DE2231148A1 - LAUGATING AND MERCERIZING SOLUTIONS - Google Patents
LAUGATING AND MERCERIZING SOLUTIONSInfo
- Publication number
- DE2231148A1 DE2231148A1 DE2231148A DE2231148A DE2231148A1 DE 2231148 A1 DE2231148 A1 DE 2231148A1 DE 2231148 A DE2231148 A DE 2231148A DE 2231148 A DE2231148 A DE 2231148A DE 2231148 A1 DE2231148 A1 DE 2231148A1
- Authority
- DE
- Germany
- Prior art keywords
- carbon atoms
- branched
- hydrocarbon radical
- sodium
- potassium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 25
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 12
- 238000009992 mercerising Methods 0.000 claims description 11
- 239000000080 wetting agent Substances 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 239000003518 caustics Substances 0.000 claims description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 8
- 229940042400 direct acting antivirals phosphonic acid derivative Drugs 0.000 claims description 6
- 150000003007 phosphonic acid derivatives Chemical class 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 229920003043 Cellulose fiber Polymers 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 3
- 239000002657 fibrous material Substances 0.000 claims 2
- 238000002386 leaching Methods 0.000 claims 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
- 230000010181 polygamy Effects 0.000 claims 1
- 238000003307 slaughter Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 239000012670 alkaline solution Substances 0.000 description 5
- 238000009736 wetting Methods 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000005259 measurement Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- OLPKZJLYSYEWBZ-UHFFFAOYSA-L P([O-])([O-])=O.CCCCCCCC.[Na+].[Na+] Chemical compound P([O-])([O-])=O.CCCCCCCC.[Na+].[Na+] OLPKZJLYSYEWBZ-UHFFFAOYSA-L 0.000 description 2
- HRKAMJBPFPHCSD-UHFFFAOYSA-N Tri-isobutylphosphate Chemical compound CC(C)COP(=O)(OCC(C)C)OCC(C)C HRKAMJBPFPHCSD-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- -1 for example Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005517 mercerization Methods 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- MVVQNBYRSDXHRF-UHFFFAOYSA-N 2-[2-hydroxyethyl(2-methylpropyl)amino]ethanol Chemical compound CC(C)CN(CCO)CCO MVVQNBYRSDXHRF-UHFFFAOYSA-N 0.000 description 1
- GVNHOISKXMSMPX-UHFFFAOYSA-N 2-[butyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCN(CCO)CCO GVNHOISKXMSMPX-UHFFFAOYSA-N 0.000 description 1
- WQTSXVADWPDOHU-UHFFFAOYSA-N CCCCCCCCCCOP(O)OCC(C)C Chemical compound CCCCCCCCCCOP(O)OCC(C)C WQTSXVADWPDOHU-UHFFFAOYSA-N 0.000 description 1
- HFRKLNSULXENNL-UHFFFAOYSA-L P([O-])([O-])=O.C(C)CCCCCCCC.[Na+].[Na+] Chemical compound P([O-])([O-])=O.C(C)CCCCCCCC.[Na+].[Na+] HFRKLNSULXENNL-UHFFFAOYSA-L 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- ZLMKQJQJURXYLC-UHFFFAOYSA-N bis(2-ethylhexoxy)-oxophosphanium Chemical compound CCCCC(CC)CO[P+](=O)OCC(CC)CCCC ZLMKQJQJURXYLC-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000009993 causticizing Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- CIBKDFOCUKQUGT-UHFFFAOYSA-N di(icosoxy)-oxophosphanium Chemical compound CCCCCCCCCCCCCCCCCCCCO[P+](=O)OCCCCCCCCCCCCCCCCCCCC CIBKDFOCUKQUGT-UHFFFAOYSA-N 0.000 description 1
- KDFMYTBUQJDSOY-UHFFFAOYSA-N didocosyl hydrogen phosphite Chemical compound CCCCCCCCCCCCCCCCCCCCCCOP(O)OCCCCCCCCCCCCCCCCCCCCCC KDFMYTBUQJDSOY-UHFFFAOYSA-N 0.000 description 1
