472A DE3027472A DE3027472C2 DE 3027472 C2 DE3027472 C2 DE 3027472C2 DE 3027472 A DE3027472 A DE 3027472A DE 3027472 A DE3027472 A DE 3027472A DE 3027472 C2 DE3027472 C2 DE 3027472C2
- Authority
- DE
- Germany
- Prior art keywords
- gold
- powder
- metal
- binder
- preparations
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
- C23C24/082—Coating starting from inorganic powder by application of heat or pressure and heat without intermediate formation of a liquid in the layer
- C23C24/085—Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
- C23C24/087—Coating with metal alloys or metal elements only
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/84—Preparations for artificial teeth, for filling teeth or for capping teeth comprising metals or alloys
- A61K6/844—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/0466—Alloys based on noble metals
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Epidemiology (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Powder Metallurgy (AREA)
- Dental Preparations (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Dental Prosthetics (AREA)
Description
Aufbrenntemperatur unter der Schmelz- bzw. Solidustemperatur der metallischen Pulverzusätze liegt. Bewährt haben sich Aufbrenntemperaturen zwischen 600 und 11000C und Aufbrennzeiten zwischen 0,5 und 10 Minuten. Die Goldschichten verbinden sich unter diesen Bedingungen mit allen gängigen Aufbrennlegierungen auf der Basis Gold-Platin-Palladium-Silber, Gold-Silber, Gold-Palladium, Nickel-Chrom, Kobalt-Chrom und Kobalt-Palladium zu einem unlösbaren Verbund. Die erfindungsgemäßen goldhaltigen Präparate sind damit für alle edelmetallhaltigen und edelmetallfreien Aufbrennlegierungen geeignetFiring temperature is below the melting or solidus temperature of the metallic powder additives. Firing temperatures between 600 and 1100 0 C and firing times between 0.5 and 10 minutes have proven to be effective. Under these conditions, the gold layers bond to all common bonding alloys based on gold-platinum-palladium-silver, gold-silver, gold-palladium, nickel-chromium, cobalt-chromium and cobalt-palladium to form an indissoluble bond. The gold-containing preparations according to the invention are therefore suitable for all bonding alloys containing and without precious metals.
Die so hergestellte Zwischenschicht bewirkt eine sehr gute Verankerung der Keramikschicht mit dem metallischen Kronen- oder Brückenteil. Hierzu eignen sich eile is bekannten dentalkeramischen Massen Biegeversuche an keramikverblendeten Legierungsblechen, die mit einer Zwischenschicht aus einem erfindungsgemäßen Goldpräparat überzogen waren, zeigten, daß bei gewaltsamer Absprengung der Keramikschicht vom Metall der Bruch in der Keramik selbst erfolgt Eine Trennung der Zwischenschicht von der Aufbrennlegierung bzw. von der Keramik konnte in keinem Fall beobachtet werden.The intermediate layer produced in this way ensures very good anchoring of the ceramic layer to the metal crown or bridge part. All known dental ceramic materials are suitable for this. Bending tests on ceramic-faced alloy sheets that were coated with an intermediate layer made of a gold preparation according to the invention showed that if the ceramic layer is violently detached from the metal, the fracture occurs in the ceramic itself. A separation of the intermediate layer from the bonding alloy or from the ceramic could not be observed in any case.
Im folgenden sind beispielhaft die Zusammensetzun- 2s gen einiger erfindungsgemäßen goldhaltigen Präparate angegeben:The following are examples of the compositions of some gold-containing preparations according to the invention:
1. 75% Goldpulver, kristallin. Teilchengröße <10&mgr;&eegr;&igr; 5% Pulver aus Palladiumlegierung mit 20% Gold und 5% Zinn, Teilchengröße < 20 &mgr;&pgr;&igr;1. 75% gold powder, crystalline. Particle size <10 μηι 5% powder of palladium alloy with 20% gold and 5% tin, particle size <20 μηι 15% Butyldiglycolacetat 5% Polymethylmethacrylat.15% butyl diglycol acetate 5% polymethyl methacrylate.