- XFUSKHPBJXJFRA-UHFFFAOYSA-N dihexyl hydrogen phosphite Chemical compound CCCCCCOP(O)OCCCCCC XFUSKHPBJXJFRA-UHFFFAOYSA-N 0.000 description 1
- BAKDLAFAVHBXHW-UHFFFAOYSA-N dioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP([O-])OCCCCCCCCCCCCCCCCCC BAKDLAFAVHBXHW-UHFFFAOYSA-N 0.000 description 1
- NFORZJQPTUSMRL-UHFFFAOYSA-N dipropan-2-yl hydrogen phosphite Chemical compound CC(C)OP(O)OC(C)C NFORZJQPTUSMRL-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000000622 irritating effect Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- LUDZNSYVABYULG-UHFFFAOYSA-N propyl tetradecyl hydrogen phosphite Chemical compound CCCCCCCCCCCCCCOP(O)OCCC LUDZNSYVABYULG-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/288—Phosphonic or phosphonous acids or derivatives thereof
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment Of Fiber Materials (AREA)
Description
FARBWERKE HOECHST AG voriaals Meister Lucius & Brüning Aktenzeichen: - HOE 72/F 185 2231148 FARBWERKE HOECHST AG previously as master Lucius & Brüning file number: - HOE 72 / F 185 2231148
Datum: 20. Juni 1972 Dr. Gr/stl Laugier- und MercerisierlösungenDate: June 20, 1972 Dr. Gr / stl caustic and mercerising solutions
Beim Mercerisieren und Laugieren wirken Alkalilaugen, deren Stärke den Erfordernissen angepaßt wird, auf die Ware ein. Damit der Vorgang möglichst rasch abläuft und eine kontinuierliche und rationelle Arbeitsweise gestattet, ist es notwendig, daß die Ware schnell und gleichmäßig mit der alkalischen Lösung durchtränkt wird. Zu diesem Zweck setzt man den Lösungen Netsmittel zu. Solche Netzmittel sollen leicht löslich in der Lauge sein, in kürzester Zeit die maximale Schrumpfung der Cellulosefaser bewirken und auch nach längerer Lagerung der Laugen gelöst bleiben.During mercerization and causticizing, alkaline solutions, the strength of which is adapted to the requirements, act on the goods. In order to the process runs as quickly as possible and allows a continuous and efficient way of working, it is necessary that the goods is soaked quickly and evenly with the alkaline solution. For this purpose, wetting agents are added to the solutions. Such Wetting agents should be easily soluble in the lye, bring about maximum shrinkage of the cellulose fiber in the shortest possible time and remain dissolved even after prolonged storage.
So ist es bekannt, Alkylsulfate, Alkansulfonate, Alkylaryj.su 1— fonate, Ligninsulfonsäuren, sulfierte Terpenabkömmlinge, alkylierte Naphthalinsulfonsäuren und ähnliche Verbindungen als Netzmittel in Mercerisierlaugen einzusetzen. Ferner "wird in der deutschen Auslegeschrift 1 01*1 O67 die Anwendung von-Gemischen von solchen Mono- und Polysulfonsäuren oder ihren Salzen in Mercerisier- und Laugierbädern beschrieben. Diese Verbindungen wurden durch Sulfochlorierung von aliphatischen oder cycloaliphatischen Kohlenwasserst<fffen mit 10 bis 20 Kohlenstoffatomen gewonnen.Thus it is known to use alkyl sulfates, alkanesulfonates, alkylaryj.su 1— phonates, lignosulfonic acids, sulfated terpene derivatives, alkylated naphthalenesulfonic acids and similar compounds to be used as a wetting agent in mercerising liquors. Furthermore "in the German Auslegeschrift 1 01 * 1 O67 the use of mixtures of such mono- and polysulfonic acids or their salts in mercerizing and caustic baths. These Compounds were made by sulfochlorination of aliphatic or cycloaliphatic hydrocarbons with 10 to 20 Obtained carbon atoms.
üblicherweise werden die Netzmittel mit anderen Hilfsstoffen kombiniert, welche die bei der Mercerisierung von der Faser abgelösten Produkte, wie z.B. Celluloseabbauverbindungen oder Reste von Schlichten, dispergieren und in der Schwebe halten. Gleichzeitig wirken diese Hilfsstoffe synergistisch auf das Netzvermögen der Netzmittel ein. Bekannt ist die Anwendung von niedermolekularen Alkoholen, wie z.B. Isopropanol, Butanolen, Alkanolaminen, Glykolen und deren Derivaten, PolyglykolenThe wetting agents are usually combined with other auxiliaries which disperse the products detached from the fiber during the mercerization, such as cellulose degradation compounds or residues of sizes, and keep them in suspension. At the same time, these auxiliaries have a synergistic effect on the wetting properties of the wetting agents. The use of low molecular weight alcohols, such as, for example, isopropanol, butanols, alkanolamines, glycols and their derivatives, polyglycols, is known
309885/1184309885/1184
und anderen Verbindungen, die unter anderem in Lindner '!Tenside, Textilhilfsmittel, Waschrohstoffe", Bd. II, 196^9- Seiten 1476 bis 1^78 beschrieben sind.and other connections, including in Lindner ' ! Surfactants, textile auxiliaries, washing raw materials ", Vol. II, 196 ^ 9 - pages 1476 to 1 ^ 78 are described.
Die bisher gebräuchlichen Produkte erfüllen nicht alle Erfordernisse der Praxis zu gleicher Zeit. Entweder sie benetzen die Paser sehr schnell, müssen dann jedoch in höheren Konzentrationen angewendet werden, oder sie sind in den alkalischen Lösungen nicht ausreichend langzeitstabil, verlieren ihre Wirksamkeit oder fallen aus. In vielen Fällen stört ferner ihr starkes Schäumen.The products in use up to now do not meet all practical requirements at the same time. Either them wet the pasers very quickly, but then have to be used in higher concentrations or they are in the alkaline ones Solutions do not have sufficient long-term stability, lose their effectiveness or fail. In many cases it is also annoying their strong foaming.
Es wurde nun gefunden, daß Laugier- und Mercerisierlösungen mit hervorragender Hetzwirkung und hoher Beständigkeit erhalten werden, wenn diesen Lösungen, die 10 bis *J00 g/l Natrium-, · Kalium- oder Lithiumhydroxid oder Gemische dieser Alkalien enthalten, als Netzmittel 1 bis 5 g/l von Phosphonsäurederivaten der allgemeinen FormelIt has now been found that caustic and mercerising solutions with excellent irritant effect and high resistance can be obtained if these solutions containing 10 to * J00 g / l sodium, · Potassium or lithium hydroxide or mixtures of these alkalis contain 1 to 5 g / l of phosphonic acid derivatives as wetting agents the general formula
R einen aliphatischen unverzweigten, verzweigten oder cyclischen Kohlenwasserstoffrest mit 6 bis 10 C-Atomen und X und Y Wasserstoff, Natrium, Kalium oder einen aliphatischen unverzweigten oder verzweigten Wasserstoffrest mit 1 bis *J C-Atomen bedeuten, wobei X und Y verschieden oder gleich sein können, zugesetzt werden.R is an aliphatic unbranched, branched or cyclic one Hydrocarbon radical with 6 to 10 carbon atoms and X and Y hydrogen, sodium, potassium or an aliphatic unbranched or branched hydrogen radicals with 1 to * J C atoms mean where X and Y can be different or the same, are added.
Die erfindungsgemäß als Netzmittel zu verwendenden Phosphonsäurederivate können mit besonderem Vorteil nach dem Verfahren der deutschen Offenlegungsschriften 1 963 011I und 2 043 520 hergestellt werden. Danach werden Alk&nphoaphonsäurediester der allgemeinen FormelAccording to the invention as a wetting agent to be used can phosphonic acid 1963 01 1 I and 2,043,520 are prepared particularly advantageously by the process of German Offenlegungsschriften Nos. Thereafter, alkaphonic acid diesters are of the general formula
309885/1184309885/1184
BAD ORIGINALBATH ORIGINAL
2231H82231H8
worin R1 eine Alkylgruppe mit 2 bis 22 C-Atomen und R? und R Alkylgruppen mit 1 bis 22 C-Atomen bedeuten durch Addition von · -Olefinen mit 2 bis 22 C-Atomen an Dialkylphosphite der allgemeinen Formelwherein R 1 is an alkyl group with 2 to 22 carbon atoms and R ? and R denotes alkyl groups having 1 to 22 carbon atoms by addition of · olefins having 2 to 22 carbon atoms onto dialkyl phosphites of the general formula
hergestellt.manufactured.
R„ und R, haben die obengenannte Bedeutung.R "and R, have the meaning given above.