2. 65% Goldpulver, kristallin, Teilchengröße <10&mgr;&eegr;&igr;2. 65% gold powder, crystalline, particle size <10μηι
10% Pulver aus Goldlegierung mit 10% Platin, 3% Zinn und 2% Indium, Teilchengröße <37 &mgr;&pgr;&igr; 18% Butyldiglycolacetat10% gold alloy powder with 10% platinum, 3% tin and 2% indium, particle size <37 μια 18% butyl diglycol acetate
7% Äthylzellulose7% ethyl cellulose 3.70% Goldpulver, kristallin, < 10 &mgr;&pgr;&igr; 10% Palladiumpulver, <37 &mgr;&pgr;&igr; 15%Terpineol 5% Nitrozellulose3.70% gold powder, crystalline, < 10 μια 10% palladium powder, <37 μια 15% terpineol 5% nitrocellulose
4.40% Goldpulver, kristallin, < 10 &mgr;&pgr;&igr;4.40% gold powder, crystalline, < 10 μαι 35% Goldpulver, plättchenförmig, < 10 &mgr;&pgr;&igr; 5% Kobaltpulver35% gold powder, platelet-shaped, < 10 μιγ 5% cobalt powder
16% Hochsiedender aliphatischer Kohlenwasserstoff16% High boiling aliphatic hydrocarbon
4% Polyisobutylen4% polyisobutylene 5.50% Goldpulver, kristallin, < 10 &mgr;&pgr;&igr; 25% Goldpulver, plättchenförmig, < 10 &mgr;&pgr;&igr; 5% Pulver aus einer Kobaltlegierung mit 27% Cr, 5,5% Mo, 1 % Si10,7% Mn und 0,5% Fe, < 37 &mgr;&pgr;&igr; 15%Terpineol5.50% gold powder, crystalline, < 10 μια 25% gold powder, platelet-shaped, < 10 μια 5% powder from a cobalt alloy with 27% Cr, 5.5% Mo, 1% Si 1 0.7% Mn and 0.5% Fe, < 37 μια 15% terpineol
5% Äthylzellulose5% ethyl cellulose
6060
b5b5
Claims (6)
Aufbrennlegierungen in der Dentaltechnik vor dem 5 Andererseits ist seit langem auch die Bedeutung einer Verblenden mit keramischen Massen, bestehend hinreichenden Verzahnung zwischen den metallischen aus Goldpulver, einem Haftmittel und einem bei Aufbrennlegierungen und der Dentalkeramik für einen Raumtemperatur flüssigen, bei Brenntemperatur guten Verbund bekannt Gerade der Anteil der sogesich verflüchtigenden oder verbrennenden Binde- nannten physikalischen Bindung hängt sehr stark von mittel aus einem oder mehreren organischen Lö- io der Größe, der Gestaltung und der Rauhigkeit der mit sungsmitteln und einem oder mehreren Harzbe- der Keramik zu verbindenden Oberfläche ab.
standteilen, dadurch gekennzeichnet, daß es aus Aus der DE-OS 25 25 274 ist es bekannt, goldhaltige 50 bis 94 Gew.-°/o Goldpulver mit einer Teilchen- Präparate zu verwenden, die neben Goldpulver und eigröße kleiner 30 &mgr;&pgr;&igr;, 5 bis 40 Gew.-% Bindemitteln nem Flußmittel noch Porzellan- und Zirkoniumoxidpul- und 1 bis 20Gew.-% eines Metallpuivers als Haft- 15 ver sehr kleiner Korngrößen enthalten. Dieses Präparat mittel besteht, dessen Teilchengröße größer als die führt jedoch beim Einbrennen auf die Aufbrennlegiedes verwendeten Goldpulvers ist und dessen rung zu einer unästhetischen grauweißen Schicht
Schmelztemperatur über der des Goldes liegt. Es war daher Aufgabe der Erfindung, goldhaltige Prä-1. Gold-containing preparation for coating metallic parts, in particular for coating metals.
Ceramic bonding alloys in dental technology before 5 On the other hand, the importance of sufficient interlocking between the metallic ceramics and the dental ceramics for a good bond has long been known for veneering with ceramic masses consisting of gold powder, an adhesive and a binding agent made of one or more organic solvents and one or more resin coatings. The proportion of the so-called physical bond depends very strongly on the size, shape and roughness of the surface to be bonded to the ceramic.