PiIr die Umsetzung kommen als Dialkylphosphite beispielsweise in Betracht: Diinethylphosphit, Diäthylptiosphit, Diisopropylphosphit, Di-n-hexylphosphit,.Di-2-äthyl-hexylphosphit, Decyl-isobutylphosphit, Propyl-tetradecylphosphit, Dioctadecylphosphit, Dieicosylphosphit und Didocosylphosphit.PiIr the implementation come as dialkyl phosphites, for example Consideration: diethyl phosphite, diethyl phosphite, diisopropyl phosphite, Di-n-hexyl phosphite, di-2-ethyl-hexyl phosphite, decyl isobutyl phosphite, Propyl tetradecyl phosphite, dioctadecyl phosphite, Dieicosyl phosphite and didocosyl phosphite.
Aus den Alkanphosphon3äurediestern kann man nach bekannten Methoden die Salze oder Säuren herstellen. ■From the alkanephosphonic acid diesters one can use known Methods that produce salts or acids. ■
Die gemäß der Erfindung zu verwendenden Phosphonsaurederivate sind leicht und klar löslich und besitzen im alkalischen Bereich ein so hervorragendes Netzvermögen, daß gegenüber herkömmlichen NetzinitteIn mit geringeren Einsatzmengen gearbeitet werden kann. Die Anwendungskonzentrationen liegen zwischen 1 und 5 g/l Laugier- oder Mercerisierlösung. Dadurch sind, diese Verbindungen nicht nur sehr wirtschaftlich, sondern belasten auch# das Abwasser kaum. Außerdem bilden die erfindungsgemäß zu verwendenden Phosphonsaurederivate in den alkalischen Lösungen praktisch keinen Schaum. Das Netzvermögen verringert sich auch bei Lagerung der alkalischen Lösungen nicht. Ein bevorzugtesThe phosphonic acid derivatives to be used according to the invention are readily and clearly soluble and have such excellent wetting properties in the alkaline range that smaller amounts can be used compared with conventional wetting agents. The application concentrations are between 1 and 5 g / l caustic or mercerising solution. Thus, these compounds are not only very economical, but also burden the sewage # little. In addition, the phosphonic acid derivatives to be used according to the invention form practically no foam in the alkaline solutions. The wetting power does not decrease even when the alkaline solutions are stored. A preferred one
0 9 8 8 5/1184 bad ORIGINAL0 9 8 8 5/1184 bad ORIGINAL
2231H82231H8
Anwendungsgebiet sind Mercerisierlaugen, die einen hohen Gehalt von etwa 150 bis 300 g, vorzugsweise 200 bis 250 g Natrium-, Kalium- oder Lithiumhydroxid oder Gemische dieser Alkalien pro Liter aufweisen.It is used in mercerising liquors which have a high content of about 150 to 300 g, preferably 200 to 250 g of sodium, potassium or lithium hydroxide or mixtures of these alkalis per liter.
Durch die an sich bekannten Zusätze von niederen Alkoholen z.B. Isopropanol oder Butanol, oder Alkanolamine^ wie z.B. Butyldiäthanolamin kann eine weitere Verbesserung des Netzvermögens erreicht werden.Through the per se known additions of lower alcohols e.g. isopropanol or butanol, or alkanolamines ^ such as e.g. Butyl diethanolamine can further improve wetting properties can be achieved.
Die Zusammensetzung der Laugier- und Mercerisierlösungen, in denen die erfindungsgemäße Anwendung der Phosphonsäurederivate erfolgt, ist an sich bekannt. Die Lösungen enthalten im allgemeinen 10 bi3 1IOO g Natrium-, Kalium- oder Lithiumhydroxid oder Gemische dieser Alkalien im Liter und erforderlichenfalls die üblichen Hilfsstoffe; sie werden bei Temperaturen zwischen etwa 0 und 25°C verwendet. Betreffend ihrer weiteren Zusammensetzung sei auf Lindner, "Tenside, Textilhilfsmittel, Waschrohstofffe", Band II 196*1, Seiten 1176 bis 1478, sowie Ullmanne Encyclopädie der technischen Chemie, 3« Auflage Band 17, 1966, Seiten 176 bis 177 verwiesen. The composition of the caustic and mercerising solutions in which the phosphonic acid derivatives are used according to the invention is known per se. The solutions generally contain 10 to 1 100 g of sodium, potassium or lithium hydroxide or mixtures of these alkalis per liter and, if necessary, the usual auxiliaries; they are used at temperatures between about 0 and 25 ° C. With regard to their further composition , reference is made to Lindner, "Tenside, Textilhilfsmittel, Waschrohstofffe", Volume II 196 * 1, pages 1176 to 1478, and Ullmanne Encyclopadie der technischen Chemie, 3rd edition, Volume 17, 1966, pages 176-177.
Im übrigen ist es nicht unter allen Umständen notwendig, die nach den Patentanmeldungen P 1 963 01Ί.9 und P 2 043 520.5 · hergestellten Alkanphosphonsäurediester zunächst in die entsprechenden Säuren oder Alkalisalze zu überführen, um diese in der erfindungsgemäßen Weise zu verwenden. Es ist ebenso möglich, die Ester direkt den Laugier- und Mercerisierlöoungen zuzufügen, da die Ester alsbald in der alkalischen Flüssigkeit au den Salzen hydrolysiert werden.Moreover, it is not necessary in all circumstances, to transfer the Alkanphosphonsäurediester prepared according to the patent applications P 1963 and P 2043 01Ί.9 520.5 · first into the corresponding acids or alkali salts to use these in the inventive manner. It is also possible to add the esters directly to the caustic and mercerising solutions, since the esters are soon hydrolyzed from the salts in the alkaline liquid.
In den folgenden Beispielen soll anhand von Mercerisierlaugen der Vorteil der erfindungsgemäß zu verwendenden Phosphonsäurederivate näher erläutert werden, ohne daß die Anwendung auf diese Mercerisierlaugen beschränkt bleiben soll.The following examples are based on mercerising liquors the advantage of the phosphonic acid derivatives to be used according to the invention are explained in more detail without affecting the application this mercerising liquor should remain limited.
Da das Netzvermögen von stark alkalischen Flüssigkeiten nicht »it den üblichen Geräten nach DIN 53 901 gemessen werden kann,Since the wetting power of strongly alkaline liquids is not »It can be measured with the usual devices according to DIN 53 901,
309885/1184309885/1184
BAD ORIGINALBATH ORIGINAL
dient als Maß für das Netzverinögen einer Mercerisieflauge die Schrumpfung von Baumwolle in dieser Lauge. Für die Versuche wurde ein Prüfgerät für Mercerisierlaugen nach· Hintzrnann verwendet. Dieses Gerät ist eingehend beschrieben in "Melliand Textilberichte" (I968) Heft 3» Seiten 311 bis 315 und Heft i| Seiten 450 bis 456. Gearbeitet wurde bei 2O°C mit einer Füllmenge von 250 em^ bei 33 g Belastung. Für die Messungen dienten Baumwollstränge (70/2-fach) von 27,4 cm Länge. Jeweils bei einer Einwirkungsdauer der Lauge von 5, 10, 20, 30, 45, 60, 75 und 90 Sekunden wurde die eingetretene Schrumpfung gemessen. Aus den erhaltenen Schrumpfungswerten in mrn wurden die Schrumpfgeschwindigkeiten in mm/sec. berechnet. · 'serves as a measure of the network properties of a mercerized liquor Cotton shrinkage in this liquor. For the trials A tester for mercerizing liquors according to Hintzrnann was used. This device is described in detail in "Melliand Textile Reports" (1968) issue 3 »pages 311 to 315 and issue i | Pages 450 to 456. Work was carried out at 20 ° C with one filling quantity of 250 em ^ at 33 g load. Served for the measurements Cotton strands (70/2 ply) 27.4 cm long. One at a time Duration of exposure to the lye of 5, 10, 20, 30, 45, 60, 75 and The shrinkage that occurred was measured for 90 seconds. The shrinkage values in mrn became the shrinkage rates in mm / sec. calculated. · '