From DE-OS 25 25 274 it is known to use preparations which, in addition to gold powder and a flux, also contain porcelain and zirconium oxide powder and 1 to 20% by weight of a metal powder as an adhesive, the particle size of which is larger than that of the gold powder used and which, however, leads to an unaesthetic grey-white layer when fired onto the firing alloy.
melting temperature is higher than that of gold. The aim of the invention was therefore to produce gold-containing
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3027472A DE3027472C2 (en) | 1980-07-19 | 1980-07-19 | Gold-containing preparation for coating metallic parts |
CH4720/81A CH653249A5 (en) | 1980-07-19 | 1981-07-17 | Gold-containing product for coating metallic components |
JP11238881A JPS5741372A (en) | 1980-07-19 | 1981-07-20 | Gold containing preparation for coating metal part |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3027472A DE3027472C2 (en) | 1980-07-19 | 1980-07-19 | Gold-containing preparation for coating metallic parts |
Publications (2)
Publication Number | Publication Date |
---|---|
DE3027472A1 DE3027472A1 (en) | 1982-02-25 |
DE3027472C2 true DE3027472C2 (en) | 1987-02-19 |
Family
ID=6107642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE3027472A Expired DE3027472C2 (en) | 1980-07-19 | 1980-07-19 | Gold-containing preparation for coating metallic parts |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPS5741372A (en) |
CH (1) | CH653249A5 (en) |
DE (1) | DE3027472C2 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4466830A (en) * | 1982-11-19 | 1984-08-21 | E. I. Du Pont De Nemours And Company | Thick film gold metallization composition |
DE3733828A1 (en) * | 1987-10-07 | 1989-04-20 | Kerstin Koerber | Composite material for dental and denture restoration |
DE3811628A1 (en) * | 1988-04-07 | 1989-10-19 | Heraeus Edelmetalle Gmbh | METHOD FOR PRODUCING SINTERED METAL SPARE PARTS |
DE4000302C1 (en) * | 1990-01-08 | 1991-07-25 | Degussa Ag, 6000 Frankfurt, De | |
JPH0629415U (en) * | 1992-09-28 | 1994-04-19 | 有限会社内藤貴金属製作所 | earrings |
US5674293A (en) * | 1996-01-19 | 1997-10-07 | Implant Sciences Corp. | Coated orthopaedic implant components |
US5980974A (en) * | 1996-01-19 | 1999-11-09 | Implant Sciences Corporation | Coated orthopaedic implant components |
US5855950A (en) * | 1996-12-30 | 1999-01-05 | Implant Sciences Corporation | Method for growing an alumina surface on orthopaedic implant components |
GB9928069D0 (en) * | 1999-11-29 | 2000-01-26 | Johnson Matthey Plc | Liquid compositions |
FR2832427B1 (en) * | 2001-11-16 | 2004-03-19 | A R V | PROCESS FOR THE SURFACE TREATMENT OF TITANIUM AND ITS ALLOYS, PRODUCTS OBTAINED, AND DENTAL APPLICATIONS |
-
1980
- 1980-07-19 DE DE3027472A patent/DE3027472C2/en not_active Expired
-
1981
- 1981-07-17 CH CH4720/81A patent/CH653249A5/en not_active IP Right Cessation
- 1981-07-20 JP JP11238881A patent/JPS5741372A/en active Granted
Non-Patent Citations (1)
Title |
---|
NICHTS-ERMITTELT |
Also Published As
Publication number | Publication date |
---|---|
JPS5741372A (en) | 1982-03-08 |
DE3027472A1 (en) | 1982-02-25 |
JPH029112B2 (en) | 1990-02-28 |
CH653249A5 (en) | 1985-12-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8110 | Request for examination paragraph 44 | ||
D2 | Grant after examination | ||
8364 | No opposition during term of opposition | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: DEGUSSA-HUELS AG, 60311 FRANKFURT, DE |
|
8339 | Ceased/non-payment of the annual fee |