Alle geprüften Mercerisierlaugen enthielten 220 g Natriumhydroxid im Liter und dazu die nachfolgend aufgeführten Netzmittel und Hilfsstoffe. "All mercerising liquors tested contained 220 g sodium hydroxide per liter and the wetting agents and auxiliary substances listed below. "
Lauge Nr. 1: 2,5 g/l Dinatrium-n-octanphosphonatLye No. 1: 2.5 g / l disodium n-octane phosphonate
Lauge Nr. 2: 2,5 g/l Natrium-methyl-n-oc-tanphosphonatLye No. 2: 2.5 g / l sodium methyl-n-oc-tanphosphonate
Lauge Nr. 3:·. ■ 2,5 g/l CaraphanphosphonsäureLye # 3: ·. ■ 2.5 g / l caraphanephosphonic acid
Lauge Hr. 4: 2,5 g/l Natrium-äthyl-n-octanphosphonatLye Mr. 4: 2.5 g / l sodium ethyl n-octane phosphonate
Lauge Nr. 5: 1,5 g/l Dinatrium-n-octanphosphonatLye No. 5: 1.5 g / l disodium n-octane phosphonate
1,2 g/l Isobutyldiäthanolan5.n 0*05 g/l Triisobutylphosphat -1.2 g / l isobutyl diethanolane 5.n 0 * 05 g / l triisobutyl phosphate -
0,5 g/l n-Butanol ·0.5 g / l n-butanol
Lauge Nr. 6: 1,5 g/l Paraffinpolysulfonat (aus η-Paraffin mitLye No. 6: 1.5 g / l paraffin polysulfonate (from η-paraffin with
einer Kettenlänge von 14 bis 18 C-Atomen)a chain length of 14 to 18 carbon atoms)
1,2 g/l Isobutyldiäthanolamin1.2 g / l isobutyl diethanolamine
0,05 g/l Triisobutylphosphat0.05 g / l triisobutyl phosphate
0,5 g/l n-Bütanol Stand der Technik0.5 g / l n-butanol state of the art
Die MeßerEebnisse sind in der Tabeile I zusammengefaßt.The measurement results are summarized in Table I.
309885/11Ö4309885 / 11Ö4
BAD ORIGINALBATH ORIGINAL
Zeit sec.Time sec.
Schrumpfung mm Schrumpfgeschwindigkeit mrn/sec.Shrinkage mm shrinkage speed mrn / sec.
Lauge Lauge Lauge Lauge Lauge Lauge Lauge 1 1 2 3 4 5Lye Lye Lye Lye Lye Lye Lye 1 1 2 3 4 5
n.24h Lauge Lauge Lauge Lauge Lauge Lauge Laugen.24h lye lye lye lye lye lye
n.24hn.24h
co NJ
co
Die Tabellenwerte legen überzeugend den Vorteil der gemäß der Erfindung zu verwendenden Phosphhonsäurederivate dar. Anhand der Meßergebnisse mit der Lauge 3 ist das nach ?Λ Stunden noch unveränderte Netzvermögen der erfindungsgemäßen Mercerisierlaugen zu erkennen. Zur weiteren Erläuterung sind die Werte der Schrumpfung in Abhängigkeit von der Zeit bei Verwendung der Laugen Nr. 5 und 6 in der Figur I dargestellt.. Die Figur II zeigt die dazugehörenden V/erte der Schrumpf geschwindigkeit in Abhängigkeit von der Zeit.The table values set convincingly the advantage of according to the invention to be used Phosphhonsäurederivate. Based on the measurement results with the lye 3 is after? Λ hours still unchanged net assets of mercerizing invention to detect. For further explanation, the values of the shrinkage as a function of time when using alkaline solutions No. 5 and 6 are shown in FIG. I. FIG. II shows the associated values of the shrinkage rate as a function of time.
BAD ORIGINAL 'BATH ORIGINAL '
309885/1184309885/1184
Claims (3)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2231148A DE2231148A1 (en) | 1972-06-26 | 1972-06-26 | LAUGATING AND MERCERIZING SOLUTIONS |
| NL7308635A NL7308635A (en) | 1972-06-26 | 1973-06-21 | |
| US372391A US3890093A (en) | 1972-06-26 | 1973-06-21 | Mercerizing solutions |
| IT25761/73A IT989413B (en) | 1972-06-26 | 1973-06-22 | SOLUTION OF LISCIVIATION AND MERCERIZATION |
| BR4667/73A BR7304667D0 (en) | 1972-06-26 | 1973-06-25 | BLEACHING AND MERCERIZATION SOLUTIONS AND PROCESS FOR BLEACHING AND MERCERIZING CELLULOSE FIBER MATERIALS |
| JP48070883A JPS4948996A (en) | 1972-06-26 | 1973-06-25 | |
| BE132757A BE801479A (en) | 1972-06-26 | 1973-06-26 | Leaching and mercerization solutions for cellulosic fibers |
| GB3019073A GB1430118A (en) | 1972-06-26 | 1973-06-26 | Solutions for treating or mercerizing cellulosic fibrous material |
| FR7323243A FR2190971B1 (en) | 1972-06-26 | 1973-06-26 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2231148A DE2231148A1 (en) | 1972-06-26 | 1972-06-26 | LAUGATING AND MERCERIZING SOLUTIONS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2231148A1 true DE2231148A1 (en) | 1974-01-31 |
Family
ID=5848784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2231148A Pending DE2231148A1 (en) | 1972-06-26 | 1972-06-26 | LAUGATING AND MERCERIZING SOLUTIONS |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3890093A (en) |
| JP (1) | JPS4948996A (en) |
| BE (1) | BE801479A (en) |
| BR (1) | BR7304667D0 (en) |
| DE (1) | DE2231148A1 (en) |
| FR (1) | FR2190971B1 (en) |
| GB (1) | GB1430118A (en) |
| IT (1) | IT989413B (en) |
| NL (1) | NL7308635A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3346578A1 (en) * | 1983-12-23 | 1985-07-18 | Sandoz-Patent-GmbH, 7850 Lörrach | Composition and process for the single-bath single-stage alkaline pretreatment of cellulose-containing textile materials |
| DE4131951A1 (en) * | 1991-09-25 | 1993-04-08 | Boehme Chem Fab Kg | Use of alkane phosphonic acid and its salt or half ester - as thermostable stabiliser for high temp. treatment of substrates |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH671668B5 (en) * | 1981-08-22 | 1990-03-30 | Sandoz Ag | |
| US4494952A (en) * | 1982-09-08 | 1985-01-22 | Ciba-Geigy Corporation | Wetting agents and their use as mercerizing assistants |
| JP2010104568A (en) * | 2008-10-30 | 2010-05-13 | Taeko Sato | Scratcher |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US325654A (en) * | 1885-09-08 | Traction-chain gearing | ||
| US1980342A (en) * | 1930-08-06 | 1934-11-13 | Firm Chem Fab R Baumheier Ag | Sulphonated oils, fats or acids thereof and the process of manufacturing the same |
| US2236617A (en) * | 1938-12-20 | 1941-04-01 | Colgate Palmolive Peet Co | Treatment of textiles |
| US2403038A (en) * | 1944-12-14 | 1946-07-02 | Monsanto Chemicals | Surface-active agents |
| US2478390A (en) * | 1947-12-18 | 1949-08-09 | Du Pont | Polymerization of polymerizable mono-olefinic hydrocarbons in the presence of saturated aliphatic esters of inorganic oxy acids of phosphorus, sulfur, and silicon |
-
1972
- 1972-06-26 DE DE2231148A patent/DE2231148A1/en active Pending
-
1973
- 1973-06-21 US US372391A patent/US3890093A/en not_active Expired - Lifetime
- 1973-06-21 NL NL7308635A patent/NL7308635A/xx not_active Application Discontinuation
- 1973-06-22 IT IT25761/73A patent/IT989413B/en active
- 1973-06-25 BR BR4667/73A patent/BR7304667D0/en unknown
- 1973-06-25 JP JP48070883A patent/JPS4948996A/ja active Pending
- 1973-06-26 GB GB3019073A patent/GB1430118A/en not_active Expired
- 1973-06-26 FR FR7323243A patent/FR2190971B1/fr not_active Expired
- 1973-06-26 BE BE132757A patent/BE801479A/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3346578A1 (en) * | 1983-12-23 | 1985-07-18 | Sandoz-Patent-GmbH, 7850 Lörrach | Composition and process for the single-bath single-stage alkaline pretreatment of cellulose-containing textile materials |
| DE4131951A1 (en) * | 1991-09-25 | 1993-04-08 | Boehme Chem Fab Kg | Use of alkane phosphonic acid and its salt or half ester - as thermostable stabiliser for high temp. treatment of substrates |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4948996A (en) | 1974-05-11 |
| FR2190971A1 (en) | 1974-02-01 |
| US3890093A (en) | 1975-06-17 |
| BR7304667D0 (en) | 1974-09-05 |
| IT989413B (en) | 1975-05-20 |
| BE801479A (en) | 1973-12-26 |
| NL7308635A (en) | 1973-12-28 |
| FR2190971B1 (en) | 1976-11-12 |
| GB1430118A (en) | 1976-03-31 |
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